Sn42Bi58 low-temperature eutectic solder Sn42Bi58

Sn-42Bi-58: 42 % tin and 58 % bismuth by weight, each ±0.5 (eutectic alloy)

Also known as Sn42/Bi58

Sn42Bi58 is a lead-free eutectic solder of 42 % tin and 58 % bismuth by weight, each within ±0.5 (AIM datasheet).

8 sources · Updated 2026-11-01 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Melting point

138 °C

Tensile strength

8,000 psi or 9.71 ksi

Joint strength

6800 psi

Thermal conductivity

0.19 W/cm-°C

Recipe, share of the weight

  • Sn not statedTin
  • Bi not statedBismuth

Best for

Second-solder reflow on circuit boards and other low-temperature soldering, where the joint has to melt at 138 °C (AIM datasheet)

Weakest at

Thermal fatigue resistance, which AIM rates Poor against Excellent for SAC305, and a wetting rating of Fair

Risk at a glance

  • People None found. Hazard data limited
  • If it fails High. Thermal fatigue of solder joints
  • Corrosion No data. No corrosion data recorded

Quick facts: Sn42Bi58

Key properties of Sn42Bi58
PropertyValueBasis
Density8.72 g/cm³2 sourced values across conditions
Yield strength41.6 to 49.1 MPa2 sourced values across conditions
Tensile strength55.2 to 66.9 MPa3 sourced values across conditions
Young's modulus11.9 GPa1 sourced value
Thermal conductivity19 W/(m·K)1 sourced value
Thermal expansion (CTE)15 ppm/K1 sourced value
Melting point138 °C2 sourced values across conditions
Electrical resistivity1.7e-8 to 3.5e-7 Ω·m2 sourced values across conditions

What is the density of Sn42Bi58 low-temperature eutectic solder?

Sn42Bi58 low-temperature eutectic solder has a density of 8.72 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the thermal conductivity of Sn42Bi58 low-temperature eutectic solder?

Sn42Bi58 low-temperature eutectic solder has a thermal conductivity of 19 W/(m·K). The source and test conditions are listed in the properties table on this page.

What is the coefficient of thermal expansion of Sn42Bi58 low-temperature eutectic solder?

Sn42Bi58 low-temperature eutectic solder has a coefficient of thermal expansion of 15 ppm/K. The source and test conditions are listed in the properties table on this page.

What is the melting point of Sn42Bi58 low-temperature eutectic solder?

Sn42Bi58 low-temperature eutectic solder has a melting point of 138 °C. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the yield strength of Sn42Bi58 low-temperature eutectic solder?

Sn42Bi58 low-temperature eutectic solder has a yield strength of 41.6 to 49.1 MPa. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is Sn42Bi58 low-temperature eutectic solder used for?

Uses recorded in the sources include Second-solder reflow for circuit board assembly; Solder paste, solid and cored wire, foil, powder, bar, ingot and anode; Lead-free replacement in low-temperature solders.

Why it exists

Sn42Bi58 is a lead-free eutectic solder that melts at 138 °C, printed on both AIM sheets. The lower melting point is what makes it suited to second-solder reflow on circuit boards, the application AIM names first. Bismuth is the larger share of the alloy. The sources read here rate its thermal fatigue resistance Poor, which is the main trade against its low melting point.

Where it's used

Circuit board assembly

AIM says Sn42/Bi58 is typically used for second-solder reflow in circuit board assembly and for other low-temperature soldering requirements. The datasheet lists paste, solid and cored wire, foil, powder, bar, ingot and anode forms.

Lead-free low-temperature solders

USGS says bismuth is a nontoxic replacement for lead in solders. It also says cadmium, indium, lead and tin can partially replace bismuth in low-temperature solders.

Recipe

Sn-42Bi-58: 42 % tin and 58 % bismuth by weight, each ±0.5 (eutectic alloy)

Sn42Bi58 is a eutectic alloy of 42 % tin and 58 % bismuth by weight, each within ±0.5 (AIM datasheet). The datasheet also prints a table of maximum impurity levels, in percent, for twelve elements, set against the IPC standard it names.

