Samarium(III) oxide Sm2O3
Sm2O3 · CAS 12060-58-1 · cubic
Samarium(III) oxide (Sm2O3, CAS 12060-58-1) is a solid with a cubic crystal structure and a molecular weight of 348.7 g/mol per PubChem.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Neutron absorber
Reactor control rods (supplier listing)
Optical glass
Optical and infrared-absorbing glasses (supplier listing)
Melting point
2325 °C (SDS) and 2335 °C (Nanografi)
Recipe, share of the weight
- Sm not statedSamarium
- O not statedOxygen
Best for
Dense rare-earth oxide for optical and infrared-absorbing glass and for neutron-absorber uses, as listed by suppliers
Weakest at
No space or radiation test data for Sm2O3, and melting-point and density values that differ between suppliers and PubChem
Risk at a glance
- People Low. Hazard data conflict: PubChem and the SDS differ
- If it fails Moderate. Moisture pick-up by the hygroscopic powder
- Corrosion Moderate. Sm2O3 is air sensitive and hygroscopic according to the Thermo Fisher SDS.
Quick facts: Sm2O3
| Property | Value | Basis |
|---|---|---|
| Density | 8.35 to 8.43 g/cm³ | 2 sourced values across conditions |
| Young's modulus | 191 GPa | 1 sourced value |
| Melting point | 2,325 to 2,335 °C | 2 sourced values across conditions |
What is the density of Samarium(III) oxide (Sm2O3)?
Samarium(III) oxide (Sm2O3) has a density of 8.35 to 8.43 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the melting point of Samarium(III) oxide (Sm2O3)?
Samarium(III) oxide (Sm2O3) has a melting point of 2,325 to 2,335 °C. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the Young's modulus of Samarium(III) oxide (Sm2O3)?
Samarium(III) oxide (Sm2O3) has a Young's modulus of 191 GPa. The source and test conditions are listed in the properties table on this page.
What is Samarium(III) oxide (Sm2O3) used for?
Uses recorded in the sources include Neutron absorber in control rods for nuclear power reactors (supplier listing); Optical and infrared-absorbing glasses (supplier listing); High-k gate dielectric in MOS devices (research).
Why it exists
Samarium(III) oxide is a dense, high-melting rare-earth oxide. Suppliers list it for neutron absorbers in reactor control rods and for optical and infrared-absorbing glasses. Samarium is also on the USGS 2025 critical mineral list, so its supply is closely watched.
Where it's used
Neutron absorbers in reactor control rods (supplier listing)
Nanografi lists neutron absorber in control rods for nuclear power reactors among the important application areas of its Sm2O3 powder. No test result for this use was read.
Optical and infrared-absorbing glasses
Nanografi lists optical and infrared-absorbing glasses as a further application area of the same powder.
High-k dielectric research in MOS devices
The 2019 modelling paper says the most promising electronic device applications for Sm2O3 are MOS and ReRAM devices, and quotes a dielectric constant of up to 15 for amorphous films.
Recipe
Sm2O3
Sm2O3 is samarium(III) oxide. Each formula unit combines two samarium atoms with three oxygen atoms, and PubChem gives the formula as O3Sm2 with a molecular weight of 348.7 g/mol.
| Ingredient | Share of the weight | What it does |
|---|---|---|
| Samarium Sm | not stated | The metal centre, held in the +3 state in Sm2O3. |
| Oxygen O | not stated | Oxygen anions around each samarium. The 2019 modelling paper describes each Sm as six-coordinated in a distorted octahedron in the cubic crystal. |
Weight shares are as printed in the sources.
What it can do
Neutron absorber
Reactor control rods (supplier listing)
Nanografi lists neutron absorber in control rods for nuclear power reactors as an application of its Sm2O3 powder. No test result for this use was read.
Optical glass
Optical and infrared-absorbing glasses (supplier listing)
Nanografi lists optical and infrared-absorbing glasses as a further application of the same powder.
Melting point
2325 °C (SDS) and 2335 °C (Nanografi)
The Thermo Fisher SDS prints a melting point of 2325 °C, and the Nanografi page prints 2335 °C for the same oxide.
How it compares
Sm2O3 is a dense, high-melting oxide with a cubic crystal structure. PubChem gives 8.347 g/cm3 at 25 °C for its density, while the Nanografi page gives 8.43 g/cm3. Its melting point is printed as 2325 °C in the SDS and 2335 °C on the Nanografi page, and the modelling paper gives a calculated bulk modulus of 137.26 GPa for the cubic crystal. Its main space-relevant case is as a dielectric and optical material in research, with no flight record found.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.
