Samarium(III) oxide Sm2O3

Sm2O3 · CAS 12060-58-1 · cubic

Samarium(III) oxide (Sm2O3, CAS 12060-58-1) is a solid with a cubic crystal structure and a molecular weight of 348.7 g/mol per PubChem.

8 sources · Updated 2026-11-01 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Neutron absorber

Reactor control rods (supplier listing)

Optical glass

Optical and infrared-absorbing glasses (supplier listing)

Melting point

2325 °C (SDS) and 2335 °C (Nanografi)

Recipe, share of the weight

  • Sm not statedSamarium
  • O not statedOxygen

Best for

Dense rare-earth oxide for optical and infrared-absorbing glass and for neutron-absorber uses, as listed by suppliers

Weakest at

No space or radiation test data for Sm2O3, and melting-point and density values that differ between suppliers and PubChem

Risk at a glance

  • People Low. Hazard data conflict: PubChem and the SDS differ
  • If it fails Moderate. Moisture pick-up by the hygroscopic powder
  • Corrosion Moderate. Sm2O3 is air sensitive and hygroscopic according to the Thermo Fisher SDS.

Quick facts: Sm2O3

Key properties of Sm2O3
PropertyValueBasis
Density8.35 to 8.43 g/cm³2 sourced values across conditions
Young's modulus191 GPa1 sourced value
Melting point2,325 to 2,335 °C2 sourced values across conditions

What is the density of Samarium(III) oxide (Sm2O3)?

Samarium(III) oxide (Sm2O3) has a density of 8.35 to 8.43 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the melting point of Samarium(III) oxide (Sm2O3)?

Samarium(III) oxide (Sm2O3) has a melting point of 2,325 to 2,335 °C. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the Young's modulus of Samarium(III) oxide (Sm2O3)?

Samarium(III) oxide (Sm2O3) has a Young's modulus of 191 GPa. The source and test conditions are listed in the properties table on this page.

What is Samarium(III) oxide (Sm2O3) used for?

Uses recorded in the sources include Neutron absorber in control rods for nuclear power reactors (supplier listing); Optical and infrared-absorbing glasses (supplier listing); High-k gate dielectric in MOS devices (research).

Why it exists

Samarium(III) oxide is a dense, high-melting rare-earth oxide. Suppliers list it for neutron absorbers in reactor control rods and for optical and infrared-absorbing glasses. Samarium is also on the USGS 2025 critical mineral list, so its supply is closely watched.

Where it's used

Neutron absorbers in reactor control rods (supplier listing)

Nanografi lists neutron absorber in control rods for nuclear power reactors among the important application areas of its Sm2O3 powder. No test result for this use was read.

Optical and infrared-absorbing glasses

Nanografi lists optical and infrared-absorbing glasses as a further application area of the same powder.

High-k dielectric research in MOS devices

The 2019 modelling paper says the most promising electronic device applications for Sm2O3 are MOS and ReRAM devices, and quotes a dielectric constant of up to 15 for amorphous films.

Recipe

Sm2O3

Sm2O3 is samarium(III) oxide. Each formula unit combines two samarium atoms with three oxygen atoms, and PubChem gives the formula as O3Sm2 with a molecular weight of 348.7 g/mol.

What Sm2O3 is made of
IngredientShare of the weightWhat it does
Samarium Sm not stated The metal centre, held in the +3 state in Sm2O3.
Oxygen O not stated Oxygen anions around each samarium. The 2019 modelling paper describes each Sm as six-coordinated in a distorted octahedron in the cubic crystal.

Weight shares are as printed in the sources.

What it can do

Neutron absorber

Reactor control rods (supplier listing)

Nanografi lists neutron absorber in control rods for nuclear power reactors as an application of its Sm2O3 powder. No test result for this use was read.

Optical glass

Optical and infrared-absorbing glasses (supplier listing)

Nanografi lists optical and infrared-absorbing glasses as a further application of the same powder.

