Monel 400 Alloy 400 (UNS N04400)
Nickel-copper solid-solution alloy: 63.0 min nickel plus cobalt, 28.0 to 34.0 copper, 2.5 max iron, 2.0 max manganese, 0.5 max silicon, 0.3 max carbon, 0.024 max sulfur (wt%)
Also known as UNS N04400, EN 2.4360, EN 2.4361, EN name NiCu30Fe, DIN 17750, DIN 17751 · 26 more
Monel 400 (UNS N04400, W.Nr.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Recipe, share of the weight
- Ni minimum, nickel plus cobaltNickel plus cobalt
- Cu 28 to 34%Copper
- Fe 2.5 maximumIron
- Mn 2.0 maximumManganese
- Si 0.5 maximumSilicon
- C 0.3 maximumCarbon
- S 0.024 maximumSulfur
Best for
Seawater, hydrofluoric-acid and reducing-acid service, and marine valves, pump shafts and fasteners, where corrosion resistance matters more than high strength
Weakest at
Stagnant seawater (crevice and pitting corrosion), caustic at high temperature and stress (stress-corrosion cracking), and low strength in the annealed condition
Risk at a glance
- People Moderate. Metal flagged by nickel and copper records; no alloy SDS
- If it fails High. Caustic stress-corrosion cracking
- Corrosion Severe. Not useful in highly oxidising acids such as nitric or nitrous acid (ATI).
Quick facts: Alloy 400 (UNS N04400)
| Property | Value | Basis |
|---|---|---|
| Density | 8.8 to 8.83 g/cm³ | 2 sourced values across conditions |
| Yield strength | 172 to 345 MPa | 4 sourced values across conditions |
| Tensile strength | 483 to 621 MPa | 4 sourced values across conditions |
| Young's modulus | 179 to 180 GPa | 2 sourced values across conditions |
| Thermal conductivity | 22 W/(m·K) | 1 sourced value |
| Thermal expansion (CTE) | 13.9 to 14.2 ppm/K | 2 sourced values across conditions |
| Melting point | 1,300 to 1,350 °C | 1 sourced value |
| Specific heat | 427 to 430 J/(kg·K) | 2 sourced values across conditions |
| Electrical resistivity | 5.1e-7 Ω·m | 2 sourced values across conditions |
What is the density of Monel 400?
Monel 400 has a density of 8.8 to 8.83 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the thermal conductivity of Monel 400?
Monel 400 has a thermal conductivity of 22 W/(m·K). The source and test conditions are listed in the properties table on this page.
What is the coefficient of thermal expansion of Monel 400?
Monel 400 has a coefficient of thermal expansion of 13.9 to 14.2 ppm/K. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the melting point of Monel 400?
Monel 400 has a melting point of 1,300 to 1,350 °C. The source and test conditions are listed in the properties table on this page.
What is the yield strength of Monel 400?
Monel 400 has a yield strength of 172 to 345 MPa. The range covers 4 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What are the other names and codes for Monel 400?
Monel 400 is also written as UNS N04400, EN 2.4360, EN 2.4361, EN name NiCu30Fe, DIN 17750, DIN 17751. Each code is printed in the source listed beside it in the designations table.
What is Monel 400 used for?
Uses recorded in the sources include Gasoline and fresh water tanks; Marine fixtures and fasteners; Boiler feedwater heaters, heat exchangers and deaerating heaters.
Why it exists
Monel 400 comes from a nickel-copper ore developed in the early twentieth century, whose nickel and copper were in about the ratio now specified for the alloy (ATI). Special Metals says it combines high strength and toughness with excellent resistance to many corrosive environments, and its name is a trademark now held by Special Metals (Wikipedia). Marine and chemical processing use it because it resists seawater and reducing acids (Special Metals).
Where it's used
Marine and chemical service
Special Metals names valves and pumps, pump and propeller shafts, marine fixtures and fasteners, chemical processing equipment, and crude petroleum stills, process vessels and piping as typical applications.
Heat exchangers and boiler feedwater heaters
Boiler feedwater heaters, other heat exchangers and deaerating heaters are typical applications (Special Metals).
Fuel and water tanks
Gasoline and fresh water tanks are typical applications (Special Metals).
Aircraft structures, historical
Wikipedia says Monel metal was used in bulk in aircraft construction, including the frames and skins of experimental rocket planes such as the X-15, though the article does not name the grade.
Recipe
Nickel-copper solid-solution alloy: 63.0 min nickel plus cobalt, 28.0 to 34.0 copper, 2.5 max iron, 2.0 max manganese, 0.5 max silicon, 0.3 max carbon, 0.024 max sulfur (wt%)
Monel 400 is a single-phase nickel-copper alloy. Special Metals gives the limiting composition in weight percent, with nickel plus cobalt at least 63.0, copper 28.0 to 34.0, and iron 2.5 maximum, manganese 2.0 maximum, silicon 0.5 maximum, carbon 0.3 maximum and sulfur 0.024 maximum. Nickel and copper are mutually soluble in all proportions, so the alloy is one solid-solution phase (Wikipedia). Special Metals says it is hardened only by cold working.
| Ingredient | Share of the weight | What it does |
|---|---|---|
| Nickel plus cobalt Ni | minimum, nickel plus cobalt | Matrix of the single-phase solid solution, with copper |
| Copper Cu | 28 to 34% | Mutually soluble with nickel in all proportions, so the alloy is single-phase (Wikipedia) |
| Iron Fe | 2.5 maximum | Residual element, limited to 2.5 percent |
| Manganese Mn | 2.0 maximum | Residual element, limited to 2.0 percent |
| Silicon Si | 0.5 maximum | Residual element, limited to 0.5 percent |
| Carbon C | 0.3 maximum | Residual element, limited to 0.3 percent |
| Sulfur S | 0.024 maximum | Residual element, limited to 0.024 percent |
Weight shares are as printed in the sources.
What it can do
Seawater
Very low corrosion rates in flowing seawater (Special Metals), and Wikipedia says it resists rapidly flowing seawater.
Hydrofluoric acid
Exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point (Special Metals).
Strength in the annealed condition
Annealed rod and bar give 75 to 90 ksi tensile and 25 to 50 ksi yield, and annealed hot-rolled plate gives 70 to 85 ksi tensile (Special Metals Table 4, composite ranges).
Stiffness
Tension modulus is 26.0 times 10^3 ksi (Special Metals Table 2), and ATI gives 180 GPa for annealed plate, sheet and strip.
Low temperature
Wikipedia says the alloy does not undergo a ductile-to-brittle transition even when cooled to the temperature of liquid hydrogen.
How it compares
Compare with [Inconel 625](/profiles/inconel-625/), the chromium-bearing nickel alloy on this site. Monel 400 has no chromium in its limiting composition, and its composition is nickel with 28.0 to 34.0 percent copper (Special Metals Table 1). Monel K-500 is a different, age-hardened alloy and is not covered by this profile.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.
