Beryllium oxide BeO
BeO (beryllium oxide) · CAS 1304-56-9 · hexagonal, P6_3mc
Also known as CAS 1304-56-9, Beryllium oxide, Beryllia, Thermalox 995
Beryllium oxide (BeO, beryllia) is an oxide ceramic that conducts heat better than almost any electrical insulator, second only to diamond according to Materion.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Carry heat away
285 W/m°K
Stay strong
221 Mpa
Recipe, share of the weight
- Be 36.0%Beryllium
- O 64.0%Oxygen
Best for
Heat spreaders and packages that must move a lot of heat while staying electrically insulating, where the beryllium dust hazard can be controlled
Weakest at
Health: beryllium dust, fume and mist are toxic and carcinogenic by inhalation. Mechanical strength is lower than alumina according to the American Beryllia page
Risk at a glance
- People No data. No hazard data recorded
- If it fails High. Airborne beryllium from machining or crushing fired parts
- Corrosion Severe. Soluble in hot strong acid and fused alkali
Quick facts: BeO
| Property | Value | Basis |
|---|---|---|
| Density | 3.01 g/cm³ | 3 sourced values across conditions |
| Thermal conductivity | 285 W/(m·K) | 2 sourced values across conditions |
| Melting point | 2,578 °C | 1 sourced value |
What is the density of Beryllium oxide (BeO)?
Beryllium oxide (BeO) has a density of 3.01 g/cm³. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the thermal conductivity of Beryllium oxide (BeO)?
Beryllium oxide (BeO) has a thermal conductivity of 285 W/(m·K). The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the melting point of Beryllium oxide (BeO)?
Beryllium oxide (BeO) has a melting point of 2,578 °C. The source and test conditions are listed in the properties table on this page.
What are the other names and codes for Beryllium oxide (BeO)?
Beryllium oxide (BeO) is also written as CAS 1304-56-9, Beryllium oxide, Beryllia, Thermalox 995. Each code is printed in the source listed beside it in the designations table.
What is Beryllium oxide (BeO) used for?
Uses recorded in the sources include Aerospace electronics; Microwave devices, vacuum tubes, gas lasers and magnetrons; Heat sinks and spreaders for CPUs, lasers and power amplifiers.
Why it exists
Beryllium oxide combines high thermal conductivity with electrical insulation. Materion says it is the second highest thermal conductivity of any electrical insulator after diamond, nine times that of alumina, and up to 80 percent higher than aluminium nitride. The Frontiers review adds high-temperature radiation stability and high strength. The same properties make it attractive in electronics and reactors. The price is the toxicity of beryllium: the grade must be chosen with the dust hazard in mind.
Where it's used
Aerospace and defense electronics
Materion lists aerospace electronics as an application of its beryllium oxide ceramics. It also lists microwave devices, vacuum tubes, gas lasers and magnetrons among the uses of its BeO powder.
Heat spreaders and power packages
Wikipedia says BeO is used in heat sinks and spreaders for CPUs, lasers and power amplifiers, and in some power semiconductor packages between the chip and the mounting base.
Reactors and proposed space power
The Frontiers review describes BeO as a candidate reflector and moderator in reactors. Wikipedia says it has been proposed as a moderator for naval gas-cooled reactors and for NASA's Kilopower reactor for space applications. These are reactor and proposal uses, not flown ones.
Recipe
BeO (beryllium oxide)
BeO is beryllium oxide, with one beryllium atom bonded to one oxygen atom per formula unit . CIAAW 2024 standard atomic weights are 9.0122 for beryllium and 15.999 for oxygen. Commercial BeO is made by calcining beryllium hydroxide, carbonate or sulfate. PubChem says practically all commercial BeO is calcined at 1000 °C or higher ('high-fired'), and beryllium sulfate is calcined at carefully controlled temperatures to tailor its properties. Wikipedia also lists dehydration of the hydroxide and burning of the metal in air, which gives some beryllium nitride.
| Ingredient | Atoms per unit | Share of the weight | What it does |
|---|---|---|---|
| Beryllium Be | 1 | 36.0% | Metal atom in each BeO formula unit |
| Oxygen O | 1 | 64.0% | Oxide anion in each BeO formula unit |
Weight shares are calculated from standard atomic weights.
What it can do
Carry heat away
285 W/m°K
measured
Materion gives 285 W/m°K for Thermalox 995 (99.5% BeO). American Beryllia gives 285 W/mK at room temperature for an unnamed grade. Both are in the properties table.
Insulate electrically
American Beryllia calls BeO an electrical insulator with bulk resistivity on the order of 10 16 Ωcm. The exponent is lost in the printed text, so no number is entered.
Stay strong
221 Mpa
measured
Materion gives 221 MPa flexural strength for Thermalox 995. American Beryllia says BeO strength is normally lower than that of alumina.
How it compares
Materion says BeO is nine times more thermally conductive than alumina and up to 80 percent more than aluminium nitride, and that it is more chemically stable than AlN in oxidizing environments. Its density is 3.01 g/cm3 against 4.00 g/cm3 for alumina and 3.26 g/cm3 for AlN, both from American Beryllia. Its melting point of 2578 °C is from the CRC Handbook. The compared numbers come from different sources and grades, so they should be read as direction, not as exact ratios.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.