| Measurement | Sm2O3 | Al2O3 | BaTiO3 | BeO | CaTiO3 | RCF | CeO2 | CoO and Co3O4 | CuO, Cu2O | HfO2 | Fe2O3, Fe3O4 | LSM | PZT | MgO | NiO | Nb2O5 | Al2Si4O10(OH)2 | Ln2O3 | SiO | MgO-SiO2 | SnO2, ITO | TiO2 | WO3 | V2O5 | Y2O3 | ZnO | Mg-PSZ, ATZ, ZTA | YSZ |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Thermal behavior and safety | ||||||||||||||||||||||||||||
| melting point | 2325 °C3 | 2030 to 2072 °C | 1625 °C | 2578 °C | 1975 °C | 1760 °C | 2600 °C | 1830 °C | 1326 °C | 2774 °C | no data | > 1650 °C | no data | 2800 °C | 1984 °C | 1500 °C | no data | 2304 °C | 1702 °C | no data | 1630 °C | 1850 °C | 1472 °C | 690 °C | 2410 °C | 1975 °C | no data | no data |
| melting pointValue printed on a supplier product page | 2335 °C4 | 2030 to 2072 °C | 1625 °C | 2578 °C | 1975 °C | 1760 °C | 2600 °C | 1830 °C | 1326 °C | 2774 °C | no data | > 1650 °C | no data | 2800 °C | 1984 °C | 1500 °C | no data | 2304 °C | 1702 °C | no data | 1630 °C | 1850 °C | 1472 °C | 690 °C | 2410 °C | 1975 °C | no data | no data |
| Physical and electrical | ||||||||||||||||||||||||||||
| Density | 8.347 g/cm³1 | 3.72 g/cm³ | 6.08 - | 3.01 g/cu cm | 4.1 g/cc | 64 kg/m3 | 7.65 g/cm³ | 6.45 g/cm³ | 6 - | 9.68 g/cc | 5.24 g/cm³ | 2 g/cm³ | 7.8 g/cm³ | 3.58 g/cm³ | 6.67 g/cm³ | 4.6 g/cm³ | 2.3 g/cc | 6.51 g/cm³ | 2.13 g/cc | 2.8 g/cm³ | 6.95 g/mL | 4 g/cm³ | 7.2 g/cm³ | 3.4 - | > 4.9 g/cm³ | 5.67 g/cm³ | 5.72 g/cm³ | 6.02 g/cm³ |
| Density | 8.43 g/cm³2 | 3.72 g/cm³ | 6.08 - | 3.01 g/cu cm | 4.1 g/cc | 64 kg/m3 | 7.65 g/cm³ | 6.45 g/cm³ | 6 - | 9.68 g/cc | 5.24 g/cm³ | 2 g/cm³ | 7.8 g/cm³ | 3.58 g/cm³ | 6.67 g/cm³ | 4.6 g/cm³ | 2.3 g/cc | 6.51 g/cm³ | 2.13 g/cc | 2.8 g/cm³ | 6.95 g/mL | 4 g/cm³ | 7.2 g/cm³ | 3.4 - | > 4.9 g/cm³ | 5.67 g/cm³ | 5.72 g/cm³ | 6.02 g/cm³ |
| Other measurements | ||||||||||||||||||||||||||||
| boiling point | 4118 °C5 | no data | no data | no data | no data | no data | no data | no data | no data | 5400 °C | no data | no data | no data | 3600 °C | no data | no data | no data | no data | 1880 °C | no data | no data | no data | 1837 °C | no data | no data | no data | no data | no data |
| molecular weight | 348.7 g/mol6 | no data | no data | no data | no data | no data | 172.1 g/mol | no data | no data | no data | no data | no data | no data | no data | no data | 265.8 g/mol | no data | no data | no data | no data | no data | no data | no data | 181.9 g/mol | no data | no data | no data | no data |
| Lattice parameter a, cubic Sm2O3 (conference abstract) | 10.94 Å7 | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | 4.212 Å | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
| Measured band gap, cubic Sm2O3 crystal | 4.9 eV8 | no data | no data | 10.6 eV | no data | no data | no data | no data | 2.17 eV | 5.65 eV | no data | 4.11 eV | no data | no data | 3.6 to 4 eV | no data | no data | no data | no data | no data | 3.6 eV | 3.23 eV | no data | no data | no data | 3.37 eV | no data | no data |
| Dielectric constant of amorphous Sm2O3 films, upper value quoted | < 15 -9 | 9.7 - | 3000 - | no data | 146 - | no data | no data | no data | no data | 22 to 25 - | no data | no data | 1800 - | 9.65 - | no data | no data | 2 to 4 - | no data | no data | 6 - | no data | no data | no data | no data | no data | 8.75 - | 28 - | 29 - |
| Bulk modulus, cubic Sm2O3, experimental range quoted | 130 to 149 GPa10 | no data | no data | no data | 181 GPa | no data | no data | no data | no data | no data | no data | no data | no data | 155 GPa | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
| Bulk modulus, cubic Sm2O3, calculatedCalculated value from the modelling paper | 137.3 GPa | no data | no data | no data | 181 GPa | no data | no data | no data | no data | no data | no data | no data | no data | 155 GPa | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
| Young's modulus, cubic Sm2O3, calculatedCalculated value from the modelling paper | 191.1 GPa | 370 GPa | no data | no data | no data | no data | no data | no data | no data | no data | 120 to 180 kN/mm2 | no data | no data | 249 GPa | no data | no data | no data | no data | no data | 120 GPa | no data | no data | no data | no data | 160 GPa | no data | 200 GPa | 210 GPa |
| Acute oral LD50, Sm2O3, rat | > 5 g/kg11 | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
Why choose it, and why not
Good for
- Optical and infrared-absorbing glass, as supplier listings describe.
- Research on high-k dielectrics, where the 2019 modelling paper quotes a dielectric constant of up to 15 for amorphous films.
