Crystalline polyvinyl fluoride with white pigment PVF (white Tedlar)
(C2H3F)n, poly(vinyl fluoride), CAS 24981-14-4 · CAS 24981-14-4
White-pigmented Tedlar is DuPont's polyvinyl fluoride film, made of the repeat unit minus CH2-CHF.
Evidence level
5 of 5
Flown or field-proven
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Recipe, share of the weight
- not statedVinyl fluoride
- not statedTitanium dioxide
Best for
Protective outer films on solar arrays and aircraft interiors where weathering, UV stability and chemical resistance matter
Weakest at
Atomic oxygen erosion of thin films, which can peel at the edges, and the low tensile strength of the 1.5 and 2.0 mil white grades
Risk at a glance
- People No data. No hazard data recorded
- If it fails No data. No failure risks recorded
- Corrosion No data. No corrosion data recorded
Quick facts: PVF (white Tedlar)
| Property | Value | Basis |
|---|---|---|
| Density | 1.37 to 1.72 g/cm³ | 2 sourced values across conditions |
| Tensile strength | 55 to 62 MPa | 2 sourced values across conditions |
| Young's modulus | 2.66 GPa | 1 sourced value |
| Thermal expansion (CTE) | 97 ppm/K | 1 sourced value |
| Melting point | 185 to 210 °C | 1 sourced value |
| Specific heat | 1,050 J/(kg·K) | 1 sourced value |
| Maximum service temperature | 107 °C | 1 sourced value |
What is the density of Crystalline polyvinyl fluoride with white pigment?
Crystalline polyvinyl fluoride with white pigment has a density of 1.37 to 1.72 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the coefficient of thermal expansion of Crystalline polyvinyl fluoride with white pigment?
Crystalline polyvinyl fluoride with white pigment has a coefficient of thermal expansion of 97 ppm/K. The source and test conditions are listed in the properties table on this page.
What is the melting point of Crystalline polyvinyl fluoride with white pigment?
Crystalline polyvinyl fluoride with white pigment has a melting point of 185 to 210 °C. The source and test conditions are listed in the properties table on this page.
What is the tensile strength of Crystalline polyvinyl fluoride with white pigment?
Crystalline polyvinyl fluoride with white pigment has a tensile strength of 55 to 62 MPa. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the Young's modulus of Crystalline polyvinyl fluoride with white pigment?
Crystalline polyvinyl fluoride with white pigment has a Young's modulus of 2.66 GPa. The source and test conditions are listed in the properties table on this page.
What is Crystalline polyvinyl fluoride with white pigment used for?
Uses recorded in the sources include Insulating bags on aircraft exterior walls and cargo spaces; Photovoltaic module backsheet; Commercial aircraft cabin interior walls and ceilings.
Why it exists
PVF is a semi-crystalline fluoropolymer that DuPont sells as Tedlar. On the MISSE 2 flight the white grade eroded at 1.01e-25 cm3/atom, far below the 3.19e-24 cm3/atom of clear Tedlar, so the pigment is what protects it in low Earth orbit.
Where it's used
Use
Insulating bags on aircraft exterior walls, and cabin interior wall and ceiling films.
Use
Protective backsheets for photovoltaic modules, where the white film sits on the bottom surface.
Use
Decorative and protective coatings, and release films for high-temperature resin processing.
Recipe
(C2H3F)n, poly(vinyl fluoride), CAS 24981-14-4; the white grade adds titanium dioxide pigment
PVF is a linear polymer of vinyl fluoride, -(CH2-CHF)n-. Vinyl fluoride is polymerised in aqueous suspension or emulsion under high pressure with a peroxide initiator, and the resin is then dissolved in a polar solvent, cast and biaxially oriented into thin film. The white grade adds titanium dioxide pigment during processing.
| Ingredient | Share of the weight | What it does |
|---|---|---|
| Vinyl fluoride | not stated | Repeat unit of the polymer; the C-F bond and the chain give the thermal stability and chemical resistance. |
| Titanium dioxide | not stated | White pigment that shields the film from atomic oxygen; NASA ties the very different erosion yields of clear and white Tedlar to it. |
Weight shares are as printed in the sources.
What it can do
Strength
White Tedlar resists weathering and UV, stays flexible from -72 degC to 107 degC in continuous use, and resists acids, bases and most solvents. Its density is 1.37 to 1.72 g/cc and its dielectric constant is 11 for the 2.0 mil satin white grade.
How it compares
In the MISSE 2 table white Tedlar eroded at 1.01e-25 cm3/atom against 3.19e-24 cm3/atom for clear Tedlar, so the pigment cuts erosion by about a factor of thirty. Its melting point of 185 to 210 degC is modest, and its tensile strength of 55 to 62 MPa is low for a structural polymer.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.