| Measurement | BeO | Al2O3 | BaTiO3 | CaTiO3 | RCF | CeO2 | CoO and Co3O4 | CuO, Cu2O | HfO2 | Fe2O3, Fe3O4 | LSM | PZT | MgO | NiO | Nb2O5 | Al2Si4O10(OH)2 | Ln2O3 | SiO | MgO-SiO2 | SnO2, ITO | TiO2 | WO3 | V2O5 | Y2O3 | ZnO | Mg-PSZ, ATZ, ZTA | YSZ |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Thermal behavior and safety | |||||||||||||||||||||||||||
| Melting point, beryllium oxide (CRC Handbook via PubChem) | 2578 °C4 | 2030 to 2072 °C | 1625 °C | 1975 °C | 1760 °C | 2600 °C | 1830 °C | 1326 °C | 2774 °C | no data | no data | no data | 2800 °C | 1984 °C | 1500 °C | no data | 2304 °C | 1702 °C | no data | 1630 °C | 1850 °C | 1472 °C | 690 °C | 2410 °C | 1975 °C | no data | no data |
| Thermal conductivity, Thermalox 995 (Materion)Value from the Materion technical details table | 285 W/m°K | 30 W/(m·K) | 6 W/mK | no data | 0.06 W/(m·K) | no data | no data | no data | 1.5 W/mK | 5 to 10 W/m K | no data | no data | 42 W/(m·K) | no data | no data | no data | no data | no data | 2 W/(m·K) | no data | no data | no data | no data | 14.5 W/mK | 50 W/mK | 2.2 W/(m·K) | 2.2 W/(m·K) |
| Thermal conductivity, unnamed beryllium oxide (American Beryllia)Vendor statement, as printed | 285 W/mK | 30 W/(m·K) | 6 W/mK | no data | 0.06 W/(m·K) | no data | no data | no data | 1.5 W/mK | 5 to 10 W/m K | no data | no data | 42 W/(m·K) | no data | no data | no data | no data | no data | 2 W/(m·K) | no data | no data | no data | no data | 14.5 W/mK | 50 W/mK | 2.2 W/(m·K) | 2.2 W/(m·K) |
| Physical and electrical | |||||||||||||||||||||||||||
| Density, beryllium oxide (CRC Handbook via PubChem) | 3.01 g/cu cm1 | 3.72 g/cm³ | 6.08 - | 4.1 g/cc | 64 kg/m3 | 7.65 g/cm³ | 6.45 g/cm³ | 6 - | 9.68 g/cc | 5.24 g/cm³ | 2 g/cm³ | 7.8 g/cm³ | 3.58 g/cm³ | 6.67 g/cm³ | 4.6 g/cm³ | 2.3 g/cc | 6.51 g/cm³ | 2.13 g/cc | 2.8 g/cm³ | 6.95 g/mL | 4 g/cm³ | 7.2 g/cm³ | 3.4 - | > 4.9 g/cm³ | 5.67 g/cm³ | 5.72 g/cm³ | 6.02 g/cm³ |
| Density, beryllium oxide (Frontiers review, Table 1) | 3.01 g/cm³2 | 3.72 g/cm³ | 6.08 - | 4.1 g/cc | 64 kg/m3 | 7.65 g/cm³ | 6.45 g/cm³ | 6 - | 9.68 g/cc | 5.24 g/cm³ | 2 g/cm³ | 7.8 g/cm³ | 3.58 g/cm³ | 6.67 g/cm³ | 4.6 g/cm³ | 2.3 g/cc | 6.51 g/cm³ | 2.13 g/cc | 2.8 g/cm³ | 6.95 g/mL | 4 g/cm³ | 7.2 g/cm³ | 3.4 - | > 4.9 g/cm³ | 5.67 g/cm³ | 5.72 g/cm³ | 6.02 g/cm³ |
| Theoretical density, beryllium oxide (American Beryllia) | 3.01 g/cc3 | 3.72 g/cm³ | 6.08 - | 4.1 g/cc | 64 kg/m3 | 7.65 g/cm³ | 6.45 g/cm³ | 6 - | 9.68 g/cc | 5.24 g/cm³ | 2 g/cm³ | 7.8 g/cm³ | 3.58 g/cm³ | 6.67 g/cm³ | 4.6 g/cm³ | 2.3 g/cc | 6.51 g/cm³ | 2.13 g/cc | 2.8 g/cm³ | 6.95 g/mL | 4 g/cm³ | 7.2 g/cm³ | 3.4 - | > 4.9 g/cm³ | 5.67 g/cm³ | 5.72 g/cm³ | 6.02 g/cm³ |
| Other measurements | |||||||||||||||||||||||||||
| Flexural strength, Thermalox 995 (Materion) | 221 Mpa5 | 379 MPa | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | 7 MPa | no data | no data | 400 MPa | no data | no data | 190 MPa | no data | no data | no data | no data | 180 MPa | no data | 900 MPa | 1240 MPa |
| Refractive index, beryllia (American Beryllia)Vendor optical properties list, as printed | 1.719 -6 | no data | 2.416 - | no data | no data | no data | no data | no data | no data | no data | no data | no data | 1.708 - | no data | 2.091 - | no data | 1.93 - | no data | no data | no data | no data | no data | no data | 1.92 - | no data | no data | no data |
| Band gap, beryllium oxide (Wikipedia infobox) | 10.6 eV7 | no data | no data | no data | no data | no data | no data | 2.17 eV | 5.65 eV | no data | no data | no data | no data | 3.6 to 4 eV | no data | no data | no data | no data | no data | 3.6 eV | 3.23 eV | no data | no data | no data | 3.37 eV | no data | no data |
| Lattice constant a, beryllium oxide (wurtzite cell) | 2.698 Å8 | no data | no data | no data | no data | no data | no data | 4.23 Å | no data | no data | no data | no data | no data | 4.169 Å | no data | no data | no data | no data | no data | no data | 0.3785 nm | no data | no data | no data | 3.25 Å | no data | no data |
| Lattice constant c, beryllium oxide (wurtzite cell) | 4.377 Å9 | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | 0.9515 nm | no data | no data | no data | 5.207 Å | no data | no data |
| Solubility in water, beryllium oxide at 30 °C (CRC Handbook via PubChem) | 2 ug/100 mL10 | no data | no data | no data | no data | no data | 4.88 mg/L | no data | no data | no data | no data | no data | 86 mg/L | 3×10^-5 g/l | no data | no data | no data | no data | no data | no data | no data | no data | 0.8 g/100ml | no data | no data | no data | no data |
| Abbe number, beryllia (American Beryllia) | 93.25 -11 | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
Why choose it, and why not
Good for
- Heat spreaders and packages that must move heat while staying electrically insulating, as in aerospace electronics and power packages.