| Measurement | Alloy 400 (UNS N04400) | IN718 (UNS N07718) | IN625 (UNS N06625) | FeNi36 | Ni-Mo | C-22 | C-276 (UNS N10276) | X (UNS N06002) | UNS N07214 | H230 (UNS N06230) | UNS N08800 | Alloy 825 (UNS N08825) | Alloy 600 (UNS N06600, W.Nr. 2.4816) | Alloy 601 | Alloy 617 | X-750 (UNS N07750) | Fe-Ni-Co | K-500 | Ni | Ni3Al, NiAl | NiBe2 | Ni-alloys | UNS N07090 (W. Nr. 2.4632) | UNS N07001 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Thermal behavior and safety | ||||||||||||||||||||||||
| melting point | 1300 to 1350 °C3 | 1260 °C | 1290 to 1350 °C | 1427 °C | 1370 to 1418 °C | 1357 to 1399 °C | 1323 to 1371 °C | 1260 to 1355 °C | 1355 to 1400 °C | 1301 to 1371 °C | 1357 to 1385 °C | 1370 to 1400 °C | 1354 to 1413 °C | 1360 to 1411 °C | 1330 to 1380 °C | 1393 to 1427 °C | 1450 °C | 1315 to 1350 °C | 1455 °C | no data | 1195 to 1325 °C | 1425 °C | 1370 °C | 1330 to 1360 °C |
| Thermal conductivity | 22 W/m°C7 | 79 BTU·in/ft²·h·°F | 9.8 W/m°C | 72.85 Btu·in/(hr·ft²·°F) | 11.2 W/m.°C | 10.1 W/(m·K) | 10.5 W/m.°C | 9.2 W/(m·K) | 12 W/m-°C | 8.9 W/(m·°C) | 11.5 W/m°C | 11.1 W/(m·K) | 14.9 W/(m·K) | 11.2 W/(m·K) | 13.4 W/(m·K) | 83 Btu/in./hr/sq ft/°F | 17.5 W/m °K | 17.5 W/m °C | 70.3 W/(m·K) | no data | 48 W/(m·K) | 13 W/(m·K) | 11.47 W/(m·K) | 19.1 W/(m·°C) |
| specific heat | 427 J/kg°C8 | 435 J/kg °C | 410 J/(kg·K) | 515 J/(kg·K) | 373 J/kg.°C | 410 J/(kg·K) | 427 J/kg.°C | 486 J/(kg·K) | 452 J/kg-°C | 397 J/kg·°C | 460 J/kg·°C | 440 J/(kg·K) | 444 J/kg °C | 448 J/(kg·K) | 419 J/(kg·K) | 0.103 Btu/lb/°F | 500 J/(kg. K) | 419 J/kg °C | 456 J/(kg·K) | no data | no data | 500 J/(kg·K) | 446 J/(kg·K) | no data |
| specific heat | 430 J/kg·K11 | 435 J/kg °C | 410 J/(kg·K) | 515 J/(kg·K) | 373 J/kg.°C | 410 J/(kg·K) | 427 J/kg.°C | 486 J/(kg·K) | 452 J/kg-°C | 397 J/kg·°C | 460 J/kg·°C | 440 J/(kg·K) | 444 J/kg °C | 448 J/(kg·K) | 419 J/(kg·K) | 0.103 Btu/lb/°F | 500 J/(kg. K) | 419 J/kg °C | 456 J/(kg·K) | no data | no data | 500 J/(kg·K) | 446 J/(kg·K) | no data |
| Physical and electrical | ||||||||||||||||||||||||
| Density | 8.8 g/cm³1 | 0.297 lb/in3 | 8.44 g/cm³ | 8.05 g/cm³ | 9.22 g/cm³ | 8.69 g/cm³ | 8.89 g/cm³ | 8.22 g/cm³ | 8.05 g/cm³ | 8.97 g/cm³ | 7.94 g/cm³ | 8.14 g/cm³ | 0.306 lb/in3 | 8.11 Mg/m3 | 8.36 g/cm³ | 8.28 g/cm³ | 8.36 g/cm³ | 8.45 g/cm³ | 8.89 g/cm³ | 7.5 g/cm³ | 8.27 g/cm³ | 8.2 g/cm³ | 8.18 g/cm³ | 8.19 g/cm³ |
| Density | 8.83 g/cm³2 | 0.297 lb/in3 | 8.44 g/cm³ | 8.05 g/cm³ | 9.22 g/cm³ | 8.69 g/cm³ | 8.89 g/cm³ | 8.22 g/cm³ | 8.05 g/cm³ | 8.97 g/cm³ | 7.94 g/cm³ | 8.14 g/cm³ | 0.306 lb/in3 | 8.11 Mg/m3 | 8.36 g/cm³ | 8.28 g/cm³ | 8.36 g/cm³ | 8.45 g/cm³ | 8.89 g/cm³ | 7.5 g/cm³ | 8.27 g/cm³ | 8.2 g/cm³ | 8.18 g/cm³ | 8.19 g/cm³ |
| electrical resistivity | 0.511 µΩ·m9 | 725 ohm circ mil/ft | 129 µΩ-cm | 84 µΩ·cm | 1.37 μohm.m | 1.14 µΩ·m | 1.23 μohm.m | 114.8 µohm-cm | 135.9 µohm-cm | 125 µohm-m | 0.989 µΩ·m | 112 µΩ·cm | 1.03 µΩ·m | 1.18 µΩ·m | 1.22×10^-4 Ω·cm | 731 ohm circ mil/ft | 49 μΩcm | 0.615 µΩ·m | 0.096 µΩ·m | no data | < 28.7 µΩ·cm | 45 µΩ·cm | 1.18 µΩ·m | 1.24 µΩ·m |
| electrical resistivity | 51 µΩ-cm12 | 725 ohm circ mil/ft | 129 µΩ-cm | 84 µΩ·cm | 1.37 μohm.m | 1.14 µΩ·m | 1.23 μohm.m | 114.8 µohm-cm | 135.9 µohm-cm | 125 µohm-m | 0.989 µΩ·m | 112 µΩ·cm | 1.03 µΩ·m | 1.18 µΩ·m | 1.22×10^-4 Ω·cm | 731 ohm circ mil/ft | 49 μΩcm | 0.615 µΩ·m | 0.096 µΩ·m | no data | < 28.7 µΩ·cm | 45 µΩ·cm | 1.18 µΩ·m | 1.24 µΩ·m |
| electrical conductivity | 34 % IACS27 | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | no data | > 6 %IACS | no data | no data | no data |
| Temperature behavior | ||||||||||||||||||||||||
| curie temperature | 21 to 49 °C4 | -112 °C | < -196 °C | 279 °C | no data | no data | no data | no data | no data | no data | -115 °C | < -196 °C | -124 °C | no data | no data | no data | 435 °C | -65 °C | 360 °C | no data | no data | 450 °C | no data | no data |
| Other measurements | ||||||||||||||||||||||||
| elastic modulus | 26 10^3 ksi5 | 29 ksi x 10^3 | 207.5 GPa | 140 GPa | 216 GPa | 206 GPa | 205 GPa | 205 GPa | 218 GPa | 209 GPa | 196.5 GPa | 196 GPa | 214 GPa | 206.5 GPa | 211 GPa | 31 10^3 ksi | 138 kN/mm2 | 179 GPa | 205 GPa | 200 GPa | 195 to 210 GPa | no data | 204 GPa | 211 GPa |
| elastic modulus | 180 GPa6 | 29 ksi x 10^3 | 207.5 GPa | 140 GPa | 216 GPa | 206 GPa | 205 GPa | 205 GPa | 218 GPa | 209 GPa | 196.5 GPa | 196 GPa | 214 GPa | 206.5 GPa | 211 GPa | 31 10^3 ksi | 138 kN/mm2 | 179 GPa | 205 GPa | 200 GPa | 195 to 210 GPa | no data | 204 GPa | 211 GPa |
| poissons ratioTable 2, Poisson's Ratio row, printed as 0.32 | 0.32 - | 0.294 - | 0.278 - | no data | no data | no data | 0.31 - | 0.32 - | no data | 0.31 - | 0.339 - | no data | 0.324 - | 0.272 - | no data | 0.29 - | no data | no data | no data | no data | 0.3 - | no data | no data | no data |
| Thermal expansion (CTE) | 14.2 µm/m°C10 | 8.91 ppm/°F | 12.8 ppm/°C | 1.3 ppm/K | 10.6 μm/m.°C | 12.4 ppm/K | 11.2 μm/m.°C | 13.9 µm/(m·K) | 14.6 µm/m-°C | 11.8 ppm/K | 14.4 µm/m/°C | 13.9 ppm/K | 10.4 ppm/K | 13.75 µm/m/°C | 11.6 µm/(m·K) | 7 10-6 in./in./°F | 5.86 10-6/°C | 13.7 10-6/°C | 13.3 ppm/K | no data | 14.5 ppm/K | 8 ppm/K | 12.7 µm/(m·K) | 14.3 µm/m·°C |
| Thermal expansion (CTE) | 13.9 10^-6/°C13 | 8.91 ppm/°F | 12.8 ppm/°C | 1.3 ppm/K | 10.6 μm/m.°C | 12.4 ppm/K | 11.2 μm/m.°C | 13.9 µm/(m·K) | 14.6 µm/m-°C | 11.8 ppm/K | 14.4 µm/m/°C | 13.9 ppm/K | 10.4 ppm/K | 13.75 µm/m/°C | 11.6 µm/(m·K) | 7 10-6 in./in./°F | 5.86 10-6/°C | 13.7 10-6/°C | 13.3 ppm/K | no data | 14.5 ppm/K | 8 ppm/K | 12.7 µm/(m·K) | 14.3 µm/m·°C |
| ultimate tensile strength | 75 to 90 ksi14 | 201 ksi | 120 to 150 ksi | 65 ksi | 862 MPa | 690 to 950 MPa | 792 MPa | 760 MPa | 975 MPa | 837 MPa | 590 MPa | 662 MPa | 550 to 690 MPa | 675 MPa | 710 MPa | > 165 ksi | 450 to 585 N/mm2 | 621 to 758 MPa | 380 to 520 MPa | 2300 MPa | 660 to 900 MPa | 500 MPa | 1175 MPa | 1027 MPa |
| yield strength | 25 to 50 ksi15 | 171 ksi | 60 to 95 ksi | 40 ksi | 421 MPa | > 310 MPa | 356 MPa | 340 MPa | 577 MPa | 417 MPa | 250 MPa | 338 MPa | 170 to 345 MPa | 292 MPa | 340 MPa | > 105 ksi | > 200 N/mm2 | 276 to 414 MPa | 105 to 210 MPa | no data | 280 to 480 MPa | 280 MPa | 752 MPa | 586 MPa |
| elongation | 35 to 60 %16 | 26 % | 30 to 60 % | 35 % | 53 % | > 45 % | 61 % | 48.9 % | 37.3 % | 47.3 % | 17 % | 45 % | 35 to 55 % | 46 % | 62 % | > 20 % | > 25 % | 20 to 35 % | 40 to 55 % | no data | > 30 % | 35 % | 30 % | 43 % |
| ultimate tensile strength | 70 to 85 ksi17 | 201 ksi | 120 to 150 ksi | 65 ksi | 862 MPa | 690 to 950 MPa | 792 MPa | 760 MPa | 975 MPa | 837 MPa | 590 MPa | 662 MPa | 550 to 690 MPa | 675 MPa | 710 MPa | > 165 ksi | 450 to 585 N/mm2 | 621 to 758 MPa | 380 to 520 MPa | 2300 MPa | 660 to 900 MPa | 500 MPa | 1175 MPa | 1027 MPa |
| yield strength | 28 to 50 ksi18 | 171 ksi | 60 to 95 ksi | 40 ksi | 421 MPa | > 310 MPa | 356 MPa | 340 MPa | 577 MPa | 417 MPa | 250 MPa | 338 MPa | 170 to 345 MPa | 292 MPa | 340 MPa | > 105 ksi | > 200 N/mm2 | 276 to 414 MPa | 105 to 210 MPa | no data | 280 to 480 MPa | 280 MPa | 752 MPa | 586 MPa |
| ultimate tensile strength | 70 to 85 ksi19 | 201 ksi | 120 to 150 ksi | 65 ksi | 862 MPa | 690 to 950 MPa | 792 MPa | 760 MPa | 975 MPa | 837 MPa | 590 MPa | 662 MPa | 550 to 690 MPa | 675 MPa | 710 MPa | > 165 ksi | 450 to 585 N/mm2 | 621 to 758 MPa | 380 to 520 MPa | 2300 MPa | 660 to 900 MPa | 500 MPa | 1175 MPa | 1027 MPa |
| yield strength | > 28 ksi20 | 171 ksi | 60 to 95 ksi | 40 ksi | 421 MPa | > 310 MPa | 356 MPa | 340 MPa | 577 MPa | 417 MPa | 250 MPa | 338 MPa | 170 to 345 MPa | 292 MPa | 340 MPa | > 105 ksi | > 200 N/mm2 | 276 to 414 MPa | 105 to 210 MPa | no data | 280 to 480 MPa | 280 MPa | 752 MPa | 586 MPa |
| elongation | > 35 %21 | 26 % | 30 to 60 % | 35 % | 53 % | > 45 % | 61 % | 48.9 % | 37.3 % | 47.3 % | 17 % | 45 % | 35 to 55 % | 46 % | 62 % | > 20 % | > 25 % | 20 to 35 % | 40 to 55 % | no data | > 30 % | 35 % | 30 % | 43 % |
| ultimate tensile strength | 75000 psi22 | 201 ksi | 120 to 150 ksi | 65 ksi | 862 MPa | 690 to 950 MPa | 792 MPa | 760 MPa | 975 MPa | 837 MPa | 590 MPa | 662 MPa | 550 to 690 MPa | 675 MPa | 710 MPa | > 165 ksi | 450 to 585 N/mm2 | 621 to 758 MPa | 380 to 520 MPa | 2300 MPa | 660 to 900 MPa | 500 MPa | 1175 MPa | 1027 MPa |
