Chromium carbide (Cr3C2) Cr3C2
Cr3C2 · CAS 12012-35-0 · orthorhombic, Pnma
Chromium carbide (Cr3C2) is a hard, grey-black ceramic powder with an orthorhombic crystal structure.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Hardness
2280 kg/mm2
Stiffness
423.7 GPa
Density
6.68 g/cm3
Melting point
1890 °C
Recipe, share of the weight
- Cr not statedChromium
- C not statedCarbon
Best for
Hard wear-resistant coatings and tool or mould parts, where the powder is used for thermal spray (the supplier FAQ lists thermal spray coatings for wear protection)
Weakest at
Oxidation at high temperature: the sources read make only a general claim and give no oxidation onset, and the supplier SDS warns that moisture releases methane
Risk at a glance
- People None found. Harmful by inhalation or ingestion, per PubChem
- If it fails Moderate. Methane release on contact with moisture
- Corrosion Moderate. The supplier safety data sheet says Cr3C2 reacts with moisture to form methane gas.
Quick facts: Cr3C2
| Property | Value | Basis |
|---|---|---|
| Density | 6.68 g/cm³ | 2 sourced values across conditions |
| Young's modulus | 424 GPa | 1 sourced value |
| Melting point | 1,890 to 1,980 °C | 2 sourced values across conditions |
What is the density of Chromium carbide (Cr3C2)?
Chromium carbide (Cr3C2) has a density of 6.68 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the melting point of Chromium carbide (Cr3C2)?
Chromium carbide (Cr3C2) has a melting point of 1,890 to 1,980 °C. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the Young's modulus of Chromium carbide (Cr3C2)?
Chromium carbide (Cr3C2) has a Young's modulus of 424 GPa. The source and test conditions are listed in the properties table on this page.
What is Chromium carbide (Cr3C2) used for?
Uses recorded in the sources include Cutting tools, drilling bits and wear parts; Coatings for turbine components and thermal spray; Grain refinement agent in cemented carbide.
Why it exists
Chromium carbide (Cr3C2) is a hard ceramic powder made of chromium and carbon. Its supplier calls it a hard, durable coating material for protection against wear, corrosion and high temperatures, and lists it for cutting tools, drilling bits, wear-resistant parts and molds. It is supplied as a grey-black powder, and the supplier names thermal spray as a use. Its hardness and stiffness are the main reasons it is used. Its melting values disagree between two supplier sheets, and no measured high-temperature oxidation figure was found in the sources read.
Where it's used
Cutting tools, drilling bits and molds
The supplier says the powder is commonly used in cutting tools, drilling bits, wear-resistant parts and molds.
Turbine coatings and thermal spray
The supplier lists coatings for turbine components, and its FAQ names thermal spray coatings for wear protection. These are supplier statements; no field test was found.
Grain refiner in cemented carbide
The 2022 paper says chromium carbides can be used as grain refinement agents in cemented carbide and other wear-resistance components.
Recipe
Cr3C2
Chromium carbide (Cr3C2) is a binary compound of chromium and carbon with an orthorhombic crystal structure. The 2022 paper lists Cr3C2 among the stable binary chromium carbides at ambient pressure, alongside the other two carbides it studies. Wikipedia describes two production routes: mechanical alloying of chromium and graphite followed by hot isostatic pressing under argon, and a self-propagating exothermic reaction that uses chromium oxide, aluminum and graphite.
| Ingredient | Share of the weight | What it does |
|---|---|---|
| Chromium Cr | not stated | The metal in the compound. The paper says metallic bonding runs between neighbouring chromium atoms, and the chromium-carbon bonds give the hardness it reports. |
| Carbon C | not stated | Bonds covalently to chromium in the paper's bonding analysis; the Cr-C bond strength is the basis of its theoretical hardness. |
Weight shares are as printed in the sources.
What it can do
Hardness
2280 kg/mm2
measured
The supplier gives a microhardness of 2280 kg/mm2 with no test method stated. The paper quotes a Vickers hardness of 15.1 to 18.9 GPa for Cr3C2 from earlier studies, and calculates a theoretical hardness of 18.2 GPa.
Stiffness
423.7 GPa
worked out from the formula
The 2022 paper calculates a Young's modulus of 423.7 GPa and a Poisson's ratio of 0.28 at zero pressure. These are calculated values, not measurements.
Density
6.68 g/cm3
measured
Two suppliers print a density of 6.68: one in gm/cc in a 2012 safety data sheet, and one in g/cm3 on a product page.
Melting point
1890 °C
measured
The supplier product page gives a melting point of 1890 °C, and its 2012 safety data sheet gives 1980.0 °C. The two supplier values differ, and neither prints a method.