What Sn42Bi58 is made of
IngredientShare of the weightWhat it does
Tin Sn not stated 42 % by weight, ±0.5 (AIM datasheet). The datasheet gives the composition only; no atomic weight is recorded here.
Bismuth Bi not stated 58 % by weight, ±0.5 (AIM datasheet). The datasheet gives the composition only; no atomic weight is recorded here. Bismuth is the larger share of this eutectic.

Weight shares are as printed in the sources.

What it can do

Melting point

138 °C

measured

The eutectic melting point is 138 °C (280 °F), per the AIM datasheet and the AIM information sheet.

Tensile strength

8,000 psi or 9.71 ksi

measured

The two AIM sheets disagree. The datasheet prints 8,000 psi and the information sheet prints 9.71 ksi for the same alloy, and neither gives a test method.

Joint strength

6800 psi

measured

The AIM information sheet prints 6800 psi, the highest joint strength value in its performance table. The substrate and test method are not stated.

Thermal conductivity

0.19 W/cm-°C

measured

The AIM datasheet prints 0.19 W/cm-°C at 85 °C.

How it compares

Sn42Bi58 melts lower than SAC305 and Sn63/Pb37 on the same AIM information sheet, which prints the melting point of each. Its joint strength of 6800 psi is the highest value in that sheet's performance table. Its thermal fatigue rating is Poor, the same as Sn63/Pb37 and below the Excellent rating for SAC305, and its wetting rating is Fair, below the Excellent rating given to both SAC305 and Sn63/Pb37. Its tensile strength is 9.71 ksi on the information sheet and 8,000 psi on the datasheet, and the two AIM sheets disagree. The sheet does not print a tensile value for SAC305, so no tensile comparison is made.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Compare every grade in the family.

Benchmarks
MeasurementSn42Bi58
Thermal behavior and safety
Eutectic melting point (AIM datasheet)138 °C1
Melting point (AIM alloy information sheet)138 °C2
Thermal conductivity (AIM datasheet)0.19 W/cm-°C7
Latent heat of fusion (AIM datasheet)44.8 J/g14
Melting range, solidus to liquidus, Sn-58 wt% Bi (Kang et al. 2021)130.2 to 139 ºC16
Physical and electrical
Density (AIM datasheet)8.72 g/cc3
Density (AIM alloy information sheet, as printed)0.309 lbs/in34
Electrical resistivity (AIM datasheet)1.72 µΩ-cm5
Electrical conductivity (AIM datasheet)4.5 % IACS6
Electrical resistivity (NIST Table 2.2.19)Range printed in the NIST table30 to 35 μΩ-cm22
Other measurements
Coefficient of thermal expansion (AIM datasheet)15 ppm/°C8
Tensile strength (AIM datasheet)8000 psi9
Tensile strength (AIM alloy information sheet)9.71 ksi10
0.2 % yield strength (AIM alloy information sheet)6.03 ksi11
Shear strength (AIM datasheet)500 psi12
Elongation (AIM datasheet)55 %13
Joint strength (AIM alloy information sheet)6800 psi15
Tensile strength (NIST Table 1.2, row A6 Sn-58Bi)8766 psi17
0.2 % offset yield strength (NIST Table 1.2, row A6 Sn-58Bi)7119 psi18
Elastic modulus (NIST Table 1.2, row A6 Sn-58Bi)1720 ksi19
Total elongation (NIST Table 1.2, row A6 Sn-58Bi)Value printed in the NIST table46 %20
Shear strength at room temperature (NIST Table 1.16, ring-and-plug)Value printed in the NIST table48 MPa21
Shear strength at 100 °C (NIST Table 1.16, ring-and-plug)Value printed in the NIST table15.6 MPa

Why choose it, and why not

Good for

  • Second-solder reflow on circuit boards. The alloy melts at 138 °C as printed (AIM datasheet).
  • Joint strength. AIM prints 6800 psi, the highest value in its joint strength table (AIM information sheet).

Watch out for

  • Thermal fatigue resistance is rated Poor by AIM, against Excellent for SAC305.
  • Wetting is rated Fair by AIM, against Excellent for SAC305 and Sn63/Pb37.
  • The two AIM sheets disagree on tensile strength (8,000 psi against 9.71 ksi), and neither gives a test method.