| yield strength | 35000 psi23 | 171 ksi | 60 to 95 ksi | 40 ksi | 421 MPa | > 310 MPa | 356 MPa | 340 MPa | 577 MPa | 417 MPa | 250 MPa | 338 MPa | 170 to 345 MPa | 292 MPa | 340 MPa | > 105 ksi | > 200 N/mm2 | 276 to 414 MPa | 105 to 210 MPa | no data | 280 to 480 MPa | 280 MPa | 752 MPa | 586 MPa |
| elongation | 45 %24 | 26 % | 30 to 60 % | 35 % | 53 % | > 45 % | 61 % | 48.9 % | 37.3 % | 47.3 % | 17 % | 45 % | 35 to 55 % | 46 % | 62 % | > 20 % | > 25 % | 20 to 35 % | 40 to 55 % | no data | > 30 % | 35 % | 30 % | 43 % |
| yield strength | 21000 psi25 | 171 ksi | 60 to 95 ksi | 40 ksi | 421 MPa | > 310 MPa | 356 MPa | 340 MPa | 577 MPa | 417 MPa | 250 MPa | 338 MPa | 170 to 345 MPa | 292 MPa | 340 MPa | > 105 ksi | > 200 N/mm2 | 276 to 414 MPa | 105 to 210 MPa | no data | 280 to 480 MPa | 280 MPa | 752 MPa | 586 MPa |
| ultimate tensile strength | 53000 psi26 | 201 ksi | 120 to 150 ksi | 65 ksi | 862 MPa | 690 to 950 MPa | 792 MPa | 760 MPa | 975 MPa | 837 MPa | 590 MPa | 662 MPa | 550 to 690 MPa | 675 MPa | 710 MPa | > 165 ksi | 450 to 585 N/mm2 | 621 to 758 MPa | 380 to 520 MPa | 2300 MPa | 660 to 900 MPa | 500 MPa | 1175 MPa | 1027 MPa |
Why choose it, and why not
Good for
- Seawater and marine parts that need strength with corrosion resistance, such as valves, pump and propeller shafts and fasteners (Special Metals).
- Hydrofluoric-acid service, including the reacting section of alkylation units (Wikipedia; Special Metals).
- Chemical processing in reducing acids, and heat exchangers and boiler feedwater heaters (Special Metals).
Watch out for
- Stagnant seawater can cause crevice and pitting corrosion, although flowing seawater gives very low corrosion rates (Special Metals).
- Caustic stress-corrosion cracking can occur at high temperature, high stress and high caustic concentration (ATI).
- Strength ranges are composites for various product sizes and are not specification values (Special Metals Table 4).
- Some heats are magnetic at room temperature and others are not, because the Curie temperature sits near room temperature (Special Metals Table 2).
- Galvanic attack on steel in salt water (Wikipedia).
- The corrosion entries are qualitative. No corrosion rate or test number was read in this run.
Monel 400 is a nickel-copper alloy for seawater, chemical and hydrofluoric-acid service. Its annealed strength is modest, so state the temper on every design, design for flowing rather than stagnant seawater, and stress-relieve where stress-corrosion cracking is a concern.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Other names and standards
The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.
| System | Codes |
|---|---|
| UNS | N04400 |
| EN | 2.4360, 2.4361 (printed with 2.4360) |
| EN name | NiCu30Fe |
| DIN | 17750 (plate, strip and sheet), 17751 (pipe and tube), 17752 (rod and bar), 17753 (wire), 17754 (forgings) |
| BS | 3072 NA13 (sheet and plate), 3073 NA13 (strip), 3074 NA13 (tube), 3075 NA13 (wire), 3076 NA13 (bar) |
| ASTM | B127 (plate, sheet and strip), B163 (condenser and heat exchanger tube), B164 (rod, bar and wire), B165 (seamless pipe and tube), B564 (forgings) |
| ASME | SB 127 (plate, sheet and strip), SB 164 (rod, bar and wire), SB 165 (seamless pipe and tube) |
| AMS | 4544 (sheet, strip and plate), 4574 (seamless tubing), 4675 (bars and forgings), 4730 (wire), 4731 (wire and ribbon) |
| Federal | QQ-N-281 (plate, sheet, strip, bar, rod, wire and forgings) |
| Trade name | MONEL alloy 400, Monel 400, Alloy 400, ATI 400 |
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Density | Table 2, Physical Constants, Density g/cm3 row, printed as 8.80; the lb/in3 row prints 0.318 | basis Table 2 physical constant; no test temperature or condition printed | — |
| 2 | Density | Density section, printed as 0.319 lb/in3 and 8.83 g/cm3; the specific gravity is also printed as 8.83 | basis typical value on the ATI data sheet; no temperature or condition stated | — |
| 3 | melting point | Table 2, Melting Range, °C row, printed as 1300-1350; the F row prints 2370-2460 | basis melting range as printed in Table 2 (2370 to 2460 F) | — |
| 4 | curie temperature | Table 2, Curie Temperature, °C row, printed as 21-49 | basis Curie range as printed in Table 2 (70 to 120 F); some heats are magnetic at room temperature and others are not | — |
| 5 | elastic modulus | Table 2, Modulus of Elasticity, Tension row, printed as 26.0 (10^3 ksi); the compression row also prints 26.0 | basis tension modulus; no test temperature printed (Figure 1 gives the temperature effect and was not read) | — |
| 6 | elastic modulus | Mechanical Properties, Elastic Modulus column, annealed plate, sheet and strip row, printed as 26x10^6 psi (180 GPa) | condition annealedproduct plate, sheet and striptemperature room temperaturebasis typical value on the ATI data sheet | — |
| 7 | Thermal conductivity | Table 3, Thermal Conductivity W/m°C column, row 70 F (21 C), printed as 22.0; the Btu-in/h/ft2/F column prints 151 for the same row | temperature 70 F (21 C)basis Table 3 row 70 F (21 C); footnote a says the values also apply to R-405, the free-machining version of this alloy | — |
| 8 | specific heat | Table 3, Specific Heat J/kg°C column, row 70 F (21 C), printed as 427; the Btu/lb/F column prints 0.102 | temperature 70 F (21 C)basis Table 3 row 70 F (21 C); footnote a also applies to R-405 | — |
| 9 | electrical resistivity | Table 3, Electrical Resistivity µΩ·m column, row 70 F (21 C), printed as 0.511 | temperature 70 F (21 C)condition annealed material (footnote c)basis Table 3 row 70 F (21 C) | — |
| 10 | Thermal expansion (CTE) | Table 3, Mean Linear Expansion µm/m°C column, row 200 F (100 C), printed as 14.2; the in/in/F column prints 7.7 x 10^-6 | condition annealed material (footnote b)temperature 70 F (21 C) to 200 F (100 C)basis mean linear expansion from 70 F to the row temperature, as printed in Table 3 | — |
| 11 | specific heat | Physical Properties, Specific Heat, room temperature values, printed as 430 Joules/kg K | temperature room temperaturebasis room-temperature value printed on the ATI data sheet; condition not stated | — |
| 12 | electrical resistivity | Physical Properties, Electrical Resistivity, printed as 51.0 Microhm-cm | basis value printed on the ATI data sheet with no temperature or condition stated | — |
| 13 | Thermal expansion (CTE) | Linear Coefficient of Thermal Expansion table, row 200 F (93 C), 10^-6/C column, printed as 13.9; the 10^-6/F column prints 7.7 | temperature 70 F (21 C) to 200 F (93 C)basis mean linear expansion, typical value on the ATI data sheet | — |
| 14 | ultimate tensile strength | Table 4, Rod and Bar, Annealed row, tensile strength column, printed as 75-90 ksi (517-620 MPa) | condition annealedproduct rod and bartemperature room temperaturebasis composite range for various product sizes, not for specification (footnote a) | — |
| 15 | yield strength | Table 4, Rod and Bar, Annealed row, yield strength (0.2% offset) column, printed as 25-50 ksi (172-345 MPa) | condition annealedproduct rod and bartemperature room temperature, 0.2 percent offsetbasis composite range for various product sizes, not for specification (footnote a) | — |
| 16 | elongation | Table 4 prints 60-35 percent for the annealed row; recorded here low to high | condition annealedproduct rod and bartemperature room temperature | — |
| 17 | ultimate tensile strength | Table 4, Plate, Hot-Rolled Annealed row, tensile strength column, printed as 70-85 ksi (482-586 MPa) | condition hot-rolled, annealedproduct platetemperature room temperaturebasis composite range for various product sizes, not for specification (footnote a) | — |
| 18 | yield strength | Table 4, Plate, Hot-Rolled Annealed row, yield strength column, printed as 28-50 ksi (193-345 MPa) | condition hot-rolled, annealedproduct platetemperature room temperature, 0.2 percent offsetbasis composite range for various product sizes, not for specification (footnote a) | — |
| 19 | ultimate tensile strength | ATI product page, plate table, annealed, printed as 70 min - 85 max ksi (485 min - 585 max MPa) | condition annealedproduct plate (ASTM B127, ASME SB-127, AMS 4544)temperature room temperaturebasis minimum and maximum printed on the ATI product page | — |
| 20 | yield strength | ATI product page, plate table, annealed, printed as 28 min ksi (195 min MPa) | condition annealedproduct plate (ASTM B127, ASME SB-127, AMS 4544)temperature room temperature, 0.2 percent offsetbasis minimum printed on the ATI product page | — |