How it compares
Chromium carbide sits among the hard refractory carbides. Its supplier microhardness of 2280 kg/mm2 and its calculated theoretical hardness of 18.2 GPa are both high. The sources read here give no direct side-by-side comparison with the other carbides in this collection. The two supplier melting values, 1890 °C and 1980.0 °C, disagree and are shown side by side. Oxidation in air is not quantified in the sources read. The hardness values are not directly comparable: the supplier figure has no test method, and the paper's figures are calculated or quoted from other studies.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.
| Measurement | Cr3C2 | Al4C3 | B4C | HfC | MAX | Mo2C | NbC | SiC | TaC | TiC | ZrC |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Thermal behavior and safety | |||||||||||
| melting pointSupplier specification value | 1890 °C | 2100 °C | no data | 3890 °C | 1663 K | 2687 °C | 3608 °C | no data | 3880 °C | 3290 K | 3532 °C |
| Melting point, 2012 supplier SDS (conflicts with the product page)Manufacturer SDS value | 1980 °C2 | 2100 °C | no data | 3890 °C | 1663 K | 2687 °C | 3608 °C | no data | 3880 °C | 3290 K | 3532 °C |
| Physical and electrical | |||||||||||
| Specific gravity printed in the supplier SDS | 6.68 gm/cc1 | 2.36 g/cm³ | 2.5 gm/cm³ | 12.2 g/cm³ | 4.47 g/cm³ | 9.18 g/cm³ | 7.82 g/cm³ | 3.08 g/cm³ | 14.5 g/cm³ | 4.93 g/cm³ | 6.73 g/cm³ |
| Density printed on a second supplier pageSupplier specification value | 6.68 g/cm³ | 2.36 g/cm³ | 2.5 gm/cm³ | 12.2 g/cm³ | 4.47 g/cm³ | 9.18 g/cm³ | 7.82 g/cm³ | 3.08 g/cm³ | 14.5 g/cm³ | 4.93 g/cm³ | 6.73 g/cm³ |
| Microhardness, supplier specification (test not stated)Supplier specification value | 2280 kg/mm2 | no data | no data | no data | 4 to 6 GPa | no data | no data | no data | 22.8 GPa | no data | no data |
| Theoretical hardness, first-principles, zero pressure | 18.2 GPa4 | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
| Vickers hardness range for Cr3C2 quoted from earlier measurements | 15.1 to 18.9 GPa5 | no data | no data | no data | 4 to 6 GPa | no data | no data | no data | 22.8 GPa | no data | no data |
| Other measurements | |||||||||||
| boiling pointManufacturer SDS value | 3800 °C3 | no data | no data | no data | no data | no data | no data | no data | 5500 °C | no data | no data |
| bulk modulus | 314.7 GPa6 | no data | no data | no data | 135 GPa | no data | no data | no data | no data | 268 GPa | no data |
| shear modulus | 166.1 GPa7 | no data | no data | no data | 113 GPa | no data | no data | no data | no data | 181 GPa | no data |
| Young's modulus, calculated | 423.7 GPa8 | no data | 440 GPa | no data | 265 GPa | no data | no data | 395 GPa | 537 GPa | 444 GPa | 435 GPa |
| poissons ratio | 0.28 -9 | no data | 0.18 - | no data | no data | no data | no data | no data | no data | no data | 0.18 unitless |
| Lattice parameter a, calculated at zero pressure | 5.48 Å10 | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
| Lattice parameter b, calculated at zero pressureCalculated in a first-principles study | 2.79 Å | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
| Lattice parameter c, calculated at zero pressureCalculated in a first-principles study | 11.47 Å | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
Why choose it, and why not
Good for
- Hard wear parts. The supplier says it is used in cutting tools, drilling bits, wear-resistant parts and molds.
- Thermal spray coatings. The supplier FAQ lists thermal spray coatings for wear protection.
- Stiff hard coatings in design studies. The paper's calculated Young's modulus of 423.7 GPa is a theoretical value.
Watch out for
- Moisture reaction. The SDS says the powder reacts with moisture to form methane gas.
- Conflicting melting values. The product page gives 1890 °C and the 2012 SDS gives 1980.0 °C.
- Oxidation in air is not quantified. The paper says 'outstanding oxidation resistance under a high temperature environment' without a figure.
- Crystal structure is printed two ways. Two supplier pages say Rhombohedral; the paper gives orthorhombic, space group Pnma.
