Lanthanum strontium manganite LSM

La1-xSrxMnO3, a perovskite solid solution of lanthanum manganite with strontium replacing part of the lanthanum · CAS 66402-68-4 · perovskite; rhombohedral

Lanthanum strontium manganite (LSM, La1-xSrxMnO3) is a perovskite oxide in which strontium replaces part of the lanthanum.

8 sources · Updated 2026-10-26 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Curie range

About 350 to 370 K

Apparent density

2.0 g/cm3

Particle size

15 to 45 µm

Recipe, share of the weight

  • La not statedLanthanum
  • Sr not statedStrontium
  • Mn not statedManganese
  • O not statedOxygen

Best for

Solid oxide fuel cell cathode work, where Wikipedia says the thermal expansion is well matched to yttria-stabilized zirconia

Weakest at

The sources read here give no measured electrical conductivity, thermal expansion coefficient or melting point. The Curie range is a Wikipedia figure, not a single measurement.

Risk at a glance

  • People Low. Harmful on skin contact; SDSs disagree on eye damage
  • If it fails Moderate. Contact with strong oxidizing agents
  • Corrosion No data. No corrosion data recorded

Quick facts: LSM

Key properties of LSM
PropertyValueBasis
Density2 g/cm³1 sourced value

What is the density of Lanthanum strontium manganite (LSM)?

Lanthanum strontium manganite (LSM) has a density of 2 g/cm³. The source and test conditions are listed in the properties table on this page.

What is Lanthanum strontium manganite (LSM) used for?

Uses recorded in the sources include Solid oxide fuel cell cathode; Colossal-magnetoresistance research material.

Why it exists

Lanthanum strontium manganite (LSM, La1-xSrxMnO3) is a perovskite oxide in which strontium replaces part of the lanthanum in LaMnO3. Wikipedia says it is widely used as a cathode in solid oxide fuel cells and that it is one of the manganites that show colossal magnetoresistance. Its cathode use depends on electronic conduction and on a thermal expansion that the article says is well matched to yttria-stabilized zirconia, the usual electrolyte. The sources read here give no measured conductivity, thermal expansion or melting point, so the case rests on composition, the Curie range and the supplier listings.

Where it's used

Solid oxide fuel cell cathode

Wikipedia says LSMO is widely used as a cathode material in solid oxide fuel cells, citing Armstrong and Virkar (2002). The source names no cell or stack model.

Colossal-magnetoresistance research

Wikipedia lists LSMO among the perovskite manganites that show colossal magnetoresistance, where the resistance changes dramatically in an applied magnetic field. The article names no device.

Recipe

La1-xSrxMnO3, a perovskite solid solution of lanthanum manganite with strontium replacing part of the lanthanum

LSM is a lanthanum manganite in which strontium replaces part of the lanthanum, giving La1-xSrxMnO3. Wikipedia defines x as the fraction of La ions replaced by Sr, and its figure caption gives La0.7Sr0.3MnO3 as an example. Both supplier safety sheets describe the powder as a mix of lanthanum oxide, strontium oxide and manganese oxide, not as one named compound.

What LSM is made of
IngredientShare of the weightWhat it does
Lanthanum La not stated The large metal ion of the perovskite structure. Part of it is replaced by strontium.
Strontium Sr not stated Replaces part of the lanthanum. Wikipedia gives x, the replaced fraction, as the composition variable.
Manganese Mn not stated The manganese ion in the manganese-oxygen framework. Wikipedia says the conductivity is highest near x = 0.3.
Oxygen O not stated Three oxygen per formula unit in the ABO3 perovskite structure, according to Wikipedia.

Weight shares are as printed in the sources.

What it can do

Curie range

About 350 to 370 K

measured

Wikipedia gives a Curie temperature of about 350 to 370 K for the composition near x = 0.3. The same article says conductivity is highest near that composition.

Apparent density

2.0 g/cm3

measured

A supplier powder page gives an apparent density of 2.0 g/cm3. This is a bulk powder figure, not a crystal density.

