Crystalline polyvinyl fluoride with white pigment PVF (white Tedlar)

(C2H3F)n, poly(vinyl fluoride), CAS 24981-14-4 · CAS 24981-14-4

White-pigmented Tedlar is DuPont's polyvinyl fluoride film, made of the repeat unit minus CH2-CHF.

8 sources · Updated 2026-10-20 · CC BY 4.0

Evidence level

5 of 5

Flown or field-proven

Recipe, share of the weight

  • not statedVinyl fluoride
  • not statedTitanium dioxide

Best for

Protective outer films on solar arrays and aircraft interiors where weathering, UV stability and chemical resistance matter

Weakest at

Atomic oxygen erosion of thin films, which can peel at the edges, and the low tensile strength of the 1.5 and 2.0 mil white grades

Risk at a glance

  • People No data. No hazard data recorded
  • If it fails No data. No failure risks recorded
  • Corrosion No data. No corrosion data recorded

Quick facts: PVF (white Tedlar)

Key properties of PVF (white Tedlar)
PropertyValueBasis
Density1.37 to 1.72 g/cm³2 sourced values across conditions
Tensile strength55 to 62 MPa2 sourced values across conditions
Young's modulus2.66 GPa1 sourced value
Thermal expansion (CTE)97 ppm/K1 sourced value
Melting point185 to 210 °C1 sourced value
Specific heat1,050 J/(kg·K)1 sourced value
Maximum service temperature107 °C1 sourced value

What is the density of Crystalline polyvinyl fluoride with white pigment?

Crystalline polyvinyl fluoride with white pigment has a density of 1.37 to 1.72 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the coefficient of thermal expansion of Crystalline polyvinyl fluoride with white pigment?

Crystalline polyvinyl fluoride with white pigment has a coefficient of thermal expansion of 97 ppm/K. The source and test conditions are listed in the properties table on this page.

What is the melting point of Crystalline polyvinyl fluoride with white pigment?

Crystalline polyvinyl fluoride with white pigment has a melting point of 185 to 210 °C. The source and test conditions are listed in the properties table on this page.

What is the tensile strength of Crystalline polyvinyl fluoride with white pigment?

Crystalline polyvinyl fluoride with white pigment has a tensile strength of 55 to 62 MPa. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the Young's modulus of Crystalline polyvinyl fluoride with white pigment?

Crystalline polyvinyl fluoride with white pigment has a Young's modulus of 2.66 GPa. The source and test conditions are listed in the properties table on this page.

What is Crystalline polyvinyl fluoride with white pigment used for?

Uses recorded in the sources include Insulating bags on aircraft exterior walls and cargo spaces; Photovoltaic module backsheet; Commercial aircraft cabin interior walls and ceilings.

Why it exists

PVF is a semi-crystalline fluoropolymer that DuPont sells as Tedlar. On the MISSE 2 flight the white grade eroded at 1.01e-25 cm3/atom, far below the 3.19e-24 cm3/atom of clear Tedlar, so the pigment is what protects it in low Earth orbit.

Where it's used

Use

Insulating bags on aircraft exterior walls, and cabin interior wall and ceiling films.

Use

Protective backsheets for photovoltaic modules, where the white film sits on the bottom surface.

Use

Decorative and protective coatings, and release films for high-temperature resin processing.

Recipe

(C2H3F)n, poly(vinyl fluoride), CAS 24981-14-4; the white grade adds titanium dioxide pigment

PVF is a linear polymer of vinyl fluoride, -(CH2-CHF)n-. Vinyl fluoride is polymerised in aqueous suspension or emulsion under high pressure with a peroxide initiator, and the resin is then dissolved in a polar solvent, cast and biaxially oriented into thin film. The white grade adds titanium dioxide pigment during processing.

What PVF (white Tedlar) is made of
IngredientShare of the weightWhat it does
Vinyl fluoride not stated Repeat unit of the polymer; the C-F bond and the chain give the thermal stability and chemical resistance.
Titanium dioxide not stated White pigment that shields the film from atomic oxygen; NASA ties the very different erosion yields of clear and white Tedlar to it.

Weight shares are as printed in the sources.

What it can do

Strength

White Tedlar resists weathering and UV, stays flexible from -72 degC to 107 degC in continuous use, and resists acids, bases and most solvents. Its density is 1.37 to 1.72 g/cc and its dielectric constant is 11 for the 2.0 mil satin white grade.