Melting point

2325 °C (SDS) and 2335 °C (Nanografi)

The Thermo Fisher SDS prints a melting point of 2325 °C, and the Nanografi page prints 2335 °C for the same oxide.

How it compares

Sm2O3 is a dense, high-melting oxide with a cubic crystal structure. PubChem gives 8.347 g/cm3 at 25 °C for its density, while the Nanografi page gives 8.43 g/cm3. Its melting point is printed as 2325 °C in the SDS and 2335 °C on the Nanografi page, and the modelling paper gives a calculated bulk modulus of 137.26 GPa for the cubic crystal. Its main space-relevant case is as a dielectric and optical material in research, with no flight record found.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.

Benchmarks
MeasurementSm2O3Al2O3BaTiO3BeOCaTiO3RCFCeO2CoO and Co3O4CuO, Cu2OHfO2Fe2O3, Fe3O4LSMPZTMgONiONb2O5Al2Si4O10(OH)2Ln2O3SiOMgO-SiO2SnO2, ITOTiO2WO3V2O5Y2O3ZnOMg-PSZ, ATZ, ZTAYSZ
Thermal behavior and safety
melting point2325 °C32030 to 2072 °C1625 °C2578 °C1975 °C1760 °C2600 °C1830 °C1326 °C2774 °Cno data> 1650 °Cno data2800 °C1984 °C1500 °Cno data2304 °C1702 °Cno data1630 °C1850 °C1472 °C690 °C2410 °C1975 °Cno datano data
melting pointValue printed on a supplier product page2335 °C42030 to 2072 °C1625 °C2578 °C1975 °C1760 °C2600 °C1830 °C1326 °C2774 °Cno data> 1650 °Cno data2800 °C1984 °C1500 °Cno data2304 °C1702 °Cno data1630 °C1850 °C1472 °C690 °C2410 °C1975 °Cno datano data
Physical and electrical
Density8.347 g/cm³13.72 g/cm³6.08 -3.01 g/cu cm4.1 g/cc64 kg/m37.65 g/cm³6.45 g/cm³6 -9.68 g/cc5.24 g/cm³2 g/cm³7.8 g/cm³3.58 g/cm³6.67 g/cm³4.6 g/cm³2.3 g/cc6.51 g/cm³2.13 g/cc2.8 g/cm³6.95 g/mL4 g/cm³7.2 g/cm³3.4 -> 4.9 g/cm³5.67 g/cm³5.72 g/cm³6.02 g/cm³
Density8.43 g/cm³23.72 g/cm³6.08 -3.01 g/cu cm4.1 g/cc64 kg/m37.65 g/cm³6.45 g/cm³6 -9.68 g/cc5.24 g/cm³2 g/cm³7.8 g/cm³3.58 g/cm³6.67 g/cm³4.6 g/cm³2.3 g/cc6.51 g/cm³2.13 g/cc2.8 g/cm³6.95 g/mL4 g/cm³7.2 g/cm³3.4 -> 4.9 g/cm³5.67 g/cm³5.72 g/cm³6.02 g/cm³
Other measurements
boiling point4118 °C5no datano datano datano datano datano datano datano data5400 °Cno datano datano data3600 °Cno datano datano datano data1880 °Cno datano datano data1837 °Cno datano datano datano datano data
molecular weight348.7 g/mol6no datano datano datano datano data172.1 g/molno datano datano datano datano datano datano datano data265.8 g/molno datano datano datano datano datano datano data181.9 g/molno datano datano datano data
Lattice parameter a, cubic Sm2O3 (conference abstract)10.94 Å7no datano datano datano datano datano datano datano datano datano datano datano data4.212 Åno datano datano datano datano datano datano datano datano datano datano datano datano datano data
Measured band gap, cubic Sm2O3 crystal4.9 eV8no datano data10.6 eVno datano datano datano data2.17 eV5.65 eVno data4.11 eVno datano data3.6 to 4 eVno datano datano datano datano data3.6 eV3.23 eVno datano datano data3.37 eVno datano data
Dielectric constant of amorphous Sm2O3 films, upper value quoted< 15 -99.7 -3000 -no data146 -no datano datano datano data22 to 25 -no datano data1800 -9.65 -no datano data2 to 4 -no datano data6 -no datano datano datano datano data8.75 -28 -29 -
Bulk modulus, cubic Sm2O3, experimental range quoted130 to 149 GPa10no datano datano data181 GPano datano datano datano datano datano datano datano data155 GPano datano datano datano datano datano datano datano datano datano datano datano datano datano data
Bulk modulus, cubic Sm2O3, calculatedCalculated value from the modelling paper137.3 GPano datano datano data181 GPano datano datano datano datano datano datano datano data155 GPano datano datano datano datano datano datano datano datano datano datano datano datano datano data
Young's modulus, cubic Sm2O3, calculatedCalculated value from the modelling paper191.1 GPa370 GPano datano datano datano datano datano datano datano data120 to 180 kN/mm2no datano data249 GPano datano datano datano datano data120 GPano datano datano datano data160 GPano data200 GPa210 GPa
Acute oral LD50, Sm2O3, rat> 5 g/kg11no datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano data