Sn42Bi58 is the low-melting choice in the AIM range. It gives up thermal fatigue resistance and wetting for a 138 °C melting point, and the printed joint strength is high. The sources read here do not cover its corrosion, space or service-temperature behaviour.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Other names and standards

The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.

Other names and standards
SystemCodes
Trade nameSn42/Bi58

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Eutectic melting point (AIM datasheet)Printed as the eutectic melting point in the Description and as a Features list itembasis eutectic composition, 42 % Sn and 58 % Bi as printed; the datasheet also prints 280 °F—
2Melting point (AIM alloy information sheet)Value printed in the AIM alloy information sheet, which agrees with the datasheetbasis Sn42/Bi58 row of the technical information table—
3Density (AIM datasheet)Value printed in the Properties table of the datasheettemperature not stated in the datasheet—
4Density (AIM alloy information sheet, as printed)Value printed in the Common and Specialty Solder Alloys table of the information sheetbasis Bi58 row of the bismuth section of the alloy table, printed in lbs/in.3 and not converted—
5Electrical resistivity (AIM datasheet)Value printed in parentheses in the Electrical Conductivity row of the Properties tabletemperature not stated in the datasheet—
6Electrical conductivity (AIM datasheet)Value printed in the Properties table of the datasheettemperature not stated in the datasheet—
7Thermal conductivity (AIM datasheet)Value printed in the Properties table of the datasheettemperature 85 °C, as printed in the row label—
8Coefficient of thermal expansion (AIM datasheet)Value printed in the Properties table of the datasheet, printed as PPM/° Ctemperature 20 °C, as printed in the row label—
9Tensile strength (AIM datasheet)Value printed in the Properties table of the datasheet, printed as 8,000 PSIform as printed in the datasheet; the form and test method are not statedThe AIM alloy information sheet prints 9.71 ksi for the same alloy (see the next row). Neither source states a test method, so the two values should not be compared directly.
10Tensile strength (AIM alloy information sheet)Value printed in the Technical Information table of the alloy information sheetform as printed in the information sheet; the form and test method are not statedThe AIM datasheet prints 8,000 psi (8.0 ksi) for the same alloy. The sources disagree and neither states a test method.
110.2 % yield strength (AIM alloy information sheet)Value printed in the Technical Information table of the alloy information sheetbasis 0.2 % yield strength, as printed in the column headerform as printed; test method not stated—
12Shear strength (AIM datasheet)Value printed in the Properties table of the datasheettest not stated in the datasheet—
13Elongation (AIM datasheet)Value printed in the Properties table of the datasheettest not stated in the datasheetThe AIM alloy information sheet prints a uniform elongation of 1.3 for this alloy without a unit, so it is not recorded. The two sheets give different elongation figures.
14Latent heat of fusion (AIM datasheet)Value printed in the Properties table of the datasheetbasis eutectic alloy as printed—
15Joint strength (AIM alloy information sheet)Value printed in the joint strength column of the alloy information sheet's performance tablebasis joint strength column of the alloy performance table; the substrate and test method are not stated—
16Melting range, solidus to liquidus, Sn-58 wt% Bi (Kang et al. 2021)Range printed in the review's Section 2.1 text, which refers to its Table 1basis Sn-58 wt% Bi, the same composition as Sn42/Bi58 (Bi at 58 %); the review cites earlier work for it and notes that the heating rate affects the value—
17Tensile strength (NIST Table 1.2, row A6 Sn-58Bi)Value printed in the NIST table, which also prints 60.4 MPa for the same rowform not stated in the NIST table; the table credits the NCMS 1998 tensile programmealloy A6 Sn-58Bi, Bi 58 % by massThe AIM datasheet prints 8,000 psi and the AIM information sheet prints 9.71 ksi for this alloy. The three values differ, no source prints a test method, so they are shown side by side and not reconciled.
180.2 % offset yield strength (NIST Table 1.2, row A6 Sn-58Bi)Value printed in the NIST table, which also prints 49.1 MPa for the same rowbasis 0.2 % offset, as printed in the column headingform not stated in the NIST tableThe AIM information sheet prints 6.03 ksi for the 0.2 % yield strength of this alloy. The two sources differ and neither prints a test method.
19Elastic modulus (NIST Table 1.2, row A6 Sn-58Bi)Value printed in the NIST table, which also prints 11.9 GPa for the same rowform not stated in the NIST table—
20Total elongation (NIST Table 1.2, row A6 Sn-58Bi)—basis total elongation as printed; the same row prints a uniform elongation of 3 %form not stated in the NIST tableThe AIM datasheet prints 55 % elongation for this alloy. The two figures differ and neither source prints a test method.
21Shear strength at room temperature (NIST Table 1.16, ring-and-plug)—test ring-and-plug shear test at 1 mm/mintemperature room temperature, as printed in the column headingThe AIM datasheet prints 500 psi shear strength with no test method, so the NIST and AIM values are not comparable.
22Electrical resistivity (NIST Table 2.2.19)—temperature not stated in the NIST tableThe AIM datasheet prints 1.72 µΩ-cm for this alloy. The NIST range is much higher, and the two are shown side by side and not reconciled.

