Stainless steel 316L 316L (UNS S31603)
Fe balance
Also known as UNS S31603, EN 1.4404, EN 1.4435, EN name X2CrNiMo17-12-2, DIN X2CrNiMo 17 13 2, JIS SUS316L · 8 more
Type 316L is the extra-low-carbon form of 316, an austenitic chromium-nickel stainless steel with 2 to 3 percent molybdenum added.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Strength
485 MPa
Stiffness
193 GPa
Density
8.03 g/cm³
Heat
1390 °C
Recipe, share of the weight
- Fe balance (the rest)Iron
- Cr 16 to 18%Chromium
- Ni 10 to 14%Nickel
- Mo 2 to 3%Molybdenum
- C 0 to 0.03%Carbon
- Mn 0 to 2%Manganese
- Si 0 to 0.75%Silicon
- P 0 to 0.045%Phosphorus
- S 0 to 0.03%Sulfur
- N 0 to 0.1%Nitrogen
Best for
Welded parts in chloride or marine service, and vacuum hardware that is vacuum-fired
Weakest at
Long holds near 650 C form sigma phase, and seawater service needs a pitting resistance equivalent number greater than 40 (Wikipedia)
Risk at a glance
- People None found. Not checked against a 316L safety data sheet
- If it fails High. Pitting and crevice corrosion in seawater or chloride service
- Corrosion Moderate. Chloride ions cause pitting and crevice corrosion in susceptible stainless steels; for submerged seawater a pitting resistance equivalent number greater than 40 is typically specified.
Quick facts: 316L (UNS S31603)
| Property | Value | Basis |
|---|---|---|
| Density | 7.99 to 8.03 g/cm³ | 3 sourced values across conditions |
| Yield strength | 170 to 290 MPa | 3 sourced values across conditions |
| Tensile strength | 485 to 558 MPa | 3 sourced values across conditions |
| Young's modulus | 193 to 200 GPa | 2 sourced values across conditions |
| Thermal conductivity | 14.6 to 16.2 W/(m·K) | 2 sourced values across conditions |
| Thermal expansion (CTE) | 16 to 16.5 ppm/K | 2 sourced values across conditions |
| Melting point | 1,390 to 1,440 °C | 1 sourced value |
| Specific heat | 450 J/(kg·K) | 1 sourced value |
| Electrical resistivity | 7.4e-7 Ω·m | 1 sourced value |
What is the density of Stainless steel 316L?
Stainless steel 316L has a density of 7.99 to 8.03 g/cm³. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the thermal conductivity of Stainless steel 316L?
Stainless steel 316L has a thermal conductivity of 14.6 to 16.2 W/(m·K). The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the coefficient of thermal expansion of Stainless steel 316L?
Stainless steel 316L has a coefficient of thermal expansion of 16 to 16.5 ppm/K. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the melting point of Stainless steel 316L?
Stainless steel 316L has a melting point of 1,390 to 1,440 °C. The source and test conditions are listed in the properties table on this page.
What is the yield strength of Stainless steel 316L?
Stainless steel 316L has a yield strength of 170 to 290 MPa. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What are the other names and codes for Stainless steel 316L?
Stainless steel 316L is also written as UNS S31603, EN 1.4404, EN 1.4435, EN name X2CrNiMo17-12-2, DIN X2CrNiMo 17 13 2, JIS SUS316L. Each code is printed in the source listed beside it in the designations table.
What is Stainless steel 316L used for?
Uses recorded in the sources include Aerospace structures; Parts exposed to marine atmospheres; Ultra-high-vacuum chamber walls (laboratory).
Why it exists
Type 316L is the low-carbon version of 316. Adding 2 to 3 percent molybdenum to the chromium-nickel steel improves resistance to chloride pitting, and UPMET says the molybdenum-bearing 316 family is more resistant to pitting and crevice corrosion than Type 304. The 0.030 percent carbon limit reduces the carbide precipitation that follows welding. The datasheets list it for aerospace structures and parts exposed to marine atmospheres, and NIST tested vacuum-fired 316L for vacuum chambers.
Where it's used
Marine parts
Combined Metals lists parts exposed to marine atmospheres among the industries supplied. Wikipedia calls 316L the preferred steel for marine environments because of its greater resistance to pitting corrosion.
Aerospace structures
UPMET lists aerospace structures among the industry applications for 316 and 316L sheet, coil and bar. The datasheet gives no flight or space test data.
Vacuum hardware
In NIST's comparison of seven vacuum chambers, the vacuum-fired 316L chamber had hydrogen outgassing below 1 x 10^-11 Pa L/s/cm2, in the same ultra-low class as the titanium and aluminium chambers. The unfired 316L chamber was higher.
Medical implants
Wikipedia says 316L is the preferred grade for medical implants because it resists sensitization. No space use is implied; it is recorded here for context.
Recipe
Fe balance; 16.0 to 18.0 Cr, 10.0 to 14.0 Ni, 2.00 to 3.00 Mo, max 0.030 C, max 2.00 Mn, max 0.75 Si, max 0.045 P, max 0.030 S, max 0.10 N (wt%)
316L is an iron-based austenitic stainless steel. Its nominal composition, from the Combined Metals and UPMET data sheets, is 16 to 18 wt% chromium, 10 to 14 wt% nickel and 2 to 3 wt% molybdenum, with carbon held to 0.030 wt% maximum and iron as the balance. UPMET lists the product as coil, sheet, bar and precision strip. The NIST vacuum study fired its 316L-XHV chamber at about 950 C for 24 hours under vacuum.
| Ingredient | Share of the weight | What it does |
|---|---|---|
| Iron Fe | balance (the rest) | The matrix of the alloy. |
| Chromium Cr | 16 to 18% | Forms the passive oxide film that gives corrosion resistance. |
| Nickel Ni | 10 to 14% | Holds the austenite structure. |
| Molybdenum Mo | 2 to 3% | Increases general corrosion resistance and resistance to chloride pitting (Combined Metals). |
| Carbon C | 0 to 0.03% | Kept low so that chromium carbide does not form at grain boundaries after welding. |
| Manganese Mn | 0 to 2% | Impurity and processing element held to a maximum. |
| Silicon Si | 0 to 0.75% | Held to a maximum. |
| Phosphorus P | 0 to 0.045% | Impurity held low. |
| Sulfur S | 0 to 0.03% | Impurity held low. |
| Nitrogen N | 0 to 0.1% | Held to a maximum. |
Weight shares are as printed in the sources.
What it can do
Strength
485 MPa
measured
The minimum tensile strength is 485 MPa and the minimum yield is 170 MPa for plate, sheet and strip (ATI). Annealed typical values are 558 MPa tensile and 290 MPa yield (Combined Metals).
Stiffness
193 GPa
measured
Young's modulus is 193 GPa at 20 C (Combined Metals) or 200 GPa (UPMET).
Density
8.03 g/cm³
measured
Density is 7.99 g/cm3 at 20 C (Combined Metals), 8.027 g/cm3 (UPMET) or 8.03 g/cm3 (ATI).
Heat
1390 °C
measured
The melting range is 1,390 to 1,440 C (UPMET). Combined Metals says the alloy is somewhat stronger at elevated temperatures than Type 304.
How it compares
Combined Metals says that the properties of 316L are similar to Type 304 except that it is somewhat stronger at elevated temperatures. UPMET says the molybdenum-bearing 316 family is more resistant to general corrosion and to pitting and crevice corrosion than Type 304. No Type 304 numbers were read in this run, so the table below compares 316L only with itself across three properties.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.