How it compares

In the MISSE 2 table white Tedlar eroded at 1.01e-25 cm3/atom against 3.19e-24 cm3/atom for clear Tedlar, so the pigment cuts erosion by about a factor of thirty. Its melting point of 185 to 210 degC is modest, and its tensile strength of 55 to 62 MPa is low for a structural polymer.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.

Benchmarks
MeasurementPVF (white Tedlar)AFPCTFE (CTFE, Kel-F)ECTFE (Halar)ETFEFEPPFAPTFEPVDF (Kynar)PVF
Thermal behavior and safety
Melting point, PVF film185 °C5no data210 °C238 °C265 °C255 °C302 °Cno datano datano data
Specific heat, TWH20BS31.05 kJ/kg K19no datano datano datano datano data1172 J/(kg·K)no datano datano data
Physical and electrical
Density, white Tedlar MISSE 2 sample (ref 12)1.624 g/cm³32.146 g/cm³2.133 g/cm³1.68 g/cm³1.74 g/cm³2.144 g/cm³2.138 g/cm³2.17 g/cm³no data1.379 g/cm³
Density, DuPont Tedlar PVF films, typical range1.37 g/cc42.146 g/cm³2.133 g/cm³1.68 g/cm³1.74 g/cm³2.144 g/cm³2.138 g/cm³2.17 g/cm³no data1.379 g/cm³
Temperature behavior
Lower glass transition, PVF-20 °C6160 °C45 °Cno datano datano datano data170 K-40 °Cno data
Upper glass transition, PVF40 °C7160 °C45 °Cno datano datano datano data170 K-40 °Cno data
Other measurements
Atomic oxygen erosion yield, white Tedlar, MISSE 2 flight1.01×10^-25 cm³/atom11.98×10^-25 cm³/atom8.31×10^-25 cm³/atom1.79×10^-24 cm³/atom9.61×10^-25 cm³/atom2×10^-25 cm³/atom1.73×10^-25 cm³/atom1.42×10^-25 cm³/atom1.29×10^-24 cm³/atom3.19×10^-24 cm³/atom
Atomic oxygen erosion yield, clear Tedlar, MISSE 2 flight (comparison)3.19×10^-24 cm³/atom21.98×10^-25 cm³/atom8.31×10^-25 cm³/atom1.79×10^-24 cm³/atom9.61×10^-25 cm³/atom2×10^-25 cm³/atom1.73×10^-25 cm³/atom1.42×10^-25 cm³/atom1.29×10^-24 cm³/atom3.19×10^-24 cm³/atom
Continuous use, lower limit (Tedlar)-72 °C8no datano data-76 °Cno datano datano data-200 °Cno data-72 °C
Continuous use, upper limit (Tedlar)107 °C9no data175 °C149 °C150 °C204 °C260 °C260 °Cno data107 °C
Ultimate tensile strength, min, TWH15BL3 (1.5 mil low gloss white)55 MPa1026.9 MPa34 MPa7000 psi40 MPa20 MPa21 MPano datano data8 kpsi
Ultimate tensile strength, min, TWH20BS3 (2.0 mil satin white)62 MPa1126.9 MPa34 MPa7000 psi40 MPa20 MPa21 MPano datano data8 kpsi
Ultimate elongation, min, TWH15BL3 (1.5 mil low gloss white)90 %1217.1 %100 %200 %300 %300 %300 %no datano data90 %
Ultimate elongation, min, TWH20BS3 (2.0 mil satin white)110 %1317.1 %100 %200 %300 %300 %300 %no datano data90 %
Tensile modulus (MD), TWH20BS32655 MPa141.6 GPa5.65 GPa2.4×10^5 psi1075 MPano data480 MPano datano datano data
Moisture absorption, water immersion0.5 %150.01 %no data0.1 %no data0.01 %no datano datano data0.5 %
Dielectric constant, TWH20BS3, 1 kHz11 -161.93 unitlessno data2.5 none2.6 dimensionless2.03 -2 -2.1 dimensionlessno datano data
Dielectric strength, TWH20BS33.5 kV/mil172.1 kV/0.1 mmno data500 V/milno data80 kV/mm260 kV/mm30 kV/mmno datano data
Refractive index, clear and white PVF1.46 nD181.31 unitlessno datano datano datano data1.35 -no datano data1.46 nD
Linear coefficient of expansion (MD), TWH20BS39.7×10^-5 m/mK20no datano data5.6×10^-5 in/in/°Fno datano datano data12 x 10^-5 per °Cno data2.8×10^-5 in/in/degF
Crystallinity, PVF20 %21no datano datano data12.6 %no datano datano datano datano data
Hours to embrittlement, aging in air (white grades)3000 h22no datano datano datano datano datano datano datano datano data