| 21 | elongation | ATI product page, plate table, annealed, printed as 35% min | condition annealedproduct plate (ASTM B127, ASME SB-127, AMS 4544)temperature room temperaturebasis minimum printed on the ATI product page | — |
| 22 | ultimate tensile strength | Properties Applicable to Plate, Sheet and Strip, annealed row, ultimate tensile strength column, printed as 75,000 psi (520 MPa) | condition annealedproduct plate, sheet and striptemperature room temperaturebasis typical value on the ATI data sheet | — |
| 23 | yield strength | Properties Applicable to Plate, Sheet and Strip, annealed row, yield strength column, printed as 35,000 psi (240 MPa) | condition annealedproduct plate, sheet and striptemperature room temperature, 0.2 percent offsetbasis typical value on the ATI data sheet | — |
| 24 | elongation | Properties Applicable to Plate, Sheet and Strip, annealed row, elongation column, printed as 45 percent in 2 in (51 mm) | condition annealedproduct plate, sheet and striptemperature room temperaturebasis typical value in 2 in (51 mm) on the ATI data sheet | — |
| 25 | yield strength | Short Time Elevated Temperature Properties table, row 1000 F (538 C), printed as 21,000 psi (145 MPa) | condition annealedtemperature 1000 F (538 C)basis short-time test, 0.2 percent offset yield strength, typical value on the ATI data sheet | — |
| 26 | ultimate tensile strength | Short Time Elevated Temperature Properties table, row 1000 F (538 C), printed as 53,000 psi (370 MPa) | condition annealedtemperature 1000 F (538 C)basis short-time test, typical value on the ATI data sheet | — |
| 27 | electrical conductivity | Properties section, first paragraph on Monel alloy 400, printed as approximately 34% IACS | basis approximate value in the Properties section; no temperature or condition printed | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Flowing seawater | low | Very low corrosion rates in flowing seawater (Special Metals); Wikipedia says it resists rapidly flowing seawater.1 |
| Stagnant seawater | moderate | Crevice and pitting corrosion in stagnant seawater (Special Metals).2 |
| Hydrofluoric acid, all concentrations up to the boiling point | low | Exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point (Special Metals).3 |
| Range of media, including seawater, hydrofluoric acid, sulfuric acid and alkalies | low | ESPI Metals lists seawater, hydrofluoric acid, sulfuric acid and alkalies among the media in which Alloy 400 resists corrosion.4 |
| Stress-corrosion cracking in fresh and industrial waters | low | Resistant to stress-corrosion cracking and pitting in most fresh and industrial waters (Special Metals).5 |
| Chloride stress-corrosion cracking | low | Exceptionally resistant to chloride stress-corrosion cracking (ATI).6 |
| Caustic at high temperature and high stress | moderate | Caustic stress-corrosion cracking can occur at high temperature, high stress and high caustic concentration (ATI).7 |
| Sulfur-bearing gases and molten sulfur | moderate | Attacked by sulfur-bearing gases above about 700 F (371 C); molten sulfur attacks it above about 500 F (260 C) (ATI).8 |
| Sulfuric and hydrochloric acids under reducing conditions | low | Resists many forms of sulfuric and hydrochloric acid under reducing conditions (Special Metals; ATI).9 |
| Highly oxidising acids, nitric and nitrous | severe | Not useful in highly oxidising acids such as nitric or nitrous acid (ATI).10 |
| Galvanic contact with steel in salt water | moderate | Galvanic attack on steel in salt water, so Monel must be insulated from steel in shipbuilding (Wikipedia).11 |
| Sour oil and gas service (NACE MR-01-75) | not rated | Listed in NACE MR-01-75 for oil and gas service; no sour-service test result was read.12 |
| Creep and long-term high temperature | not rated | ATI says creep resistance should be considered above about 650 F (343 C).13 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Flowing seawater | Special Metals says alloy 400 products exhibit very low corrosion rates in flowing seawater. No corrosion rate or exposure time is printed. | condition flowing seawaterbasis qualitative statement, no corrosion rate or exposure time printed |
| 2 | Stagnant seawater | Special Metals says stagnant conditions have been shown to induce crevice and pitting corrosion. No test result is printed. | condition stagnant seawaterbasis qualitative statement, no test result printed |
| 3 | Hydrofluoric acid, all concentrations up to the boiling point | Special Metals says alloy 400 offers exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point, and that it is perhaps the most resistant of all commonly used engineering alloys. No corrosion rate is printed. | temperature up to the boiling pointbasis qualitative statement, no corrosion rate printed |
| 4 | Range of media, including seawater, hydrofluoric acid, sulfuric acid and alkalies | ESPI Metals describes Alloy 400 as having high strength and excellent corrosion resistance in a range of media, including seawater, hydrofluoric acid, sulfuric acid, and alkalies. This is a supplier summary, so it supports the Special Metals statements and gives no numbers. | basis qualitative supplier summary, no numbers |
| 5 | Stress-corrosion cracking in fresh and industrial waters | Special Metals says alloy 400 is also resistant to stress corrosion cracking and pitting in most fresh and industrial waters, and it recommends stress relief as a precaution against stress-corrosion cracking in certain environments. | basis qualitative statement; no test stress or medium printed |
| 6 | Chloride stress-corrosion cracking | ATI says the alloy is exceptionally resistant to chloride stress corrosion cracking. No test stress, medium or time is printed. | basis qualitative statement; no test stress or medium printed |
| 7 | Caustic at high temperature and high stress | ATI says the alloy is a consideration for cooler alkaline caustic conditions, but high temperature, high stress and high concentrations of caustic have produced caustic stress corrosion cracking in the material. | condition high temperature, high stress and high caustic concentrationbasis qualitative statement; no temperatures or concentrations printed |
| 8 | Sulfur-bearing gases and molten sulfur | ATI says the alloy is attacked in sulfur-bearing gases above about 700 F (371 C), and that molten sulfur attacks the alloy at temperatures over about 500 F (260 C). | temperature above about 700 F (371 C) in sulfur-bearing gases; over about 500 F (260 C) for molten sulfurbasis printed temperatures, no exposure time |
| 9 | Sulfuric and hydrochloric acids under reducing conditions | Special Metals says alloy 400 is resistant to many forms of sulfuric and hydrochloric acids under reducing conditions. ATI says it is used in reducing acids such as sulfuric and hydrochloric, especially in the absence of aeration and oxidising species. | basis qualitative statements; no concentrations or temperatures printed |
| 10 | Highly oxidising acids, nitric and nitrous | ATI says the alloy is not useful in highly oxidising acids such as nitric or nitrous acids, and points to high-chromium stainless steels for those environments. | basis qualitative statement |
| 11 | Galvanic contact with steel in salt water | Wikipedia says electrolytic action in salt water means Monel must be carefully insulated from other metals such as steel, and it records a yacht whose steel skeleton deteriorated through electrolytic interaction with Monel. | condition direct contact with steel in salt waterbasis qualitative account, no rate printed |
| 12 | Sour oil and gas service (NACE MR-01-75) | Special Metals says the alloy is listed in NACE MR-01-75 for oil and gas service. No sour-service test data were read in this run. | standard NACE MR-01-75 (listed) |
| 13 | Creep and long-term high temperature | ATI says creep resistance should be a consideration above about 650 F (343 C). No creep or rupture data were read. | temperature above about 650 F (343 C)basis qualitative statement; no creep data printed |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
No safety data sheet for solid Monel 400 was read. The flags come from PubChem records for nickel (about 63 percent of the alloy) and copper (28.0 to 34.0 percent).