| Measurement | 316L (UNS S31603) | 304 (UNS S30400) | 301 (UNS S30100) | 303 (UNS S30300) | 316 (UNS S31600) | 302 | 304L (UNS S30403) | 309 | 310S (UNS S31008, EN 1.4845) | 317L | 321 | 347 | 347H | 904L (UNS N08904, EN 1.4539) | Nitronic 60 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Thermal behavior and safety | |||||||||||||||
| melting point | 1390 °C7 | 1673 K | 1399 to 1421 °C | 1455 °C | 1390 °C | 1420 °C | 1399 to 1421 °C | 2550 to 2650 °F | 1410 °C | 1390 to 1440 °C | 1398 to 1446 °C | 1398 to 1446 °C | 2550 to 2635 degF | 1300 to 1390 °C | no data |
| specific heat | 450 J/kg °K8 | 490 J/kg.K | 500 J/kg.K | 500 J/kg°C | 450 J/kg.K | 500 J/kg K | 500 J/kg·K | 502 J/kg·K | 480 J/(kg·K) | 500 J/(kg·K) | 500 J/kg K | 500 J/(kg·K) | 485 J/(kg.°C) | 450 J/(kg·K) | 0.12 Btu/lb °F |
| Thermal conductivity | 14.6 W/m·K9 | 14 W/m.K | 16.3 W/m.K | 15 W/m°C | 14.6 W/m.K | 16.2 W/(m·K) | 16.3 W/m·K | 15.6 W/m·K | 13 W/(m·K) | 14 W/(m·K) | 16.3 W/(m·K) | 16.3 W/(m·K) | 14 W/m.°C | 12 W/(m·K) | 9 Btu/ft hr °F |
| Thermal conductivity | 16.2 W/m·K10 | 14 W/m.K | 16.3 W/m.K | 15 W/m°C | 14.6 W/m.K | 16.2 W/(m·K) | 16.3 W/m·K | 15.6 W/m·K | 13 W/(m·K) | 14 W/(m·K) | 16.3 W/(m·K) | 16.3 W/(m·K) | 14 W/m.°C | 12 W/(m·K) | 9 Btu/ft hr °F |
| Physical and electrical | |||||||||||||||
| Density | 8.03 g/cm³1 | 7.85 Mg/m3 | 8.03 g/cm³ | 7.9 kg/dm3 | 8.027 g/cm³ | 7.9 g/cm³ | 7.9 g/cm³ | 8.03 g/cm³ | 7.8 kg/dm3 | 8.027 g/cm³ | 7.92 g/cm³ | 7.96 g/cm³ | 7.98 kg/dm3 | 7.95 g/cm³ | 7.622 gm/cm³ |
| Density | 8.027 g/cm³2 | 7.85 Mg/m3 | 8.03 g/cm³ | 7.9 kg/dm3 | 8.027 g/cm³ | 7.9 g/cm³ | 7.9 g/cm³ | 8.03 g/cm³ | 7.8 kg/dm3 | 8.027 g/cm³ | 7.92 g/cm³ | 7.96 g/cm³ | 7.98 kg/dm3 | 7.95 g/cm³ | 7.622 gm/cm³ |
| Density | 7.99 g/cm³3 | 7.85 Mg/m3 | 8.03 g/cm³ | 7.9 kg/dm3 | 8.027 g/cm³ | 7.9 g/cm³ | 7.9 g/cm³ | 8.03 g/cm³ | 7.8 kg/dm3 | 8.027 g/cm³ | 7.92 g/cm³ | 7.96 g/cm³ | 7.98 kg/dm3 | 7.95 g/cm³ | 7.622 gm/cm³ |
| electrical resistivity | 74 μΩ·cm13 | 65 10-8 ohm.m | 72 µΩ·cm | 72 microhm-cm | 69 10-8 ohm.m | 72 µΩ·cm | 72 microhm-cm | 78 µΩ·cm | 0.86 Ω·mm²/m | 475 Ohm-circ mil/ft | 72 microhm·cm | 72 µΩ·cm | no data | 95.2 µΩ·cm | 98.2 microhm-cm |
| Other measurements | |||||||||||||||
| elastic modulus | 193 GPa4 | 200 GPa | 193 GPa | 193 GPa | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 195 GPa | 200 GPa | 193 GPa | 193 GPa | 200 GPa | 195 GPa | 180 GPa |
| elastic modulus | 200 GPa5 | 200 GPa | 193 GPa | 193 GPa | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 195 GPa | 200 GPa | 193 GPa | 193 GPa | 200 GPa | 195 GPa | 180 GPa |
| shear modulus | 82 GPa6 | no data | no data | no data | 82 GPa | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data |
| Thermal expansion (CTE) | 16.5 10-6 cm/cm/°C11 | no data | 16.6 10-6/K | 16 10-6/°C | 16.5 10-6/K | 16.6 µm/(m·°C) | 16.6 10-6 cm/cm/°C | 15.6 µm/(m·K) | 16.5 ppm/K | 16.5 10^-6 cm/cm/°C | 16.6 ppm/K | 16.6 ppm/K | 9.2 in/in.degF x 10^-6 | 15.8 ppm/K | 15.8 µm/m/°C |
| Thermal expansion (CTE) | 16 μm/m·°C12 | no data | 16.6 10-6/K | 16 10-6/°C | 16.5 10-6/K | 16.6 µm/(m·°C) | 16.6 10-6 cm/cm/°C | 15.6 µm/(m·K) | 16.5 ppm/K | 16.5 10^-6 cm/cm/°C | 16.6 ppm/K | 16.6 ppm/K | 9.2 in/in.degF x 10^-6 | 15.8 ppm/K | 15.8 µm/m/°C |
| ultimate tensile strength | 485 MPa14 | > 515 MPa | 515 MPa | > 517 MPa | 515 MPa | 655 MPa | > 485 MPa | 621 MPa | 610 MPa | > 515 MPa | > 515 MPa | > 515 MPa | > 75 ksi | 530 to 730 MPa | > 655 MPa |
| ultimate tensile strength | 485 MPa15 | > 515 MPa | 515 MPa | > 517 MPa | 515 MPa | 655 MPa | > 485 MPa | 621 MPa | 610 MPa | > 515 MPa | > 515 MPa | > 515 MPa | > 75 ksi | 530 to 730 MPa | > 655 MPa |
| ultimate tensile strength | 558 MPa16 | > 515 MPa | 515 MPa | > 517 MPa | 515 MPa | 655 MPa | > 485 MPa | 621 MPa | 610 MPa | > 515 MPa | > 515 MPa | > 515 MPa | > 75 ksi | 530 to 730 MPa | > 655 MPa |
| yield strength | 170 MPa17 | > 205 MPa | 205 MPa | > 172 MPa | 205 MPa | 290 MPa | > 170 MPa | 290 MPa | 290 MPa | > 205 MPa | > 205 MPa | > 205 MPa | > 30 ksi | > 240 MPa | > 345 MPa |
| yield strength | 170 MPa18 | > 205 MPa | 205 MPa | > 172 MPa | 205 MPa | 290 MPa | > 170 MPa | 290 MPa | 290 MPa | > 205 MPa | > 205 MPa | > 205 MPa | > 30 ksi | > 240 MPa | > 345 MPa |
| yield strength | 290 MPa19 | > 205 MPa | 205 MPa | > 172 MPa | 205 MPa | 290 MPa | > 170 MPa | 290 MPa | 290 MPa | > 205 MPa | > 205 MPa | > 205 MPa | > 30 ksi | > 240 MPa | > 345 MPa |
| elongation | 40 %20 | > 40 % | 40 % | > 35 % | 40 % | 55 % | > 40 % | 49 % | 42 % | > 40 % | > 35 % | > 40 % | > 40 % | > 35 % | > 35 % |
| elongation | 40 %21 | > 40 % | 40 % | > 35 % | 40 % | 55 % | > 40 % | 49 % | 42 % | > 40 % | > 35 % | > 40 % | > 40 % | > 35 % | > 35 % |
| elongation | 50 %22 | > 40 % | 40 % | > 35 % | 40 % | 55 % | > 40 % | 49 % | 42 % | > 40 % | > 35 % | > 40 % | > 40 % | > 35 % | > 35 % |
Why choose it, and why not
Good for
- Welded corrosion-resistant parts in chloride-bearing service, where the low-carbon grade limits sensitization.
- Vacuum hardware that is vacuum-fired. The NIST study found its hydrogen outgassing in the ultra-low class.
- Marine parts exposed to salt air, which Combined Metals lists as a use.
Watch out for
- Chloride pitting. A pitting resistance equivalent number above 40 is typically specified for submerged seawater, and 316 and 316L are not suitable for seawater condenser tubes.
- Sigma phase. Long holds near 650 C form sigma, chi and Laves phases alongside the carbides, and sensitize the steel.
- Strength is modest for a structural steel, with a minimum yield of 170 MPa on the ATI and UPMET datasheets, so the design must allow for it.
316L is the choice when a 304-type steel would pit in chloride service and the part must be welded. Its limits are its heat history and its chloride limit, so specify the low-carbon grade for welds and check a pitting resistance above 40 for seawater.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Other names and standards
The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.
| System | Codes |
|---|---|
| UNS | S31603 |
| EN | 1.4404, 1.4435 |
| EN name | X2CrNiMo17-12-2 |
| DIN | X2CrNiMo 17 13 2 |
| JIS | SUS316L |
| AISI | 316L |
| BS | 316S11 (nearest equivalent) |
| ISO | X2CrNiMo17-12-2 |
| ASTM | A240, A276, A182, A312 TP316L |
| ASME | SA-182 F 316L |
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Density | Physical properties row of the ATI table, value in g/cm3 as printed (the 0.29 lb/in3 entry is the imperial value) | basis density row, shown for plate, sheet and striptemperature not statedform plate, sheet, strip | — |
| 2 | Density | Physical Properties table, printed as 0.29 lb/in3 (8.027 g/cm3) | basis physical properties table, no temperature stated | — |
| 3 | Density | Physical Properties table, metric column as printed | temperature 20 C (printed as At 20oC)basis Physical Properties table, metric column | — |
| 4 | elastic modulus | Physical Properties table, Modulus of Elasticity row, printed as 193 x 10 MPa in tension with the exponent garbled in the PDF text; 193 x 10^3 MPa equals 193 GPa | temperature 20 C (printed as At 20oC)loading tensionunit in source 193 x 10^3 MPa | — |
| 5 | elastic modulus | Physical Properties table, Modulus of Elasticity in Tension row, GPa value as printed in brackets | loading tensionbasis no temperature statedunit in source 29 x 10^6 psi | — |
| 6 | shear modulus | Physical Properties table, Modulus of Shear row, GPa value as printed in brackets | basis no temperature statedunit in source 11.9 x 10^6 psi | — |
| 7 | melting point | Physical Properties table, Melting Range row, range printed in C in brackets; minimum and maximum as printed | basis melting range as printedunit in source 2540 to 2630 F | — |
| 8 | specific heat | Specific Heat table, value at 20 C as printed in J/kg K | temperature 20 C (68 F) | — |
| 9 | Thermal conductivity | Thermal Conductivity table, value in W/m K as printed | temperature range 20 to 100 C (68 to 212 F) | — |
| 10 | Thermal conductivity | Physical Properties table, metric value at 100 C as printed | temperature 100 C (printed as 100oC) | — |
| 11 | Thermal expansion (CTE) | Linear Coefficient of Thermal Expansion table, mean value for 20 to 100 C printed as 16.5 x 10^-6 cm/cm/C | temperature range 20 to 100 C (68 to 212 F)basis mean coefficient over the range | — |
| 12 | Thermal expansion (CTE) | Coefficient of Expansion row, metric value as printed in μm/m-oC | temperature range 0 to 100 C (printed as 0-100oC) | — |
| 13 | electrical resistivity | Electrical Resistivity row, metric value as printed in μ ohm.cm | temperature 20 C (printed as At 20oC) | — |
| 14 | ultimate tensile strength | Mechanical properties table, tensile strength row, minimum as printed (70 ksi min, 485 min) | form plate, sheet, stripbasis minimum value as printed (ASTM A240 per the page)temper not stated | — |
| 15 | ultimate tensile strength | Mechanical Properties of 316/316L table, Ultimate Tensile Strength row, MPa value in the 316L column | alloy Type 316L (S31603) columnbasis table value, minimum or typical not statedtemper not statedunit in source 70,000 psi | — |
| 16 | ultimate tensile strength | Typical Room Temperature Mechanical Properties table, Annealed (Min) row, MPa as printed; the data sheet notes the values are based on ASTM A240 | temper annealedbasis Annealed (Min) row of the typical room temperature tableunit in source 81 ksi | — |
| 17 | yield strength | Mechanical properties table, yield strength row, minimum as printed (25 ksi min, 170 min) | form plate, sheet, stripbasis minimum value as printed; offset not stated on this pagetemper not stated | — |