Watch out for
- Two supplier melting points (2325 °C and 2335 °C) and two densities (8.347 and 8.43 g/cm3) differ, so check the source that matches the grade and form you need.
- PubChem's aquatic toxicity warnings and the SDS's not-hazardous classification disagree.
- No space or radiation test on Sm2O3 was found, so treat the neutron-absorber and glass uses as supplier claims.
Sm2O3 is a dense, high-melting rare-earth oxide with useful supplier-listed uses in neutron absorbers and optical glasses, and a research record as a high-k dielectric. For space work it is unproven: no flight or radiation test was found, and the melting point and density values differ between sources.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Density | Database value, read from the PubChem record for CID 159425 | temperature 25 °Cform Sm2O3 powder | — |
| 2 | Density | Value printed on a supplier product page (not a test method stated) | form Sm2O3 powder (micron powder product, 325 mesh, supplier listing) | Supplier value. It differs from the PubChem value of 8.347 g/cm3 and from the 8.347 printed in the Thermo Fisher SDS. |
| 3 | melting point | Value printed in a supplier safety data sheet, Section 9 | purity 99.9 weight percent Sm2O3 (Thermo Fisher Cat. No. 36278) | The PubChem record gives no melting point for Sm2O3, so this value comes from the supplier SDS. |
| 4 | melting point | — | form nanopowder and powder listings on the supplier page | Supplier value. It is 10 °C above the 2325 °C printed in the Thermo Fisher SDS. |
| 5 | boiling point | Value printed on a supplier product page, in the same sentence as the 2335 °C melting point | form samarium oxide nanopowder listing | Supplier value for a nanopowder listing, not a PubChem or SDS value. |
| 6 | molecular weight | Computed property read from the PubChem record for CID 159425 | basis computed by PubChem from the molecular formula | — |
| 7 | Lattice parameter a, cubic Sm2O3 (conference abstract) | X-ray diffraction, as reported in the abstract of a 2025 conference contribution | crystal system cubictemperature sample calcined at 500 and 700 °C (the abstract does not say which calcination temperature gives this lattice parameter) | From a conference abstract, not a peer-reviewed paper. |
| 8 | Measured band gap, cubic Sm2O3 crystal | Measured value quoted in Section 3.1.3 of the modelling paper | crystal system cubicbasis value quoted by the 2019 paper from earlier measurements (its references 41 and 42) | Quoted value, not measured by the authors of the 2019 paper. The paper gives 4.7 eV for monoclinic and 5.1 eV for hexagonal Sm2O3 for comparison. |
| 9 | Dielectric constant of amorphous Sm2O3 films, upper value quoted | Literature value quoted in the Introduction of the modelling paper | phase amorphous filmsbasis value quoted by the paper from three earlier film studies (its references 27 to 29) | A quoted upper value for thin amorphous films. Film thickness and deposition method are not given in the text read. |
| 10 | Bulk modulus, cubic Sm2O3, experimental range quoted | Experimental values quoted in Table 3 of the modelling paper | crystal system cubicbasis experimental range quoted by the paper from its references 40, 35 and 90 | — |
| 11 | Acute oral LD50, Sm2O3, rat | Value printed in a supplier safety data sheet, Section 11 (component information) | species ratroute oral | The SDS prints the value as greater than 5 g/kg, so 5 is a lower bound. No dermal or inhalation figure is listed. |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Moist air and water (storage and handling) | moderate | Sm2O3 is air sensitive and hygroscopic according to the Thermo Fisher SDS.1 |
| Acids | moderate | Sm2O3 is described as soluble in acids and is listed as incompatible with acids.2 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Moist air and water (storage and handling) | The SDS lists exposure to moist air or water as a condition to avoid and says to keep the powder dry in a tightly closed container. It gives no mass-gain figure, so the rate of moisture uptake is not known from this source. | form powderexposure not quantified |
| 2 | Acids | The PubChem record quotes Hawley for insoluble in water and soluble in acids, and the SDS lists acids as incompatible. Neither source gives a dissolution rate or temperature, so the rating is qualitative. | basis qualitative solubility statementexposure not tested in the sources read |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
PubChem's GHS record lists aquatic toxicity warnings, while the Thermo Fisher SDS calls the product not hazardous under OSHA.
- Aquatic
- PubChem's GHS record gives the signal word Warning with H400 and H410 in 44.6 percent of company reports each.
- SDS
- The Thermo Fisher SDS prints an oral LD50 greater than 5 g/kg in rat and no GHS label elements.
- Dust
- Avoid breathing dust and use exhaust ventilation, as the SDS directs.
Moisture and acids
The SDS calls the powder air sensitive and hygroscopic, and lists acids as incompatible.
- Storage
- Keep the container tightly closed in a dry, cool, well-ventilated place.
- Acids
- PubChem describes the oxide as soluble in acids, so acid contact removes material.
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Moisture pick-up by the hygroscopic powdermoderate severity | Storage or handling in moist air or contact with waterThe SDS calls the powder air sensitive and hygroscopic and asks for dry, tightly closed storage. The SDS gives no mass-gain figure, so the effect on composition is not quantified. |
| Reaction with acidsmoderate severity | Contact with acids, which the SDS lists as incompatibleSm2O3 is a basic oxide that PubChem describes as soluble in acids, so oxide is lost from a part or powder exposed to acid. No rate or temperature is printed. |
Handling and storage
- Avoid contact with skin and eyes and do not breathe dust. Handle the product only in a closed system or with appropriate exhaust ventilation.