- Nickel record
- PubChem aggregated nickel GHS lists skin sensitisation (H317, 99.9 percent of reports), suspected cancer (H351, 72.9 percent) and organ damage from prolonged exposure (H372, 99.7 percent).
- Copper record
- PubChem aggregated copper GHS lists very toxic to aquatic life (H400, 43.1 percent) and very toxic with long-lasting effects (H410, 18.8 percent).
If a part sees the wrong conditions
These results come from the datasheets and the Wikipedia article, not from field incidents.
- Stagnant seawater
- Special Metals says stagnant seawater induces crevice and pitting corrosion, although flowing seawater gives very low corrosion rates.
- Caustic at high stress
- ATI says high temperature, high stress and high caustic concentration have produced caustic stress-corrosion cracking.
- Overheating
- Special Metals says the alloy must not be heated above 2150 F, where permanent damage may result.
Handling and heat treatment
- Stress relief
- Stress relief at 1000 to 1200 F for 1 hour, then slow cooling, is strongly recommended against stress-corrosion cracking in certain environments (Special Metals).
- Hot forming
- Hot forming runs from 1200 to 2150 F, with heavy reductions at 1700 to 2150 F (Special Metals).
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Crevice and pitting corrosion in stagnant seawatermoderate severity | Stagnant seawater, rather than flowing seawaterSpecial Metals says stagnant conditions have been shown to induce crevice and pitting corrosion. |
| Caustic stress-corrosion crackinghigh severity | High temperature, high stress and high concentrations of causticATI says these conditions have produced caustic stress corrosion cracking in the material. |
| Attack by sulfur-bearing gases and molten sulfurmoderate severity | Sulfur-bearing gases above about 700 F (371 C); molten sulfur above about 500 F (260 C)ATI says the alloy is attacked in these environments. |
| Sulfur embrittlement during annealingmoderate severity | Annealing in an atmosphere with sulfur compounds, held for an extended time at the anneal temperature rangeATI says sulfur will embrittle the material with extended exposure at the anneal temperature range. |
| Overheating during hot workinghigh severity | Heating above 2150 F, or prolonged soaking at hot-working temperaturesSpecial Metals says in no case should the alloy be heated above 2150 F, where permanent damage may result, and that prolonged soaking at hot-working temperatures is detrimental. |
| Galvanic attack on steel in salt waterhigh severity | Direct contact with steel in salt waterWikipedia says electrolytic action in salt water attacked a steel skeleton in contact with Monel, so the metals must be insulated. |
| Work hardening during machininglow severity | Machining at fast speeds or high feed ratesWikipedia says Monel is very difficult to machine because it work-hardens very quickly and must be turned at slow speeds and low feed rates. |
Handling and storage
- Anneal in the range of 1400 to 1800 F for short times, in an atmosphere as free of sulfur compounds as possible (ATI).
- Stress relief at 1000 to 1200 F for 1 hour, followed by slow cooling, is strongly recommended as a precaution against stress-corrosion cracking in certain environments (Special Metals).
- ATI gives a low-temperature stress relief of about 575 F (300 C) for 1 to 3 hours on cold-deformed material.
- Stress equalizing holds cold-worked material at about 575 F for about 3 hours (Special Metals).
- Hot form at 1200 to 2150 F, with heavy reductions at 1700 to 2150 F, and never heat above 2150 F (Special Metals).
- Weld with MONEL Filler Metal 60 (AWS A5.14/ERNiCu-7) or MONEL Welding Electrode 190 (AWS A5.11/ENiCu-7) (Special Metals).
- ATI says no preheat or post-weld heat treatment is generally required, and the joint must be free of lubricants, paint and scale.
- Machine at slow speeds and low feed rates, because the alloy work-hardens quickly (Wikipedia).
Mitigations
- Stress relieve after cold working, as Special Metals recommends, as a precaution against stress-corrosion cracking in certain environments.
- Design for flowing rather than stagnant seawater, since Special Metals reports very low corrosion rates in flowing seawater and crevice and pitting in stagnant conditions.
- Insulate Monel from steel in salt water to avoid galvanic attack (Wikipedia).
- Anneal in a sulfur-free atmosphere, since sulfur embrittles the alloy during extended annealing (ATI).
Supply and geography
How common the raw materials are and where they come from.
Nickel
Globally, nickel resources have been estimated to contain more than 350 million tons of nickel (USGS)
- Top producers (2025)
- Indonesia 66.7%, Philippines 6.9%, Russia 5.1%, Canada 3.6%
- Recycling
- In 2025, nickel recovered from scrap accounted for approximately 60% of apparent consumption (USGS).
- Substitutes
- Titanium alloys can substitute for nickel or nickel-base alloys in corrosive environments (USGS).
Copper
World resources: identified resources contain 1.5 billion tons of unextracted copper (2.1 billion tons including past production), and undiscovered resources an estimated 3.5 billion tons (USGS, 2015 assessment)
- Top producers (2025)
- Chile 23%, Congo (Kinshasa) 13.9%, Peru 11.7%, China 7.8%
- Critical mineral lists
- US: listed
- Recycling
- Old scrap provided an estimated 160,000 tons of copper in 2025, and new scrap an estimated 760,000 tons; copper recovered from scrap contributed about 30% of the U.S. copper supply (USGS).
- Substitutes
- Aluminum substitutes for copper in automobile radiators, cooling and refrigeration tube, electrical equipment and power cable. Titanium and steel are used in heat exchangers (USGS).
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
Show the full YAML
spore: profile
id: monel-400
spore_version: 0.2
family: nickel-alloys
name: Monel 400
abbreviation: Alloy 400 (UNS N04400)
role: corrosion-resistant solid-solution nickel-copper alloy
category: metals
type: nickel-superalloys
summary: |
Monel 400 (UNS N04400, W.Nr. 2.4360 and 2.4361) is a single-phase nickel-copper solid-solution alloy with at least 63.0 percent nickel plus cobalt and 28.0 to 34.0 percent copper. Special Metals says it can be hardened only by cold working, and that it combines high strength and toughness with excellent resistance to many corrosive environments, especially seawater and hydrofluoric acid. Annealed material is the softest condition: Special Metals gives 75 to 90 ksi tensile for annealed rod and bar, and ATI gives 75,000 psi typical for annealed plate, sheet and strip.
