Chromium carbide (Cr3C2) Cr3C2

Cr3C2 · CAS 12012-35-0 · orthorhombic, Pnma

Chromium carbide (Cr3C2) is a hard, grey-black ceramic powder with an orthorhombic crystal structure.

8 sources · Updated 2026-11-01 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Hardness

2280 kg/mm2

Stiffness

423.7 GPa

Density

6.68 g/cm3

Melting point

1890 °C

Recipe, share of the weight

  • Cr not statedChromium
  • C not statedCarbon

Best for

Hard wear-resistant coatings and tool or mould parts, where the powder is used for thermal spray (the supplier FAQ lists thermal spray coatings for wear protection)

Weakest at

Oxidation at high temperature: the sources read make only a general claim and give no oxidation onset, and the supplier SDS warns that moisture releases methane

Risk at a glance

  • People None found. Harmful by inhalation or ingestion, per PubChem
  • If it fails Moderate. Methane release on contact with moisture
  • Corrosion Moderate. The supplier safety data sheet says Cr3C2 reacts with moisture to form methane gas.

Quick facts: Cr3C2

Key properties of Cr3C2
PropertyValueBasis
Density6.68 g/cm³2 sourced values across conditions
Young's modulus424 GPa1 sourced value
Melting point1,890 to 1,980 °C2 sourced values across conditions

What is the density of Chromium carbide (Cr3C2)?

Chromium carbide (Cr3C2) has a density of 6.68 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the melting point of Chromium carbide (Cr3C2)?

Chromium carbide (Cr3C2) has a melting point of 1,890 to 1,980 °C. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the Young's modulus of Chromium carbide (Cr3C2)?

Chromium carbide (Cr3C2) has a Young's modulus of 424 GPa. The source and test conditions are listed in the properties table on this page.

What is Chromium carbide (Cr3C2) used for?

Uses recorded in the sources include Cutting tools, drilling bits and wear parts; Coatings for turbine components and thermal spray; Grain refinement agent in cemented carbide.

Why it exists

Chromium carbide (Cr3C2) is a hard ceramic powder made of chromium and carbon. Its supplier calls it a hard, durable coating material for protection against wear, corrosion and high temperatures, and lists it for cutting tools, drilling bits, wear-resistant parts and molds. It is supplied as a grey-black powder, and the supplier names thermal spray as a use. Its hardness and stiffness are the main reasons it is used. Its melting values disagree between two supplier sheets, and no measured high-temperature oxidation figure was found in the sources read.

Where it's used

Cutting tools, drilling bits and molds

The supplier says the powder is commonly used in cutting tools, drilling bits, wear-resistant parts and molds.

Turbine coatings and thermal spray

The supplier lists coatings for turbine components, and its FAQ names thermal spray coatings for wear protection. These are supplier statements; no field test was found.

Grain refiner in cemented carbide

The 2022 paper says chromium carbides can be used as grain refinement agents in cemented carbide and other wear-resistance components.

Recipe

Cr3C2

Chromium carbide (Cr3C2) is a binary compound of chromium and carbon with an orthorhombic crystal structure. The 2022 paper lists Cr3C2 among the stable binary chromium carbides at ambient pressure, alongside the other two carbides it studies. Wikipedia describes two production routes: mechanical alloying of chromium and graphite followed by hot isostatic pressing under argon, and a self-propagating exothermic reaction that uses chromium oxide, aluminum and graphite.

What Cr3C2 is made of
IngredientShare of the weightWhat it does
Chromium Cr not stated The metal in the compound. The paper says metallic bonding runs between neighbouring chromium atoms, and the chromium-carbon bonds give the hardness it reports.
Carbon C not stated Bonds covalently to chromium in the paper's bonding analysis; the Cr-C bond strength is the basis of its theoretical hardness.

Weight shares are as printed in the sources.

What it can do

Hardness

2280 kg/mm2

measured

The supplier gives a microhardness of 2280 kg/mm2 with no test method stated. The paper quotes a Vickers hardness of 15.1 to 18.9 GPa for Cr3C2 from earlier studies, and calculates a theoretical hardness of 18.2 GPa.

Stiffness

423.7 GPa

worked out from the formula

The 2022 paper calculates a Young's modulus of 423.7 GPa and a Poisson's ratio of 0.28 at zero pressure. These are calculated values, not measurements.

Density

6.68 g/cm3

measured

Two suppliers print a density of 6.68: one in gm/cc in a 2012 safety data sheet, and one in g/cm3 on a product page.

Melting point

1890 °C

measured

The supplier product page gives a melting point of 1890 °C, and its 2012 safety data sheet gives 1980.0 °C. The two supplier values differ, and neither prints a method.