- Keep in a dry, cool, well-ventilated place in a tightly closed container. Keep away from acids, strong oxidizing agents and carbon dioxide.
Mitigations
- Wear chemical safety goggles or eyeglasses and gloves as the SDS directs, and use a particle filter where dust may be breathed.
Supply and geography
How common the raw materials are and where they come from.
Samarium and rare earths (USGS 2025 mine production, rare-earth oxide equivalent, all rare earths, not samarium alone)
Not read in a source opened for this profile.
- Top producers (2025)
- China 69.2%, United States 13.1%, Australia 7.4%, Burma 5.6%
- Critical mineral lists
- US: listed
- Recycling
- USGS: limited quantities of rare earths were recovered from batteries, permanent magnets and fluorescent lamps. The chapter does not single out samarium oxide.
- Substitutes
- USGS: substitutes are available for many applications but generally are less effective.
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
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spore: profile
id: samarium-oxide
spore_version: 0.2
family: oxide-ceramics
name: Samarium(III) oxide
abbreviation: Sm2O3
role: neutron-absorber and optical-glass oxide, and a high-k dielectric studied for MOS devices
category: ceramics
type: oxides
summary: |
Samarium(III) oxide (Sm2O3, CAS 12060-58-1) is a solid with a cubic crystal structure and a molecular weight of 348.7 g/mol per PubChem. PubChem gives a density of 8.347 g/cm3 at 25 °C. A Nanografi product page gives 8.43 g/cm3, and the melting point is printed as 2325 °C in a Thermo Fisher safety data sheet and as 2335 °C on the Nanografi page. Suppliers list the oxide for neutron absorbers in reactor control rods and for optical and infrared-absorbing glasses. An open-access 2019 modelling paper quotes a dielectric constant of up to 15 for amorphous films. No space flight, vacuum or radiation test on Sm2O3 was found in the sources read.
best_for: Dense rare-earth oxide for optical and infrared-absorbing glass and for neutron-absorber uses, as listed by suppliers
weakest_at: No space or radiation test data for Sm2O3, and melting-point and density values that differ between suppliers and PubChem
identity:
formula: Sm2O3
cas: 12060-58-1
crystal_system: cubic
source: saip-sm2o3-poster
where: Abstract (XRD confirms a cubic structure). CAS 12060-58-1 and molecular formula O3Sm2 from PubChem CID 159425, Names and Identifiers
tags:
environments: []
stresses: []
applications:
- radiation-shielding
- optics-and-cameras
- electronics-and-chips
properties:
- benchmark: density
value: 8.347
unit: g/cm3
scope: material
conditions:
temperature: 25 °C
form: Sm2O3 powder
method: Database value, read from the PubChem record for CID 159425
status: ground
source: pubchem-sm2o3
where: Chemical and Physical Properties, Experimental Properties, Density
- benchmark: density
value: 8.43
unit: g/cm3
scope: material
conditions:
form: Sm2O3 powder (micron powder product, 325 mesh, supplier listing)
method: Value printed on a supplier product page (not a test method stated)
status: ground
note: Supplier value. It differs from the PubChem value of 8.347 g/cm3 and from the 8.347 printed in the Thermo Fisher SDS.
source: nanografi-sm2o3-powder
where: Product specification block, density field
- benchmark: melting_point
value: 2325
unit: °C
scope: material
conditions:
purity: 99.9 weight percent Sm2O3 (Thermo Fisher Cat. No. 36278)
method: Value printed in a supplier safety data sheet, Section 9
status: ground
note: The PubChem record gives no melting point for Sm2O3, so this value comes from the supplier SDS.
source: wsu-sm2o3-sds
where: Section 9, Physical and chemical properties, Melting Point/Range row
- benchmark: melting_point
value: 2335
unit: °C
scope: material
conditions:
form: nanopowder and powder listings on the supplier page
method: Value printed on a supplier product page
status: ground
note: Supplier value. It is 10 °C above the 2325 °C printed in the Thermo Fisher SDS.
source: nanografi-sm2o3-powder
where: Product specification block, melting point field
- benchmark: boiling_point
value: 4118
unit: °C
scope: material
conditions:
form: samarium oxide nanopowder listing
method: Value printed on a supplier product page, in the same sentence as the 2335 °C melting point
status: ground
note: Supplier value for a nanopowder listing, not a PubChem or SDS value.
source: nanografi-sm2o3-nano
where: Product description, melting and boiling points sentence
- benchmark: molecular_weight
value: 348.7
unit: g/mol
scope: material
conditions:
basis: computed by PubChem from the molecular formula
method: Computed property read from the PubChem record for CID 159425
status: calculated
source: pubchem-sm2o3
where: Computed Properties, Molecular Weight
- benchmark: lattice_parameter
label: Lattice parameter a, cubic Sm2O3 (conference abstract)
value: 10.94
unit: Å
scope: material
conditions:
crystal_system: cubic
temperature: sample calcined at 500 and 700 °C (the abstract does not say which calcination temperature gives this lattice parameter)
method: X-ray diffraction, as reported in the abstract of a 2025 conference contribution
status: ground
note: From a conference abstract, not a peer-reviewed paper.