Chromium carbide is a hard wear-resistant powder for coatings and tool parts. Its hardness data are stronger than its melting and oxidation data, and the supplier figures should be checked against a current SDS before use.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Specific gravity printed in the supplier SDS | Manufacturer SDS value (Stanford Advanced Materials, version 2.0, revision 5 September 2012) | basis printed as Specific Gravity (water=1); no temperature, powder form or test method printedunit in source gm/cc | — |
| 2 | Melting point, 2012 supplier SDS (conflicts with the product page) | — | basis printed as Melting Point: 1980.0 C in the SDS physical characteristics; no test method | This value disagrees with the 1890 °C product-page value. Both are kept side by side; neither is backed by a measurement method in the sources read. |
| 3 | boiling point | — | basis printed as Boiling Point: 3800.0 C in the SDS physical characteristics; no pressure or method printed | Not checked against any other source read in this run; kept only as printed. |
| 4 | Theoretical hardness, first-principles, zero pressure | Calculated in a first-principles study (CASTEP, density functional theory); a computed value, not a measurement | basis calculated at zero applied pressure; the table column is headed H Gaopressure 0 GPa | — |
| 5 | Vickers hardness range for Cr3C2 quoted from earlier measurements | Range quoted in the paper from other research groups | basis range across earlier studies quoted by the paper, which says reported values differ with sample preparation and measurement protocol; load not given | — |
| 6 | bulk modulus | Calculated in a first-principles study (CASTEP, density functional theory) | basis zero pressure; Voigt-Reuss-Hill average of calculated elastic constants | — |
| 7 | shear modulus | Calculated in a first-principles study (CASTEP, density functional theory) | basis zero pressure; Voigt-Reuss-Hill average of calculated elastic constants | — |
| 8 | Young's modulus, calculated | Calculated in a first-principles study (CASTEP, density functional theory) | basis zero pressure; Voigt-Reuss-Hill average of calculated elastic constants | — |
| 9 | poissons ratio | Calculated in a first-principles study (CASTEP, density functional theory) | basis zero pressure; calculated from the Voigt-Reuss-Hill averages | — |
| 10 | Lattice parameter a, calculated at zero pressure | Calculated in a first-principles study; the table lists experimental values beside it, which are not used here | basis zero pressure, orthorhombic cell | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Moisture and water contact | moderate | The supplier safety data sheet says Cr3C2 reacts with moisture to form methane gas.1 |
| Strong oxidizing agents, acids and bases | low | The supplier SDS lists strong oxidizing agents, acids and bases as materials to avoid.2 |
| High-temperature air | not rated | The 2022 paper describes outstanding oxidation resistance at high temperature, without a figure.3 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Moisture and water contact | The 2012 SDS states that the powder reacts with moisture to form methane gas, and it lists moisture among the materials to avoid. The sheet gives no reaction rate, temperature or test. | basis supplier statement, no test conditions |
| 2 | Strong oxidizing agents, acids and bases | The SDS gives this as an incompatibility statement without concentrations, times or test results. | basis incompatibility list, no test data |
| 3 | High-temperature air | The paper's introduction describes 'outstanding oxidation resistance under a high temperature environment' for the binary chromium carbides. It gives no oxidation onset temperature, exposure time or test method, so this is a general statement only. | basis general statement in the introduction; no test |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
PubChem's hazards summary says the material may be harmful after ingestion, inhalation or skin contact, and may damage eyes. The supplier SDS calls chromium a confirmed human carcinogen. These are supplier and database summaries, not incident records.
- Summary
- PubChem's hazards summary reads 'May be harmful after ingestion, inhalation, or skin contact; May damage eyes'.
- Carcinogen labels differ
- The 2012 SDS calls chromium a 'Confirmed human carcinogen'. PubChem's carcinogen classification reads '3, not classifiable as to its carcinogenicity to humans.'
- Flammability
- The supplier product page lists the hazard statement 'Flammable solid' with the signal word 'Warning'.
If the powder is heated or burns
These statements come from supplier sheets and database summaries, not from field incidents.
- Fire
- The SDS says the material 'may emit toxic fumes if involved in a fire', and it calls for full face, self-contained breathing apparatus for firefighters.
- Oxidized chromium
- PubChem says trivalent chromium 'may be oxidized to hexavalent chromium, a known carcinogen'.
Handling and storage
- Moisture
- The SDS says the powder 'reacts with moisture to form methane gas'. It asks for storage in a cool, dry area in a tightly sealed container, under an inert gas such as argon.
- Exposure limits
- PubChem prints '0.5 [mg/m3], as Cr' for both the PEL and the TLV. The SDS prints '0.5 mg/m3' and '1 mg/m3' under the headings ACGIH-TLV and OSHA PEL.
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Methane release on contact with moisturemoderate severity | Contact with moisture or waterThe SDS says the powder reacts with moisture to form methane gas. |
Side effects on surrounding parts
| Affects | Effect |
|---|---|
| Firefighters and people near a fire | The SDS says 'Chromium carbide may emit toxic fumes if involved in a fire'. |
| Workers handling heated or oxidized material | PubChem notes that trivalent chromium 'may be oxidized to hexavalent chromium, a known carcinogen'. |
Handling and storage
- Store in a cool, dry area, in a tightly sealed container, under an inert gas such as argon, as the SDS directs.
- Keep the powder away from moisture, strong oxidizing agents, acids and bases, which the SDS lists as materials to avoid.
- Take care not to raise dust, and use a NIOSH-approved dust respirator where the SDS requires it.
- PubChem prints the PEL and the TLV as '0.5 [mg/m3], as Cr'. The SDS prints '0.5 mg/m3' and '1 mg/m3' under the headings ACGIH-TLV and OSHA PEL, so the two sources do not agree on the PEL.
Supply and geography
How common the raw materials are and where they come from.
Chromium (the metal in Cr3C2; the carbon supply is not covered by any source read in this run)
- Top producers (2025)
- South Africa 45.1%, Turkey 17.6%, Kazakhstan 13.7%, India 5.9%
- Critical mineral lists
- US: listed
- Recycling
- USGS: 'In 2025, recycled chromium (contained in reported stainless-steel scrap receipts) accounted for 21% of apparent consumption.'