- Microwave, vacuum-tube, magnetron and gas-laser parts, as Materion lists them.
Watch out for
- Beryllium dust is toxic and carcinogenic by inhalation. Handling needs dust control at every step.
- Grade data differ. The Materion values are for Thermalox 995 only, and the American Beryllia values name no grade.
- Electrical resistivity and thermal expansion are not entered, because the printed values lost their exponents.
Beryllium oxide is one of the best electrical insulators for conducting heat, and it suits electronics where aluminium nitride is not enough. Its toxicity is serious, so it suits only applications where the dust hazard can be controlled, and the grade should be checked on its own data sheet.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Other names and standards
The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.
| System | Codes |
|---|---|
| CAS | 1304-56-9 |
| Name | Beryllium oxide, Beryllia |
| Trade name | Thermalox 995 |
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Density, beryllium oxide (CRC Handbook via PubChem) | Value from the CRC Handbook, 94th edition, as printed in the PubChem record | grade beryllium oxide, no grade or purity statedtemperature 25 °C (printed beside the value) | — |
| 2 | Density, beryllium oxide (Frontiers review, Table 1) | Table of moderator properties in an open-access review | grade beryllium oxide as a neutron moderator; no grade statedtemperature not stated | — |
| 3 | Theoretical density, beryllium oxide (American Beryllia) | Vendor comparison of theoretical density values, as printed | grade unnamed beryllium oxide (vendor page does not name a grade)temperature not stated | — |
| 4 | Melting point, beryllium oxide (CRC Handbook via PubChem) | Value from the CRC Handbook, 94th edition, as printed in the Wikipedia infobox (which cites Haynes p. 4.51) | grade beryllium oxide, no grade or purity statedpressure atmospheric (standard) | — |
| 5 | Flexural strength, Thermalox 995 (Materion) | Value from the Materion technical details table; test method not stated | grade Thermalox 995 (99.5% BeO, Materion)temperature not stated on the product page | — |
| 6 | Refractive index, beryllia (American Beryllia) | — | grade unnamed beryllium oxidewavelength not statedtemperature not stated | — |
| 7 | Band gap, beryllium oxide (Wikipedia infobox) | Infobox value in Wikipedia; the source of the infobox figure is not given on the page read | grade beryllium oxide, wurtzite phasetemperature not stated | The vendor page gives a wurtzite phase band gap of 10.4 to 10.6 eV; the infobox value is the upper end of that range. |
| 8 | Lattice constant a, beryllium oxide (wurtzite cell) | Crystallographic value in the Wikipedia infobox, as printed | crystal hexagonal wurtzite-type celltemperature not stated | — |
| 9 | Lattice constant c, beryllium oxide (wurtzite cell) | Crystallographic value in the Wikipedia infobox, as printed | crystal hexagonal wurtzite-type celltemperature not stated | — |
| 10 | Solubility in water, beryllium oxide at 30 °C (CRC Handbook via PubChem) | Value from the CRC Handbook, 76th edition (1995 to 1996), as printed in the PubChem record; not a canonical property, so the name is a short snake_case name | solvent watertemperature 30 °C | — |
| 11 | Abbe number, beryllia (American Beryllia) | Vendor optical properties list, as printed ("Vd = 93.25") | grade unnamed beryllium oxidewavelength not stated | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Water | low | Very low solubility in water1 |
| Concentrated sulfuric acid and fused potassium hydroxide | severe | Soluble in hot strong acid and fused alkali2 |
| Oxidizing chemicals | low | More chemically stable than aluminium nitride in oxidizing environments3 |
| Oxygen and hydrogen at high temperature | low | Very stable with O2 and H2 at 2000 °C4 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Water | The CRC Handbook figure in the PubChem record is 2 ug/100 mL at 30 °C. The PubChem record does not give a hydrolysis rate. Unlike aluminium nitride, no source read here says that water decomposes beryllium oxide. | medium watertemperature 30 °C |
| 2 | Concentrated sulfuric acid and fused potassium hydroxide | The CRC Handbook entry in PubChem says beryllium oxide is soluble in concentrated sulfuric acid and in fused potassium hydroxide. No rate, temperature or concentration is printed. | medium concentrated sulfuric acid; fused potassium hydroxidetemperature not stated |
| 3 | Oxidizing chemicals | Materion says BeO is more chemically stable than AlN ceramic in environments that contain oxidizing chemicals. No test data are given. | — |
| 4 | Oxygen and hydrogen at high temperature | The Frontiers review says BeO has a very stable performance with O2 and H2 even at a temperature of 2000 °C. The review gives no rate or test method. | atmosphere oxygen and hydrogentemperature 2000 °C |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
The hazard comes from dust, fume and mist. The fired solid is much less of a hazard, but PubChem's aggregate of ECHA reports classifies the compound as fatal if inhaled.
- Inhalation
- PubChem lists H330 (fatal if inhaled) and H350i (may cause cancer by inhalation), with H372 for organ damage from prolonged or repeated exposure.
- Chronic disease
- PubChem says repeated or prolonged exposure may cause chronic beryllium disease. Wikipedia names berylliosis, a chronic allergic-type lung disease.
- Exposure limits
- OSHA sets 0.2 µg/m3 as an 8-hour TWA and 2.0 µg/m3 as a 15-minute limit, with an action level of 0.1 µg/m3.
Fired parts
Once fired into a solid, the ceramic is safe to handle unless machining creates dust.
- Machining
- Wikipedia says crushing or grinding poses a risk, while clean breakage releases little dust.