source: saip-sm2o3-poster
where: Abstract, sentence beginning "The structural analysis through x-ray diffraction"
- benchmark: band_gap
label: Measured band gap, cubic Sm2O3 crystal
value: 4.9
unit: eV
scope: material
conditions:
crystal_system: cubic
basis: value quoted by the 2019 paper from earlier measurements (its references 41 and 42)
method: Measured value quoted in Section 3.1.3 of the modelling paper
status: ground
note: Quoted value, not measured by the authors of the 2019 paper. The paper gives 4.7 eV for monoclinic and 5.1 eV for hexagonal Sm2O3 for comparison.
source: olsson-cai-2019
where: Section 3.1.3 Electronic Properties, first sentence on measured band gaps
- benchmark: dielectric_constant
label: Dielectric constant of amorphous Sm2O3 films, upper value quoted
value: 15
bound: upper
unit: '-'
scope: material
conditions:
phase: amorphous films
basis: value quoted by the paper from three earlier film studies (its references 27 to 29)
method: Literature value quoted in the Introduction of the modelling paper
status: ground
note: A quoted upper value for thin amorphous films. Film thickness and deposition method are not given in the text read.
source: olsson-cai-2019
where: Introduction, paragraph on high-k dielectric use (text "up to 15 for the amorphous films")
- benchmark: bulk_modulus
label: Bulk modulus, cubic Sm2O3, experimental range quoted
value: 130
value_high: 149
bound: range
unit: GPa
scope: material
conditions:
crystal_system: cubic
basis: experimental range quoted by the paper from its references 40, 35 and 90
method: Experimental values quoted in Table 3 of the modelling paper
status: ground
source: olsson-cai-2019
where: Table 3, Experimental row, Bulk modulus column
- benchmark: bulk_modulus
label: Bulk modulus, cubic Sm2O3, calculated
value: 137.26
unit: GPa
scope: material
conditions:
crystal_system: cubic
basis: ab initio calculation in the modelling paper, with an interatomic potential
method: Calculated value from the modelling paper
status: calculated
source: olsson-cai-2019
where: Table 3, Cubic row, B (GPa) column
- benchmark: elastic_modulus
label: Young's modulus, cubic Sm2O3, calculated
value: 191.06
unit: GPa
scope: material
conditions:
crystal_system: cubic
basis: calculated value in the modelling paper
method: Calculated value from the modelling paper
status: calculated
source: olsson-cai-2019
where: Table 3, Cubic row, E (GPa) column
- benchmark: ld50_oral
label: Acute oral LD50, Sm2O3, rat
value: 5
bound: lower
unit: g/kg
scope: material
conditions:
species: rat
route: oral
method: Value printed in a supplier safety data sheet, Section 11 (component information)
status: ground
note: The SDS prints the value as greater than 5 g/kg, so 5 is a lower bound. No dermal or inhalation figure is listed.
source: wsu-sm2o3-sds
where: Section 11, Component Information table, LD50 Oral column
corrosion:
- environment: Moist air and water (storage and handling)
headline: Sm2O3 is air sensitive and hygroscopic according to the Thermo Fisher SDS.
effect: The SDS lists exposure to moist air or water as a condition to avoid and says to keep the powder dry in a tightly closed container. It gives no mass-gain figure, so the rate of moisture uptake is not known from this source.
rating: moderate
conditions:
form: powder
exposure: not quantified
source: wsu-sm2o3-sds
where: Section 10 (Stability, Conditions to Avoid) and Section 7 (Storage)
- environment: Acids
headline: Sm2O3 is described as soluble in acids and is listed as incompatible with acids.
effect: The PubChem record quotes Hawley for insoluble in water and soluble in acids, and the SDS lists acids as incompatible. Neither source gives a dissolution rate or temperature, so the rating is qualitative.
rating: moderate
conditions:
basis: qualitative solubility statement
exposure: not tested in the sources read
source: pubchem-sm2o3
where: Experimental Properties, Physical Description (Hawley entry)
risks:
hazards:
- text: PubChem's GHS record gives the signal word Warning and lists H400 (very toxic to aquatic life) and H410 (very toxic to aquatic life with long lasting effects), each in 44.6% of company reports.
ghs:
- H400
- H410
source: pubchem-sm2o3
where: Safety and Hazards, GHS Classification (ECHA C and L notifications summary)
- text: PubChem also notes that this chemical does not meet GHS hazard criteria in 55.4% (129 of 233) of company reports, so the notifications disagree.
ghs: []
source: pubchem-sm2o3
where: Safety and Hazards, GHS Classification, Note
- text: The Thermo Fisher SDS says the product is not considered hazardous by the 2012 OSHA Hazard Communication Standard and has no label elements. It prints an oral LD50 greater than 5 g/kg in rat.
ghs: []
source: wsu-sm2o3-sds
where: Section 2 (Hazard identification) and Section 11 (Component Information)
failure_risks:
- mode: Moisture pick-up by the hygroscopic powder
trigger: Storage or handling in moist air or contact with water
consequence: The SDS calls the powder air sensitive and hygroscopic and asks for dry, tightly closed storage. The SDS gives no mass-gain figure, so the effect on composition is not quantified.