| Measurement | PVF (white Tedlar) | AF | PCTFE (CTFE, Kel-F) | ECTFE (Halar) | ETFE | FEP | PFA | PTFE | PVDF (Kynar) | PVF |
|---|---|---|---|---|---|---|---|---|---|---|
| Thermal behavior and safety | ||||||||||
| Melting point, PVF film | 185 °C5 | no data | 210 °C | 238 °C | 265 °C | 255 °C | 302 °C | no data | no data | no data |
| Specific heat, TWH20BS3 | 1.05 kJ/kg K19 | no data | no data | no data | no data | no data | 1172 J/(kg·K) | no data | no data | no data |
| Physical and electrical | ||||||||||
| Density, white Tedlar MISSE 2 sample (ref 12) | 1.624 g/cm³3 | 2.146 g/cm³ | 2.133 g/cm³ | 1.68 g/cm³ | 1.74 g/cm³ | 2.144 g/cm³ | 2.138 g/cm³ | 2.17 g/cm³ | no data | 1.379 g/cm³ |
| Density, DuPont Tedlar PVF films, typical range | 1.37 g/cc4 | 2.146 g/cm³ | 2.133 g/cm³ | 1.68 g/cm³ | 1.74 g/cm³ | 2.144 g/cm³ | 2.138 g/cm³ | 2.17 g/cm³ | no data | 1.379 g/cm³ |
| Temperature behavior | ||||||||||
| Lower glass transition, PVF | -20 °C6 | 160 °C | 45 °C | no data | no data | no data | no data | 170 K | -40 °C | no data |
| Upper glass transition, PVF | 40 °C7 | 160 °C | 45 °C | no data | no data | no data | no data | 170 K | -40 °C | no data |
| Other measurements | ||||||||||
| Atomic oxygen erosion yield, white Tedlar, MISSE 2 flight | 1.01×10^-25 cm³/atom1 | 1.98×10^-25 cm³/atom | 8.31×10^-25 cm³/atom | 1.79×10^-24 cm³/atom | 9.61×10^-25 cm³/atom | 2×10^-25 cm³/atom | 1.73×10^-25 cm³/atom | 1.42×10^-25 cm³/atom | 1.29×10^-24 cm³/atom | 3.19×10^-24 cm³/atom |
| Atomic oxygen erosion yield, clear Tedlar, MISSE 2 flight (comparison) | 3.19×10^-24 cm³/atom2 | 1.98×10^-25 cm³/atom | 8.31×10^-25 cm³/atom | 1.79×10^-24 cm³/atom | 9.61×10^-25 cm³/atom | 2×10^-25 cm³/atom | 1.73×10^-25 cm³/atom | 1.42×10^-25 cm³/atom | 1.29×10^-24 cm³/atom | 3.19×10^-24 cm³/atom |
| Continuous use, lower limit (Tedlar) | -72 °C8 | no data | no data | -76 °C | no data | no data | no data | -200 °C | no data | -72 °C |
| Continuous use, upper limit (Tedlar) | 107 °C9 | no data | 175 °C | 149 °C | 150 °C | 204 °C | 260 °C | 260 °C | no data | 107 °C |
| Ultimate tensile strength, min, TWH15BL3 (1.5 mil low gloss white) | 55 MPa10 | 26.9 MPa | 34 MPa | 7000 psi | 40 MPa | 20 MPa | 21 MPa | no data | no data | 8 kpsi |
| Ultimate tensile strength, min, TWH20BS3 (2.0 mil satin white) | 62 MPa11 | 26.9 MPa | 34 MPa | 7000 psi | 40 MPa | 20 MPa | 21 MPa | no data | no data | 8 kpsi |
| Ultimate elongation, min, TWH15BL3 (1.5 mil low gloss white) | 90 %12 | 17.1 % | 100 % | 200 % | 300 % | 300 % | 300 % | no data | no data | 90 % |
| Ultimate elongation, min, TWH20BS3 (2.0 mil satin white) | 110 %13 | 17.1 % | 100 % | 200 % | 300 % | 300 % | 300 % | no data | no data | 90 % |
| Tensile modulus (MD), TWH20BS3 | 2655 MPa14 | 1.6 GPa | 5.65 GPa | 2.4×10^5 psi | 1075 MPa | no data | 480 MPa | no data | no data | no data |
| Moisture absorption, water immersion | 0.5 %15 | 0.01 % | no data | 0.1 % | no data | 0.01 % | no data | no data | no data | 0.5 % |
| Dielectric constant, TWH20BS3, 1 kHz | 11 -16 | 1.93 unitless | no data | 2.5 none | 2.6 dimensionless | 2.03 - | 2 - | 2.1 dimensionless | no data | no data |
| Dielectric strength, TWH20BS3 | 3.5 kV/mil17 | 2.1 kV/0.1 mm | no data | 500 V/mil | no data | 80 kV/mm | 260 kV/mm | 30 kV/mm | no data | no data |
| Refractive index, clear and white PVF | 1.46 nD18 | 1.31 unitless | no data | no data | no data | no data | 1.35 - | no data | no data | 1.46 nD |
| Linear coefficient of expansion (MD), TWH20BS3 | 9.7×10^-5 m/mK20 | no data | no data | 5.6×10^-5 in/in/°F | no data | no data | no data | 12 x 10^-5 per °C | no data | 2.8×10^-5 in/in/degF |
| Crystallinity, PVF | 20 %21 | no data | no data | no data | 12.6 % | no data | no data | no data | no data | no data |
| Hours to embrittlement, aging in air (white grades) | 3000 h22 | no data | no data | no data | no data | no data | no data | no data | no data | no data |
Why choose it, and why not
Good for
- Outer films on solar arrays and aircraft interiors where weathering and atomic oxygen protection matter, and thin protective layers over less durable materials.
Watch out for
- Thin white film can erode and peel under atomic oxygen, and the 1.5 and 2.0 mil grades have a tensile strength of only 55 to 62 MPa. Overheating releases hydrogen fluoride.