If the part gets wet
Beryllium oxide is almost insoluble in water, and it dissolves only in strong acid or fused alkali.
- Water
- The CRC Handbook gives 2 ug/100 mL at 30 °C in water.
- Acid and alkali
- It is soluble in concentrated sulfuric acid and in fused potassium hydroxide, according to the CRC Handbook.
Hot oxidizing air
Beryllium oxide is chemically stable in oxygen and hydrogen.
- Stability
- The Frontiers review says BeO performs very stably with O2 and H2 even at 2000 °C. Materion says it is more chemically stable than AlN in oxidizing environments.
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Airborne beryllium from machining or crushing fired partshigh severity | Machining, grinding or crushing of fired beryllium oxide that generates dustAirborne beryllium dust, which is the main inhalation hazard in the material's handling. Wikipedia says clean breakage releases little dust, but crushing or grinding can pose a risk. |
Handling and storage
- OSHA sets the beryllium permissible exposure limit at 0.2 µg/m3 as an 8-hour time-weighted average and 2.0 µg/m3 as a 15-minute short-term exposure limit. The action level is 0.1 µg/m3 as an 8-hour TWA.
- Once fired into solid form, beryllium oxide is safe to handle if it is not machined to produce dust. Crushing or grinding poses a risk (Wikipedia).
- Keep beryllium oxide powder and dust out of the air. PubChem's hazards summary warns that dust or fume inhalation may cause chemical pneumonitis.
Supply and geography
How common the raw materials are and where they come from.
Beryllium (feedstock for beryllium oxide)
USGS: identified world resources of beryllium are more than 100,000 tons, and about 60% of them are in the United States.
- Top producers (2025)
- United States 53.5%, Brazil 18.6%, China 17.9%, Nigeria 9.3%, Mozambique 0.7%
- Recycling
- USGS: recovered beryllium from new and old scrap may account for as much as 20% to 25% of total beryllium consumption.
- Substitutes
- USGS: aluminum nitride or boron nitride may be substituted for beryllium oxide.
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
Show the full YAML
spore: profile
id: beryllium-oxide
spore_version: 0.2
family: oxide-ceramics
name: Beryllium oxide
abbreviation: BeO
role: electrically insulating, high-thermal-conductivity ceramic (beryllia)
category: ceramics
type: oxides
summary: 'Beryllium oxide (BeO, beryllia) is an oxide ceramic that conducts heat better than almost any electrical insulator, second only to diamond according to Materion. PubChem and the CRC Handbook give a density of 3.01 g/cm3 and a melting point of 2578 °C. Materion gives Thermalox 995 (99.5% BeO) a thermal conductivity of 285 W/m°K and a flexural strength of 221 MPa. The material is used in RF and microwave devices, power packages and heat spreaders. Its dust is toxic: PubChem classifies the compound with H330 and H350i, and OSHA sets very low airborne beryllium limits.'
best_for: Heat spreaders and packages that must move a lot of heat while staying electrically insulating, where the beryllium dust hazard can be controlled
weakest_at: 'Health: beryllium dust, fume and mist are toxic and carcinogenic by inhalation. Mechanical strength is lower than alumina according to the American Beryllia page'
identity:
formula: BeO (beryllium oxide)
cas: 1304-56-9
crystal_system: hexagonal
space_group: P6_3mc
source: pubchem-beo
where: Names and Identifiers (CID 14775, Beryllium Oxide); Wikipedia infobox for crystal system and space group
designations:
- system: CAS
code: 1304-56-9
source: pubchem-beo
where: Names and Identifiers > Other Identifiers > CAS
- system: Name
code: Beryllium oxide
source: pubchem-beo
where: Names and Identifiers > Record Title
- system: Name
code: Beryllia
source: materion-beo
where: Product description, first paragraph ("BeO (or beryllia)")
- system: Trade name
code: Thermalox 995
note: Materion grade name (99.5% BeO); its values are kept separate
source: materion-beo
where: Technical Details table, Thermalox 995 Properties
tags:
environments: []
stresses:
- extreme-heat
applications:
- thermal-control
- electronics-and-chips
properties:
- benchmark: density
label: Density, beryllium oxide (CRC Handbook via PubChem)
value: 3.01
unit: g/cu cm
scope: material
conditions:
grade: beryllium oxide, no grade or purity stated
temperature: 25 °C (printed beside the value)
method: Value from the CRC Handbook, 94th edition, as printed in the PubChem record
status: ground
source: pubchem-beo
where: Experimental Properties > Density, CRC Handbook p. 4-51; second entry "3.01 @25 °C"
- benchmark: density
label: Density, beryllium oxide (Frontiers review, Table 1)
value: 3.01
unit: g/cm3
scope: material
conditions:
grade: beryllium oxide as a neutron moderator; no grade stated
temperature: not stated
method: Table of moderator properties in an open-access review
status: ground
source: frontiers-beo-review
where: Table 1 (Moderator, Density column), BeO row
- benchmark: density
label: Theoretical density, beryllium oxide (American Beryllia)
value: 3.01
unit: g/cc
scope: material
conditions:
grade: unnamed beryllium oxide (vendor page does not name a grade)
temperature: not stated
method: Vendor comparison of theoretical density values, as printed
status: ground
source: americanberyllia-beo
where: Physical properties list, bullet on density (BeO 3.01 g/cc, Al2O3 4.00 g/cc, AlN 3.26 g/cc)
- benchmark: melting_point
label: Melting point, beryllium oxide (CRC Handbook via PubChem)
value: 2578
unit: °C
scope: material
conditions:
grade: beryllium oxide, no grade or purity stated
pressure: atmospheric (standard)
method: Value from the CRC Handbook, 94th edition, as printed in the Wikipedia infobox (which cites Haynes p. 4.51)
status: ground
source: wiki-beo