- Substitutes
- USGS: 'Chromium has no substitute in stainless steel, the leading end use, or in superalloys, the major strategic end use.'
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
Show the full YAML
spore: profile
id: chromium-carbide
spore_version: 0.2
family: carbide-nitride-boride-ceramics
name: Chromium carbide (Cr3C2)
abbreviation: Cr3C2
role: hard grey-black carbide powder for thermal-spray wear coatings, cutting tools and wear parts
category: ceramics
type: carbides
summary: |
Chromium carbide (Cr3C2) is a hard, grey-black ceramic powder with an orthorhombic crystal structure. Stanford Advanced Materials gives a melting point of 1890 °C and a microhardness of 2280 kg/mm2 for its Cr3C2 powder, with no test method stated. Its 2012 safety data sheet gives a specific gravity of 6.68 gm/cc and a melting point of 1980.0 °C, so the two supplier melting values disagree. A 2022 first-principles study calculates a Young's modulus of 423.7 GPa and a theoretical hardness of 18.2 GPa for Cr3C2; these are calculated values, not measurements.
best_for: Hard wear-resistant coatings and tool or mould parts, where the powder is used for thermal spray (the supplier FAQ lists thermal spray coatings for wear protection)
weakest_at: 'Oxidation at high temperature: the sources read make only a general claim and give no oxidation onset, and the supplier SDS warns that moisture releases methane'
identity:
formula: Cr3C2
cas: 12012-35-0
crystal_system: orthorhombic
space_group: Pnma
source: paper
where: Introduction (Cr3C2 listed as Pnma among the binary chromium carbides); Section 2, Table 2 text 'For orthorhombic system (Cr7C3, Cr3C2)'. CAS printed on the supplier product page (sam-product) and SDS (sam-msds).
tags:
environments: []
stresses:
- extreme-heat
applications:
- mechanisms
- structures
properties:
- benchmark: density
label: Specific gravity printed in the supplier SDS
value: 6.68
unit: gm/cc
scope: material
conditions:
basis: printed as Specific Gravity (water=1); no temperature, powder form or test method printed
unit_in_source: gm/cc
method: Manufacturer SDS value (Stanford Advanced Materials, version 2.0, revision 5 September 2012)
status: ground
source: sam-msds
where: Section III, Specific Gravity (water=1) row
- benchmark: density
label: Density printed on a second supplier page
value: 6.68
unit: g/cm3
scope: material
conditions:
basis: printed as Density in the Specifications section; not labelled true or bulk; no temperature or test method printed
method: Supplier specification value
status: ground
source: sputter-cr3c2
where: Specifications section, Density row
- benchmark: melting_point
value: 1890
unit: °C
scope: material
conditions:
basis: stated by the supplier with no test method; the description paragraph on the same page also gives 1890°C
method: Supplier specification value
status: ground
source: sam-product
where: Specification section, Melting point row; Description paragraph
- benchmark: melting_point
label: Melting point, 2012 supplier SDS (conflicts with the product page)
value: 1980
unit: °C
scope: material
conditions:
basis: 'printed as Melting Point: 1980.0 C in the SDS physical characteristics; no test method'
method: Manufacturer SDS value
status: ground
note: This value disagrees with the 1890 °C product-page value. Both are kept side by side; neither is backed by a measurement method in the sources read.
source: sam-msds
where: Section III, Melting Point row
- benchmark: boiling_point
value: 3800
unit: °C
scope: material
conditions:
basis: 'printed as Boiling Point: 3800.0 C in the SDS physical characteristics; no pressure or method printed'
method: Manufacturer SDS value
status: ground
note: Not checked against any other source read in this run; kept only as printed.