| 18 | yield strength | Mechanical Properties of 316/316L table, Yield Strength 0.2% Offset row, MPa value in the 316L column | alloy Type 316L (S31603) columnoffset 0.2%basis table value, minimum or typical not statedtemper not statedunit in source 25,000 psi | — |
| 19 | yield strength | Typical Room Temperature Mechanical Properties table, 0.2% YS column, Annealed (Min) row, MPa as printed; the same row is labelled typical in the header note | temper annealedoffset 0.2%basis Annealed (Min) row of the typical room temperature tableunit in source 42 ksi | — |
| 20 | elongation | Mechanical properties table, elongation row, as printed (40% min) | form plate, sheet, stripbasis minimum as printedgauge length not stated on this pagetemper not stated | — |
| 21 | elongation | Mechanical Properties of 316/316L table, Percent Elongation row, 316L column | alloy Type 316L (S31603) columngauge length 2 in or 51 mmbasis table value, minimum or typical not statedtemper not stated | — |
| 22 | elongation | Typical Room Temperature Mechanical Properties table, Elongation column, Annealed (Min) row, as printed | temper annealedgauge length 2 in (50.8 mm)basis Annealed (Min) row of the typical room temperature table | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Chloride-bearing water and submerged seawater | moderate | Chloride ions cause pitting and crevice corrosion in susceptible stainless steels; for submerged seawater a pitting resistance equivalent number greater than 40 is typically specified.1 |
| Sulfuric, hydrochloric, acetic, formic and tartaric acids; acid sulfates and alkaline chlorides | low | Combined Metals says corrosion resistance is improved against these acids and salts, and that molybdenum improves resistance to chloride pitting.2 |
| Heating or slow cooling through 450 to 900 C, as in a weld heat-affected zone | moderate | Chromium carbide forms at grain boundaries in this range; 316L limits carbon to 0.030 percent maximum to reduce it.3 |
| Long isothermal holds at 650 C | moderate | Sigma phase forms at grain boundaries after long holds; the study saw it after 1000 h at 650 C.4 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Chloride-bearing water and submerged seawater | Wikipedia says 316 and 316L, although used commonly in marine applications, are not suitable for condenser tubes in seawater because they are susceptible to crevice and pitting corrosion. It calls 316L the preferred steel for marine environments because of its greater resistance to pitting corrosion than most other grades of steel without molybdenum. | solution chloride, seawatercriterion pitting resistance equivalent number greater than 40 for submerged service (Wikipedia) |
| 2 | Sulfuric, hydrochloric, acetic, formic and tartaric acids; acid sulfates and alkaline chlorides | The data sheet says the molybdenum addition increases general corrosion resistance and improves resistance to pitting from chloride ion solutions. UPMET says the molybdenum-bearing 316 family is more resistant to general corrosion and pitting and crevice corrosion than Type 304. No corrosion rate or test result for 316L was read in this run. | basis qualitative datasheet statement, no test conditions given |
| 3 | Heating or slow cooling through 450 to 900 C, as in a weld heat-affected zone | Thermal Processing says austenitic stainless steels become sensitized in the 450 to 900 C range, with chromium carbide precipitating at grain boundaries, and sensitization occurs when carbon is above about 0.02 percent. The L designation controls carbon to below 0.030 percent to improve weldability and limit chromium carbide. Deliberate sensitization is done by holding at 650 C for one to two hours, and testing follows ASTM A262. | temperature 450 to 900 Ccarbon threshold above about 0.02 percentcarbon limit L below 0.030 percenttest ASTM A262, deliberate 650 C hold for 1 to 2 h |
| 4 | Long isothermal holds at 650 C | A study of AISI 316L (0% cold work, and 40% cold work followed by annealing) found M23C6 carbide, chi and sigma phases precipitated at grain boundaries, with sigma in the 650 C for 1000 h condition. The authors say sigma kinetics are very slow, so it can take hundreds to thousands of hours to form, and that precipitation of carbides and sigma, chi and Laves phases causes sensitisation of the steel. | temperature 650 Ctime 100, 300 and 1000 h annealing seriesmaterial condition 0% cold work, and 40% cold work then annealing |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
The PubChem records below are for elemental nickel, chromium and molybdenum, not for the finished alloy.
- Nickel
- PubChem lists elemental nickel as Danger: H317 (skin sensitiser), H351 (suspected carcinogen) and H372 (organ damage on repeated exposure).
- Chromium
- PubChem lists elemental chromium with H317, H319 and H334 in notifications that carry hazard codes. Half of the 2,404 reports say it does not meet GHS criteria.
- Molybdenum
- PubChem's notifications for the element are mixed. Some carry H228 (flammable solid) and H361 (suspected of damaging fertility or the unborn child); others carry H315, H319 and H335.
- Workshop
- Cutting, grinding and welding stainless steel can release metal fume and dust. No fume source was read in this run, so check the supplier safety data sheet before work.
Welding and heat
Sensitization is the main fabrication risk, and the L grade is made low-carbon to limit it.
- Range
- Holding or slow cooling between 450 and 900 C precipitates chromium carbide at grain boundaries (Thermal Processing).
- Fix
- 316L limits carbon to 0.030 percent maximum. UPMET lists 316 with up to 0.08 percent carbon, so 316L is the welded choice.
In seawater
Pitting and crevice corrosion are the main failure routes in chloride service.
- Seawater
- Wikipedia says a pitting resistance equivalent number greater than 40 is typically specified for submerged seawater service.
- Condenser tubes
- Wikipedia says 316 and 316L are not suitable for seawater condenser tubes because they are susceptible to crevice and pitting corrosion.
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Intergranular (sensitization) corrosion after welding or slow coolingmoderate severity | Slow cooling or holding through 450 to 900 C, as in a weld heat-affected zoneChromium carbide at grain boundaries leaves the boundary open to attack. The 0.030 percent carbon limit makes this much less likely than in the higher-carbon 316. |
| Pitting and crevice corrosion in seawater or chloride servicehigh severity | Submerged seawater or chloride-bearing water where the pitting resistance equivalent number is not above 40316 and 316L are not suitable for seawater condenser tubes because they are susceptible to crevice and pitting corrosion (Wikipedia). |
| Sigma phase precipitation after long holds near 650 Cmoderate severity | Hundreds to thousands of hours at 650 C, as in long service or slow cooling through the rangeThe study reports that carbides and sigma, chi and Laves phases precipitate and cause sensitisation of the steel. The datasheets read here do not give a service temperature limit for this. |
Handling and storage
- Specify 316L, not 316, for welded parts in corrosive service. UPMET lists 316 with up to 0.08 percent carbon and 316L with a 0.030 percent maximum.
- Avoid holding 316L between 450 and 900 C during fabrication or service, because chromium carbide and sigma phase form in that range.
- The datasheets give ASTM A240 minimums for plate, sheet and strip, and separate annealed typical values. Check the mill certificate for the form and temper being bought.
Mitigations
- For vacuum service, vacuum-fire the parts at about 950 C for 24 hours under vacuum. In NIST's seven-chamber comparison, unfired 304L, 316L and 316LN chambers gave hydrogen outgassing of 4.0 to 8.0 x 10^-11 Pa L/s/cm2, while the vacuum-fired 316L-XHV chamber gave below 1 x 10^-11.
- For submerged seawater service, a pitting resistance equivalent number greater than 40 is typically specified as the minimum (Wikipedia).
- Use the low-carbon 316L rather than 316 wherever the part will be welded, so that carbide precipitation at the weld is limited.
Supply and geography
How common the raw materials are and where they come from.
Nickel
Stainless and alloy steel plus nickel-containing alloys typically account for more than 85% of US domestic consumption. World reserves are more than 140,000,000 t, of which Indonesia holds 62,000,000 t (USGS 2026).
- Top producers (2025)
- Indonesia 66.7%, Philippines 6.9%, Russia 5.1%, New Caledonia 3.6%, Canada 3.6%, China 3.1%
- Recycling
- Nickel recovered from scrap accounted for about 60% of US apparent consumption in 2025, and most recycled nickel goes into new alloys and stainless steel (USGS 2026).
- Substitutes
- Low-nickel, duplex or ultrahigh-chromium stainless steels have been substituted for austenitic grades in construction (USGS 2026); Titanium alloys can substitute for nickel or nickel-base alloys in corrosive environments (USGS 2026)
Nickel import reliance, United States
US net import reliance was an estimated 41% of apparent consumption in 2025 (USGS 2026).
- Recycling
- Recycled nickel was about 60% of apparent consumption in 2025.
Chromium
World resources are greater than 12 billion t of shipping-grade chromite, and 95% of world chromium resources lie in Kazakhstan and southern Africa (USGS 2026).
- Top producers (2025)
- South Africa 45.1%, Turkey 17.6%, Kazakhstan 13.7%, India 5.9%, Brazil 3.9%, Zimbabwe 3.9%
- Recycling
- Recycled chromium in stainless-steel scrap receipts was 21% of US apparent consumption in 2025 (USGS 2026).