where: Infobox, Melting point 2,578 °C (CRC Handbook cited)
- benchmark: thermal_conductivity
label: Thermal conductivity, Thermalox 995 (Materion)
value: 285
unit: W/m°K
scope: material
conditions:
grade: Thermalox 995 (99.5% BeO, Materion)
temperature: not stated on the product page
method: Value from the Materion technical details table
status: ground
source: materion-beo
where: 'Technical Details, Thermalox 995 Properties (''Thermal Conductivity: 285 W/m°K'')'
- benchmark: thermal_conductivity
label: Thermal conductivity, unnamed beryllium oxide (American Beryllia)
value: 285
unit: W/mK
scope: material
conditions:
grade: unnamed beryllium oxide (vendor page does not name a grade)
temperature: room temperature (page text)
method: Vendor statement, as printed
status: ground
source: americanberyllia-beo
where: Thermal properties bullet, "thermal conductivity of Beryllium Oxide at Room Temperature is 285 W/mK"
- benchmark: flexural_strength
label: Flexural strength, Thermalox 995 (Materion)
value: 221
unit: Mpa
scope: material
conditions:
grade: Thermalox 995 (99.5% BeO, Materion)
temperature: not stated on the product page
method: Value from the Materion technical details table; test method not stated
status: ground
source: materion-beo
where: 'Technical Details, Thermalox 995 Properties (''Flexural Strength: 221 Mpa'')'
- benchmark: refractive_index
label: Refractive index, beryllia (American Beryllia)
value: 1.719
unit: '-'
scope: material
conditions:
grade: unnamed beryllium oxide
wavelength: not stated
temperature: not stated
method: Vendor optical properties list, as printed
status: ground
source: americanberyllia-beo
where: 'Selected Optical Properties of Beryllia, ''Refractive Index: 1.719'''
- benchmark: band_gap
label: Band gap, beryllium oxide (Wikipedia infobox)
value: 10.6
unit: eV
scope: material
conditions:
grade: beryllium oxide, wurtzite phase
temperature: not stated
method: Infobox value in Wikipedia; the source of the infobox figure is not given on the page read
status: ground
note: The vendor page gives a wurtzite phase band gap of 10.4 to 10.6 eV; the infobox value is the upper end of that range.
source: wiki-beo
where: Properties infobox, "Band gap 10.6 eV"
- benchmark: lattice_constant_a
label: Lattice constant a, beryllium oxide (wurtzite cell)
value: 2.6979
unit: Å
scope: material
conditions:
crystal: hexagonal wurtzite-type cell
temperature: not stated
method: Crystallographic value in the Wikipedia infobox, as printed
status: ground
source: wiki-beo
where: Structure infobox, LattConst_a
- benchmark: lattice_constant_c
label: Lattice constant c, beryllium oxide (wurtzite cell)
value: 4.3772
unit: Å
scope: material
conditions:
crystal: hexagonal wurtzite-type cell
temperature: not stated
method: Crystallographic value in the Wikipedia infobox, as printed
status: ground
source: wiki-beo
where: Structure infobox, LattConst_c
- benchmark: water_solubility
label: Solubility in water, beryllium oxide at 30 °C (CRC Handbook via PubChem)
value: 2
unit: ug/100 mL
scope: material
conditions:
solvent: water
temperature: 30 °C
method: Value from the CRC Handbook, 76th edition (1995 to 1996), as printed in the PubChem record; not a canonical property, so the name is a short snake_case name
status: ground
source: pubchem-beo
where: Experimental Properties > Solubility, CRC Handbook p. 4-44, entry "2 ug/100 mL in water at 30 °C"
- benchmark: abbe_number
label: Abbe number, beryllia (American Beryllia)
value: 93.25
unit: '-'
scope: material
conditions:
grade: unnamed beryllium oxide
wavelength: not stated
method: Vendor optical properties list, as printed ("Vd = 93.25")
status: ground
source: americanberyllia-beo
where: 'Selected Optical Properties of Beryllia, ''Abbe number: Vd = 93.25'''
corrosion:
- environment: Water
headline: Very low solubility in water
effect: The CRC Handbook figure in the PubChem record is 2 ug/100 mL at 30 °C. The PubChem record does not give a hydrolysis rate. Unlike aluminium nitride, no source read here says that water decomposes beryllium oxide.
rating: low
conditions:
medium: water
temperature: 30 °C
source: pubchem-beo
where: Experimental Properties > Solubility, CRC Handbook p. 4-44
- environment: Concentrated sulfuric acid and fused potassium hydroxide
headline: Soluble in hot strong acid and fused alkali
effect: The CRC Handbook entry in PubChem says beryllium oxide is soluble in concentrated sulfuric acid and in fused potassium hydroxide. No rate, temperature or concentration is printed.
rating: severe
conditions:
medium: concentrated sulfuric acid; fused potassium hydroxide
temperature: not stated
source: pubchem-beo
where: Experimental Properties > Solubility, CRC Handbook p. 4-44
- environment: Oxidizing chemicals
headline: More chemically stable than aluminium nitride in oxidizing environments
effect: Materion says BeO is more chemically stable than AlN ceramic in environments that contain oxidizing chemicals. No test data are given.
rating: low
source: materion-beo
where: Beryllium Oxide Ceramics Outperform Competitive Products' section
- environment: Oxygen and hydrogen at high temperature
headline: Very stable with O2 and H2 at 2000 °C
effect: The Frontiers review says BeO has a very stable performance with O2 and H2 even at a temperature of 2000 °C. The review gives no rate or test method.
rating: low
conditions:
atmosphere: oxygen and hydrogen
temperature: 2000 °C
source: frontiers-beo-review
where: Section on physical and chemical properties
risks:
hazards:
- text: PubChem aggregates 49 company reports from 7 ECHA C&L notifications for beryllium oxide. Its GHS hazard statements are H301, H315, H317, H319, H330, H335, H350i and H372, with signal word Danger. The statements include H330 (fatal if inhaled) and H350i (may cause cancer by inhalation).