source: sam-msds
where: Section III, Boiling Point row
- benchmark: vickers_hardness
label: Microhardness, supplier specification (test not stated)
value: 2280
unit: kg/mm2
scope: material
conditions:
basis: printed as Microhardness in the Specification section; no load or test method stated
method: Supplier specification value
status: ground
source: sam-product
where: Specification section, Microhardness row
- benchmark: theoretical_hardness
label: Theoretical hardness, first-principles, zero pressure
value: 18.2
unit: GPa
scope: material
conditions:
basis: calculated at zero applied pressure; the table column is headed H Gao
pressure: 0 GPa
method: Calculated in a first-principles study (CASTEP, density functional theory); a computed value, not a measurement
status: calculated
source: paper
where: Section 3 text ('The theoretical hardness of Cr7C3, Cr3C2 and Cr23C6 was found to be 13.5, 18.2 and 10.1 GPa'); Table 4
- benchmark: vickers_hardness
label: Vickers hardness range for Cr3C2 quoted from earlier measurements
value: 15.1
value_high: 18.9
bound: range
unit: GPa
scope: material
conditions:
basis: range across earlier studies quoted by the paper, which says reported values differ with sample preparation and measurement protocol; load not given
method: Range quoted in the paper from other research groups
status: ground
source: paper
where: Introduction, paragraph 2 (Hν (Cr3C2) = 15.1–18.9 GPa, with cited references)
- benchmark: bulk_modulus
value: 314.7
unit: GPa
scope: material
conditions:
basis: zero pressure; Voigt-Reuss-Hill average of calculated elastic constants
method: Calculated in a first-principles study (CASTEP, density functional theory)
status: calculated
source: paper
where: Table 2, Cr3C2 row, B/GPa column
- benchmark: shear_modulus
value: 166.1
unit: GPa
scope: material
conditions:
basis: zero pressure; Voigt-Reuss-Hill average of calculated elastic constants
method: Calculated in a first-principles study (CASTEP, density functional theory)
status: calculated
source: paper
where: Table 2, Cr3C2 row, G/GPa column
- benchmark: elastic_modulus
label: Young's modulus, calculated
value: 423.7
unit: GPa
scope: material
conditions:
basis: zero pressure; Voigt-Reuss-Hill average of calculated elastic constants
method: Calculated in a first-principles study (CASTEP, density functional theory)
status: calculated
source: paper
where: Table 2, Cr3C2 row, E/GPa column
- benchmark: poissons_ratio
value: 0.28
unit: '-'
scope: material
conditions:
basis: zero pressure; calculated from the Voigt-Reuss-Hill averages
method: Calculated in a first-principles study (CASTEP, density functional theory)
status: calculated
source: paper
where: Table 2, Cr3C2 row, v column
- benchmark: lattice_parameter_a
label: Lattice parameter a, calculated at zero pressure
value: 5.48
unit: Å
scope: material
conditions:
basis: zero pressure, orthorhombic cell
method: Calculated in a first-principles study; the table lists experimental values beside it, which are not used here
status: calculated
source: paper
where: Table 1, Cr3C2 row, a column
- benchmark: lattice_parameter_b
label: Lattice parameter b, calculated at zero pressure
value: 2.79
unit: Å
scope: material
conditions:
basis: zero pressure, orthorhombic cell
method: Calculated in a first-principles study
status: calculated
source: paper
where: Table 1, Cr3C2 row, b column
- benchmark: lattice_parameter_c
label: Lattice parameter c, calculated at zero pressure
value: 11.47
unit: Å
scope: material
conditions:
basis: zero pressure, orthorhombic cell
method: Calculated in a first-principles study
status: calculated
source: paper
where: Table 1, Cr3C2 row, c column
corrosion:
- environment: Moisture and water contact
headline: The supplier safety data sheet says Cr3C2 reacts with moisture to form methane gas.
effect: The 2012 SDS states that the powder reacts with moisture to form methane gas, and it lists moisture among the materials to avoid. The sheet gives no reaction rate, temperature or test.
rating: moderate
conditions:
basis: supplier statement, no test conditions
source: sam-msds
where: Section V (Incompatibility) and Section VII (handling paragraph)
- environment: Strong oxidizing agents, acids and bases
headline: The supplier SDS lists strong oxidizing agents, acids and bases as materials to avoid.
effect: The SDS gives this as an incompatibility statement without concentrations, times or test results.
rating: low
conditions:
basis: incompatibility list, no test data
source: sam-msds
where: Section V (Incompatibility - materials to avoid)
- environment: High-temperature air
headline: The 2022 paper describes outstanding oxidation resistance at high temperature, without a figure.
effect: The paper's introduction describes 'outstanding oxidation resistance under a high temperature environment' for the binary chromium carbides. It gives no oxidation onset temperature, exposure time or test method, so this is a general statement only.
rating: unknown
conditions:
basis: general statement in the introduction; no test
source: paper
where: Introduction, paragraph 1
risks:
hazards:
- text: PubChem's hazards summary for the chromium carbide record reads 'May be harmful after ingestion, inhalation, or skin contact; May damage eyes'.
ghs: []
source: pubchem-cr3c2
where: Safety and Hazards, Hazards Identification, Hazards Summary (CID 3650773)
- text: The supplier product page lists the hazard statement 'Flammable solid' with the signal word 'Warning'.
ghs: []
source: sam-product
where: Safety information block
failure_risks:
- mode: Methane release on contact with moisture
trigger: Contact with moisture or water
consequence: The SDS says the powder reacts with moisture to form methane gas.
severity: moderate
source: sam-msds
where: Section V (Hazardous decomposition or byproducts) and Section VII
side_effects:
- text: The SDS says 'Chromium carbide may emit toxic fumes if involved in a fire'.
affects: Firefighters and people near a fire
source: sam-msds
where: Section IV, Unusual fire and explosion hazards
- text: PubChem notes that trivalent chromium 'may be oxidized to hexavalent chromium, a known carcinogen'.
affects: Workers handling heated or oxidized material
source: pubchem-cr3c2
where: Toxicity, Health Effects
handling:
- text: Store in a cool, dry area, in a tightly sealed container, under an inert gas such as argon, as the SDS directs.
source: sam-msds
where: Section VII and Section VIII (Other)
- text: Keep the powder away from moisture, strong oxidizing agents, acids and bases, which the SDS lists as materials to avoid.