How it compares

Chromium carbide sits among the hard refractory carbides. Its supplier microhardness of 2280 kg/mm2 and its calculated theoretical hardness of 18.2 GPa are both high. The sources read here give no direct side-by-side comparison with the other carbides in this collection. The two supplier melting values, 1890 °C and 1980.0 °C, disagree and are shown side by side. Oxidation in air is not quantified in the sources read. The hardness values are not directly comparable: the supplier figure has no test method, and the paper's figures are calculated or quoted from other studies.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.

Benchmarks
MeasurementCr3C2Al4C3B4CHfCMAXMo2CNbCSiCTaCTiCZrC
Thermal behavior and safety
melting pointSupplier specification value1890 °C2100 °Cno data3890 °C1663 K2687 °C3608 °Cno data3880 °C3290 K3532 °C
Melting point, 2012 supplier SDS (conflicts with the product page)Manufacturer SDS value1980 °C22100 °Cno data3890 °C1663 K2687 °C3608 °Cno data3880 °C3290 K3532 °C
Physical and electrical
Specific gravity printed in the supplier SDS6.68 gm/cc12.36 g/cm³2.5 gm/cm³12.2 g/cm³4.47 g/cm³9.18 g/cm³7.82 g/cm³3.08 g/cm³14.5 g/cm³4.93 g/cm³6.73 g/cm³
Density printed on a second supplier pageSupplier specification value6.68 g/cm³2.36 g/cm³2.5 gm/cm³12.2 g/cm³4.47 g/cm³9.18 g/cm³7.82 g/cm³3.08 g/cm³14.5 g/cm³4.93 g/cm³6.73 g/cm³
Microhardness, supplier specification (test not stated)Supplier specification value2280 kg/mm2no datano datano data4 to 6 GPano datano datano data22.8 GPano datano data
Theoretical hardness, first-principles, zero pressure18.2 GPa4no datano datano datano datano datano datano datano datano datano data
Vickers hardness range for Cr3C2 quoted from earlier measurements15.1 to 18.9 GPa5no datano datano data4 to 6 GPano datano datano data22.8 GPano datano data
Other measurements
boiling pointManufacturer SDS value3800 °C3no datano datano datano datano datano datano data5500 °Cno datano data
bulk modulus314.7 GPa6no datano datano data135 GPano datano datano datano data268 GPano data
shear modulus166.1 GPa7no datano datano data113 GPano datano datano datano data181 GPano data
Young's modulus, calculated423.7 GPa8no data440 GPano data265 GPano datano data395 GPa537 GPa444 GPa435 GPa
poissons ratio0.28 -9no data0.18 -no datano datano datano datano datano datano data0.18 unitless
Lattice parameter a, calculated at zero pressure5.48 Å10no datano datano datano datano datano datano datano datano datano data
Lattice parameter b, calculated at zero pressureCalculated in a first-principles study2.79 Åno datano datano datano datano datano datano datano datano datano data
Lattice parameter c, calculated at zero pressureCalculated in a first-principles study11.47 Åno datano datano datano datano datano datano datano datano datano data

Why choose it, and why not

Good for

  • Hard wear parts. The supplier says it is used in cutting tools, drilling bits, wear-resistant parts and molds.
  • Thermal spray coatings. The supplier FAQ lists thermal spray coatings for wear protection.
  • Stiff hard coatings in design studies. The paper's calculated Young's modulus of 423.7 GPa is a theoretical value.

Watch out for

  • Moisture reaction. The SDS says the powder reacts with moisture to form methane gas.
  • Conflicting melting values. The product page gives 1890 °C and the 2012 SDS gives 1980.0 °C.
  • Oxidation in air is not quantified. The paper says 'outstanding oxidation resistance under a high temperature environment' without a figure.
  • Crystal structure is printed two ways. Two supplier pages say Rhombohedral; the paper gives orthorhombic, space group Pnma.