ghs:
- H301
- H315
- H317
- H319
- H330
- H335
- H350i
- H372
source: pubchem-beo
where: Safety and Hazards > Hazards Identification > GHS Classification
- text: 'PubChem hazards summary: beryllium oxide is a severe skin, eye and respiratory tract irritant; dust or fume inhalation may cause chemical pneumonitis; repeated or prolonged exposure may cause chronic beryllium disease; and prolonged contact may cause beryllium sensitization.'
ghs: []
source: pubchem-beo
where: Safety and Hazards > Hazards Identification > Hazards Summary
- text: Wikipedia lists an oral LD50 of 15 mg/kg in mice and says beryllium oxide is carcinogenic in powdered form and may cause berylliosis, a chronic allergic-type lung disease.
ghs: []
source: wiki-beo
where: Infobox (LD50) and Safety section
failure_risks:
- mode: Airborne beryllium from machining or crushing fired parts
trigger: Machining, grinding or crushing of fired beryllium oxide that generates dust
consequence: Airborne beryllium dust, which is the main inhalation hazard in the material's handling. Wikipedia says clean breakage releases little dust, but crushing or grinding can pose a risk.
severity: high
source: wiki-beo
where: Safety section
side_effects: []
handling:
- text: OSHA sets the beryllium permissible exposure limit at 0.2 µg/m3 as an 8-hour time-weighted average and 2.0 µg/m3 as a 15-minute short-term exposure limit. The action level is 0.1 µg/m3 as an 8-hour TWA.
source: osha-beryllium-1910-1024
where: 29 CFR 1910.1024 paragraphs (c)(1), (c)(2) and (b), Action level definition
- text: Once fired into solid form, beryllium oxide is safe to handle if it is not machined to produce dust. Crushing or grinding poses a risk (Wikipedia).
source: wiki-beo
where: Safety section
- text: Keep beryllium oxide powder and dust out of the air. PubChem's hazards summary warns that dust or fume inhalation may cause chemical pneumonitis.
source: pubchem-beo
where: Safety and Hazards > Hazards Identification > Hazards Summary
mitigations: []
uses:
- application: electronics-and-chips
device: Aerospace electronics
example: Materion lists aerospace electronics among the applications of its beryllium oxide ceramics, along with laser systems, medical equipment and electronics manufacturing.
source: materion-beo
where: Benefits and Applications section
- application: electronics-and-chips
device: Microwave devices, vacuum tubes, gas lasers and magnetrons
example: Materion says its BeO powder is used to form critical thermally conductive components for high-performance semiconductor applications, microwave devices, vacuum tubes, gas lasers and magnetrons.
source: materion-beo
where: Beryllium Oxide Powder for Thermally Conductive Components section
- application: thermal-control
device: Heat sinks and spreaders for CPUs, lasers and power amplifiers
example: Wikipedia says beryllium oxide is used in heat sinks and spreaders that cool electronic devices, such as CPUs, lasers and power amplifiers, and that some power semiconductor packages use it between the chip and the mounting base.
source: wiki-beo
where: Uses section, Electronics paragraph
supply:
- subject: Beryllium (feedstock for beryllium oxide)
abundance: 'USGS: identified world resources of beryllium are more than 100,000 tons, and about 60% of them are in the United States.'
producers:
- country: United States
share_percent: 53.5
year: 2025
- country: Brazil
share_percent: 18.6
year: 2025
- country: China
share_percent: 17.9
year: 2025
- country: Nigeria
share_percent: 9.3
year: 2025
- country: Mozambique
share_percent: 0.7
year: 2025
critical_lists: []
recycling: 'USGS: recovered beryllium from new and old scrap may account for as much as 20% to 25% of total beryllium consumption.'
substitutes:
- 'USGS: aluminum nitride or boron nitride may be substituted for beryllium oxide.'
source: usgs-mcs2026-beryllium
where: 'World Mine Production and Reserves table, 2025e column (beryllium content, metric tons). Shares are calculated by Space Mushroom against the printed world total of 430 t: United States 230, Brazil 80, China 77, Nigeria 40, Mozambique 3. Recycling and Substitutes sections; World Resources paragraph.'
documents:
- title: PubChem PUG-View record, Beryllium Oxide (CID 14775)
type: database
url: https://pubchem.ncbi.nlm.nih.gov/rest/pug_view/data/compound/14775/JSON
year: 2026
- title: Materion, Beryllium Oxide Ceramics and Powder (product page with Thermalox 995 table)
type: datasheet
url: https://materion.com/products/technical-ceramics/beryllium-oxide-ceramics
- title: American Beryllia, Beryllium Oxide (vendor properties page)
type: datasheet
url: https://americanberyllia.com/beryllium-oxide
- title: BeO Utilization in Reactors for the Improvement of Extreme Reactor Environments - A Review (open access)
type: paper
url: https://www.frontiersin.org/articles/10.3389/fenrg.2021.669832/full
year: 2021
- title: USGS Mineral Commodity Summaries 2026, Beryllium
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-beryllium.pdf
year: 2026
- title: CIAAW Abridged Standard Atomic Weights 2024
type: database
url: https://www.ciaaw.org/abridged-atomic-weights.htm
year: 2024
- title: 29 CFR 1910.1024, Beryllium (OSHA general industry standard, text via Cornell LII)
type: standard
url: https://www.law.cornell.edu/cfr/text/29/1910.1024
gaps:
- Electrical resistivity is not entered. American Beryllia prints the bulk resistivity as 10 16 Ωcm, with the exponent lost from the text, so the number cannot be matched to the page.
- Coefficient of thermal expansion is not entered. American Beryllia prints 7.5 in./in./°C for 25 to 1000 °C with no 10 to the minus 6 exponent, so the unit as printed is not usable. No other source read gives a number.