source: sam-msds
where: Section V
- text: Take care not to raise dust, and use a NIOSH-approved dust respirator where the SDS requires it.
source: sam-msds
where: Section VII and Section VIII (Respiratory)
- text: PubChem prints the PEL and the TLV as '0.5 [mg/m3], as Cr'. The SDS prints '0.5 mg/m3' and '1 mg/m3' under the headings ACGIH-TLV and OSHA PEL, so the two sources do not agree on the PEL.
source: pubchem-cr3c2
where: Exposure Control and Personal Protection (PEL and TLV); the SDS figures are in Section II
uses:
- application: mechanisms
device: Cutting tools, drilling bits and wear parts
example: The supplier says Chromium Carbide Powder is commonly used in the production of cutting tools, drilling bits, wear-resistant parts, molds, and coatings for turbine components.
source: sam-product
where: Chromium Carbide Powder Applications section
- application: structures
device: Coatings for turbine components and thermal spray
example: The same supplier page lists coatings for turbine components, and its FAQ names thermal spray coatings for wear protection.
source: sam-product
where: Chromium Carbide Powder Applications section; FAQs
- application: mechanisms
device: Grain refinement agent in cemented carbide
example: The 2022 paper says chromium carbides can be used as grain refinement agents in cemented carbide and other wear-resistance components.
source: paper
where: Introduction, paragraph 1
supply:
- subject: Chromium (the metal in Cr3C2; the carbon supply is not covered by any source read in this run)
producers:
- country: South Africa
share_percent: 45.1
year: 2025
- country: Turkey
share_percent: 17.6
year: 2025
- country: Kazakhstan
share_percent: 13.7
year: 2025
- country: India
share_percent: 5.9
year: 2025
critical_lists:
- list: USGS 2025 List of Critical Minerals (the page lists Chromium, used in stainless steel)
listed: true
recycling: 'USGS: ''In 2025, recycled chromium (contained in reported stainless-steel scrap receipts) accounted for 21% of apparent consumption.'''
substitutes:
- 'USGS: ''Chromium has no substitute in stainless steel, the leading end use, or in superalloys, the major strategic end use.'''
source: usgs-mcs2026-chromium
where: 'World Mine Production and Reserves table, 2025e column (chromium content in thousand metric tons; world total 51,000 rounded; shares calculated by Space Mushroom against that total); Recycling; Substitutes. Critical list: USGS 2025 critical minerals page (usgs-crit2025).'
gaps:
- Oxidation onset in air for dense Cr3C2 was not found in any source read in this run. A search snippet for the powder was not opened and is not used.
- No thermal conductivity, coefficient of thermal expansion, specific heat or band gap for Cr3C2 was found in any source read.
- No bulk or tap density was found in a fetched source. The American Elements pages were blocked by a browser check, and search snippets are not used.
- The PubChem web page was blocked by a browser check. The PubChem REST record was read instead; it gives a hazards summary and exposure limits but no GHS hazard statements, so the GHS field is empty.
- No UNS, EN, ASTM or other designation for Cr3C2 was printed in a source read in this run. Identity uses the CAS number printed on the supplier product page and SDS.
- Crystal structure is printed as Rhombohedral on two supplier pages. The paper gives orthorhombic, space group Pnma, and that is what identity records.
- 'Melting point conflicts: the product page gives 1890 °C and the 2012 SDS gives 1980.0 °C. Wikipedia gives a different melting value, which is not used. Wikipedia is cited for production routes only.'
- The 2012 SDS boiling point is not confirmed by any other source read in this run.
- 'Exposure limits differ between PubChem and the SDS, as shown in risks.handling. Carcinogen labels also differ: the SDS calls chromium a confirmed human carcinogen, while PubChem gives a carcinogen classification (see the PubChem record).'
- Atomic weights of chromium and carbon were not read in a fetched page, so story.recipe.parts has no atomic_weight.
- The paper's other quoted Vickers hardness ranges for Cr3C2 are not recorded as separate rows; the paper gives them without measurement details.
- 'Property names not in spores/property-canon.yaml: vickers_hardness (used for microhardness and the quoted range), theoretical_hardness, lattice_parameter_a, lattice_parameter_b and lattice_parameter_c.'
- The paper's elastic, bulk, shear and lattice values are first-principles results at zero pressure, marked status calculated. They are not measured values.
- Supply covers chromium only. The EU critical raw materials list was not opened in this run, so no EU listing is recorded.
- No space, vacuum, radiation or atomic-oxygen results for Cr3C2 were found.
- The IPEN paper on attrition-milled Cr3C2 refused the connection and was not read.