Why choose it, and why not

Good for

  • Outer films on solar arrays and aircraft interiors where weathering and atomic oxygen protection matter, and thin protective layers over less durable materials.

Watch out for

  • Thin white film can erode and peel under atomic oxygen, and the 1.5 and 2.0 mil grades have a tensile strength of only 55 to 62 MPa. Overheating releases hydrogen fluoride.

White Tedlar is a practical, weather-resistant fluoropolymer film with strong atomic oxygen protection from its pigment. It is best used as a thin, supported outer layer rather than a structural part, and it needs a fuller ageing and radiation data set before a long mission design relies on it.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Atomic oxygen erosion yield, white Tedlar, MISSE 2 flightValue printed in NASA Table I as the MISSE 2 erosion yield for the white-pigment PVF rowenvironment low Earth orbit, ISS MISSE 2 PEACE Polymers trayfluence 8.43e21 atoms/cm2unit in source cm3/atom—
2Atomic oxygen erosion yield, clear Tedlar, MISSE 2 flight (comparison)Value printed in NASA Table I for clear PVF, with the text in section 2.2 comparing it with white Tedlarenvironment low Earth orbit, ISS MISSE 2 PEACE Polymers trayfluence 8.43e21 atoms/cm2unit in source cm3/atom—
3Density, white Tedlar MISSE 2 sample (ref 12)Density printed in NASA Table II, column Density, ref. 12 (density gradient column testing)sample MISSE 2 PEACE Polymers film—
4Density, DuPont Tedlar PVF films, typical rangeTypical range printed in DuPont General Properties, Table 1, for all PVF film typestest standard ASTM D-1505temperature 22 °C (72 degF)—
5Melting point, PVF filmRange printed in the Wikipedia PVF article, Properties sectionbasis range quoted for the polymer; the commercial atactic film shows a peak at 190 °C—
6Lower glass transition, PVFRange printed in the Wikipedia PVF article as the lower Tg, written there as -15 to -20 °Ctransition lower—
7Upper glass transition, PVFRange printed in the Wikipedia PVF article as the upper Tgtransition upper—
8Continuous use, lower limit (Tedlar)Value printed in DuPont General Properties, Thermal table, row Temperature Rangebasis continuous use—
9Continuous use, upper limit (Tedlar)Value printed in DuPont General Properties, Thermal table, row Temperature Rangebasis continuous use; short cycles or release up to 175 °C—
10Ultimate tensile strength, min, TWH15BL3 (1.5 mil low gloss white)Minimum value printed in DuPont General Properties, Table 2grade TWH15BL3test standard ASTM D-882direction MD—
11Ultimate tensile strength, min, TWH20BS3 (2.0 mil satin white)Minimum value printed in DuPont General Properties, Table 2grade TWH20BS3test standard ASTM D-882direction MD—
12Ultimate elongation, min, TWH15BL3 (1.5 mil low gloss white)Minimum value printed in DuPont General Properties, Table 2grade TWH15BL3test standard ASTM D-882direction MD—
13Ultimate elongation, min, TWH20BS3 (2.0 mil satin white)Minimum value printed in DuPont General Properties, Table 2grade TWH20BS3test standard ASTM D-882direction MD—
14Tensile modulus (MD), TWH20BS3Value printed in DuPont General Properties, Table 2, MPa row (385 kpsi as printed alongside)grade TWH20BS3test standard ASTM D-882direction MD—
15Moisture absorption, water immersionValue printed in DuPont General Properties, Table 1, row Moisture Absorptionbound less than 0.5 % for most types, printed as <0.5test standard water immersion, 22 °C (72 degF)—
16Dielectric constant, TWH20BS3, 1 kHzValue printed in DuPont General Properties, Table 1, Electrical blockgrade TWH20BS3frequency 1 Kc at 22 °C (72 degF) as printedtest standard ASTM D-150—
17Dielectric strength, TWH20BS3Value printed in DuPont General Properties, Table 1, Electrical blockgrade TWH20BS3test standard ASTM D-150—
18Refractive index, clear and white PVFValue printed in DuPont General Properties, Table 1, Physical blocktemperature 30 °C (86 degF)test standard ASTM D-542, Abbe refractometer—
19Specific heat, TWH20BS3Value printed in DuPont General Properties, Table 2, kJ/kg K rowgrade TWH20BS3method printed DuPont 990, thermal analyzer—
20Linear coefficient of expansion (MD), TWH20BS3Value printed in DuPont General Properties, Table 2, row Linear Coefficient of Expansion (MD)grade TWH20BS3direction MDtemperature 50 to 70 °Ctest standard ASTM D-696—
21Crystallinity, PVFRange printed in the Wikipedia PVF article, Properties section; a secondary summarybasis depends on polymerization method and thermal history—
22Hours to embrittlement, aging in air (white grades)Value printed in DuPont General Properties, Table 2, row Aging in Air, Hours to embrittlementtemperature 300 degF oven, as printed—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Atomic oxygen in low Earth orbit, MISSE 2, about 4 years not rated White Tedlar eroded far less than clear Tedlar, because its titanium dioxide pigment shields the film.1
Thin films in atomic oxygen not rated Thin films can erode through and peel, which removes the protective ash layer.2
Outdoor UV and weathering not rated Tedlar shows minimal colour change after repeated UV exposure in Florida.3
Heat ageing in air not rated Film embrittles only after about 3000 hours in a 300 degF oven.4
Acids, bases and solvents at room temperature not rated PVF films resist acids, bases and common solvents at room temperature.5
Corrosion details
#EnvironmentDetailsTest conditions
1 Atomic oxygen in low Earth orbit, MISSE 2, about 4 years Erosion yield of 1.01e-25 cm3/atom for white against 3.19e-24 cm3/atom for clear, as printed in NASA Table I. fluence 8.43e21 atoms/cm2
2 Thin films in atomic oxygen NASA notes that thin polymers eroded faster at their perimeter and could peel up, so the ash covered the surface only partly. thickness thin film
3 Outdoor UV and weathering DuPont reports a 15-year Florida exposure test in which Tedlar PVF film shows minimal colour change; the chart is not printed with numbers. exposure 15-year exposure test in Florida
4 Heat ageing in air DuPont prints 3,000 hours to embrittlement for all four grades in air oven aging at 300 degF. temperature 300 degF
5 Acids, bases and solvents at room temperature DuPont reports no visible effect after 1 year immersion in acids, bases or solvents at 25 degC; Wikipedia says PVF films resist acids, bases and aliphatic, aromatic and alcohol liquids at room temperature. temperature 25 °Cduration 1 year immersion