White Tedlar is a practical, weather-resistant fluoropolymer film with strong atomic oxygen protection from its pigment. It is best used as a thin, supported outer layer rather than a structural part, and it needs a fuller ageing and radiation data set before a long mission design relies on it.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Atomic oxygen erosion yield, white Tedlar, MISSE 2 flight | Value printed in NASA Table I as the MISSE 2 erosion yield for the white-pigment PVF row | environment low Earth orbit, ISS MISSE 2 PEACE Polymers trayfluence 8.43e21 atoms/cm2unit in source cm3/atom | — |
| 2 | Atomic oxygen erosion yield, clear Tedlar, MISSE 2 flight (comparison) | Value printed in NASA Table I for clear PVF, with the text in section 2.2 comparing it with white Tedlar | environment low Earth orbit, ISS MISSE 2 PEACE Polymers trayfluence 8.43e21 atoms/cm2unit in source cm3/atom | — |
| 3 | Density, white Tedlar MISSE 2 sample (ref 12) | Density printed in NASA Table II, column Density, ref. 12 (density gradient column testing) | sample MISSE 2 PEACE Polymers film | — |
| 4 | Density, DuPont Tedlar PVF films, typical range | Typical range printed in DuPont General Properties, Table 1, for all PVF film types | test standard ASTM D-1505temperature 22 °C (72 degF) | — |
| 5 | Melting point, PVF film | Range printed in the Wikipedia PVF article, Properties section | basis range quoted for the polymer; the commercial atactic film shows a peak at 190 °C | — |
| 6 | Lower glass transition, PVF | Range printed in the Wikipedia PVF article as the lower Tg, written there as -15 to -20 °C | transition lower | — |
| 7 | Upper glass transition, PVF | Range printed in the Wikipedia PVF article as the upper Tg | transition upper | — |
| 8 | Continuous use, lower limit (Tedlar) | Value printed in DuPont General Properties, Thermal table, row Temperature Range | basis continuous use | — |
| 9 | Continuous use, upper limit (Tedlar) | Value printed in DuPont General Properties, Thermal table, row Temperature Range | basis continuous use; short cycles or release up to 175 °C | — |
| 10 | Ultimate tensile strength, min, TWH15BL3 (1.5 mil low gloss white) | Minimum value printed in DuPont General Properties, Table 2 | grade TWH15BL3test standard ASTM D-882direction MD | — |
| 11 | Ultimate tensile strength, min, TWH20BS3 (2.0 mil satin white) | Minimum value printed in DuPont General Properties, Table 2 | grade TWH20BS3test standard ASTM D-882direction MD | — |
| 12 | Ultimate elongation, min, TWH15BL3 (1.5 mil low gloss white) | Minimum value printed in DuPont General Properties, Table 2 | grade TWH15BL3test standard ASTM D-882direction MD | — |
| 13 | Ultimate elongation, min, TWH20BS3 (2.0 mil satin white) | Minimum value printed in DuPont General Properties, Table 2 | grade TWH20BS3test standard ASTM D-882direction MD | — |
| 14 | Tensile modulus (MD), TWH20BS3 | Value printed in DuPont General Properties, Table 2, MPa row (385 kpsi as printed alongside) | grade TWH20BS3test standard ASTM D-882direction MD | — |
| 15 | Moisture absorption, water immersion | Value printed in DuPont General Properties, Table 1, row Moisture Absorption | bound less than 0.5 % for most types, printed as <0.5test standard water immersion, 22 °C (72 degF) | — |
| 16 | Dielectric constant, TWH20BS3, 1 kHz | Value printed in DuPont General Properties, Table 1, Electrical block | grade TWH20BS3frequency 1 Kc at 22 °C (72 degF) as printedtest standard ASTM D-150 | — |
| 17 | Dielectric strength, TWH20BS3 | Value printed in DuPont General Properties, Table 1, Electrical block | grade TWH20BS3test standard ASTM D-150 | — |
| 18 | Refractive index, clear and white PVF | Value printed in DuPont General Properties, Table 1, Physical block | temperature 30 °C (86 degF)test standard ASTM D-542, Abbe refractometer | — |
| 19 | Specific heat, TWH20BS3 | Value printed in DuPont General Properties, Table 2, kJ/kg K row | grade TWH20BS3method printed DuPont 990, thermal analyzer | — |
| 20 | Linear coefficient of expansion (MD), TWH20BS3 | Value printed in DuPont General Properties, Table 2, row Linear Coefficient of Expansion (MD) | grade TWH20BS3direction MDtemperature 50 to 70 °Ctest standard ASTM D-696 | — |
| 21 | Crystallinity, PVF | Range printed in the Wikipedia PVF article, Properties section; a secondary summary | basis depends on polymerization method and thermal history | — |
| 22 | Hours to embrittlement, aging in air (white grades) | Value printed in DuPont General Properties, Table 2, row Aging in Air, Hours to embrittlement | temperature 300 degF oven, as printed | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Atomic oxygen in low Earth orbit, MISSE 2, about 4 years | not rated | White Tedlar eroded far less than clear Tedlar, because its titanium dioxide pigment shields the film.1 |
| Thin films in atomic oxygen | not rated | Thin films can erode through and peel, which removes the protective ash layer.2 |
| Outdoor UV and weathering | not rated | Tedlar shows minimal colour change after repeated UV exposure in Florida.3 |
| Heat ageing in air | not rated | Film embrittles only after about 3000 hours in a 300 degF oven.4 |
| Acids, bases and solvents at room temperature | not rated | PVF films resist acids, bases and common solvents at room temperature.5 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Atomic oxygen in low Earth orbit, MISSE 2, about 4 years | Erosion yield of 1.01e-25 cm3/atom for white against 3.19e-24 cm3/atom for clear, as printed in NASA Table I. | fluence 8.43e21 atoms/cm2 |
| 2 | Thin films in atomic oxygen | NASA notes that thin polymers eroded faster at their perimeter and could peel up, so the ash covered the surface only partly. | thickness thin film |
| 3 | Outdoor UV and weathering | DuPont reports a 15-year Florida exposure test in which Tedlar PVF film shows minimal colour change; the chart is not printed with numbers. | exposure 15-year exposure test in Florida |
| 4 | Heat ageing in air | DuPont prints 3,000 hours to embrittlement for all four grades in air oven aging at 300 degF. | temperature 300 degF |
| 5 | Acids, bases and solvents at room temperature | DuPont reports no visible effect after 1 year immersion in acids, bases or solvents at 25 degC; Wikipedia says PVF films resist acids, bases and aliphatic, aromatic and alcohol liquids at room temperature. | temperature 25 °Cduration 1 year immersion |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
Workers who polymerise or handle vinyl fluoride, which is an…
Workers who sand or cut white Tedlar, because the pigment dust may…
Anyone handling PVF that has been heated above about 350 degC, which…
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Thin films can erode through in atomic oxygen and peel, which… | Thin films can erode through in atomic oxygen and peel, which removes the protection of the pigment ash layer. |
| The 1.5 and 2.0 mil white grades have a minimum tensile strength of… | The 1.5 and 2.0 mil white grades have a minimum tensile strength of 55 and 62 MPa, which is low for structural loads. |
Side effects on surrounding parts
| Affects | Effect |
|---|---|
| Surroundings | After excessive exposure the fluoride content in urine increased, although PVF has not caused skin reactions or toxic effects. |
Handling and storage
- Avoid making dust from sanding or cutting, and treat the film's pigment dust as possibly containing heavy metals.