best_for: Seawater, hydrofluoric-acid and reducing-acid service, and marine valves, pump shafts and fasteners, where corrosion resistance matters more than high strength
weakest_at: Stagnant seawater (crevice and pitting corrosion), caustic at high temperature and stress (stress-corrosion cracking), and low strength in the annealed condition
identity:
formula: 'Nickel-copper solid-solution alloy: 63.0 min nickel plus cobalt, 28.0 to 34.0 copper, 2.5 max iron, 2.0 max manganese, 0.5 max silicon, 0.3 max carbon, 0.024 max sulfur (wt%)'
source: sm-monel400
where: Table 1, Limiting Chemical Composition (Special Metals); UNS N04400 and W.Nr. 2.4360 and 2.4361 from the opening paragraph; the plate, sheet and strip composition on the ATI product page agrees
designations:
- system: UNS
code: N04400
source: sm-monel400
where: Opening paragraph, UNS N04400 with W.Nr. 2.4360 and 2.4361; Available Products and Specifications
- system: EN
code: '2.4360'
source: sm-monel400
where: Available Products and Specifications, Werkstoff Nr. 2.4360 and 2.4361
- system: EN
code: '2.4361'
note: printed with 2.4360
source: sm-monel400
where: Available Products and Specifications, the second number printed for this alloy
- system: EN name
code: NiCu30Fe
source: wiki-monel
where: Reference list, citation title Monel 400 (NiCu30Fe, 2.4360, N04400, NA13)
- system: ASTM
code: B127
note: plate, sheet and strip
source: sm-monel400
where: Available Products and Specifications, Plate, Sheet, and Strip list
- system: ASTM
code: B163
note: condenser and heat exchanger tube
source: sm-monel400
where: Available Products and Specifications, Pipe and Tube list
- system: ASTM
code: B164
note: rod, bar and wire
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: ASTM
code: B165
note: seamless pipe and tube
source: sm-monel400
where: Available Products and Specifications, Pipe and Tube list
- system: ASTM
code: B564
note: forgings
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: ASME
code: SB 127
note: plate, sheet and strip
source: sm-monel400
where: Available Products and Specifications, Plate, Sheet, and Strip list
- system: ASME
code: SB 164
note: rod, bar and wire
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: ASME
code: SB 165
note: seamless pipe and tube
source: sm-monel400
where: Available Products and Specifications, Pipe and Tube list
- system: AMS
code: '4544'
note: sheet, strip and plate
source: sm-monel400
where: Available Products and Specifications, Plate, Sheet, and Strip list
- system: AMS
code: '4574'
note: seamless tubing
source: sm-monel400
where: Available Products and Specifications, Pipe and Tube list
- system: AMS
code: '4675'
note: bars and forgings
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: AMS
code: '4730'
note: wire
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: AMS
code: '4731'
note: wire and ribbon
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: Federal
code: QQ-N-281
note: plate, sheet, strip, bar, rod, wire and forgings
source: sm-monel400
where: Available Products and Specifications, QQ-N-281 entries
- system: DIN
code: '17750'
note: plate, strip and sheet
source: sm-monel400
where: Available Products and Specifications, Plate, Sheet, and Strip list
- system: DIN
code: '17751'
note: pipe and tube
source: sm-monel400
where: Available Products and Specifications, Pipe and Tube list
- system: DIN
code: '17752'
note: rod and bar
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: DIN
code: '17753'
note: wire
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: DIN
code: '17754'
note: forgings
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: BS
code: 3072 NA13
note: sheet and plate
source: sm-monel400
where: Available Products and Specifications, Plate, Sheet, and Strip list
- system: BS
code: 3073 NA13
note: strip
source: sm-monel400
where: Available Products and Specifications, Plate, Sheet, and Strip list
- system: BS
code: 3074 NA13
note: tube
source: sm-monel400
where: Available Products and Specifications, Pipe and Tube list
- system: BS
code: 3075 NA13
note: wire
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: BS
code: 3076 NA13
note: bar
source: sm-monel400
where: Available Products and Specifications, Bar, Rod, Wire, and Forgings list
- system: Trade name
code: MONEL alloy 400
source: sm-monel400
where: Title and Table 1 heading
- system: Trade name
code: Monel 400
source: wiki-monel
where: Alloy table, Monel 400 row
- system: Trade name
code: Alloy 400
source: sm-monel400
where: Introduction, Alloy 400 is widely used in many fields
- system: Trade name
code: ATI 400
source: ati-tds
where: Title page, ATI 400 alloy (UNS N04400)
tags:
environments: []
stresses: []
applications:
- propulsion-and-tanks
- structures
- thermal-control
- mechanisms
properties:
- benchmark: density
value: 8.8
unit: g/cm3
scope: material
conditions:
basis: Table 2 physical constant; no test temperature or condition printed
method: Table 2, Physical Constants, Density g/cm3 row, printed as 8.80; the lb/in3 row prints 0.318
status: ground
source: sm-monel400
where: Table 2, Density g/cm3 row
- benchmark: density
value: 8.83
unit: g/cm3
scope: material
conditions:
basis: typical value on the ATI data sheet; no temperature or condition stated
method: Density section, printed as 0.319 lb/in3 and 8.83 g/cm3; the specific gravity is also printed as 8.83
status: ground
source: ati-tds
where: Physical Properties, Density section
- benchmark: melting_point
value: 1300
value_high: 1350
bound: range
unit: °C
scope: material
conditions:
basis: melting range as printed in Table 2 (2370 to 2460 F)
method: Table 2, Melting Range, °C row, printed as 1300-1350; the F row prints 2370-2460
status: ground
source: sm-monel400
where: Table 2, Melting Range, °C row
- benchmark: curie_temperature
value: 21
value_high: 49
bound: range
unit: °C
scope: material
conditions:
basis: Curie range as printed in Table 2 (70 to 120 F); some heats are magnetic at room temperature and others are not
method: Table 2, Curie Temperature, °C row, printed as 21-49
status: ground
source: sm-monel400
where: Table 2, Curie Temperature, °C row
- benchmark: elastic_modulus
value: 26
unit: 10^3 ksi
scope: material
conditions:
basis: tension modulus; no test temperature printed (Figure 1 gives the temperature effect and was not read)
method: Table 2, Modulus of Elasticity, Tension row, printed as 26.0 (10^3 ksi); the compression row also prints 26.0
status: ground
source: sm-monel400
where: Table 2, Modulus of Elasticity, Tension row
- benchmark: elastic_modulus
value: 180
unit: GPa
scope: material
conditions:
condition: annealed
product: plate, sheet and strip
temperature: room temperature
basis: typical value on the ATI data sheet
method: Mechanical Properties, Elastic Modulus column, annealed plate, sheet and strip row, printed as 26x10^6 psi (180 GPa)
status: ground
source: ati-tds
where: Mechanical Properties, Properties Applicable to Plate, Sheet and Strip, Elastic Modulus column
- benchmark: poissons_ratio
value: 0.32
unit: '-'
scope: material
conditions:
basis: Table 2, Poisson's ratio row; no test temperature printed
method: Table 2, Poisson's Ratio row, printed as 0.32
status: ground
source: sm-monel400
where: Table 2, Poisson's Ratio row
- benchmark: thermal_conductivity
value: 22
unit: W/m°C
scope: material
conditions:
temperature: 70 F (21 C)
basis: Table 3 row 70 F (21 C); footnote a says the values also apply to R-405, the free-machining version of this alloy
method: Table 3, Thermal Conductivity W/m°C column, row 70 F (21 C), printed as 22.0; the Btu-in/h/ft2/F column prints 151 for the same row
status: ground
source: sm-monel400
where: Table 3, Thermal Properties, row 70 F (21 C)
- benchmark: specific_heat
value: 427
unit: J/kg°C
scope: material
conditions:
temperature: 70 F (21 C)
basis: Table 3 row 70 F (21 C); footnote a also applies to R-405
method: Table 3, Specific Heat J/kg°C column, row 70 F (21 C), printed as 427; the Btu/lb/F column prints 0.102
status: ground
source: sm-monel400
where: Table 3, Thermal Properties, row 70 F (21 C)
- benchmark: electrical_resistivity
value: 0.511
unit: µΩ·m
scope: material
conditions:
temperature: 70 F (21 C)
condition: annealed material (footnote c)
basis: Table 3 row 70 F (21 C)
method: Table 3, Electrical Resistivity µΩ·m column, row 70 F (21 C), printed as 0.511
status: ground
source: sm-monel400
where: Table 3, Thermal Properties, row 70 F (21 C)
- benchmark: cte
value: 14.2
unit: µm/m°C
scope: material
conditions:
condition: annealed material (footnote b)
temperature: 70 F (21 C) to 200 F (100 C)
basis: mean linear expansion from 70 F to the row temperature, as printed in Table 3
method: Table 3, Mean Linear Expansion µm/m°C column, row 200 F (100 C), printed as 14.2; the in/in/F column prints 7.7 x 10^-6
status: ground
source: sm-monel400
where: Table 3, Mean Linear Expansion, row 200 F (100 C)
- benchmark: specific_heat
value: 430
unit: J/kg·K
scope: material
conditions:
temperature: room temperature
basis: room-temperature value printed on the ATI data sheet; condition not stated
method: Physical Properties, Specific Heat, room temperature values, printed as 430 Joules/kg K
status: ground
source: ati-tds
where: Physical Properties, Specific Heat
- benchmark: electrical_resistivity
value: 51
unit: µΩ-cm
scope: material
conditions:
basis: value printed on the ATI data sheet with no temperature or condition stated
method: Physical Properties, Electrical Resistivity, printed as 51.0 Microhm-cm
status: ground
source: ati-tds
where: Physical Properties, Electrical Resistivity
- benchmark: cte
value: 13.9
unit: 10^-6/°C
scope: material
conditions:
temperature: 70 F (21 C) to 200 F (93 C)
basis: mean linear expansion, typical value on the ATI data sheet
method: Linear Coefficient of Thermal Expansion table, row 200 F (93 C), 10^-6/C column, printed as 13.9; the 10^-6/F column prints 7.7
status: ground
source: ati-tds
where: Linear Coefficient of Thermal Expansion table, row 200 F (93 C)
- benchmark: ultimate_tensile_strength
value: 75
value_high: 90
bound: range
unit: ksi
scope: material
conditions:
condition: annealed
product: rod and bar
temperature: room temperature
basis: composite range for various product sizes, not for specification (footnote a)
method: Table 4, Rod and Bar, Annealed row, tensile strength column, printed as 75-90 ksi (517-620 MPa)
status: ground
source: sm-monel400
where: Table 4, Rod and Bar, Annealed row, Tensile Strength
- benchmark: yield_strength
value: 25
value_high: 50
bound: range
unit: ksi
scope: material
conditions:
condition: annealed
product: rod and bar
temperature: room temperature, 0.2 percent offset
basis: composite range for various product sizes, not for specification (footnote a)
method: Table 4, Rod and Bar, Annealed row, yield strength (0.2% offset) column, printed as 25-50 ksi (172-345 MPa)
status: ground
source: sm-monel400
where: Table 4, Rod and Bar, Annealed row, Yield Strength
- benchmark: elongation
value: 35
value_high: 60
bound: range
unit: '%'
scope: material
conditions:
condition: annealed
product: rod and bar
temperature: room temperature
method: Table 4 prints 60-35 percent for the annealed row; recorded here low to high
status: ground
source: sm-monel400
where: Table 4, Rod and Bar, Annealed row, Elongation
- benchmark: ultimate_tensile_strength
value: 70
value_high: 85
bound: range
unit: ksi
scope: material
conditions:
condition: hot-rolled, annealed
product: plate
temperature: room temperature
basis: composite range for various product sizes, not for specification (footnote a)
method: Table 4, Plate, Hot-Rolled Annealed row, tensile strength column, printed as 70-85 ksi (482-586 MPa)
status: ground
source: sm-monel400
where: Table 4, Plate, Hot-Rolled Annealed row, Tensile Strength
- benchmark: yield_strength
value: 28
value_high: 50
bound: range
unit: ksi
scope: material
conditions:
condition: hot-rolled, annealed
product: plate
temperature: room temperature, 0.2 percent offset
basis: composite range for various product sizes, not for specification (footnote a)
method: Table 4, Plate, Hot-Rolled Annealed row, yield strength column, printed as 28-50 ksi (193-345 MPa)
status: ground
source: sm-monel400
where: Table 4, Plate, Hot-Rolled Annealed row, Yield Strength
- benchmark: ultimate_tensile_strength
value: 70
value_high: 85
bound: range
unit: ksi
scope: material
conditions:
condition: annealed
product: plate (ASTM B127, ASME SB-127, AMS 4544)
temperature: room temperature
basis: minimum and maximum printed on the ATI product page
method: ATI product page, plate table, annealed, printed as 70 min - 85 max ksi (485 min - 585 max MPa)
status: ground
source: ati-page
where: ATI product page, Plate table, annealed, Tensile Strength
- benchmark: yield_strength
value: 28
bound: lower
unit: ksi
scope: material
conditions:
condition: annealed
product: plate (ASTM B127, ASME SB-127, AMS 4544)
temperature: room temperature, 0.2 percent offset
basis: minimum printed on the ATI product page
method: ATI product page, plate table, annealed, printed as 28 min ksi (195 min MPa)
status: ground
source: ati-page
where: ATI product page, Plate table, annealed, Yield Strength
- benchmark: elongation
value: 35
bound: lower
unit: '%'
scope: material
conditions:
condition: annealed
product: plate (ASTM B127, ASME SB-127, AMS 4544)
temperature: room temperature
basis: minimum printed on the ATI product page
method: ATI product page, plate table, annealed, printed as 35% min
status: ground
source: ati-page
where: ATI product page, Plate table, annealed, Elongation
- benchmark: ultimate_tensile_strength
value: 75000
unit: psi
scope: material
conditions:
condition: annealed
product: plate, sheet and strip
temperature: room temperature
basis: typical value on the ATI data sheet
method: Properties Applicable to Plate, Sheet and Strip, annealed row, ultimate tensile strength column, printed as 75,000 psi (520 MPa)
status: ground
source: ati-tds
where: Mechanical Properties, Properties Applicable to Plate, Sheet and Strip, annealed row
- benchmark: yield_strength
value: 35000
unit: psi
scope: material
conditions:
condition: annealed
product: plate, sheet and strip
temperature: room temperature, 0.2 percent offset
basis: typical value on the ATI data sheet
method: Properties Applicable to Plate, Sheet and Strip, annealed row, yield strength column, printed as 35,000 psi (240 MPa)
status: ground
source: ati-tds
where: Mechanical Properties, Properties Applicable to Plate, Sheet and Strip, annealed row
- benchmark: elongation
value: 45
unit: '%'
scope: material
conditions:
condition: annealed
product: plate, sheet and strip
temperature: room temperature
basis: typical value in 2 in (51 mm) on the ATI data sheet
method: Properties Applicable to Plate, Sheet and Strip, annealed row, elongation column, printed as 45 percent in 2 in (51 mm)
status: ground
source: ati-tds
where: Mechanical Properties, Properties Applicable to Plate, Sheet and Strip, annealed row
- benchmark: yield_strength
value: 21000
unit: psi
scope: material
conditions:
condition: annealed
temperature: 1000 F (538 C)
basis: short-time test, 0.2 percent offset yield strength, typical value on the ATI data sheet
method: Short Time Elevated Temperature Properties table, row 1000 F (538 C), printed as 21,000 psi (145 MPa)
status: ground
source: ati-tds
where: Short Time Elevated Temperature Properties table, row 1000 F (538 C), yield strength column
- benchmark: ultimate_tensile_strength
value: 53000
unit: psi
scope: material
conditions:
condition: annealed
temperature: 1000 F (538 C)
basis: short-time test, typical value on the ATI data sheet
method: Short Time Elevated Temperature Properties table, row 1000 F (538 C), printed as 53,000 psi (370 MPa)
status: ground
source: ati-tds
where: Short Time Elevated Temperature Properties table, row 1000 F (538 C), ultimate tensile strength column
- benchmark: electrical_conductivity
value: 34
unit: '% IACS'
scope: material
conditions:
basis: approximate value in the Properties section; no temperature or condition printed
method: Properties section, first paragraph on Monel alloy 400, printed as approximately 34% IACS
status: ground
source: wiki-monel
where: Properties section, Monel alloy 400 paragraph
corrosion:
- environment: Flowing seawater
headline: Very low corrosion rates in flowing seawater (Special Metals); Wikipedia says it resists rapidly flowing seawater.
effect: Special Metals says alloy 400 products exhibit very low corrosion rates in flowing seawater. No corrosion rate or exposure time is printed.
rating: low
conditions:
condition: flowing seawater
basis: qualitative statement, no corrosion rate or exposure time printed
source: sm-monel400
where: Corrosion Resistance section, first paragraph
- environment: Stagnant seawater
headline: Crevice and pitting corrosion in stagnant seawater (Special Metals).
effect: Special Metals says stagnant conditions have been shown to induce crevice and pitting corrosion. No test result is printed.
rating: moderate
conditions:
condition: stagnant seawater
basis: qualitative statement, no test result printed
source: sm-monel400
where: Corrosion Resistance section, first paragraph
- environment: Hydrofluoric acid, all concentrations up to the boiling point
headline: Exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point (Special Metals).
effect: Special Metals says alloy 400 offers exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point, and that it is perhaps the most resistant of all commonly used engineering alloys. No corrosion rate is printed.
rating: low
conditions:
temperature: up to the boiling point
basis: qualitative statement, no corrosion rate printed
source: sm-monel400
where: Corrosion Resistance section, hydrofluoric acid paragraph
- environment: Range of media, including seawater, hydrofluoric acid, sulfuric acid and alkalies
headline: ESPI Metals lists seawater, hydrofluoric acid, sulfuric acid and alkalies among the media in which Alloy 400 resists corrosion.
effect: ESPI Metals describes Alloy 400 as having high strength and excellent corrosion resistance in a range of media, including seawater, hydrofluoric acid, sulfuric acid, and alkalies. This is a supplier summary, so it supports the Special Metals statements and gives no numbers.
rating: low
conditions:
basis: qualitative supplier summary, no numbers
source: espi-alloy400
where: Alloy 400 entry, technical data page
- environment: Stress-corrosion cracking in fresh and industrial waters
headline: Resistant to stress-corrosion cracking and pitting in most fresh and industrial waters (Special Metals).
effect: Special Metals says alloy 400 is also resistant to stress corrosion cracking and pitting in most fresh and industrial waters, and it recommends stress relief as a precaution against stress-corrosion cracking in certain environments.
rating: low
conditions:
basis: qualitative statement; no test stress or medium printed
source: sm-monel400
where: Corrosion Resistance section, first paragraph; Working Instructions, Thermal Treatments
- environment: Chloride stress-corrosion cracking
headline: Exceptionally resistant to chloride stress-corrosion cracking (ATI).
effect: ATI says the alloy is exceptionally resistant to chloride stress corrosion cracking. No test stress, medium or time is printed.