Particle size

15 to 45 µm

measured

The supplier powder page gives a nominal spheroidal particle size of -45 +15 µm, read here as 15 to 45 µm.

How it compares

LSM is compared here only on the three properties that have a source. Its Curie range is a single range rather than a measured transition, and its apparent density is a bulk powder figure rather than a crystal density. No melting point, conductivity or thermal expansion value could be read, so the table cannot place LSM against other cathodes on those.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.

Benchmarks
MeasurementLSMAl2O3BaTiO3BeOCaTiO3RCFCeO2CoO and Co3O4CuO, Cu2OHfO2Fe2O3, Fe3O4PZTMgONiONb2O5Al2Si4O10(OH)2Ln2O3SiOMgO-SiO2SnO2, ITOTiO2WO3V2O5Y2O3ZnOMg-PSZ, ATZ, ZTAYSZ
Physical and electrical
Apparent density, powder (Stanford Advanced Materials)2 g/cm³13.72 g/cm³6.08 -3.01 g/cu cm4.1 g/cc64 kg/m37.65 g/cm³6.45 g/cm³6 -9.68 g/cc5.24 g/cm³7.8 g/cm³3.58 g/cm³6.67 g/cm³4.6 g/cm³2.3 g/cc6.51 g/cm³2.13 g/cc2.8 g/cm³6.95 g/mL4 g/cm³7.2 g/cm³3.4 -> 4.9 g/cm³5.67 g/cm³5.72 g/cm³6.02 g/cm³
Temperature behavior
Curie temperature, composition near x = 0.3350 to 370 K2no data125 to 128 °Cno datano datano datano datano datano datano data858 K350 °Cno datano datano datano datano datano datano datano datano datano datano datano datano datano datano data
Other measurements
Nominal particle size range, spheroidal powder15 to 45 µm3no datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano data

Why choose it, and why not

Good for

  • Solid oxide fuel cell cathode work, where the article says the thermal expansion is well matched to yttria-stabilized zirconia.
  • Magnetoresistance research near a Curie range of about 350 to 370 K.

Watch out for

  • The hazard data disagree. One SDS calls the powder harmful and irritant, the other corrosive to skin and eyes.
  • No measured conductivity, thermal expansion or melting point was read, so LSM cannot yet be ranked against other cathodes on those properties.
  • The composition varies. The supplier sheets name different manganese oxides (MnO and Mn3O4), and x sets the strontium content.

LSM is a well-known SOFC cathode and a magnetoresistive oxide, but this profile holds only three sourced properties. Its supplier hazard data disagree, so handle the powder as harmful and irritant until the SDS for your exact product is checked.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Apparent density, powder (Stanford Advanced Materials)Value printed in the Specifications section of a supplier product page as Range of Apparent Density (g/cm3)form grey to black spheroidal powder, catalogue MN5871, nominal chemistry (La0.8Sr0.2)0.98MnO3basis apparent (bulk powder) density, not crystal densityThe page prints one figure, so it is given as a value and not as a range.
2Curie temperature, composition near x = 0.3Range stated in the Wikipedia article, electronic and magnetic properties section; no single measurement is givencomposition La1-xSrxMnO3 near x = 0.3 (figure caption example La0.7Sr0.3MnO3)note as stated in the articleStated as a range, not a measured point. Read as approximate.
3Nominal particle size range, spheroidal powderNominal particle size distribution printed in the Specifications section of a supplier product pageform spheroidal powder, catalogue MN5871sieve nominal -45 +15 µm band as printedCustom snake_case name, not in property-canon.yaml. The printed band is -45 +15 µm, read here as 15 to 45 µm.