severity: moderate
source: wsu-sm2o3-sds
where: Section 10 (Stability; Conditions to Avoid)
- mode: Reaction with acids
trigger: Contact with acids, which the SDS lists as incompatible
consequence: Sm2O3 is a basic oxide that PubChem describes as soluble in acids, so oxide is lost from a part or powder exposed to acid. No rate or temperature is printed.
severity: moderate
source: pubchem-sm2o3
where: Experimental Properties, Physical Description (Hawley entry); SDS Section 7 incompatible materials
side_effects: []
handling:
- text: Avoid contact with skin and eyes and do not breathe dust. Handle the product only in a closed system or with appropriate exhaust ventilation.
source: wsu-sm2o3-sds
where: Section 7 (Handling)
- text: Keep in a dry, cool, well-ventilated place in a tightly closed container. Keep away from acids, strong oxidizing agents and carbon dioxide.
source: wsu-sm2o3-sds
where: Section 7 (Storage; Incompatible Materials)
mitigations:
- text: Wear chemical safety goggles or eyeglasses and gloves as the SDS directs, and use a particle filter where dust may be breathed.
source: wsu-sm2o3-sds
where: Section 8 (Eye/face protection, skin and body protection, respiratory protection)
uses:
- application: radiation-shielding
device: Neutron absorber in control rods for nuclear power reactors (supplier listing)
example: Nanografi lists neutron absorber in control rods for nuclear power reactors among the important application areas of its samarium oxide powder. No test result for this use was read.
source: nanografi-sm2o3-powder
where: Product description, Applications list
- application: optics-and-cameras
device: Optical and infrared-absorbing glasses (supplier listing)
example: Nanografi lists optical and infrared-absorbing glasses as an important application area of its samarium oxide powder.
source: nanografi-sm2o3-powder
where: Product description, Applications list
- application: electronics-and-chips
device: High-k gate dielectric in MOS devices (research)
example: The 2019 modelling paper says the most promising electronic device applications for Sm2O3 are found in MOS and ReRAM devices and quotes a dielectric constant of up to 15 for amorphous films.
source: olsson-cai-2019
where: Introduction, first paragraphs on electronic device applications
supply:
- subject: Samarium and rare earths (USGS 2025 mine production, rare-earth oxide equivalent, all rare earths, not samarium alone)
abundance: Not read in a source opened for this profile.
producers:
- country: China
share_percent: 69.2
year: 2025
- country: United States
share_percent: 13.1
year: 2025
- country: Australia
share_percent: 7.4
year: 2025
- country: Burma
share_percent: 5.6
year: 2025
critical_lists:
- list: USGS 2025 List of Critical Minerals (samarium is listed by name)
listed: true
price: 'USGS: samarium oxide, 99.5% minimum, average price 2.82 dollars per kg in 2025e'
import_reliance: 'USGS: net import reliance for rare-earth compounds and metals was 67 percent of apparent consumption in 2025e'
export_controls: 'USGS: in April 2025 China tightened export controls covering samarium alloys, compounds, metals and oxides.'
recycling: 'USGS: limited quantities of rare earths were recovered from batteries, permanent magnets and fluorescent lamps. The chapter does not single out samarium oxide.'
substitutes:
- 'USGS: substitutes are available for many applications but generally are less effective.'
source: usgs-mcs2026-rare-earths
where: 'Salient Statistics (price, net import reliance); World Mine Production and Reserves, 2025 column (world total 390,000 t REO); Events, Trends, and Issues; Recycling; Substitutes. Shares are calculated by Space Mushroom from the printed tonnes and the rounded world total, and cover all rare earths, not samarium alone. Critical list: USGS 2025 List of Critical Minerals page.'
media: []
documents:
- title: 'PubChem: Samarium(III) oxide (CID 159425), Experimental Properties, GHS classification, Computed Properties'
type: database
url: https://pubchem.ncbi.nlm.nih.gov/rest/pug_view/data/compound/159425/JSON
year: 2026
- title: Thermo Fisher Scientific safety data sheet, Samarium(III) oxide, Cat. No. 36278 (revision 29 March 2024), hosted by Washington State University
type: sds
url: https://wpcdn.web.wsu.edu/wp-research/uploads/sites/2909/2025/05/Samarium-III-Oxide-12060-58-1.pdf
year: 2024
- title: 'Nanografi: Samarium oxide (Sm2O3) powder product page'
type: datasheet
url: https://shop.nanografi.com/rare-earth-materials/rare-earth-oxide-powder/samarium-oxide-sm2o3-powder/
year: 2026
- title: 'Nanografi: Samarium oxide nanoparticles product page'
type: datasheet
url: https://shop.nanografi.com/nanoparticles/single-metal-oxide-nanoparticles/samarium-oxide-nanoparticles/
year: 2026
- title: 'USGS Mineral Commodity Summaries 2026: Rare Earths'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-rare-earths.pdf
year: 2026
- title: 'USGS: About the 2025 List of Critical Minerals'
type: report
url: https://www.usgs.gov/programs/mineral-resources-program/science/about-2025-list-critical-minerals
year: 2025
- title: Effect of Temperature on Structural and Optical Properties of Sm2O3 (SAIP 2025 conference contribution)
type: paper
url: https://events2.saip.org.za/event/1/contributions/463/contribution.pdf
year: 2025
- title: 'Olsson, Cai, Cottom, Jakobsen and Shluger: Structural, Elastic, Vibrational and Electronic Properties of Amorphous Sm2O3 from Ab Initio Calculations (Computational Materials Science, 2019; open access via UCL Discovery)'
type: paper
url: https://discovery.ucl.ac.uk/id/eprint/10084314/1/Revised%20Manuscript.pdf
year: 2019
gaps:
- No space flight, vacuum, radiation-test or thermal-vacuum result for Sm2O3 was found in any source read. The neutron-absorber and optical-glass uses are catalogue statements from suppliers.