Why choose it, and why not

Good for

  • Optical and infrared-absorbing glass, as supplier listings describe.
  • Research on high-k dielectrics, where the 2019 modelling paper quotes a dielectric constant of up to 15 for amorphous films.

Watch out for

  • Two supplier melting points (2325 °C and 2335 °C) and two densities (8.347 and 8.43 g/cm3) differ, so check the source that matches the grade and form you need.
  • PubChem's aquatic toxicity warnings and the SDS's not-hazardous classification disagree.
  • No space or radiation test on Sm2O3 was found, so treat the neutron-absorber and glass uses as supplier claims.

Sm2O3 is a dense, high-melting rare-earth oxide with useful supplier-listed uses in neutron absorbers and optical glasses, and a research record as a high-k dielectric. For space work it is unproven: no flight or radiation test was found, and the melting point and density values differ between sources.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1DensityDatabase value, read from the PubChem record for CID 159425temperature 25 °Cform Sm2O3 powder—
2DensityValue printed on a supplier product page (not a test method stated)form Sm2O3 powder (micron powder product, 325 mesh, supplier listing)Supplier value. It differs from the PubChem value of 8.347 g/cm3 and from the 8.347 printed in the Thermo Fisher SDS.
3melting pointValue printed in a supplier safety data sheet, Section 9purity 99.9 weight percent Sm2O3 (Thermo Fisher Cat. No. 36278)The PubChem record gives no melting point for Sm2O3, so this value comes from the supplier SDS.
4melting point—form nanopowder and powder listings on the supplier pageSupplier value. It is 10 °C above the 2325 °C printed in the Thermo Fisher SDS.
5boiling pointValue printed on a supplier product page, in the same sentence as the 2335 °C melting pointform samarium oxide nanopowder listingSupplier value for a nanopowder listing, not a PubChem or SDS value.
6molecular weightComputed property read from the PubChem record for CID 159425basis computed by PubChem from the molecular formula—
7Lattice parameter a, cubic Sm2O3 (conference abstract)X-ray diffraction, as reported in the abstract of a 2025 conference contributioncrystal system cubictemperature sample calcined at 500 and 700 °C (the abstract does not say which calcination temperature gives this lattice parameter)From a conference abstract, not a peer-reviewed paper.
8Measured band gap, cubic Sm2O3 crystalMeasured value quoted in Section 3.1.3 of the modelling papercrystal system cubicbasis value quoted by the 2019 paper from earlier measurements (its references 41 and 42)Quoted value, not measured by the authors of the 2019 paper. The paper gives 4.7 eV for monoclinic and 5.1 eV for hexagonal Sm2O3 for comparison.
9Dielectric constant of amorphous Sm2O3 films, upper value quotedLiterature value quoted in the Introduction of the modelling paperphase amorphous filmsbasis value quoted by the paper from three earlier film studies (its references 27 to 29)A quoted upper value for thin amorphous films. Film thickness and deposition method are not given in the text read.
10Bulk modulus, cubic Sm2O3, experimental range quotedExperimental values quoted in Table 3 of the modelling papercrystal system cubicbasis experimental range quoted by the paper from its references 40, 35 and 90—
11Acute oral LD50, Sm2O3, ratValue printed in a supplier safety data sheet, Section 11 (component information)species ratroute oralThe SDS prints the value as greater than 5 g/kg, so 5 is a lower bound. No dermal or inhalation figure is listed.