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Strong acids, strong bases and strong oxidizing agents not rated Both SDSs list strong acids, strong bases or oxidizers as incompatible. No corrosion rate or test was read.1
High temperature in a solid oxide fuel cell stack (about 800 °C and above) not rated The cathode is said to match the thermal expansion of the usual zirconia electrolyte. No ageing or degradation study was read.2
Corrosion details
#EnvironmentDetailsTest conditions
1 Strong acids, strong bases and strong oxidizing agents The Fuel Cell Store sheet lists strong acids, strong bases and strong oxidizers as incompatible materials. The Stanford sheet says the material reacts with strong oxidizing agents. Neither gives a rate, a test result or a time scale. basis incompatibility lists in two supplier SDSs; no testform powder
2 High temperature in a solid oxide fuel cell stack (about 800 °C and above) Wikipedia says LSMO is widely used as a cathode in solid oxide fuel cells and that its thermal expansion is well matched to yttria-stabilized zirconia. The supplier powder page says it performs well above 800 °C. No ageing, degradation or corrosion study was read. basis qualitative compatibility statements; no ageing testnote a compatibility statement, not a corrosion test

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

Two supplier safety data sheets classify the powder, and they do not agree. The Stanford sheet gives irritant and harmful hazards. The Fuel Cell Store sheet, for a different composition, gives skin burns and serious eye damage.

Stanford hazards
H312 (harmful in contact with skin), H315 (causes skin irritation), H319 (causes serious eye irritation) and H335 (may cause respiratory irritation). Signal word Warning.
Fuel Cell Store hazards
H314 (causes severe skin burns and eye damage) and H318 (causes serious eye damage), signal word Danger. Strontium oxide in its composition is Skin Corr. 1B.
Component
PubChem records H315, H319 and H335, signal word Warning, for lanthanum sesquioxide, one of the components.

In a fire

Heat or fire releases metal oxide fumes. No service-incident or failure-rate data were read.

Fume
The Stanford sheet says a fire can release metal oxide fume. The Fuel Cell Store sheet lists oxides of carbon, strontium, manganese and lanthanum as decomposition products.
Mixing
The Stanford sheet says the material reacts with strong oxidizing agents. Both sheets list strong acids, strong bases or oxidizers as incompatible.

Handling and storage

Storage
Keep the container tightly sealed in a cool, dry place, away from oxidizing agents (Stanford sheet). The Fuel Cell Store sheet adds strong acids and strong bases to the incompatible list.
Dust and exposure
Use a fume hood, nitrile gloves (0.11 mm, 480 minutes penetration time) and safety glasses. Stanford advises a P100 or P3 cartridge respirator as a backup to engineering controls.
Dust clothing
Fuel Cell Store advises dustproof, corrosionproof clothing where dust forms.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Fire involving the powderlow severityPowder involved in a fireReleases metal oxide fume (Stanford sheet). The Fuel Cell Store sheet lists oxides of carbon, strontium, manganese and lanthanum as decomposition products.
Contact with strong oxidizing agentsmoderate severityMixing with strong oxidizing agents, strong acids or strong basesThe Stanford sheet says the material reacts with strong oxidizing agents. No reaction products beyond metal oxide fume are named.

Handling and storage

  • Stanford sheet: keep the container tightly sealed in a cool, dry place, away from oxidizing agents, and ensure good ventilation at the workplace.
  • Stanford sheet: use a properly operating chemical fume hood, nitrile gloves (0.11 mm thickness, 480 minutes penetration time) and safety glasses. Use a P100 or P3 respirator cartridge as a backup to engineering controls.
  • Fuel Cell Store sheet: avoid dust formation and wear dustproof, corrosionproof clothing where dust is produced.

Supply and geography

How common the raw materials are and where they come from.

Manganese (mine production, manganese content)

Top producers (2025)
South Africa 38%, Gabon 25%, Ghana 10%, Australia 8%
Critical mineral lists
US: listed
Recycling
USGS: Manganese was recycled incidentally as a constituent of ferrous and nonferrous scrap; scrap recovery specifically for manganese was negligible.
Substitutes
USGS: Manganese has no satisfactory substitute in its major applications.

Rare earths (lanthanum is one of them; not split out in the USGS table)

Top producers (2025)
China 69.2%, United States 13.1%, Australia 7.4%, Burma 5.6%
Critical mineral lists
US: listed
Recycling
USGS: Limited quantities of rare earths were recovered from batteries, permanent magnets and fluorescent lamps.
Substitutes
USGS: Substitutes are available for many applications but generally are less effective.