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

The AIM datasheet asks for ventilation and protective equipment. The AIM safety data sheet read is for the NC 273LT solder paste, not the bare alloy, and classifies that paste as very toxic to aquatic life with long lasting effects (H410). The bare alloy's hazard classification is not established here.

The alloy
AIM says to use the alloy with adequate ventilation and proper personal protective equipment, and to follow the safety data sheet for emergencies.
Bismuth in PubChem
PubChem's bismuth record says 324 of 382 company reports did not meet GHS hazard criteria, and four notifications from 58 reports carry H370 and H372. The record is for bismuth, not this alloy.

If a joint fails

These are failure routes from the AIM ratings and the printed melting point. No field or space failure data were found.

Melting
The alloy melts at 138 °C as printed. No service temperature limit is printed in either AIM sheet.
Thermal fatigue
AIM rates thermal fatigue resistance Poor for this alloy, the same as Sn63/Pb37, against Excellent for SAC305.

Handling and storage

Shelf life
Water-soluble cored wire with this alloy has a shelf life of 3 years. Other cored wire, solid wire and bar have an indefinite shelf life, per AIM.
Flux
The alloy is compatible with most electronic grade fluxes. Cleaning follows the flux maker's data sheets.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Thermal fatigue of solder jointshigh severityThermal cycling. AIM does not state the temperature range used for its rating.AIM rates the thermal fatigue resistance of Sn42/Bi58 as Poor, the same as Sn63/Pb37 and against Excellent for SAC305, on the same table.
Low wetting in solderingmoderate severitySoldering with the alloy. AIM does not state the flux or test conditions behind the rating.AIM rates the wetting characteristics of Sn42/Bi58 as Fair, against Excellent for SAC305 and Sn63/Pb37 on the same table.
Low melting point limits the service temperaturemoderate severityOperating or reflow temperature at or above 138 °CThe alloy melts at 138 °C as printed. Neither datasheet gives a service temperature limit, so the usable temperature range is not stated in any source read.

Handling and storage

  • Use with adequate ventilation and proper personal protective equipment. Refer to the accompanying safety data sheet for emergency information. Do not dispose of hazardous materials in non-approved containers.
  • Shelf life is 3 years for water-soluble cored wire made with this alloy. Other cored wire, solid wire and bar have an indefinite shelf life.
  • The alloy is compatible with most electronic grade fluxes. Cleaning follows the flux manufacturer's data sheets.

Supply and geography

How common the raw materials are and where they come from.

Tin (mine production, world)

Top producers (2025)
China 24.5%, Indonesia 21%, Peru 11.4%, Brazil 9.7%, Congo (Kinshasa) 9.3%
Recycling
USGS: about 17,000 tons of tin from old and new scrap was estimated to have been recycled in 2025.
Substitutes
USGS: epoxy resins are listed as substitutes for tin in solder.

Bismuth (refinery production, world)

Top producers (2025)
China 88%
Recycling
USGS: recycled bismuth-containing alloy scrap made up to 10% of U.S. bismuth apparent consumption for 2021 to 2025.
Substitutes
USGS: cadmium, indium, lead and tin can partially replace bismuth in low-temperature solders.

Updated