- Substitutes
- Chromium has no substitute in stainless steel, the leading end use (USGS 2026)
Chromium import reliance, United States
US net import reliance was 79% of apparent consumption in 2025 (estimated). Chromite imports 2021 to 2024: South Africa 96%, Turkey 3% (USGS 2026).
- Recycling
- Recycled chromium was 21% of apparent consumption in 2025.
Molybdenum
Molybdenum is used principally as an alloying agent in cast iron, steel and superalloys (USGS 2026). World mine production was an estimated 260,000 t of molybdenum content in 2025.
- Top producers (2025)
- China 37.3%, Chile 16.2%, United States 15.4%, Peru 15%, Mexico 6.5%
- Recycling
- Molybdenum recycled as part of new and old steel and other scrap may be as much as 30% of apparent supply (USGS 2026).
- Substitutes
- There is little substitution for molybdenum in steels and cast irons (USGS 2026)
Molybdenum export controls
The Government of China imposed export controls on molybdenum powders in February 2025, and the United States and other countries have sought alternative sources (USGS 2026).
Critical-mineral status
Nickel and chromium are on the USGS 2025 List of Critical Minerals (60 minerals, November 2025). Molybdenum is not on the list.
- Critical mineral lists
- US: listed, US: listed, US: not listed
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
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spore: profile
id: stainless-316l
spore_version: 0.2
family: stainless-austenitic
name: Stainless steel 316L
abbreviation: 316L (UNS S31603)
role: corrosion-resistant structural alloy
category: metals
type: steels-and-stainless
summary: |
Type 316L is the extra-low-carbon form of 316, an austenitic chromium-nickel stainless steel with 2 to 3 percent molybdenum added. The molybdenum improves resistance to chloride pitting, and the carbon limit of 0.030 percent maximum limits chromium carbide after welding. Datasheets give a minimum tensile strength of 485 MPa and a minimum yield strength of 170 MPa for sheet, plate and strip, and a density of 7.99 to 8.03 g/cm3. Its uses cited here are marine parts, aerospace structures and vacuum hardware. Its main limits are sensitization after slow cooling through 450 to 900 C and pitting in seawater.
best_for: Welded parts in chloride or marine service, and vacuum hardware that is vacuum-fired
weakest_at: Long holds near 650 C form sigma phase, and seawater service needs a pitting resistance equivalent number greater than 40 (Wikipedia)
identity:
formula: Fe balance; 16.0 to 18.0 Cr, 10.0 to 14.0 Ni, 2.00 to 3.00 Mo, max 0.030 C, max 2.00 Mn, max 0.75 Si, max 0.045 P, max 0.030 S, max 0.10 N (wt%)
source: cmc-316l
where: Nominal Composition table of the Combined Metals data sheet (REV 2024 01 11); the UPMET 316/316L composition table gives the same limits
designations:
- system: UNS
code: S31603
source: cmc-316l
where: Title and header of the Combined Metals data sheet (Alloy 316L Stainless Steel, UNS S31603)
- system: EN
code: '1.4404'
source: outokumpu-quarto
where: 'Supra 316L/4404 entry, ''EN: 1.4404'' with ''ASTM type: TYPE 316L / UNS S31603'''
- system: EN
code: '1.4435'
source: alleima-list
where: 'EN steel no. column, Alleima 3R60 row (S31603, 316L, 1.4435); Outokumpu Supra 316L/4435 also prints ''EN: 1.4435'''
- system: EN name
code: X2CrNiMo17-12-2
source: alloys-intl-316l
where: 316L entry, W.Nr 1.4404 followed by X2CrNiMo17-12-2
- system: DIN
code: X2CrNiMo 17 13 2
source: totalmateria-en-1-4404
where: EN 1.4404 international equivalents, row with standard DIN (free view, 15 of 1066 rows)
- system: JIS
code: SUS316L
source: totalmateria-astm-a240-316l
where: ASTM A 240 Type 316L international equivalents, row SUS316L with standard JIS (free view, 15 of 1059 rows)
- system: ISO
code: X2CrNiMo17-12-2
source: totalmateria-en-1-4404
where: EN 1.4404 international equivalents, last row, standard ISO (free view)
- system: AISI
code: 316L
source: icast-astm-a240
where: ICAST ASTM A240 UNS S31603 data sheet, cross reference table, row 316L with standard AISI
- system: ASTM
code: A240
source: cmc-316l
where: Applicable Specifications line of the Combined Metals 316L data sheet
- system: ASTM
code: A276
source: carpenter-316l
where: Applicable Specifications list on the Carpenter 316L page
- system: ASTM
code: A182
source: carpenter-316l
where: Applicable Specifications list on the Carpenter 316L page (the F316L form is not printed under ASTM)
- system: ASTM
code: A312 TP316L
source: totalmateria-astm-a312-tp316l
where: 'Page title ''ASTM A 312 TP316L'' with standard A312/A312M: 2025 (free view)'
- system: ASME
code: SA-182 F 316L
source: totalmateria-astm-a240-316l
where: ASTM A 240 Type 316L international equivalents, row SA-182 F 316L with standard ASME (free view)
- system: BS
code: 316S11
note: nearest equivalent
source: aalco-316l
where: Aalco 1.4404 (316L) sheet and plate datasheet, same 'may not be a direct equivalent' list. Totalmateria (standard B.S.) and ICAST print 316 S 11 without the hedge.
tags:
environments: []
stresses: []
applications:
- structures
properties:
- benchmark: density
value: 8.03
unit: g/cm3
scope: material
conditions:
basis: density row, shown for plate, sheet and strip
temperature: not stated
form: plate, sheet, strip
method: Physical properties row of the ATI table, value in g/cm3 as printed (the 0.29 lb/in3 entry is the imperial value)
status: ground
source: ati-316l
where: Density row of the ATI 316L table
- benchmark: density
value: 8.027
unit: g/cm3
scope: material
conditions:
basis: physical properties table, no temperature stated
method: Physical Properties table, printed as 0.29 lb/in3 (8.027 g/cm3)
status: ground
source: upmet-316l
where: Physical Properties of 316/316L table, Density row
- benchmark: density
value: 7.99
unit: g/cm3
scope: material
conditions:
temperature: 20 C (printed as At 20oC)
basis: Physical Properties table, metric column
method: Physical Properties table, metric column as printed
status: ground
source: cmc-316l
where: Physical Properties table, Density row
- benchmark: elastic_modulus
value: 193
unit: GPa
scope: material
conditions:
temperature: 20 C (printed as At 20oC)
loading: tension
unit_in_source: 193 x 10^3 MPa
method: Physical Properties table, Modulus of Elasticity row, printed as 193 x 10 MPa in tension with the exponent garbled in the PDF text; 193 x 10^3 MPa equals 193 GPa
status: ground
source: cmc-316l
where: Physical Properties table, Modulus of Elasticity (E) row
- benchmark: elastic_modulus
value: 200
unit: GPa
scope: material
conditions:
loading: tension
basis: no temperature stated
unit_in_source: 29 x 10^6 psi
method: Physical Properties table, Modulus of Elasticity in Tension row, GPa value as printed in brackets
status: ground
source: upmet-316l
where: Physical Properties of 316/316L table, Modulus of Elasticity in Tension row
- benchmark: shear_modulus
value: 82
unit: GPa
scope: material
conditions:
basis: no temperature stated
unit_in_source: 11.9 x 10^6 psi
method: Physical Properties table, Modulus of Shear row, GPa value as printed in brackets
status: ground
source: upmet-316l
where: Physical Properties of 316/316L table, Modulus of Shear row
- benchmark: melting_point
value: 1390
value_high: 1440
unit: °C
scope: material
conditions:
basis: melting range as printed
unit_in_source: 2540 to 2630 F
method: Physical Properties table, Melting Range row, range printed in C in brackets; minimum and maximum as printed
status: ground
source: upmet-316l
where: Physical Properties of 316/316L table, Melting Range row
- benchmark: specific_heat
value: 450
unit: J/kg °K
scope: material
conditions:
temperature: 20 C (68 F)
method: Specific Heat table, value at 20 C as printed in J/kg K
status: ground
source: upmet-316l
where: Physical Properties of 316/316L table, Specific Heat row at 20 C
- benchmark: thermal_conductivity
value: 14.6
unit: W/m·K
scope: material
conditions:
temperature_range: 20 to 100 C (68 to 212 F)
method: Thermal Conductivity table, value in W/m K as printed
status: ground
source: upmet-316l
where: Physical Properties of 316/316L table, Thermal Conductivity row (20 to 100 C)
- benchmark: thermal_conductivity
value: 16.2
unit: W/m·K
scope: material
conditions:
temperature: 100 C (printed as 100oC)
method: Physical Properties table, metric value at 100 C as printed
status: ground
source: cmc-316l
where: Physical Properties table, Thermal Conductivity row
- benchmark: cte
value: 16.5
unit: 10-6 cm/cm/°C
scope: material
conditions:
temperature_range: 20 to 100 C (68 to 212 F)
basis: mean coefficient over the range
method: Linear Coefficient of Thermal Expansion table, mean value for 20 to 100 C printed as 16.5 x 10^-6 cm/cm/C
status: ground
source: upmet-316l
where: Physical Properties of 316/316L table, linear CTE row for 20 to 100 C
- benchmark: cte
value: 16
unit: μm/m·°C
scope: material
conditions:
temperature_range: 0 to 100 C (printed as 0-100oC)
method: Coefficient of Expansion row, metric value as printed in μm/m-oC
status: ground
source: cmc-316l
where: Physical Properties table, Coefficient of Expansion row
- benchmark: electrical_resistivity
value: 74
unit: μΩ·cm
scope: material
conditions:
temperature: 20 C (printed as At 20oC)
method: Electrical Resistivity row, metric value as printed in μ ohm.cm
status: ground
source: cmc-316l
where: Physical Properties table, Electrical Resistivity row
- benchmark: ultimate_tensile_strength
value: 485
unit: MPa
scope: material
conditions:
form: plate, sheet, strip
basis: minimum value as printed (ASTM A240 per the page)
temper: not stated
method: Mechanical properties table, tensile strength row, minimum as printed (70 ksi min, 485 min)
status: ground
source: ati-316l
where: Mechanical properties table, Tensile Strength row
- benchmark: ultimate_tensile_strength
value: 485
unit: MPa
scope: material
conditions:
alloy: Type 316L (S31603) column