- No PubChem melting point exists for Sm2O3. The two supplier melting points (2325 °C in the SDS and 2335 °C on the Nanografi page) are both kept and not reconciled.
- Density differs between PubChem (8.347 g/cm3 at 25 °C), the Nanografi page (8.43 g/cm3) and the Thermo Fisher SDS (specific gravity 8.347, which is the same number). Both values are kept.
- Thermal expansion coefficient was not recorded. The 2019 modelling paper prints 8.11 × 10^-6 K^-1 (calculated) and 7.5 − 8.8 × 10^-6 K^-1 (experimental) in exponent form, so per the brief these are left out.
- Band gap range across the Sm2O3 phases (4.70 to 5.10 eV in the modelling paper) and thin-film band gaps (3.15 to 4.0 eV) were not recorded as properties. Only the cubic value of 4.9 eV is kept.
- The 43 dielectric constant of 1991 electron-beam films was seen only in a search summary and not read in a fetched page, so it is not used. The INIS record for the dielectric film study returned HTTP 402 and the RSC 2023 perspective returned HTTP 403, so neither was read.
- Space group of cubic Sm2O3 was not read in a source opened for this profile.
- Atomic weights for samarium and oxygen were not read in a source opened for this profile, so the recipe parts carry no atomic_weight. The molecular weight 348.7 g/mol is PubChem's.
- Abundance of samarium in the Earth's crust was not read in a source opened for this profile.
- The EU critical raw materials list was not checked for samarium.
- USGS world production is given for all rare earths. No samarium-only production figure was read, so the producer shares are rare-earth shares.
- The PubChem GHS record and the Thermo Fisher SDS disagree on hazard classification (aquatic toxicity warnings versus not hazardous under OSHA). Both are recorded.
- Several property names are not in the canonical list (band_gap, lattice_parameter, molecular_weight, ld50_oral). They use short snake_case names as the brief allows.
sources:
pubchem-sm2o3:
title: 'PubChem compound record, Samarium(III) oxide (CID 159425): Experimental Properties, Computed Properties, GHS Classification, Physical Description'
id: CID 159425; CAS 12060-58-1
url: https://pubchem.ncbi.nlm.nih.gov/rest/pug_view/data/compound/159425/JSON
year: 2026
kind: database
license: public domain (NCBI)
wsu-sm2o3-sds:
title: Thermo Fisher Scientific safety data sheet, Samarium(III) oxide, Cat. No. 36278, revision 29 March 2024 (hosted by Washington State University)
id: Cat. No. 36278; CAS 12060-58-1
url: https://wpcdn.web.wsu.edu/wp-research/uploads/sites/2909/2025/05/Samarium-III-Oxide-12060-58-1.pdf
year: 2024
kind: datasheet
license: supplier safety data sheet, linked not reproduced
nanografi-sm2o3-powder:
title: 'Nanografi: Samarium oxide (Sm2O3) powder product page'
id: supplier product page
url: https://shop.nanografi.com/rare-earth-materials/rare-earth-oxide-powder/samarium-oxide-sm2o3-powder/
year: 2026
kind: web
license: supplier web page, linked not reproduced
nanografi-sm2o3-nano:
title: 'Nanografi: Samarium oxide nanoparticles product page'
id: supplier product page
url: https://shop.nanografi.com/nanoparticles/single-metal-oxide-nanoparticles/samarium-oxide-nanoparticles/
year: 2026
kind: web
license: supplier web page, linked not reproduced
usgs-mcs2026-rare-earths:
title: Mineral Commodity Summaries 2026, Rare Earths
id: USGS MCS 2026, February 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-rare-earths.pdf
year: 2026
kind: report
license: public domain (USGS)
usgs-critical-2025:
title: About the 2025 List of Critical Minerals (USGS, final list of 60 minerals)
id: Final 2025 List of Critical Minerals
url: https://www.usgs.gov/programs/mineral-resources-program/science/about-2025-list-critical-minerals
year: 2025
kind: web
license: public domain (USGS)
saip-sm2o3-poster:
title: Effect of Temperature on Structural and Optical Properties of Sm2O3 (SAIP 2025 conference contribution)
id: SAIP 2025, contribution 463
url: https://events2.saip.org.za/event/1/contributions/463/contribution.pdf
year: 2025
kind: paper
license: conference abstract, linked not reproduced
olsson-cai-2019:
title: Structural, Elastic, Vibrational and Electronic Properties of Amorphous Sm2O3 from Ab Initio Calculations (Olsson, Cai, Cottom, Jakobsen, Shluger)
id: doi:10.1016/j.commatsci.2019.109119 (Computational Materials Science, 2019); UCL Discovery eprint 10084314
url: https://discovery.ucl.ac.uk/id/eprint/10084314/1/Revised%20Manuscript.pdf
year: 2019
kind: paper
license: open access via UCL Discovery (as listed)
license: CC-BY-4.0
updated: '2026-11-01'
review:
status: draft
method: assistant
checked_values: 13
unreachable: 2
caveats: 3
note: Drafted by an AI assistant on 2026-11-01 from pages opened in this run. Values are from PubChem, a Thermo Fisher SDS, two Nanografi product pages, a 2025 conference abstract and a 2019 open-access modelling paper, with USGS for supply. Two supplier values disagree on melting point and density and both are kept.