- No media images were added.
sources:
sam-product:
title: Chromium Carbide (Cr3C2) Powder product page, Stanford Advanced Materials (specification, description, applications, safety and FAQ sections)
id: CAS 12012-35-0; catalog CR1314
url: https://www.samaterials.com/chromium/1314-chromium-carbide-cr3c2-powder.html
kind: web
license: supplier page (cited, not reproduced)
sam-msds:
title: 'Material Safety Data Sheet: Chromium carbide, Cr3C2 (Stanford Advanced Materials, version 2.0, revision 5 September 2012), hosted by Sputter Targets'
id: CAS 12012-35-0
url: https://www.sputtertargets.net/Public/pdf/chromium-carbide-msds.pdf
year: 2012
kind: datasheet
license: supplier document (cited, not reproduced)
sputter-cr3c2:
title: Chromium Carbide Powder product page, Sputter Targets (Cr3C2 specifications)
url: https://www.sputtertargets.net/chromium-carbide-powder/
kind: web
license: supplier page (cited, not reproduced)
paper:
title: 'First Principles Investigation of Binary Chromium Carbides Cr7C3, Cr3C2 and Cr23C6: Electronic Structures, Mechanical Properties and Thermodynamic Properties under Pressure'
id: doi:10.3390/ma15020558 (Materials 15(2), 558; PMC8779879)
url: https://pmc.ncbi.nlm.nih.gov/articles/PMC8779879/
year: 2022
kind: paper
license: open access (licence as listed by the journal; not checked in this run)
usgs-mcs2026-chromium:
title: Mineral Commodity Summaries 2026, Chromium
id: USGS MCS 2026, February 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-chromium.pdf
year: 2026
kind: report
license: public domain (USGS)
usgs-crit2025:
title: About the 2025 List of Critical Minerals (USGS, final list of 60 minerals)
id: Final 2025 List of Critical Minerals, November 2025
url: https://www.usgs.gov/programs/mineral-resources-program/science/about-2025-list-critical-minerals
year: 2025
kind: web
license: public domain (USGS)
pubchem-cr3c2:
title: 'PubChem compound record CID 3650773, chromium carbide (Cr3C2, CAS 12012-35-0): hazards summary, exposure limits, toxicity'
id: CID 3650773
url: https://pubchem.ncbi.nlm.nih.gov/compound/3650773
year: 2026
kind: database
license: public domain (NCBI)
wiki-cr3c2:
title: Wikipedia, Chromium(II) carbide (composition and production routes only; numbers not used)
url: https://en.wikipedia.org/wiki/Chromium(II)_carbide
kind: web
license: CC BY-SA
documents:
- title: 'Material Safety Data Sheet: Chromium carbide, Cr3C2 (Stanford Advanced Materials, 2012)'
type: sds
url: https://www.sputtertargets.net/Public/pdf/chromium-carbide-msds.pdf
year: 2012
- title: Chromium Carbide (Cr3C2) Powder product page (Stanford Advanced Materials)
type: datasheet
url: https://www.samaterials.com/chromium/1314-chromium-carbide-cr3c2-powder.html
year: 2026
- title: First Principles Investigation of Binary Chromium Carbides Cr7C3, Cr3C2 and Cr23C6 (Materials 15(2), 558, 2022)
type: paper
url: https://pmc.ncbi.nlm.nih.gov/articles/PMC8779879/
year: 2022
- title: Mineral Commodity Summaries 2026, Chromium
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-chromium.pdf
year: 2026
- title: 'PubChem: chromium carbide (CID 3650773), hazards and toxicity sections'
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/3650773
year: 2026
license: CC-BY-4.0
updated: '2026-11-01'
review:
status: draft
method: assistant
checked_values: 15
unreachable: 2
caveats: 3
note: 'Written by an AI assistant on 2026-11-01 from pages read in this run. Unreachable as web pages: the American Elements pages (browser check) and the PubChem web page (browser check; the PubChem REST record was read instead). Calculated values are first-principles results, not measurements.'
story:
recipe:
line: 'Chromium carbide (Cr3C2) is a binary compound of chromium and carbon with an orthorhombic crystal structure. The 2022 paper lists Cr3C2 among the stable binary chromium carbides at ambient pressure, alongside the other two carbides it studies. Wikipedia describes two production routes: mechanical alloying of chromium and graphite followed by hot isostatic pressing under argon, and a self-propagating exothermic reaction that uses chromium oxide, aluminum and graphite.'
parts:
- name: Chromium
symbol: Cr
role: The metal in the compound. The paper says metallic bonding runs between neighbouring chromium atoms, and the chromium-carbon bonds give the hardness it reports.
- name: Carbon
symbol: C
role: Bonds covalently to chromium in the paper's bonding analysis; the Cr-C bond strength is the basis of its theoretical hardness.
risk_groups:
- title: For people
level: 0
verdict: Harmful by inhalation or ingestion, per PubChem
lead: PubChem's hazards summary says the material may be harmful after ingestion, inhalation or skin contact, and may damage eyes. The supplier SDS calls chromium a confirmed human carcinogen. These are supplier and database summaries, not incident records.
points:
- label: Summary
line: PubChem's hazards summary reads 'May be harmful after ingestion, inhalation, or skin contact; May damage eyes'.
- label: Carcinogen labels differ
line: The 2012 SDS calls chromium a 'Confirmed human carcinogen'. PubChem's carcinogen classification reads '3, not classifiable as to its carcinogenicity to humans.'