basis: table value, minimum or typical not stated
temper: not stated
unit_in_source: 70,000 psi
method: Mechanical Properties of 316/316L table, Ultimate Tensile Strength row, MPa value in the 316L column
status: ground
source: upmet-316l
where: Mechanical Properties of 316/316L table, Ultimate Tensile Strength row, 316L column
- benchmark: ultimate_tensile_strength
value: 558
unit: MPa
scope: material
conditions:
temper: annealed
basis: Annealed (Min) row of the typical room temperature table
unit_in_source: 81 ksi
method: Typical Room Temperature Mechanical Properties table, Annealed (Min) row, MPa as printed; the data sheet notes the values are based on ASTM A240
status: ground
source: cmc-316l
where: Typical Room Temperature Mechanical Properties table, Annealed (Min) row
- benchmark: yield_strength
value: 170
unit: MPa
scope: material
conditions:
form: plate, sheet, strip
basis: minimum value as printed; offset not stated on this page
temper: not stated
method: Mechanical properties table, yield strength row, minimum as printed (25 ksi min, 170 min)
status: ground
source: ati-316l
where: Mechanical properties table, Yield Strength row
- benchmark: yield_strength
value: 170
unit: MPa
scope: material
conditions:
alloy: Type 316L (S31603) column
offset: 0.2%
basis: table value, minimum or typical not stated
temper: not stated
unit_in_source: 25,000 psi
method: Mechanical Properties of 316/316L table, Yield Strength 0.2% Offset row, MPa value in the 316L column
status: ground
source: upmet-316l
where: Mechanical Properties of 316/316L table, Yield Strength 0.2% Offset row, 316L column
- benchmark: yield_strength
value: 290
unit: MPa
scope: material
conditions:
temper: annealed
offset: 0.2%
basis: Annealed (Min) row of the typical room temperature table
unit_in_source: 42 ksi
method: Typical Room Temperature Mechanical Properties table, 0.2% YS column, Annealed (Min) row, MPa as printed; the same row is labelled typical in the header note
status: ground
source: cmc-316l
where: Typical Room Temperature Mechanical Properties table, 0.2% YS column
- benchmark: elongation
value: 40
unit: '%'
scope: material
conditions:
form: plate, sheet, strip
basis: minimum as printed
gauge_length: not stated on this page
temper: not stated
method: Mechanical properties table, elongation row, as printed (40% min)
status: ground
source: ati-316l
where: Mechanical properties table, Elongation row
- benchmark: elongation
value: 40
unit: '%'
scope: material
conditions:
alloy: Type 316L (S31603) column
gauge_length: 2 in or 51 mm
basis: table value, minimum or typical not stated
temper: not stated
method: Mechanical Properties of 316/316L table, Percent Elongation row, 316L column
status: ground
source: upmet-316l
where: Mechanical Properties of 316/316L table, Percent Elongation row, 316L column
- benchmark: elongation
value: 50
unit: '%'
scope: material
conditions:
temper: annealed
gauge_length: 2 in (50.8 mm)
basis: Annealed (Min) row of the typical room temperature table
method: Typical Room Temperature Mechanical Properties table, Elongation column, Annealed (Min) row, as printed
status: ground
source: cmc-316l
where: Typical Room Temperature Mechanical Properties table, Elongation row
corrosion:
- environment: Chloride-bearing water and submerged seawater
headline: Chloride ions cause pitting and crevice corrosion in susceptible stainless steels; for submerged seawater a pitting resistance equivalent number greater than 40 is typically specified.
effect: Wikipedia says 316 and 316L, although used commonly in marine applications, are not suitable for condenser tubes in seawater because they are susceptible to crevice and pitting corrosion. It calls 316L the preferred steel for marine environments because of its greater resistance to pitting corrosion than most other grades of steel without molybdenum.
rating: moderate
conditions:
solution: chloride, seawater
criterion: pitting resistance equivalent number greater than 40 for submerged service (Wikipedia)
source: wiki-316
where: 'Marine grade stainless article: Suitability for marine use, and the introduction'
- environment: Sulfuric, hydrochloric, acetic, formic and tartaric acids; acid sulfates and alkaline chlorides
headline: Combined Metals says corrosion resistance is improved against these acids and salts, and that molybdenum improves resistance to chloride pitting.
effect: The data sheet says the molybdenum addition increases general corrosion resistance and improves resistance to pitting from chloride ion solutions. UPMET says the molybdenum-bearing 316 family is more resistant to general corrosion and pitting and crevice corrosion than Type 304. No corrosion rate or test result for 316L was read in this run.
rating: low
conditions:
basis: qualitative datasheet statement, no test conditions given
source: cmc-316l
where: Introduction paragraph of the Combined Metals data sheet
- environment: Heating or slow cooling through 450 to 900 C, as in a weld heat-affected zone
headline: Chromium carbide forms at grain boundaries in this range; 316L limits carbon to 0.030 percent maximum to reduce it.
effect: Thermal Processing says austenitic stainless steels become sensitized in the 450 to 900 C range, with chromium carbide precipitating at grain boundaries, and sensitization occurs when carbon is above about 0.02 percent. The L designation controls carbon to below 0.030 percent to improve weldability and limit chromium carbide. Deliberate sensitization is done by holding at 650 C for one to two hours, and testing follows ASTM A262.
rating: moderate
conditions:
temperature: 450 to 900 C
carbon_threshold: above about 0.02 percent
carbon_limit_L: below 0.030 percent
test: ASTM A262, deliberate 650 C hold for 1 to 2 h
source: thermal-processing
where: Sensitization of Austenitic Stainless Steels; Introduction (L grades); Testing for Sensitization
- environment: Long isothermal holds at 650 C
headline: Sigma phase forms at grain boundaries after long holds; the study saw it after 1000 h at 650 C.
effect: A study of AISI 316L (0% cold work, and 40% cold work followed by annealing) found M23C6 carbide, chi and sigma phases precipitated at grain boundaries, with sigma in the 650 C for 1000 h condition. The authors say sigma kinetics are very slow, so it can take hundreds to thousands of hours to form, and that precipitation of carbides and sigma, chi and Laves phases causes sensitisation of the steel.
rating: moderate
conditions:
temperature: 650 C
time: 100, 300 and 1000 h annealing series
material_condition: 0% cold work, and 40% cold work then annealing
source: pmc-sigma-316l
where: Results and discussion (650 C annealing series, sigma phase); Introduction (sigma kinetics)
risks:
hazards:
- text: 'PubChem aggregated GHS for elemental nickel (CID 935, signal Danger): H317 May cause an allergic skin reaction; H351 Suspected of causing cancer; H372 Causes damage to organs through prolonged or repeated exposure. PubChem reports that 0.1 percent (5 of 4,778) of company reports say it does not meet GHS criteria. The data cover the element, not the alloy.'
ghs:
- H317
- H351
- H372
source: pubchem-nickel
where: Safety and Hazards, GHS Classification (aggregated)
- text: 'PubChem aggregated GHS for elemental chromium (CID 23976, signal Danger): H317 (20.7 percent of notifications) May cause an allergic skin reaction; H319 (19.1 percent) Causes serious eye irritation; H334 (20.3 percent) May cause allergy or asthma symptoms if inhaled. Half of 2,404 reports say it does not meet GHS criteria.'
ghs:
- H317
- H319
- H334
source: pubchem-chromium
where: Safety and Hazards, GHS Classification (aggregated)
- text: 'PubChem notifications for elemental molybdenum (CID 23932) are mixed: H228 (30 percent) Flammable solid and H361 (29.5 percent) Suspected of damaging fertility or the unborn child for one group, and H315, H319 and H335 (skin, eye and respiratory irritation) for another. 57.4 percent of 1,523 reports say it does not meet GHS criteria.'
ghs:
- H228
- H361
- H315
- H319
- H335
source: pubchem-molybdenum
where: Safety and Hazards, GHS Classification (aggregated and per-notification entries)
failure_risks:
- mode: Intergranular (sensitization) corrosion after welding or slow cooling
trigger: Slow cooling or holding through 450 to 900 C, as in a weld heat-affected zone
consequence: Chromium carbide at grain boundaries leaves the boundary open to attack. The 0.030 percent carbon limit makes this much less likely than in the higher-carbon 316.
severity: moderate
source: thermal-processing
where: Sensitization of Austenitic Stainless Steels
- mode: Pitting and crevice corrosion in seawater or chloride service
trigger: Submerged seawater or chloride-bearing water where the pitting resistance equivalent number is not above 40
consequence: 316 and 316L are not suitable for seawater condenser tubes because they are susceptible to crevice and pitting corrosion (Wikipedia).
severity: high
source: wiki-316
where: 'Marine grade stainless article: Suitability for marine use'
- mode: Sigma phase precipitation after long holds near 650 C
trigger: Hundreds to thousands of hours at 650 C, as in long service or slow cooling through the range
consequence: The study reports that carbides and sigma, chi and Laves phases precipitate and cause sensitisation of the steel. The datasheets read here do not give a service temperature limit for this.
severity: moderate
source: pmc-sigma-316l
where: Results and discussion; Introduction
side_effects: []
handling:
- text: Specify 316L, not 316, for welded parts in corrosive service. UPMET lists 316 with up to 0.08 percent carbon and 316L with a 0.030 percent maximum.
source: upmet-316l
where: Chemical Composition tables, 316/316L
- text: Avoid holding 316L between 450 and 900 C during fabrication or service, because chromium carbide and sigma phase form in that range.