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

Workers who polymerise or handle vinyl fluoride, which is an…

Workers who sand or cut white Tedlar, because the pigment dust may…

Anyone handling PVF that has been heated above about 350 degC, which…

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Thin films can erode through in atomic oxygen and peel, which…Thin films can erode through in atomic oxygen and peel, which removes the protection of the pigment ash layer.
The 1.5 and 2.0 mil white grades have a minimum tensile strength of…The 1.5 and 2.0 mil white grades have a minimum tensile strength of 55 and 62 MPa, which is low for structural loads.

Side effects on surrounding parts

Side effects on surrounding parts
AffectsEffect
SurroundingsAfter excessive exposure the fluoride content in urine increased, although PVF has not caused skin reactions or toxic effects.

Handling and storage

  • Avoid making dust from sanding or cutting, and treat the film's pigment dust as possibly containing heavy metals.

Mitigations

  • Keep heating and processing below the temperature at which HF is lost in air, and keep it away from pigments and fillers that can react when overheated.

Supply and geography

How common the raw materials are and where they come from.

Fluorspar (CaF2), the mineral feedstock for fluorine chemicals

USGS reports that calcium fluoride is used to make anhydrous hydrogen fluoride and that acid-grade fluorspar is its leading use; PVF is made from vinyl fluoride, which is made from fluorine chemistry.

Top producers (2025)
China, Mongolia, Mexico, South Africa, Vietnam