Mitigations
- Keep heating and processing below the temperature at which HF is lost in air, and keep it away from pigments and fillers that can react when overheated.
Supply and geography
How common the raw materials are and where they come from.
Fluorspar (CaF2), the mineral feedstock for fluorine chemicals
USGS reports that calcium fluoride is used to make anhydrous hydrogen fluoride and that acid-grade fluorspar is its leading use; PVF is made from vinyl fluoride, which is made from fluorine chemistry.
- Top producers (2025)
- China, Mongolia, Mexico, South Africa, Vietnam
Documents
Datasheets, safety data sheets, papers and standards you can open.
| Document | Type | Year |
|---|---|---|
| Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit (NASA/TM-2008-215490) | report | 2008 |
| DuPont Tedlar PVF Films, General Properties | datasheet | 2011 |
| DuPont Tedlar PVF Films, General Properties brochure | datasheet | 2011 |
| DuPont Tedlar products overview | datasheet | 2022 |
| Mineral Commodity Summaries 2026: Fluorspar (USGS) | report | 2026 |
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
Show the full YAML
spore: profile
id: pvf-white-tedlar
spore_version: 0.2
family: fluoropolymers
name: Crystalline polyvinyl fluoride with white pigment
abbreviation: PVF (white Tedlar)
role: biaxially oriented fluoropolymer film with titanium dioxide pigment, used as a weather-resistant outer layer
category: polymers
type: fluoropolymers
summary: White-pigmented Tedlar is DuPont's polyvinyl fluoride film, made of the repeat unit minus CH2-CHF. On the MISSE 2 flight its atomic oxygen erosion yield was 1.01e-25 cm3/atom, about 30 times lower than clear Tedlar at 3.19e-24 cm3/atom, because the titanium dioxide pigment shields the film. DuPont rates it for continuous use from -72 to 107 degC and says it resists weathering and most chemicals.
best_for: Protective outer films on solar arrays and aircraft interiors where weathering, UV stability and chemical resistance matter
weakest_at: Atomic oxygen erosion of thin films, which can peel at the edges, and the low tensile strength of the 1.5 and 2.0 mil white grades
identity:
formula: (C2H3F)n, poly(vinyl fluoride), CAS 24981-14-4; the white grade adds titanium dioxide pigment
cas: 24981-14-4
source: wiki-pvf
where: Infobox, Identifiers and Properties; repeat unit (C2H3F)n from the Chemical formula row
tags:
environments:
- low-earth-orbit
stresses:
- atomic-oxygen
- uv
applications:
- solar-arrays
- thermal-control
- structures
properties:
- benchmark: atomic_oxygen_erosion_yield
label: Atomic oxygen erosion yield, white Tedlar, MISSE 2 flight
value: 1.01e-25
unit: cm3/atom
scope: material
conditions:
environment: low Earth orbit, ISS MISSE 2 PEACE Polymers tray
fluence: 8.43e21 atoms/cm2
unit_in_source: cm3/atom
method: Value printed in NASA Table I as the MISSE 2 erosion yield for the white-pigment PVF row
status: flight
source: nasa-ao-tool
where: Table I, row Polyvinylfluoride with white pigment, column MISSE 2 erosion yield
- benchmark: atomic_oxygen_erosion_yield
label: Atomic oxygen erosion yield, clear Tedlar, MISSE 2 flight (comparison)
value: 3.19e-24
unit: cm3/atom
scope: material
conditions:
environment: low Earth orbit, ISS MISSE 2 PEACE Polymers tray
fluence: 8.43e21 atoms/cm2
unit_in_source: cm3/atom
method: Value printed in NASA Table I for clear PVF, with the text in section 2.2 comparing it with white Tedlar
status: flight
source: nasa-ao-tool
where: Table I, row Polyvinyl fluoride, column MISSE 2 erosion yield; section 2.2 text
- benchmark: density
label: Density, white Tedlar MISSE 2 sample (ref 12)
value: 1.6241
unit: g/cm3
scope: material
conditions:
sample: MISSE 2 PEACE Polymers film
method: Density printed in NASA Table II, column Density, ref. 12 (density gradient column testing)
status: ground
source: nasa-ao-tool
where: Table II, row Crystalline polyvinylfluoride with white pigment, Density column
- benchmark: density
label: Density, DuPont Tedlar PVF films, typical range
value: 1.37
value_high: 1.72
unit: g/cc
scope: material
conditions:
test_standard: ASTM D-1505
temperature: 22 degC (72 degF)
method: Typical range printed in DuPont General Properties, Table 1, for all PVF film types
status: ground
source: dupont-tedlar-gp
where: Table 1, row Density
- benchmark: melting_point
label: Melting point, PVF film
value: 185
value_high: 210
unit: °C
scope: material
conditions:
basis: range quoted for the polymer; the commercial atactic film shows a peak at 190 °C
method: Range printed in the Wikipedia PVF article, Properties section
status: ground
source: wiki-pvf
where: Properties section, first paragraph
- benchmark: glass_transition_temperature
label: Lower glass transition, PVF
value: -20
value_high: -15
unit: °C
scope: material
conditions:
transition: lower
method: Range printed in the Wikipedia PVF article as the lower Tg, written there as -15 to -20 °C
status: ground
source: wiki-pvf
where: Properties section, sentence on transition phases