source: thermal-processing
where: Sensitization of Austenitic Stainless Steels
- text: The datasheets give ASTM A240 minimums for plate, sheet and strip, and separate annealed typical values. Check the mill certificate for the form and temper being bought.
source: cmc-316l
where: Typical Room Temperature Mechanical Properties table, note
mitigations:
- text: For vacuum service, vacuum-fire the parts at about 950 C for 24 hours under vacuum. In NIST's seven-chamber comparison, unfired 304L, 316L and 316LN chambers gave hydrogen outgassing of 4.0 to 8.0 x 10^-11 Pa L/s/cm2, while the vacuum-fired 316L-XHV chamber gave below 1 x 10^-11.
source: nist-vacuum-2020
where: Abstract; Results (hydrogen outgassing); chamber table (316L-XHV, vacuum-fired 950 C, 24 hours or more)
- text: For submerged seawater service, a pitting resistance equivalent number greater than 40 is typically specified as the minimum (Wikipedia).
source: wiki-316
where: 'Marine grade stainless article: Suitability for marine use'
- text: Use the low-carbon 316L rather than 316 wherever the part will be welded, so that carbide precipitation at the weld is limited.
source: cmc-316l
where: Opening paragraph (316L is an extra-low carbon version of Type 316 that minimizes harmful carbide precipitation due to welding)
uses:
- application: structures
device: Aerospace structures
example: UPMET lists aerospace structures among the industry applications for 316 and 316L sheet, coil and bar. No flight or space test result is given on the datasheet.
source: upmet-316l
where: Industry Applications list, 316/316L datasheet
- application: structures
device: Parts exposed to marine atmospheres
example: Combined Metals lists parts exposed to marine atmospheres among the industries supplied for 316L, alongside exhaust manifolds, heat exchangers, jet engine parts and pharmaceutical equipment.
source: cmc-316l
where: Industries supplied paragraph, opening of the Combined Metals data sheet
- application: structures
device: Ultra-high-vacuum chamber walls (laboratory)
example: In a NIST comparison of seven similar vacuum chambers, the vacuum-fired 316L chamber had hydrogen outgassing below 1 x 10^-11 Pa L/s/cm2, in the same ultra-low class as the titanium and aluminium chambers.
source: nist-vacuum-2020
where: Abstract and hydrogen outgassing results
supply:
- subject: Nickel
abundance: Stainless and alloy steel plus nickel-containing alloys typically account for more than 85% of US domestic consumption. World reserves are more than 140,000,000 t, of which Indonesia holds 62,000,000 t (USGS 2026).
producers:
- country: Indonesia
share_percent: 66.7
year: 2025
basis: 2,600,000 t of 3,900,000 t world mine production (estimated), computed
- country: Philippines
share_percent: 6.9
year: 2025
basis: 270,000 t of 3,900,000 t, computed
- country: Russia
share_percent: 5.1
year: 2025
basis: 200,000 t of 3,900,000 t, computed
- country: New Caledonia
share_percent: 3.6
year: 2025
basis: 140,000 t of 3,900,000 t, computed
- country: Canada
share_percent: 3.6
year: 2025
basis: 140,000 t of 3,900,000 t, computed
- country: China
share_percent: 3.1
year: 2025
basis: 120,000 t of 3,900,000 t, computed
critical_lists: []
recycling: Nickel recovered from scrap accounted for about 60% of US apparent consumption in 2025, and most recycled nickel goes into new alloys and stainless steel (USGS 2026).
substitutes:
- Low-nickel, duplex or ultrahigh-chromium stainless steels have been substituted for austenitic grades in construction (USGS 2026)
- Titanium alloys can substitute for nickel or nickel-base alloys in corrosive environments (USGS 2026)
source: usgs-nickel-2026
where: Domestic Production and Use; World Mine Production and Reserves table (2025e); Recycling; Substitutes
- subject: Nickel import reliance, United States
abundance: US net import reliance was an estimated 41% of apparent consumption in 2025 (USGS 2026).
producers: []
critical_lists: []
recycling: Recycled nickel was about 60% of apparent consumption in 2025.
substitutes: []
source: usgs-nickel-2026
where: Salient Statistics (net import reliance row, 2025e)
- subject: Chromium
abundance: World resources are greater than 12 billion t of shipping-grade chromite, and 95% of world chromium resources lie in Kazakhstan and southern Africa (USGS 2026).
producers:
- country: South Africa
share_percent: 45.1
year: 2025
basis: 23,000 of 51,000 thousand t gross weight (estimated), computed
- country: Turkey
share_percent: 17.6
year: 2025
basis: 9,000 of 51,000 thousand t, computed
- country: Kazakhstan
share_percent: 13.7
year: 2025
basis: 7,000 of 51,000 thousand t, computed
- country: India
share_percent: 5.9
year: 2025
basis: 3,000 of 51,000 thousand t, computed
- country: Brazil
share_percent: 3.9
year: 2025
basis: 2,000 of 51,000 thousand t, computed
- country: Zimbabwe
share_percent: 3.9
year: 2025
basis: 2,000 of 51,000 thousand t, computed
critical_lists: []
recycling: Recycled chromium in stainless-steel scrap receipts was 21% of US apparent consumption in 2025 (USGS 2026).
substitutes:
- Chromium has no substitute in stainless steel, the leading end use (USGS 2026)
source: usgs-chromium-2026
where: World Mine Production and Reserves table (2025e, gross weight); World Resources; Substitutes; Recycling
- subject: Chromium import reliance, United States
abundance: 'US net import reliance was 79% of apparent consumption in 2025 (estimated). Chromite imports 2021 to 2024: South Africa 96%, Turkey 3% (USGS 2026).'
producers: []
critical_lists: []
recycling: Recycled chromium was 21% of apparent consumption in 2025.
substitutes: []
source: usgs-chromium-2026
where: Salient Statistics (net import reliance row); Import Sources (2021 to 2024)
- subject: Molybdenum
abundance: Molybdenum is used principally as an alloying agent in cast iron, steel and superalloys (USGS 2026). World mine production was an estimated 260,000 t of molybdenum content in 2025.
producers:
- country: China
share_percent: 37.3
year: 2025
basis: 97,000 of 260,000 t molybdenum content (estimated), computed
- country: Chile
share_percent: 16.2
year: 2025
basis: 42,000 of 260,000 t, computed
- country: United States
share_percent: 15.4
year: 2025
basis: 40,000 of 260,000 t, computed
- country: Peru
share_percent: 15
year: 2025
basis: 39,000 of 260,000 t, computed
- country: Mexico
share_percent: 6.5
year: 2025
basis: 17,000 of 260,000 t, computed
critical_lists: []
recycling: Molybdenum recycled as part of new and old steel and other scrap may be as much as 30% of apparent supply (USGS 2026).
substitutes:
- There is little substitution for molybdenum in steels and cast irons (USGS 2026)
source: usgs-molybdenum-2026
where: World Mine Production and Reserves table (2025e); Domestic Production and Use; Recycling; Substitutes
- subject: Molybdenum export controls
abundance: The Government of China imposed export controls on molybdenum powders in February 2025, and the United States and other countries have sought alternative sources (USGS 2026).
producers: []
critical_lists: []
recycling: ''
substitutes: []
source: usgs-molybdenum-2026
where: Events, Trends, and Issues
- subject: Critical-mineral status
abundance: Nickel and chromium are on the USGS 2025 List of Critical Minerals (60 minerals, November 2025). Molybdenum is not on the list.
producers: []
critical_lists:
- list: 'USGS 2025 List of Critical Minerals: nickel'
listed: true
- list: 'USGS 2025 List of Critical Minerals: chromium'
listed: true
- list: 'USGS 2025 List of Critical Minerals: molybdenum'
listed: false
recycling: ''
substitutes: []
source: usgs-crit-2025
where: About the 2025 List of Critical Minerals page (bulleted list); EU critical raw materials list not read
media: []
documents:
- title: 'Combined Metals Company data sheet: Alloy 316L Stainless Steel, UNS S31603 (REV 2024 01 11)'
type: datasheet
url: https://www.combmet.com/wp-content/uploads/2024/01/316L-Alloy-Data-Sheet-CMC-2024-01-11.pdf
year: 2024
- title: 'UPMET datasheet: 316/316L Stainless Steel Sheet, Coil and Bar (AMS 5524, 5507, 5648)'
type: datasheet
url: https://www.upmet.com/sites/default/files/datasheets/316-316l.pdf
year: 2026
- title: 'ATI: 316L Austenitic Stainless Steel, UNS S31603 (product page)'
type: datasheet
url: https://atimaterials.com/Products/ati-316l
- title: Influence of 40% Cold Working and Annealing on Precipitation in AISI 316L Austenitic Stainless Steel (PMC9505488)
type: paper
url: https://pmc.ncbi.nlm.nih.gov/articles/PMC9505488/
- title: 'Fedchak et al.: Outgassing rate comparison of seven geometrically similar vacuum chambers of different materials and heat treatments (arXiv:2009.10560)'
type: paper
url: https://arxiv.org/pdf/2009.10560
year: 2020
- title: 'USGS Mineral Commodity Summaries 2026: Nickel'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-nickel.pdf
year: 2026
- title: 'USGS Mineral Commodity Summaries 2026: Chromium'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-chromium.pdf
year: 2026
- title: 'USGS Mineral Commodity Summaries 2026: Molybdenum'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-molybdenum.pdf
year: 2026
- title: 'USGS: About the 2025 List of Critical Minerals'
type: report
url: https://www.usgs.gov/programs/mineral-resources-program/science/about-2025-list-critical-minerals
year: 2025
- title: 'PubChem: Nickel (CID 935) GHS classification'
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/935
year: 2026
- title: 'PubChem: Chromium (CID 23976) GHS classification'
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/23976
year: 2026
- title: 'PubChem: Molybdenum (CID 23932) GHS classification'
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/23932
year: 2026
- title: 'Alleima: list of alloys (billets and blooms), grade table with UNS, ASTM and EN steel numbers'
type: datasheet
url: https://www.alleima.com/cz/products/billets-and-blooms/list-of-alloys
- title: 'Aalco: Stainless Steel - Austenitic - 1.4404 (316L) Sheet and Plate (Quarto Plate and CPP)'
type: datasheet
url: https://www.aalco.co.uk/datasheets/Stainless-Steel-14404-316L-Sheet-and-Plate-Quarto-Plate--CPP-Plate_346.ashx
- title: 'Carpenter Technology: 316L alloy page (UNS, applicable specifications)'
type: datasheet
url: https://www.carpentertechnology.com/alloy-finder/316L
- title: 'Outokumpu: quarto plate page, Supra 316L/4404 and Supra 316L/4435 entries'
type: datasheet
url: https://www.outokumpu.com/en/products/flat-products/quarto-plate
- title: 'ICAST Alloys: ASTM A240 UNS S31603 data sheet, cross reference table'
type: datasheet
url: https://www.icastllp.com/material_db_pdf/ASTM%20A240%20UNS%20S31603.pdf
- title: 'Alloys International: stainless steel 316L page (W.Nr and EN names, specifications)'
type: datasheet
url: https://alloysintl.com/inventory/stainless-steel/stainless_steel316L/
- title: 'Total Materia: EN 1.4404 international equivalent materials'
type: database
url: https://www.totalmateria.com/en-us/material/1055292
- title: 'Total Materia: ASTM A 240 Type 316L international equivalent materials'
type: database
url: https://www.totalmateria.com/en-us/material/1261273
- title: 'Total Materia: ASTM A 312 TP316L international equivalent materials'
type: database
url: https://www.totalmateria.com/en-us/material/1260779
gaps:
- Medical implant use is recorded in the story only, because the application list has no medical value. Wikipedia calls 316L the preferred grade for medical implants.