Chromium carbide is a hard wear-resistant powder for coatings and tool parts. Its hardness data are stronger than its melting and oxidation data, and the supplier figures should be checked against a current SDS before use.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Specific gravity printed in the supplier SDSManufacturer SDS value (Stanford Advanced Materials, version 2.0, revision 5 September 2012)basis printed as Specific Gravity (water=1); no temperature, powder form or test method printedunit in source gm/cc—
2Melting point, 2012 supplier SDS (conflicts with the product page)—basis printed as Melting Point: 1980.0 C in the SDS physical characteristics; no test methodThis value disagrees with the 1890 °C product-page value. Both are kept side by side; neither is backed by a measurement method in the sources read.
3boiling point—basis printed as Boiling Point: 3800.0 C in the SDS physical characteristics; no pressure or method printedNot checked against any other source read in this run; kept only as printed.
4Theoretical hardness, first-principles, zero pressureCalculated in a first-principles study (CASTEP, density functional theory); a computed value, not a measurementbasis calculated at zero applied pressure; the table column is headed H Gaopressure 0 GPa—
5Vickers hardness range for Cr3C2 quoted from earlier measurementsRange quoted in the paper from other research groupsbasis range across earlier studies quoted by the paper, which says reported values differ with sample preparation and measurement protocol; load not given—
6bulk modulusCalculated in a first-principles study (CASTEP, density functional theory)basis zero pressure; Voigt-Reuss-Hill average of calculated elastic constants—
7shear modulusCalculated in a first-principles study (CASTEP, density functional theory)basis zero pressure; Voigt-Reuss-Hill average of calculated elastic constants—
8Young's modulus, calculatedCalculated in a first-principles study (CASTEP, density functional theory)basis zero pressure; Voigt-Reuss-Hill average of calculated elastic constants—
9poissons ratioCalculated in a first-principles study (CASTEP, density functional theory)basis zero pressure; calculated from the Voigt-Reuss-Hill averages—
10Lattice parameter a, calculated at zero pressureCalculated in a first-principles study; the table lists experimental values beside it, which are not used herebasis zero pressure, orthorhombic cell—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Moisture and water contact moderate The supplier safety data sheet says Cr3C2 reacts with moisture to form methane gas.1
Strong oxidizing agents, acids and bases low The supplier SDS lists strong oxidizing agents, acids and bases as materials to avoid.2
High-temperature air not rated The 2022 paper describes outstanding oxidation resistance at high temperature, without a figure.3
Corrosion details
#EnvironmentDetailsTest conditions
1 Moisture and water contact The 2012 SDS states that the powder reacts with moisture to form methane gas, and it lists moisture among the materials to avoid. The sheet gives no reaction rate, temperature or test. basis supplier statement, no test conditions
2 Strong oxidizing agents, acids and bases The SDS gives this as an incompatibility statement without concentrations, times or test results. basis incompatibility list, no test data
3 High-temperature air The paper's introduction describes 'outstanding oxidation resistance under a high temperature environment' for the binary chromium carbides. It gives no oxidation onset temperature, exposure time or test method, so this is a general statement only. basis general statement in the introduction; no test

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

PubChem's hazards summary says the material may be harmful after ingestion, inhalation or skin contact, and may damage eyes. The supplier SDS calls chromium a confirmed human carcinogen. These are supplier and database summaries, not incident records.

Summary
PubChem's hazards summary reads 'May be harmful after ingestion, inhalation, or skin contact; May damage eyes'.
Carcinogen labels differ
The 2012 SDS calls chromium a 'Confirmed human carcinogen'. PubChem's carcinogen classification reads '3, not classifiable as to its carcinogenicity to humans.'
Flammability
The supplier product page lists the hazard statement 'Flammable solid' with the signal word 'Warning'.

If the powder is heated or burns

These statements come from supplier sheets and database summaries, not from field incidents.

Fire
The SDS says the material 'may emit toxic fumes if involved in a fire', and it calls for full face, self-contained breathing apparatus for firefighters.
Oxidized chromium
PubChem says trivalent chromium 'may be oxidized to hexavalent chromium, a known carcinogen'.

Handling and storage

Moisture
The SDS says the powder 'reacts with moisture to form methane gas'. It asks for storage in a cool, dry area in a tightly sealed container, under an inert gas such as argon.
Exposure limits
PubChem prints '0.5 [mg/m3], as Cr' for both the PEL and the TLV. The SDS prints '0.5 mg/m3' and '1 mg/m3' under the headings ACGIH-TLV and OSHA PEL.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Methane release on contact with moisturemoderate severityContact with moisture or waterThe SDS says the powder reacts with moisture to form methane gas.

Side effects on surrounding parts

Side effects on surrounding parts
AffectsEffect
Firefighters and people near a fireThe SDS says 'Chromium carbide may emit toxic fumes if involved in a fire'.
Workers handling heated or oxidized materialPubChem notes that trivalent chromium 'may be oxidized to hexavalent chromium, a known carcinogen'.

Handling and storage

  • Store in a cool, dry area, in a tightly sealed container, under an inert gas such as argon, as the SDS directs.
  • Keep the powder away from moisture, strong oxidizing agents, acids and bases, which the SDS lists as materials to avoid.
  • Take care not to raise dust, and use a NIOSH-approved dust respirator where the SDS requires it.
  • PubChem prints the PEL and the TLV as '0.5 [mg/m3], as Cr'. The SDS prints '0.5 mg/m3' and '1 mg/m3' under the headings ACGIH-TLV and OSHA PEL, so the two sources do not agree on the PEL.

Supply and geography

How common the raw materials are and where they come from.

Chromium (the metal in Cr3C2; the carbon supply is not covered by any source read in this run)

Top producers (2025)
South Africa 45.1%, Turkey 17.6%, Kazakhstan 13.7%, India 5.9%
Critical mineral lists
US: listed
Recycling
USGS: 'In 2025, recycled chromium (contained in reported stainless-steel scrap receipts) accounted for 21% of apparent consumption.'
Substitutes
USGS: 'Chromium has no substitute in stainless steel, the leading end use, or in superalloys, the major strategic end use.'

Updated