- benchmark: glass_transition_temperature
label: Upper glass transition, PVF
value: 40
value_high: 50
unit: °C
scope: material
conditions:
transition: upper
method: Range printed in the Wikipedia PVF article as the upper Tg
status: ground
source: wiki-pvf
where: Properties section, sentence on transition phases
- benchmark: min_service_temp
label: Continuous use, lower limit (Tedlar)
value: -72
unit: °C
scope: material
conditions:
basis: continuous use
method: Value printed in DuPont General Properties, Thermal table, row Temperature Range
status: ground
source: dupont-tedlar-gp
where: Thermal table, Temperature Range, Continuous Use (-72 to 107 °C)
- benchmark: max_service_temp
label: Continuous use, upper limit (Tedlar)
value: 107
unit: °C
scope: material
conditions:
basis: continuous use; short cycles or release up to 175 °C
method: Value printed in DuPont General Properties, Thermal table, row Temperature Range
status: ground
source: dupont-tedlar-gp
where: Thermal table, Temperature Range, Continuous Use (-72 to 107 °C)
- benchmark: ultimate_tensile_strength
label: Ultimate tensile strength, min, TWH15BL3 (1.5 mil low gloss white)
value: 55
unit: MPa
scope: material
conditions:
grade: TWH15BL3
test_standard: ASTM D-882
direction: MD
method: Minimum value printed in DuPont General Properties, Table 2
status: ground
source: dupont-tedlar-gp
where: Table 2, column TWH15BL3, row Ultimate Tensile Strength, Min. (MD)
- benchmark: ultimate_tensile_strength
label: Ultimate tensile strength, min, TWH20BS3 (2.0 mil satin white)
value: 62
unit: MPa
scope: material
conditions:
grade: TWH20BS3
test_standard: ASTM D-882
direction: MD
method: Minimum value printed in DuPont General Properties, Table 2
status: ground
source: dupont-tedlar-gp
where: Table 2, column TWH20BS3, row Ultimate Tensile Strength, Min. (MD)
- benchmark: elongation
label: Ultimate elongation, min, TWH15BL3 (1.5 mil low gloss white)
value: 90
unit: '%'
scope: material
conditions:
grade: TWH15BL3
test_standard: ASTM D-882
direction: MD
method: Minimum value printed in DuPont General Properties, Table 2
status: ground
source: dupont-tedlar-gp
where: Table 2, column TWH15BL3, row Ultimate Elongation, Min. (MD)
- benchmark: elongation
label: Ultimate elongation, min, TWH20BS3 (2.0 mil satin white)
value: 110
unit: '%'
scope: material
conditions:
grade: TWH20BS3
test_standard: ASTM D-882
direction: MD
method: Minimum value printed in DuPont General Properties, Table 2
status: ground
source: dupont-tedlar-gp
where: Table 2, column TWH20BS3, row Ultimate Elongation, Min. (MD)
- benchmark: elastic_modulus
label: Tensile modulus (MD), TWH20BS3
value: 2655
unit: MPa
scope: material
conditions:
grade: TWH20BS3
test_standard: ASTM D-882
direction: MD
method: Value printed in DuPont General Properties, Table 2, MPa row (385 kpsi as printed alongside)
status: ground
source: dupont-tedlar-gp
where: Table 2, column TWH20BS3, row Tensile Modulus (MD), MPa
- benchmark: moisture_absorption
label: Moisture absorption, water immersion
value: 0.5
unit: '%'
scope: material
conditions:
bound: less than 0.5 % for most types, printed as <0.5
test_standard: water immersion, 22 degC (72 degF)
method: Value printed in DuPont General Properties, Table 1, row Moisture Absorption
status: ground
source: dupont-tedlar-gp
where: Table 1, row Moisture Absorption
- benchmark: dielectric_constant
label: Dielectric constant, TWH20BS3, 1 kHz
value: 11
unit: '-'
scope: material
conditions:
grade: TWH20BS3
frequency: 1 Kc at 22 degC (72 degF) as printed
test_standard: ASTM D-150
method: Value printed in DuPont General Properties, Table 1, Electrical block
status: ground
source: dupont-tedlar-gp
where: Table 1, Electrical block, row Dielectric Constant, column TWH20BS3
- benchmark: dielectric_strength
label: Dielectric strength, TWH20BS3
value: 3.5
unit: kV/mil
scope: material
conditions:
grade: TWH20BS3
test_standard: ASTM D-150
method: Value printed in DuPont General Properties, Table 1, Electrical block
status: ground
source: dupont-tedlar-gp
where: Table 1, Electrical block, row Dielectric Strength (kV/mil), column TWH20BS3
- benchmark: refractive_index
label: Refractive index, clear and white PVF
value: 1.46
unit: nD
scope: material
conditions:
temperature: 30 degC (86 degF)
test_standard: ASTM D-542, Abbe refractometer
method: Value printed in DuPont General Properties, Table 1, Physical block
status: ground
source: dupont-tedlar-gp
where: Table 1, Physical block, row Refractive Index
- benchmark: specific_heat
label: Specific heat, TWH20BS3
value: 1.05
unit: kJ/kg K
scope: material
conditions:
grade: TWH20BS3
method_printed: DuPont 990, thermal analyzer
method: Value printed in DuPont General Properties, Table 2, kJ/kg K row
status: ground
source: dupont-tedlar-gp
where: Table 2, column TWH20BS3, row Specific Heat, kJ/kg K
- benchmark: cte
label: Linear coefficient of expansion (MD), TWH20BS3
value: 0.000097
unit: m/mK
scope: material
conditions:
grade: TWH20BS3