- No flight, space-thermal, radiation or cryogenic result for 316L was found in this run. The only vacuum source is a laboratory outgassing comparison of chambers, not a space test.
- Poisson's ratio, hardness at temperature and cryogenic strength were not found in the pages read in this run.
- The AZoM 316L page could not be located, the Ulbrich 316L page returned HTTP 403, and the ASM Alloy Digest is behind a paywall.
- The Combined Metals (193 GPa) and UPMET (200 GPa) Young's moduli disagree. Both are kept with their conditions.
- The UPMET electrical resistivity table labels its two columns with the wrong units, so it is not used. The Combined Metals value (74 microohm cm) is used instead.
- The Combined Metals table labels the annealed row both as minimum and as typical. The yield and tensile values are kept as printed, with the label in conditions.
- The PubChem compound web page returned a browser check to the fetch tool, so the hazard records were read from PubChem's REST data for the same CIDs. No 316L safety data sheet was read, and welding-fume hazard was not sourced.
- The sigma-phase study uses 0% and 40% cold-worked 316L, not mill-annealed sheet, so the kinetics may differ for the product bought.
- No pitting potential, critical temperature or mg/L chloride limit for 316L was found. Only the PREN above 40 rule and qualitative statements are used.
- Critical-mineral status is from the USGS 2025 list only. The EU critical raw materials list was not read.
- Nickel, chromium and molybdenum shares are mine production only. Refinery and smelting shares were not read.
- Recycling and substitutes for 316L itself were not sourced beyond the element data.
- The Wikipedia page used for marine and medical statements is titled Marine grade stainless. Its composition table was not used for any number.
- 'Designations: the BGH 1.4435 datasheet link returned HTTP 404, so EN 1.4435 is cited from the Alleima and Outokumpu grade tables only.'
- 'Designations: the F316L form is not printed under ASTM on any page read in this run. ASTM A182 is cited from the Carpenter page, and SA-182 F 316L (ASME) from Totalmateria.'
- 'Designations: the ASTM A240 summary (store.astm.org, 2002 edition), the NZ Building Code Hub A240 and A276 summaries, and the BSI EN 10088-3:2023 summary print no 316L grade name, so none is cited for a designation.'
- 'Designations: Totalmateria free views show 15 of about 1,000 equivalents per standard, so further national names may exist behind registration.'
- 'Designations: names printed for 316L outside the requested systems were not added (GOST 03CH17N14M3, ASME SA-240, SA-312, SA-276 and SA-409, AMS and other ASTM product specifications, and GB, IS, AFNOR and CSN equivalents).'
- 'Designations: the ICAST EN 1.4404 cross-reference rows for JIS, AISI and BS are misaligned (SUS 304L, 361L), so the ICAST ASTM A240 data sheet is used for those names.'
sources:
ati-316l:
title: 'ATI: 316L Austenitic Stainless Steel, UNS S31603 (product page)'
id: ATI product page, 316L
url: https://atimaterials.com/Products/ati-316l
kind: datasheet
license: ATI web page (cited, not reproduced)
cmc-316l:
title: 'Combined Metals Company data sheet: Alloy 316L Stainless Steel, UNS S31603, EN-DIN 1.4404'
id: REV 2024 01 11
url: https://www.combmet.com/wp-content/uploads/2024/01/316L-Alloy-Data-Sheet-CMC-2024-01-11.pdf
year: 2024
kind: datasheet
license: supplier data sheet (cited, not reproduced)
upmet-316l:
title: 'UPMET datasheet: 316/316L Stainless Steel Sheet, Coil and Bar (AMS 5524, 5507, 5648)'
id: UNS S31600 and S31603
url: https://www.upmet.com/sites/default/files/datasheets/316-316l.pdf
year: 2026
kind: datasheet
license: supplier data sheet (cited, not reproduced)
wiki-316:
title: 'Wikipedia: Marine grade stainless (316 and 316L; URL 316_stainless_steel)'
id: Marine grade stainless
url: https://en.wikipedia.org/wiki/316_stainless_steel
kind: web
license: CC BY-SA 4.0 (cited, not reproduced)
thermal-processing:
title: 'Thermal Processing: Intergranular Corrosion of Austenitic Stainless Steels'
id: thermalprocessing.com
url: https://thermalprocessing.com/intergranular-corrosion-of-austenitic-stainless-steels/
kind: web
license: web page (cited, not reproduced)
pmc-sigma-316l:
title: Influence of 40% Cold Working and Annealing on Precipitation in AISI 316L Austenitic Stainless Steel
id: PMC9505488
url: https://pmc.ncbi.nlm.nih.gov/articles/PMC9505488/
kind: paper
license: open-access article (cited, not reproduced)
nist-vacuum-2020:
title: 'Fedchak et al.: Outgassing rate comparison of seven geometrically similar vacuum chambers of different materials and heat treatments'
id: arXiv:2009.10560
url: https://arxiv.org/pdf/2009.10560
year: 2020
kind: paper
license: arXiv preprint (cited, not reproduced)
usgs-nickel-2026:
title: 'USGS Mineral Commodity Summaries 2026: Nickel'
id: mcs2026-nickel
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-nickel.pdf
year: 2026
kind: report
license: public domain (USGS)
usgs-chromium-2026:
title: 'USGS Mineral Commodity Summaries 2026: Chromium'
id: mcs2026-chromium
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-chromium.pdf
year: 2026
kind: report
license: public domain (USGS)
usgs-molybdenum-2026:
title: 'USGS Mineral Commodity Summaries 2026: Molybdenum'
id: mcs2026-molybdenum
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-molybdenum.pdf
year: 2026
kind: report
license: public domain (USGS)
usgs-crit-2025:
title: 'USGS: About the 2025 List of Critical Minerals'
id: 2025 List of Critical Minerals, November 2025
url: https://www.usgs.gov/programs/mineral-resources-program/science/about-2025-list-critical-minerals
year: 2025
kind: web
license: public domain (USGS)
pubchem-nickel:
title: 'PubChem: Nickel (CID 935), Safety and Hazards, GHS Classification'
id: CID 935
url: https://pubchem.ncbi.nlm.nih.gov/compound/935
kind: database
license: PubChem terms (public)
pubchem-chromium:
title: 'PubChem: Chromium (CID 23976), Safety and Hazards, GHS Classification'
id: CID 23976
url: https://pubchem.ncbi.nlm.nih.gov/compound/23976
kind: database
license: PubChem terms (public)
pubchem-molybdenum:
title: 'PubChem: Molybdenum (CID 23932), Safety and Hazards, GHS Classification'
id: CID 23932
url: https://pubchem.ncbi.nlm.nih.gov/compound/23932
kind: database
license: PubChem terms (public)
alleima-list:
title: 'Alleima: list of alloys (billets and blooms), grade table with UNS, ASTM and EN steel numbers'
id: Alleima list of alloys
url: https://www.alleima.com/cz/products/billets-and-blooms/list-of-alloys
kind: datasheet
license: web page (cited, not reproduced)
aalco-316l:
title: 'Aalco: Stainless Steel - Austenitic - 1.4404 (316L) Sheet and Plate (Quarto Plate and CPP)'
id: 1.4404 (316L) sheet and plate
url: https://www.aalco.co.uk/datasheets/Stainless-Steel-14404-316L-Sheet-and-Plate-Quarto-Plate--CPP-Plate_346.ashx
kind: datasheet
license: supplier data sheet (cited, not reproduced)
carpenter-316l:
title: 'Carpenter Technology: 316L alloy page (UNS, applicable specifications)'
id: 316L alloy finder page
url: https://www.carpentertechnology.com/alloy-finder/316L
kind: datasheet
license: manufacturer web page (cited, not reproduced)
outokumpu-quarto:
title: 'Outokumpu: quarto plate page, Supra 316L/4404 and Supra 316L/4435 entries'
id: quarto plate page
url: https://www.outokumpu.com/en/products/flat-products/quarto-plate
kind: datasheet
license: manufacturer web page (cited, not reproduced)
icast-astm-a240:
title: 'ICAST Alloys: ASTM A240 UNS S31603 data sheet, cross reference table'
id: ASTM A240 UNS S31603
url: https://www.icastllp.com/material_db_pdf/ASTM%20A240%20UNS%20S31603.pdf
kind: datasheet
license: stockist data sheet (cited, not reproduced)
alloys-intl-316l:
title: 'Alloys International: stainless steel 316L page (W.Nr and EN names, specifications)'
id: stainless_steel316L page
url: https://alloysintl.com/inventory/stainless-steel/stainless_steel316L/
kind: datasheet
license: stockist web page (cited, not reproduced)
totalmateria-en-1-4404:
title: 'Total Materia: EN 1.4404 international equivalent materials'
id: EN 1.4404 (free view)
url: https://www.totalmateria.com/en-us/material/1055292
kind: database
license: database page, free view (cited, not reproduced)
totalmateria-astm-a240-316l:
title: 'Total Materia: ASTM A 240 Type 316L international equivalent materials'
id: ASTM A 240 Type 316L (free view)
url: https://www.totalmateria.com/en-us/material/1261273
kind: database
license: database page, free view (cited, not reproduced)
totalmateria-astm-a312-tp316l:
title: 'Total Materia: ASTM A 312 TP316L international equivalent materials'
id: ASTM A 312 TP316L (free view)
url: https://www.totalmateria.com/en-us/material/1260779
kind: database
license: database page, free view (cited, not reproduced)
license: CC-BY-4.0
updated: '2026-10-24'
review:
status: draft
method: assistant
checked_values: 22
unreachable: 3
caveats: 1
note: 'Written by an AI assistant on 2026-10-24 from pages fetched in that run: three datasheets, Wikipedia marine grade stainless, the Thermal Processing sensitization page, the PMC sigma-phase study, the NIST arXiv vacuum paper, USGS 2026 nickel, chromium and molybdenum, the USGS 2025 critical list, and PubChem GHS records for nickel, chromium and molybdenum. Unreachable in this run: AZoM 316L page, Ulbrich 316L page (HTTP 403), and the PubChem web page (browser check).'