- 'Dielectric constant: Materion says its four BeO grades (purity 99.5% to 99.7%) have a dielectric constant of 6.7 against 9.7 for AlN. This is a family figure with no frequency and no single grade, so it is not entered as a property.'
- Hardness, dielectric strength, specific heat and water absorption are not printed on any page read. The Materion Thermalox 995 density of 2.85 g/cm3 appeared only in a search snippet, not on a fetched page, so it is not entered.
- Flexural strength is given for one grade only (Thermalox 995, 221 MPa). No test method or temperature is printed.
- The Wikipedia thermal conductivity of 210 W/(m·K) is an unlabelled figure with no grade or temperature, so it is not entered. The Frontiers review gives a melting point of 2570 °C (Rothman, 1962), which differs from the CRC value of 2578 °C; the CRC value is used.
- Mouse oral LD50 of 15 mg/kg comes from the Wikipedia infobox, which cites an unnamed source. It is not in the PubChem record, so it is not entered as a property.
- 'Synthesis route: the calcining, dehydrating and metal-burning routes come from Wikipedia, and the calcination temperatures from the PubChem record. No manufacturer process description was read.'
- Critical-mineral listing for beryllium was not in the USGS chapter text read; the EU list was not checked.
- 'Trade names: only Thermalox 995 was found on the Materion page read. Other grades (for example BW3250 and Thermalox V) are not covered.'
- 'Space use: no flight or vacuum result was found. The Kilopower mention is a proposal in Wikipedia, not a flown use.'
- The OSHA page on osha.gov returned HTTP 403, so the exposure limits were read from the 29 CFR 1910.1024 text at Cornell LII instead.
- Failure-risk severity labels and corrosion ratings are assistant judgement; no fetched source ranks them.
- Lattice constants and band gap come from the Wikipedia infobox, which does not name its primary source.
sources:
pubchem-beo:
title: PubChem PUG-View record, Beryllium Oxide (CID 14775)
id: CID 14775; CAS 1304-56-9
url: https://pubchem.ncbi.nlm.nih.gov/rest/pug_view/data/compound/14775/JSON
year: 2026
kind: database
license: Public domain (NCBI), cited
wiki-beo:
title: Wikipedia, Beryllium oxide (used for composition, structure, uses and toxicity only)
url: https://en.wikipedia.org/wiki/Beryllium_oxide
kind: web
license: CC BY-SA 4.0, cited
materion-beo:
title: Materion, Beryllium Oxide Ceramics and Powder (product page)
url: https://materion.com/products/technical-ceramics/beryllium-oxide-ceramics
kind: datasheet
license: Manufacturer web page, cited
americanberyllia-beo:
title: American Beryllia, Beryllium Oxide (vendor properties page)
url: https://americanberyllia.com/beryllium-oxide
kind: datasheet
license: Manufacturer web page, cited
frontiers-beo-review:
title: BeO Utilization in Reactors for the Improvement of Extreme Reactor Environments - A Review
id: doi:10.3389/fenrg.2021.669832 (Frontiers in Energy Research)
url: https://www.frontiersin.org/articles/10.3389/fenrg.2021.669832/full
year: 2021
kind: paper
license: CC BY (Frontiers open access)
usgs-mcs2026-beryllium:
title: Mineral Commodity Summaries 2026, Beryllium
id: USGS MCS 2026, February 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-beryllium.pdf
year: 2026
kind: report
license: Public domain (USGS)
ciaaw-atomic-weights:
title: Commission on Isotopic Abundances and Atomic Weights, 2024 Abridged Standard Atomic Weights
url: https://www.ciaaw.org/abridged-atomic-weights.htm
year: 2024
kind: database
license: CIAAW reference table, cited
osha-beryllium-1910-1024:
title: 29 CFR 1910.1024, Beryllium (OSHA general industry standard)
url: https://www.law.cornell.edu/cfr/text/29/1910.1024
kind: standard
license: US federal regulation, public domain
license: CC-BY-4.0
updated: '2026-10-26'
review:
status: draft
method: assistant
checked_values: 13
unreachable: 1
caveats: 3
note: Values were read in this run from the PubChem record, the Materion and American Beryllia pages, the Frontiers review, the USGS chapter, the Wikipedia infobox, the CIAAW table and the OSHA standard text. Materion values are for Thermalox 995 only. The American Beryllia values name no grade. The osha.gov page returned HTTP 403 and was not used.
story:
recipe:
line: BeO is beryllium oxide, with one beryllium atom bonded to one oxygen atom per formula unit . CIAAW 2024 standard atomic weights are 9.0122 for beryllium and 15.999 for oxygen. Commercial BeO is made by calcining beryllium hydroxide, carbonate or sulfate. PubChem says practically all commercial BeO is calcined at 1000 °C or higher ('high-fired'), and beryllium sulfate is calcined at carefully controlled temperatures to tailor its properties. Wikipedia also lists dehydration of the hydroxide and burning of the metal in air, which gives some beryllium nitride.
parts:
- name: Beryllium
symbol: Be
atoms: 1
atomic_weight: 9.0122
role: Metal atom in each BeO formula unit
source: ciaaw-atomic-weights
where: 2024 Abridged Standard Atomic Weights, beryllium row (9.0122)
- name: Oxygen
symbol: O
atoms: 1
atomic_weight: 15.999
role: Oxide anion in each BeO formula unit
source: ciaaw-atomic-weights
where: 2024 Abridged Standard Atomic Weights, oxygen row (15.999)
risk_groups:
- title: For people
verdict: Toxic dust, a carcinogen by inhalation
lead: The hazard comes from dust, fume and mist. The fired solid is much less of a hazard, but PubChem's aggregate of ECHA reports classifies the compound as fatal if inhaled.
points:
- label: Inhalation
line: PubChem lists H330 (fatal if inhaled) and H350i (may cause cancer by inhalation), with H372 for organ damage from prolonged or repeated exposure.