- label: Flammability
line: The supplier product page lists the hazard statement 'Flammable solid' with the signal word 'Warning'.
- title: If the powder is heated or burns
lead: These statements come from supplier sheets and database summaries, not from field incidents.
points:
- label: Fire
line: The SDS says the material 'may emit toxic fumes if involved in a fire', and it calls for full face, self-contained breathing apparatus for firefighters.
- label: Oxidized chromium
line: PubChem says trivalent chromium 'may be oxidized to hexavalent chromium, a known carcinogen'.
- title: Handling and storage
points:
- label: Moisture
line: The SDS says the powder 'reacts with moisture to form methane gas'. It asks for storage in a cool, dry area in a tightly sealed container, under an inert gas such as argon.
- label: Exposure limits
line: PubChem prints '0.5 [mg/m3], as Cr' for both the PEL and the TLV. The SDS prints '0.5 mg/m3' and '1 mg/m3' under the headings ACGIH-TLV and OSHA PEL.
why: Chromium carbide (Cr3C2) is a hard ceramic powder made of chromium and carbon. Its supplier calls it a hard, durable coating material for protection against wear, corrosion and high temperatures, and lists it for cutting tools, drilling bits, wear-resistant parts and molds. It is supplied as a grey-black powder, and the supplier names thermal spray as a use. Its hardness and stiffness are the main reasons it is used. Its melting values disagree between two supplier sheets, and no measured high-temperature oxidation figure was found in the sources read.
uses:
- where: Cutting tools, drilling bits and molds
line: The supplier says the powder is commonly used in cutting tools, drilling bits, wear-resistant parts and molds.
- where: Turbine coatings and thermal spray
line: The supplier lists coatings for turbine components, and its FAQ names thermal spray coatings for wear protection. These are supplier statements; no field test was found.
- where: Grain refiner in cemented carbide
line: The 2022 paper says chromium carbides can be used as grain refinement agents in cemented carbide and other wear-resistance components.
can_do:
- label: Hardness
benchmark: vickers_hardness
value: 2280 kg/mm2
line: The supplier gives a microhardness of 2280 kg/mm2 with no test method stated. The paper quotes a Vickers hardness of 15.1 to 18.9 GPa for Cr3C2 from earlier studies, and calculates a theoretical hardness of 18.2 GPa.
- label: Stiffness
benchmark: elastic_modulus
value: 423.7 GPa
line: The 2022 paper calculates a Young's modulus of 423.7 GPa and a Poisson's ratio of 0.28 at zero pressure. These are calculated values, not measurements.
- label: Density
benchmark: density
value: 6.68 g/cm3
line: 'Two suppliers print a density of 6.68: one in gm/cc in a 2012 safety data sheet, and one in g/cm3 on a product page.'
- label: Melting point
benchmark: melting_point
value: 1890 °C
line: The supplier product page gives a melting point of 1890 °C, and its 2012 safety data sheet gives 1980.0 °C. The two supplier values differ, and neither prints a method.
compare: 'Chromium carbide sits among the hard refractory carbides. Its supplier microhardness of 2280 kg/mm2 and its calculated theoretical hardness of 18.2 GPa are both high. The sources read here give no direct side-by-side comparison with the other carbides in this collection. The two supplier melting values, 1890 °C and 1980.0 °C, disagree and are shown side by side. Oxidation in air is not quantified in the sources read. The hardness values are not directly comparable: the supplier figure has no test method, and the paper''s figures are calculated or quoted from other studies.'
compare_rows:
- label: Microhardness (supplier)
benchmark: vickers_hardness
- label: Melting point (supplier)
benchmark: melting_point
- label: Young's modulus (calculated)
benchmark: elastic_modulus
handling:
- Store in a cool, dry area, in a tightly sealed container, under an inert gas such as argon, as the SDS directs.
- Keep the powder away from moisture, strong oxidizing agents, acids and bases, which the SDS lists as materials to avoid.
- Take care not to raise dust, and use a NIOSH-approved dust respirator where the SDS requires it.
- Check the supplier's current SDS for your grade, because the 2012 SDS and the product pages disagree on melting point and on exposure limits.
good_for:
- Hard wear parts. The supplier says it is used in cutting tools, drilling bits, wear-resistant parts and molds.
- Thermal spray coatings. The supplier FAQ lists thermal spray coatings for wear protection.
- Stiff hard coatings in design studies. The paper's calculated Young's modulus of 423.7 GPa is a theoretical value.
watch_out:
- Moisture reaction. The SDS says the powder reacts with moisture to form methane gas.
- Conflicting melting values. The product page gives 1890 °C and the 2012 SDS gives 1980.0 °C.
- Oxidation in air is not quantified. The paper says 'outstanding oxidation resistance under a high temperature environment' without a figure.
- Crystal structure is printed two ways. Two supplier pages say Rhombohedral; the paper gives orthorhombic, space group Pnma.
verdict: Chromium carbide is a hard wear-resistant powder for coatings and tool parts. Its hardness data are stronger than its melting and oxidation data, and the supplier figures should be checked against a current SDS before use.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
Updated