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Moist air and water (storage and handling) moderate Sm2O3 is air sensitive and hygroscopic according to the Thermo Fisher SDS.1
Acids moderate Sm2O3 is described as soluble in acids and is listed as incompatible with acids.2
Corrosion details
#EnvironmentDetailsTest conditions
1 Moist air and water (storage and handling) The SDS lists exposure to moist air or water as a condition to avoid and says to keep the powder dry in a tightly closed container. It gives no mass-gain figure, so the rate of moisture uptake is not known from this source. form powderexposure not quantified
2 Acids The PubChem record quotes Hawley for insoluble in water and soluble in acids, and the SDS lists acids as incompatible. Neither source gives a dissolution rate or temperature, so the rating is qualitative. basis qualitative solubility statementexposure not tested in the sources read

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

PubChem's GHS record lists aquatic toxicity warnings, while the Thermo Fisher SDS calls the product not hazardous under OSHA.

Aquatic
PubChem's GHS record gives the signal word Warning with H400 and H410 in 44.6 percent of company reports each.
SDS
The Thermo Fisher SDS prints an oral LD50 greater than 5 g/kg in rat and no GHS label elements.
Dust
Avoid breathing dust and use exhaust ventilation, as the SDS directs.

Moisture and acids

The SDS calls the powder air sensitive and hygroscopic, and lists acids as incompatible.

Storage
Keep the container tightly closed in a dry, cool, well-ventilated place.
Acids
PubChem describes the oxide as soluble in acids, so acid contact removes material.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Moisture pick-up by the hygroscopic powdermoderate severityStorage or handling in moist air or contact with waterThe SDS calls the powder air sensitive and hygroscopic and asks for dry, tightly closed storage. The SDS gives no mass-gain figure, so the effect on composition is not quantified.
Reaction with acidsmoderate severityContact with acids, which the SDS lists as incompatibleSm2O3 is a basic oxide that PubChem describes as soluble in acids, so oxide is lost from a part or powder exposed to acid. No rate or temperature is printed.

Handling and storage

  • Avoid contact with skin and eyes and do not breathe dust. Handle the product only in a closed system or with appropriate exhaust ventilation.
  • Keep in a dry, cool, well-ventilated place in a tightly closed container. Keep away from acids, strong oxidizing agents and carbon dioxide.

Mitigations

  • Wear chemical safety goggles or eyeglasses and gloves as the SDS directs, and use a particle filter where dust may be breathed.

Supply and geography

How common the raw materials are and where they come from.

Samarium and rare earths (USGS 2025 mine production, rare-earth oxide equivalent, all rare earths, not samarium alone)

Not read in a source opened for this profile.

Top producers (2025)
China 69.2%, United States 13.1%, Australia 7.4%, Burma 5.6%
Critical mineral lists
US: listed
Recycling
USGS: limited quantities of rare earths were recovered from batteries, permanent magnets and fluorescent lamps. The chapter does not single out samarium oxide.
Substitutes
USGS: substitutes are available for many applications but generally are less effective.

Updated