direction: MD
temperature: 50 to 70 degC
test_standard: ASTM D-696
method: Value printed in DuPont General Properties, Table 2, row Linear Coefficient of Expansion (MD)
status: ground
source: dupont-tedlar-gp
where: Table 2, column TWH20BS3, row Linear Coefficient of Expansion (MD)
- benchmark: crystallinity
label: Crystallinity, PVF
value: 20
value_high: 60
unit: '%'
scope: material
conditions:
basis: depends on polymerization method and thermal history
method: Range printed in the Wikipedia PVF article, Properties section; a secondary summary
status: ground
source: wiki-pvf
where: Properties section, sentence on crystallinity
- benchmark: hours_to_embrittlement_oven_aging
label: Hours to embrittlement, aging in air (white grades)
value: 3000
unit: h
scope: material
conditions:
temperature: 300 degF oven, as printed
method: Value printed in DuPont General Properties, Table 2, row Aging in Air, Hours to embrittlement
status: ground
source: dupont-tedlar-gp
where: Table 2, row Aging in Air, Hours to embrittlement
corrosion:
- environment: Atomic oxygen in low Earth orbit, MISSE 2, about 4 years
headline: White Tedlar eroded far less than clear Tedlar, because its titanium dioxide pigment shields the film.
effect: Erosion yield of 1.01e-25 cm3/atom for white against 3.19e-24 cm3/atom for clear, as printed in NASA Table I.
conditions:
fluence: 8.43e21 atoms/cm2
source: nasa-ao-tool
where: Table I; section 2.2 text on the pigment shielding effect
rating: unknown
- environment: Thin films in atomic oxygen
headline: Thin films can erode through and peel, which removes the protective ash layer.
effect: NASA notes that thin polymers eroded faster at their perimeter and could peel up, so the ash covered the surface only partly.
conditions:
thickness: thin film
source: nasa-ao-tool
where: Discussion section, paragraph on ash protection
rating: unknown
- environment: Outdoor UV and weathering
headline: Tedlar shows minimal colour change after repeated UV exposure in Florida.
effect: DuPont reports a 15-year Florida exposure test in which Tedlar PVF film shows minimal colour change; the chart is not printed with numbers.
conditions:
exposure: 15-year exposure test in Florida
source: dupont-tedlar-overview
where: UV Durability section, Florida weathering chart
rating: unknown
- environment: Heat ageing in air
headline: Film embrittles only after about 3000 hours in a 300 degF oven.
effect: DuPont prints 3,000 hours to embrittlement for all four grades in air oven aging at 300 degF.
conditions:
temperature: 300 degF
source: dupont-tedlar-gp
where: Table 2, row Aging in Air
rating: unknown
- environment: Acids, bases and solvents at room temperature
headline: PVF films resist acids, bases and common solvents at room temperature.
effect: DuPont reports no visible effect after 1 year immersion in acids, bases or solvents at 25 degC; Wikipedia says PVF films resist acids, bases and aliphatic, aromatic and alcohol liquids at room temperature.
conditions:
temperature: 25 degC
duration: 1 year immersion
source: dupont-tedlar-gp
where: Table 1, Chemical Resistance row
rating: unknown
uses:
- application: thermal-control
device: Insulating bags on aircraft exterior walls and cargo spaces
example: PVF film is applied to insulating bags containing glass fibre, used on exterior airplane walls, in cargo space and in air conditioning ducts.
source: wiki-pvf
where: Application section
- application: solar-arrays
device: Photovoltaic module backsheet
example: The white-pigmented film is used on the bottom surface of photovoltaic cells, and the transparent film protects the top against moisture.
source: wiki-pvf
where: Application section
- application: structures
device: Commercial aircraft cabin interior walls and ceilings
example: DuPont says Tedlar film is used extensively on cabin interior walls and ceilings of commercial aircraft, and is FAA and EASA certified for fire resistance.
source: dupont-tedlar-overview
where: Flame and Smoke section
risks:
hazards:
- text: The monomer, vinyl fluoride, is an extremely flammable gas, may explode if heated, is suspected of causing genetic defects and may cause cancer.
ghs:
- H220
- H280
- H341
- H350
source: pubchem-vinyl-fluoride
where: GHS Classification, Hazard Statements for vinyl fluoride (CID 6339)
- text: Above about 350 degC in air PVF loses hydrogen fluoride; HF is quickly absorbed into surrounding materials.
ghs: []
source: wiki-pvf
where: Properties section, thermal stability sentence; Safety section
- text: Some Tedlar formulations may contain heavy metal compounds, which can be present in dust from secondary operations such as sanding.
ghs: []
source: wiki-pvf
where: Safety section
failure_risks:
- source: nasa-ao-tool
where: Discussion section, paragraph on ash protection
mode: Thin films can erode through in atomic oxygen and peel, which…
consequence: Thin films can erode through in atomic oxygen and peel, which removes the protection of the pigment ash layer.