- label: Chronic disease
line: PubChem says repeated or prolonged exposure may cause chronic beryllium disease. Wikipedia names berylliosis, a chronic allergic-type lung disease.
- label: Exposure limits
line: OSHA sets 0.2 µg/m3 as an 8-hour TWA and 2.0 µg/m3 as a 15-minute limit, with an action level of 0.1 µg/m3.
- title: Fired parts
lead: Once fired into a solid, the ceramic is safe to handle unless machining creates dust.
verdict: Dust control during machining
points:
- label: Machining
line: Wikipedia says crushing or grinding poses a risk, while clean breakage releases little dust.
- title: If the part gets wet
lead: Beryllium oxide is almost insoluble in water, and it dissolves only in strong acid or fused alkali.
verdict: Very low water solubility
points:
- label: Water
line: The CRC Handbook gives 2 ug/100 mL at 30 °C in water.
- label: Acid and alkali
line: It is soluble in concentrated sulfuric acid and in fused potassium hydroxide, according to the CRC Handbook.
- title: Hot oxidizing air
lead: Beryllium oxide is chemically stable in oxygen and hydrogen.
verdict: Stable to 2000 °C in O2 and H2
points:
- label: Stability
line: The Frontiers review says BeO performs very stably with O2 and H2 even at 2000 °C. Materion says it is more chemically stable than AlN in oxidizing environments.
why: 'Beryllium oxide combines high thermal conductivity with electrical insulation. Materion says it is the second highest thermal conductivity of any electrical insulator after diamond, nine times that of alumina, and up to 80 percent higher than aluminium nitride. The Frontiers review adds high-temperature radiation stability and high strength. The same properties make it attractive in electronics and reactors. The price is the toxicity of beryllium: the grade must be chosen with the dust hazard in mind.'
uses:
- where: Aerospace and defense electronics
line: Materion lists aerospace electronics as an application of its beryllium oxide ceramics. It also lists microwave devices, vacuum tubes, gas lasers and magnetrons among the uses of its BeO powder.
- where: Heat spreaders and power packages
line: Wikipedia says BeO is used in heat sinks and spreaders for CPUs, lasers and power amplifiers, and in some power semiconductor packages between the chip and the mounting base.
- where: Reactors and proposed space power
line: The Frontiers review describes BeO as a candidate reflector and moderator in reactors. Wikipedia says it has been proposed as a moderator for naval gas-cooled reactors and for NASA's Kilopower reactor for space applications. These are reactor and proposal uses, not flown ones.
can_do:
- label: Carry heat away
benchmark: thermal_conductivity
line: Materion gives 285 W/m°K for Thermalox 995 (99.5% BeO). American Beryllia gives 285 W/mK at room temperature for an unnamed grade. Both are in the properties table.
- label: Insulate electrically
benchmark: electrical_resistivity
line: American Beryllia calls BeO an electrical insulator with bulk resistivity on the order of 10 16 Ωcm. The exponent is lost in the printed text, so no number is entered.
- label: Stay strong
benchmark: flexural_strength
line: Materion gives 221 MPa flexural strength for Thermalox 995. American Beryllia says BeO strength is normally lower than that of alumina.
compare: Materion says BeO is nine times more thermally conductive than alumina and up to 80 percent more than aluminium nitride, and that it is more chemically stable than AlN in oxidizing environments. Its density is 3.01 g/cm3 against 4.00 g/cm3 for alumina and 3.26 g/cm3 for AlN, both from American Beryllia. Its melting point of 2578 °C is from the CRC Handbook. The compared numbers come from different sources and grades, so they should be read as direction, not as exact ratios.
compare_rows:
- label: Thermal conductivity
benchmark: thermal_conductivity
- label: Flexural strength
benchmark: flexural_strength
- label: Density
benchmark: density
handling:
- Keep dust and fume out of the air. OSHA's limits are 0.2 µg/m3 as an 8-hour TWA and 2.0 µg/m3 over 15 minutes, with an action level of 0.1 µg/m3.
- Do not machine, grind or crush fired parts without dust control, because the dust carries the beryllium hazard.
- Treat powder and dust as toxic beryllium material. PubChem warns that dust or fume inhalation may cause chemical pneumonitis.
good_for:
- Heat spreaders and packages that must move heat while staying electrically insulating, as in aerospace electronics and power packages.
- Microwave, vacuum-tube, magnetron and gas-laser parts, as Materion lists them.
watch_out:
- Beryllium dust is toxic and carcinogenic by inhalation. Handling needs dust control at every step.
- Grade data differ. The Materion values are for Thermalox 995 only, and the American Beryllia values name no grade.
- Electrical resistivity and thermal expansion are not entered, because the printed values lost their exponents.
verdict: Beryllium oxide is one of the best electrical insulators for conducting heat, and it suits electronics where aluminium nitride is not enough. Its toxicity is serious, so it suits only applications where the dust hazard can be controlled, and the grade should be checked on its own data sheet.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
| # | Source | Type | Year | Used for |
|---|---|---|---|---|
| PubChem PUG-View record, Beryllium Oxide (CID 14775) | database | 2026 | 8 values | |
| Wikipedia, Beryllium oxide (used for composition, structure, uses and toxicity only) | web | 8 values | ||
| Materion, Beryllium Oxide Ceramics and Powder (product page) | datasheet | 5 values | ||
| American Beryllia, Beryllium Oxide (vendor properties page) | datasheet | 4 values | ||
| BeO Utilization in Reactors for the Improvement of Extreme Reactor Environments - A Review | paper | 2021 | 2 values | |
| Mineral Commodity Summaries 2026, Beryllium | report | 2026 | 1 value | |
| Commission on Isotopic Abundances and Atomic Weights, 2024 Abridged Standard Atomic Weights | database | 2024 | 0 values | |
| 29 CFR 1910.1024, Beryllium (OSHA general industry standard) | standard | 1 value |