story:
recipe:
line: Sm2O3 is samarium(III) oxide. Each formula unit combines two samarium atoms with three oxygen atoms, and PubChem gives the formula as O3Sm2 with a molecular weight of 348.7 g/mol.
parts:
- name: Samarium
symbol: Sm
role: The metal centre, held in the +3 state in Sm2O3.
- name: Oxygen
symbol: O
role: Oxygen anions around each samarium. The 2019 modelling paper describes each Sm as six-coordinated in a distorted octahedron in the cubic crystal.
risk_groups:
- title: For people
level: 1
verdict: 'Hazard data conflict: PubChem and the SDS differ'
lead: PubChem's GHS record lists aquatic toxicity warnings, while the Thermo Fisher SDS calls the product not hazardous under OSHA.
points:
- label: Aquatic
line: PubChem's GHS record gives the signal word Warning with H400 and H410 in 44.6 percent of company reports each.
- label: SDS
line: The Thermo Fisher SDS prints an oral LD50 greater than 5 g/kg in rat and no GHS label elements.
- label: Dust
line: Avoid breathing dust and use exhaust ventilation, as the SDS directs.
- title: Moisture and acids
verdict: Keep dry and away from acids
lead: The SDS calls the powder air sensitive and hygroscopic, and lists acids as incompatible.
points:
- label: Storage
line: Keep the container tightly closed in a dry, cool, well-ventilated place.
- label: Acids
line: PubChem describes the oxide as soluble in acids, so acid contact removes material.
why: Samarium(III) oxide is a dense, high-melting rare-earth oxide. Suppliers list it for neutron absorbers in reactor control rods and for optical and infrared-absorbing glasses. Samarium is also on the USGS 2025 critical mineral list, so its supply is closely watched.
uses:
- where: Neutron absorbers in reactor control rods (supplier listing)
line: Nanografi lists neutron absorber in control rods for nuclear power reactors among the important application areas of its Sm2O3 powder. No test result for this use was read.
- where: Optical and infrared-absorbing glasses
line: Nanografi lists optical and infrared-absorbing glasses as a further application area of the same powder.
- where: High-k dielectric research in MOS devices
line: The 2019 modelling paper says the most promising electronic device applications for Sm2O3 are MOS and ReRAM devices, and quotes a dielectric constant of up to 15 for amorphous films.
can_do:
- label: Neutron absorber
value: Reactor control rods (supplier listing)
line: Nanografi lists neutron absorber in control rods for nuclear power reactors as an application of its Sm2O3 powder. No test result for this use was read.
- label: Optical glass
value: Optical and infrared-absorbing glasses (supplier listing)
line: Nanografi lists optical and infrared-absorbing glasses as a further application of the same powder.
- label: Melting point
value: 2325 °C (SDS) and 2335 °C (Nanografi)
line: The Thermo Fisher SDS prints a melting point of 2325 °C, and the Nanografi page prints 2335 °C for the same oxide.
compare: Sm2O3 is a dense, high-melting oxide with a cubic crystal structure. PubChem gives 8.347 g/cm3 at 25 °C for its density, while the Nanografi page gives 8.43 g/cm3. Its melting point is printed as 2325 °C in the SDS and 2335 °C on the Nanografi page, and the modelling paper gives a calculated bulk modulus of 137.26 GPa for the cubic crystal. Its main space-relevant case is as a dielectric and optical material in research, with no flight record found.
compare_rows:
- label: Density
benchmark: density
- label: Melting point
benchmark: melting_point
- label: Bulk modulus
benchmark: bulk_modulus
handling:
- PubChem and the Thermo Fisher SDS both point to acid incompatibility. Keep the powder away from acids and strong oxidizing agents.
- The SDS asks for dry, tightly closed storage because the powder is hygroscopic.
- Avoid breathing dust, and handle in a closed system or with exhaust ventilation.
good_for:
- Optical and infrared-absorbing glass, as supplier listings describe.
- Research on high-k dielectrics, where the 2019 modelling paper quotes a dielectric constant of up to 15 for amorphous films.
watch_out:
- Two supplier melting points (2325 °C and 2335 °C) and two densities (8.347 and 8.43 g/cm3) differ, so check the source that matches the grade and form you need.
- PubChem's aquatic toxicity warnings and the SDS's not-hazardous classification disagree.
- No space or radiation test on Sm2O3 was found, so treat the neutron-absorber and glass uses as supplier claims.
verdict: 'Sm2O3 is a dense, high-melting rare-earth oxide with useful supplier-listed uses in neutron absorbers and optical glasses, and a research record as a high-k dielectric. For space work it is unproven: no flight or radiation test was found, and the melting point and density values differ between sources.'
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
Updated