- source: dupont-tedlar-gp
where: Table 2, row Ultimate Tensile Strength, Min. (MD)
mode: The 1.5 and 2.0 mil white grades have a minimum tensile strength of…
consequence: The 1.5 and 2.0 mil white grades have a minimum tensile strength of 55 and 62 MPa, which is low for structural loads.
side_effects:
- text: After excessive exposure the fluoride content in urine increased, although PVF has not caused skin reactions or toxic effects.
source: wiki-pvf
where: Safety section
handling:
- text: Avoid making dust from sanding or cutting, and treat the film's pigment dust as possibly containing heavy metals.
source: wiki-pvf
where: Safety section
mitigations:
- text: Keep heating and processing below the temperature at which HF is lost in air, and keep it away from pigments and fillers that can react when overheated.
source: wiki-pvf
where: Properties section and Safety section
supply:
- subject: Fluorspar (CaF2), the mineral feedstock for fluorine chemicals
abundance: USGS reports that calcium fluoride is used to make anhydrous hydrogen fluoride and that acid-grade fluorspar is its leading use; PVF is made from vinyl fluoride, which is made from fluorine chemistry.
producers:
- country: China
production: 6,000 thousand metric tons
year: 2025
- country: Mongolia
production: 1,500 thousand metric tons
year: 2025
- country: Mexico
production: 1,500 thousand metric tons
year: 2025
- country: South Africa
production: 410 thousand metric tons
year: 2025
- country: Vietnam
production: 160 thousand metric tons
year: 2025
source: usgs-fluorspar-2026
where: World Mine Production and Reserves table, 2025 column; world total 10,000 thousand metric tons (rounded)
media: []
documents:
- title: Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit (NASA/TM-2008-215490)
type: report
url: https://ntrs.nasa.gov/api/citations/20090011780/downloads/20090011780.pdf
year: 2008
- title: DuPont Tedlar PVF Films, General Properties
type: datasheet
url: https://polymerfilms.com/wp-content/uploads/2023/07/DuPont_Tedlar-General-Properties.pdf
year: 2011
- title: DuPont Tedlar PVF Films, General Properties brochure
type: datasheet
url: https://www.metalcoffeeshop.com/uploads/media/2022/01/dupont™-tedlar®-polyvinyl-fluoride-(pvf)-films-brochure-3.pdf
year: 2011
- title: DuPont Tedlar products overview
type: datasheet
url: https://www.metalcoffeeshop.com/uploads/media/2022/01/dupont-tedlar-products-overview.pdf
year: 2022
- title: 'Mineral Commodity Summaries 2026: Fluorspar (USGS)'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-fluorspar.pdf
year: 2026
gaps:
- No UV, radiation or thermal-cycling test value for white Tedlar was read in this run; the DuPont Florida chart and the QUV images have no printed numbers.
- No PubChem record for PVF itself was read; the hazard codes are for the vinyl fluoride monomer (CID 6339).
- No primary, peer-reviewed PVF ageing data were found; the 3000 hour embrittlement figure is a manufacturer value.
- The DuPont SDS for Tedlar was not found; the Wikipedia safety paragraph is the only hazard text for the polymer.
- Atomic weights of C, H and F are not sourced in this run, so recipe parts carry no atomic_weight field.
- Titanium dioxide share in the white grade is not printed in any fetched source; the part has no share.
- Erosion yield, hours_to_embrittlement_oven_aging and crystallinity use names that may not be in spores/property-canon.yaml; they are listed here as new names.
- No critical-mineral listing for PVF or fluorspar in this run; fluorspar's critical status is not stated in the USGS page read.
- The Goodfellow PVF page gives tensile and crystallinity figures that are secondary and were not used as properties; it is cited only for the description of the material.