story:
recipe:
line: 316L is an iron-based austenitic stainless steel. Its nominal composition, from the Combined Metals and UPMET data sheets, is 16 to 18 wt% chromium, 10 to 14 wt% nickel and 2 to 3 wt% molybdenum, with carbon held to 0.030 wt% maximum and iron as the balance. UPMET lists the product as coil, sheet, bar and precision strip. The NIST vacuum study fired its 316L-XHV chamber at about 950 C for 24 hours under vacuum.
parts:
- name: Iron
symbol: Fe
share_note: balance (the rest)
role: The matrix of the alloy.
- name: Chromium
symbol: Cr
share_percent: 16
share_high: 18
role: Forms the passive oxide film that gives corrosion resistance.
- name: Nickel
symbol: Ni
share_percent: 10
share_high: 14
role: Holds the austenite structure.
- name: Molybdenum
symbol: Mo
share_percent: 2
share_high: 3
role: Increases general corrosion resistance and resistance to chloride pitting (Combined Metals).
- name: Carbon
symbol: C
share_percent: 0
share_high: 0.03
limit: maximum
role: Kept low so that chromium carbide does not form at grain boundaries after welding.
- name: Manganese
symbol: Mn
share_percent: 0
share_high: 2
limit: maximum
role: Impurity and processing element held to a maximum.
- name: Silicon
symbol: Si
share_percent: 0
share_high: 0.75
limit: maximum
role: Held to a maximum.
- name: Phosphorus
symbol: P
share_percent: 0
share_high: 0.045
limit: maximum
role: Impurity held low.
- name: Sulfur
symbol: S
share_percent: 0
share_high: 0.03
limit: maximum
role: Impurity held low.
- name: Nitrogen
symbol: 'N'
share_percent: 0
share_high: 0.1
limit: maximum
role: Held to a maximum.
risk_groups:
- title: For people
level: 0
verdict: Not checked against a 316L safety data sheet
lead: The PubChem records below are for elemental nickel, chromium and molybdenum, not for the finished alloy.
points:
- label: Nickel
line: 'PubChem lists elemental nickel as Danger: H317 (skin sensitiser), H351 (suspected carcinogen) and H372 (organ damage on repeated exposure).'
- label: Chromium
line: PubChem lists elemental chromium with H317, H319 and H334 in notifications that carry hazard codes. Half of the 2,404 reports say it does not meet GHS criteria.
- label: Molybdenum
line: PubChem's notifications for the element are mixed. Some carry H228 (flammable solid) and H361 (suspected of damaging fertility or the unborn child); others carry H315, H319 and H335.
- label: Workshop
line: Cutting, grinding and welding stainless steel can release metal fume and dust. No fume source was read in this run, so check the supplier safety data sheet before work.
- title: Welding and heat
level: 1
verdict: Use 316L for welded parts in corrosive service
lead: Sensitization is the main fabrication risk, and the L grade is made low-carbon to limit it.
points:
- label: Range
line: Holding or slow cooling between 450 and 900 C precipitates chromium carbide at grain boundaries (Thermal Processing).
- label: Fix
line: 316L limits carbon to 0.030 percent maximum. UPMET lists 316 with up to 0.08 percent carbon, so 316L is the welded choice.
- title: In seawater
level: 1
verdict: Chloride is the watch point
lead: Pitting and crevice corrosion are the main failure routes in chloride service.
points:
- label: Seawater
line: Wikipedia says a pitting resistance equivalent number greater than 40 is typically specified for submerged seawater service.
- label: Condenser tubes
line: Wikipedia says 316 and 316L are not suitable for seawater condenser tubes because they are susceptible to crevice and pitting corrosion.
why: Type 316L is the low-carbon version of 316. Adding 2 to 3 percent molybdenum to the chromium-nickel steel improves resistance to chloride pitting, and UPMET says the molybdenum-bearing 316 family is more resistant to pitting and crevice corrosion than Type 304. The 0.030 percent carbon limit reduces the carbide precipitation that follows welding. The datasheets list it for aerospace structures and parts exposed to marine atmospheres, and NIST tested vacuum-fired 316L for vacuum chambers.
uses:
- where: Marine parts
line: Combined Metals lists parts exposed to marine atmospheres among the industries supplied. Wikipedia calls 316L the preferred steel for marine environments because of its greater resistance to pitting corrosion.
- where: Aerospace structures
line: UPMET lists aerospace structures among the industry applications for 316 and 316L sheet, coil and bar. The datasheet gives no flight or space test data.
- where: Vacuum hardware
line: In NIST's comparison of seven vacuum chambers, the vacuum-fired 316L chamber had hydrogen outgassing below 1 x 10^-11 Pa L/s/cm2, in the same ultra-low class as the titanium and aluminium chambers. The unfired 316L chamber was higher.
- where: Medical implants
line: Wikipedia says 316L is the preferred grade for medical implants because it resists sensitization. No space use is implied; it is recorded here for context.
can_do:
- label: Strength
benchmark: ultimate_tensile_strength
line: The minimum tensile strength is 485 MPa and the minimum yield is 170 MPa for plate, sheet and strip (ATI). Annealed typical values are 558 MPa tensile and 290 MPa yield (Combined Metals).
- label: Stiffness
benchmark: elastic_modulus
line: Young's modulus is 193 GPa at 20 C (Combined Metals) or 200 GPa (UPMET).
- label: Density
benchmark: density
line: Density is 7.99 g/cm3 at 20 C (Combined Metals), 8.027 g/cm3 (UPMET) or 8.03 g/cm3 (ATI).
- label: Heat
benchmark: melting_point
line: The melting range is 1,390 to 1,440 C (UPMET). Combined Metals says the alloy is somewhat stronger at elevated temperatures than Type 304.
compare: Combined Metals says that the properties of 316L are similar to Type 304 except that it is somewhat stronger at elevated temperatures. UPMET says the molybdenum-bearing 316 family is more resistant to general corrosion and to pitting and crevice corrosion than Type 304. No Type 304 numbers were read in this run, so the table below compares 316L only with itself across three properties.
compare_rows:
- label: Density
benchmark: density
- label: Stiffness
benchmark: elastic_modulus
- label: Melting range
benchmark: melting_point
handling:
- Specify 316L, not 316, for welded parts in corrosive service. UPMET lists 316 with up to 0.08 percent carbon and 316L with a 0.030 percent maximum.
- Avoid holding 316L between 450 and 900 C during fabrication or service. Sigma phase forms over hundreds to thousands of hours near 650 C.
- For vacuum service, vacuum-fire the parts at about 950 C for 24 hours under vacuum, which the NIST study found lowers hydrogen outgassing.
- The datasheets give ASTM A240 minimums for plate, sheet and strip and separate annealed typical values. Check the mill certificate for the form and temper being bought.
good_for:
- Welded corrosion-resistant parts in chloride-bearing service, where the low-carbon grade limits sensitization.
- Vacuum hardware that is vacuum-fired. The NIST study found its hydrogen outgassing in the ultra-low class.
- Marine parts exposed to salt air, which Combined Metals lists as a use.
watch_out:
- Chloride pitting. A pitting resistance equivalent number above 40 is typically specified for submerged seawater, and 316 and 316L are not suitable for seawater condenser tubes.
- Sigma phase. Long holds near 650 C form sigma, chi and Laves phases alongside the carbides, and sensitize the steel.
- Strength is modest for a structural steel, with a minimum yield of 170 MPa on the ATI and UPMET datasheets, so the design must allow for it.
verdict: 316L is the choice when a 304-type steel would pit in chloride service and the part must be welded. Its limits are its heat history and its chloride limit, so specify the low-carbon grade for welds and check a pitting resistance above 40 for seawater.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.