sources:
nasa-ao-tool:
title: Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit
id: NASA/TM-2008-215490
url: https://ntrs.nasa.gov/api/citations/20090011780/downloads/20090011780.pdf
year: 2008
kind: report
license: public domain (NASA)
wiki-pvf:
title: Polyvinyl fluoride (Wikipedia)
id: Wikipedia, en
url: https://en.wikipedia.org/wiki/Polyvinyl_fluoride
year: 2026
kind: web
license: CC BY-SA 4.0
pubchem-vinyl-fluoride:
title: Vinyl fluoride, PubChem CID 6339 (GHS classification)
id: PubChem CID 6339
url: https://pubchem.ncbi.nlm.nih.gov/compound/6339
year: 2026
kind: database
license: public domain (NIH PubChem)
dupont-tedlar-gp:
title: DuPont Tedlar PVF Films, General Properties
id: DuPont Tedlar general properties, copyright 2011
url: https://polymerfilms.com/wp-content/uploads/2023/07/DuPont_Tedlar-General-Properties.pdf
year: 2011
kind: datasheet
license: cited, not reproduced
dupont-tedlar-brochure:
title: DuPont Tedlar PVF Films, General Properties brochure
id: DuPont Tedlar brochure, copyright 2011
url: https://www.metalcoffeeshop.com/uploads/media/2022/01/dupont™-tedlar®-polyvinyl-fluoride-(pvf)-films-brochure-3.pdf
year: 2011
kind: datasheet
license: cited, not reproduced
dupont-tedlar-overview:
title: DuPont Tedlar products overview
id: DuPont Tedlar overview
url: https://www.metalcoffeeshop.com/uploads/media/2022/01/dupont-tedlar-products-overview.pdf
year: 2022
kind: datasheet
license: cited, not reproduced
usgs-fluorspar-2026:
title: 'Mineral Commodity Summaries 2026: Fluorspar (U.S. Geological Survey)'
id: USGS MCS 2026, February 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-fluorspar.pdf
year: 2026
kind: report
license: public domain (USGS)
goodfellow-pvf:
title: Polyvinylfluoride Film, Material Information (Goodfellow)
id: Goodfellow PVF film material information
url: https://www.goodfellow.com/usa/resources/polyvinylfluoride-film-material-information/
year: 2024
kind: datasheet
license: cited, not reproduced
license: CC-BY-4.0
updated: 2026-10-20T00:00:00.000Z
review:
status: draft
method: assistant
checked_values: 22
unreachable: 1
caveats: 2
note: 'Written from pages fetched in this run: 22 property values, 8 sources. The Tedlar SDS was not found; the ChemicalBook PVF SDS returned an empty page.'
story:
recipe:
line: PVF is a linear polymer of vinyl fluoride, -(CH2-CHF)n-. Vinyl fluoride is polymerised in aqueous suspension or emulsion under high pressure with a peroxide initiator, and the resin is then dissolved in a polar solvent, cast and biaxially oriented into thin film. The white grade adds titanium dioxide pigment during processing.
parts:
- name: Vinyl fluoride
monomer: C2H3F
role: Repeat unit of the polymer; the C-F bond and the chain give the thermal stability and chemical resistance.
- name: Titanium dioxide
role: White pigment that shields the film from atomic oxygen; NASA ties the very different erosion yields of clear and white Tedlar to it.
risk_groups:
- title: Workers who polymerise or handle vinyl fluoride, which is an…
- title: Workers who sand or cut white Tedlar, because the pigment dust may…
- title: Anyone handling PVF that has been heated above about 350 degC, which…
why: PVF is a semi-crystalline fluoropolymer that DuPont sells as Tedlar. On the MISSE 2 flight the white grade eroded at 1.01e-25 cm3/atom, far below the 3.19e-24 cm3/atom of clear Tedlar, so the pigment is what protects it in low Earth orbit.
uses:
- where: Use
line: Insulating bags on aircraft exterior walls, and cabin interior wall and ceiling films.
- where: Use
line: Protective backsheets for photovoltaic modules, where the white film sits on the bottom surface.
- where: Use
line: Decorative and protective coatings, and release films for high-temperature resin processing.
can_do:
- label: Strength
line: White Tedlar resists weathering and UV, stays flexible from -72 degC to 107 degC in continuous use, and resists acids, bases and most solvents. Its density is 1.37 to 1.72 g/cc and its dielectric constant is 11 for the 2.0 mil satin white grade.
compare: In the MISSE 2 table white Tedlar eroded at 1.01e-25 cm3/atom against 3.19e-24 cm3/atom for clear Tedlar, so the pigment cuts erosion by about a factor of thirty. Its melting point of 185 to 210 degC is modest, and its tensile strength of 55 to 62 MPa is low for a structural polymer.
compare_rows:
- label: Melting point
benchmark: melting_point
- label: Ultimate tensile strength
benchmark: ultimate_tensile_strength
- label: Atomic oxygen erosion yield
benchmark: atomic_oxygen_erosion_yield
handling:
- Ventilate cutting, sanding and heating areas, and wear PPE for dust. Keep heated PVF below the temperature at which hydrogen fluoride is lost in air (about 350 degC). Keep vinyl fluoride monomer, a flammable gas, away from ignition.
good_for:
- Outer films on solar arrays and aircraft interiors where weathering and atomic oxygen protection matter, and thin protective layers over less durable materials.
watch_out:
- Thin white film can erode and peel under atomic oxygen, and the 1.5 and 2.0 mil grades have a tensile strength of only 55 to 62 MPa. Overheating releases hydrogen fluoride.
verdict: White Tedlar is a practical, weather-resistant fluoropolymer film with strong atomic oxygen protection from its pigment. It is best used as a thin, supported outer layer rather than a structural part, and it needs a fuller ageing and radiation data set before a long mission design relies on it.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
| # | Source | Type | Year | Used for |
|---|---|---|---|---|
| Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit | report | 2008 | 6 values | |
| Polyvinyl fluoride (Wikipedia) | web | 2026 | 12 values | |
| Vinyl fluoride, PubChem CID 6339 (GHS classification) | database | 2026 | 1 value | |
| DuPont Tedlar PVF Films, General Properties | datasheet | 2011 | 18 values | |
| DuPont Tedlar PVF Films, General Properties brochure | datasheet | 2011 | 0 values | |
| DuPont Tedlar products overview | datasheet | 2022 | 2 values | |
| Mineral Commodity Summaries 2026: Fluorspar (U.S. Geological Survey) | report | 2026 | 1 value | |
| Polyvinylfluoride Film, Material Information (Goodfellow) | datasheet | 2024 | 0 values |