rating: low
conditions:
basis: qualitative statement; no test stress or medium printed
source: ati-tds
where: Corrosion Resistance section, reducing acids paragraph
- environment: Caustic at high temperature and high stress
headline: Caustic stress-corrosion cracking can occur at high temperature, high stress and high caustic concentration (ATI).
effect: ATI says the alloy is a consideration for cooler alkaline caustic conditions, but high temperature, high stress and high concentrations of caustic have produced caustic stress corrosion cracking in the material.
rating: moderate
conditions:
condition: high temperature, high stress and high caustic concentration
basis: qualitative statement; no temperatures or concentrations printed
source: ati-tds
where: Corrosion Resistance section, alkaline solutions paragraph
- environment: Sulfur-bearing gases and molten sulfur
headline: Attacked by sulfur-bearing gases above about 700 F (371 C); molten sulfur attacks it above about 500 F (260 C) (ATI).
effect: ATI says the alloy is attacked in sulfur-bearing gases above about 700 F (371 C), and that molten sulfur attacks the alloy at temperatures over about 500 F (260 C).
rating: moderate
conditions:
temperature: above about 700 F (371 C) in sulfur-bearing gases; over about 500 F (260 C) for molten sulfur
basis: printed temperatures, no exposure time
source: ati-tds
where: Corrosion Resistance section, sulfur paragraph
- environment: Sulfuric and hydrochloric acids under reducing conditions
headline: Resists many forms of sulfuric and hydrochloric acid under reducing conditions (Special Metals; ATI).
effect: Special Metals says alloy 400 is resistant to many forms of sulfuric and hydrochloric acids under reducing conditions. ATI says it is used in reducing acids such as sulfuric and hydrochloric, especially in the absence of aeration and oxidising species.
rating: low
conditions:
basis: qualitative statements; no concentrations or temperatures printed
source: sm-monel400
where: Corrosion Resistance section, last paragraph
- environment: Highly oxidising acids, nitric and nitrous
headline: Not useful in highly oxidising acids such as nitric or nitrous acid (ATI).
effect: ATI says the alloy is not useful in highly oxidising acids such as nitric or nitrous acids, and points to high-chromium stainless steels for those environments.
rating: severe
conditions:
basis: qualitative statement
source: ati-tds
where: Corrosion Resistance section, first paragraph
- environment: Galvanic contact with steel in salt water
headline: Galvanic attack on steel in salt water, so Monel must be insulated from steel in shipbuilding (Wikipedia).
effect: Wikipedia says electrolytic action in salt water means Monel must be carefully insulated from other metals such as steel, and it records a yacht whose steel skeleton deteriorated through electrolytic interaction with Monel.
rating: moderate
conditions:
condition: direct contact with steel in salt water
basis: qualitative account, no rate printed
source: wiki-monel
where: Marine applications section
- environment: Sour oil and gas service (NACE MR-01-75)
headline: Listed in NACE MR-01-75 for oil and gas service; no sour-service test result was read.
effect: Special Metals says the alloy is listed in NACE MR-01-75 for oil and gas service. No sour-service test data were read in this run.
rating: unknown
conditions:
standard: NACE MR-01-75 (listed)
source: sm-monel400
where: Available Products and Specifications
- environment: Creep and long-term high temperature
headline: ATI says creep resistance should be considered above about 650 F (343 C).
effect: ATI says creep resistance should be a consideration above about 650 F (343 C). No creep or rupture data were read.
rating: unknown
conditions:
temperature: above about 650 F (343 C)
basis: qualitative statement; no creep data printed
source: ati-tds
where: Short Time Elevated Temperature Properties, introductory paragraph
risks:
hazards:
- text: PubChem aggregated GHS for nickel metal (CID 935) from 4778 company reports lists H317 in 99.9 percent of reports that give a code, H351 in 72.9 percent, H372 in 99.7 percent, H350 in 22.5 percent, H360F in 18 percent, H341 in 13.5 percent, H334 in 10.3 percent and H412 in 47.2 percent. Nickel is about 63 percent of this alloy, so the record describes the metal, not the alloy.
ghs:
- H317
- H351
- H372
- H350
- H360F
- H341
- H334
- H412
source: pubchem-nickel
where: Safety and Hazards, GHS Classification (PubChem PUG View JSON, aggregated ECHA C&L notifications)
- text: PubChem aggregated GHS for copper metal (CID 23978) from 3463 company reports lists H400 in 43.1 percent of reports that give a code, H410 in 18.8 percent, H411 in 22.5 percent and H302 in 21.7 percent. Copper is 28.0 to 34.0 percent of this alloy, so the record describes the metal, not the alloy.
ghs:
- H400
- H410
- H411
- H302
source: pubchem-copper
where: Safety and Hazards, GHS Classification (PubChem PUG View JSON, aggregated ECHA C&L notifications)
failure_risks:
- mode: Crevice and pitting corrosion in stagnant seawater
trigger: Stagnant seawater, rather than flowing seawater
consequence: Special Metals says stagnant conditions have been shown to induce crevice and pitting corrosion.
severity: moderate
source: sm-monel400
where: Corrosion Resistance section, first paragraph
- mode: Caustic stress-corrosion cracking
trigger: High temperature, high stress and high concentrations of caustic
consequence: ATI says these conditions have produced caustic stress corrosion cracking in the material.
severity: high
source: ati-tds
where: Corrosion Resistance section, alkaline solutions paragraph
- mode: Attack by sulfur-bearing gases and molten sulfur
trigger: Sulfur-bearing gases above about 700 F (371 C); molten sulfur above about 500 F (260 C)
consequence: ATI says the alloy is attacked in these environments.
severity: moderate
source: ati-tds
where: Corrosion Resistance section, sulfur paragraph
- mode: Sulfur embrittlement during annealing
trigger: Annealing in an atmosphere with sulfur compounds, held for an extended time at the anneal temperature range
consequence: ATI says sulfur will embrittle the material with extended exposure at the anneal temperature range.
severity: moderate
source: ati-tds
where: Heat Treatment section
- mode: Overheating during hot working
trigger: Heating above 2150 F, or prolonged soaking at hot-working temperatures
consequence: Special Metals says in no case should the alloy be heated above 2150 F, where permanent damage may result, and that prolonged soaking at hot-working temperatures is detrimental.
severity: high
source: sm-monel400
where: Working Instructions, Heating and Pickling, Thermal Treatments
- mode: Galvanic attack on steel in salt water
trigger: Direct contact with steel in salt water
consequence: Wikipedia says electrolytic action in salt water attacked a steel skeleton in contact with Monel, so the metals must be insulated.
severity: high
source: wiki-monel
where: Marine applications section
- mode: Work hardening during machining
trigger: Machining at fast speeds or high feed rates
consequence: Wikipedia says Monel is very difficult to machine because it work-hardens very quickly and must be turned at slow speeds and low feed rates.
severity: low
source: wiki-monel
where: Properties section
side_effects: []
handling:
- text: Anneal in the range of 1400 to 1800 F for short times, in an atmosphere as free of sulfur compounds as possible (ATI).
source: ati-tds
where: Heat Treatment section
- text: Stress relief at 1000 to 1200 F for 1 hour, followed by slow cooling, is strongly recommended as a precaution against stress-corrosion cracking in certain environments (Special Metals).
source: sm-monel400
where: Working Instructions, Heating and Pickling, Thermal Treatments
- text: ATI gives a low-temperature stress relief of about 575 F (300 C) for 1 to 3 hours on cold-deformed material.
source: ati-tds
where: Heat Treatment section
- text: Stress equalizing holds cold-worked material at about 575 F for about 3 hours (Special Metals).
source: sm-monel400
where: Working Instructions, Heating and Pickling
- text: Hot form at 1200 to 2150 F, with heavy reductions at 1700 to 2150 F, and never heat above 2150 F (Special Metals).
source: sm-monel400
where: Working Instructions, Hot Forming
- text: Weld with MONEL Filler Metal 60 (AWS A5.14/ERNiCu-7) or MONEL Welding Electrode 190 (AWS A5.11/ENiCu-7) (Special Metals).
source: sm-monel400
where: Welding Products list
- text: ATI says no preheat or post-weld heat treatment is generally required, and the joint must be free of lubricants, paint and scale.
source: ati-tds
where: Weldability section
- text: Machine at slow speeds and low feed rates, because the alloy work-hardens quickly (Wikipedia).
source: wiki-monel
where: Properties section
mitigations:
- text: Stress relieve after cold working, as Special Metals recommends, as a precaution against stress-corrosion cracking in certain environments.
source: sm-monel400
where: Working Instructions, Heating and Pickling, Thermal Treatments
- text: Design for flowing rather than stagnant seawater, since Special Metals reports very low corrosion rates in flowing seawater and crevice and pitting in stagnant conditions.
source: sm-monel400
where: Corrosion Resistance section, first paragraph
- text: Insulate Monel from steel in salt water to avoid galvanic attack (Wikipedia).
source: wiki-monel
where: Marine applications section
- text: Anneal in a sulfur-free atmosphere, since sulfur embrittles the alloy during extended annealing (ATI).
source: ati-tds
where: Heat Treatment section
uses:
- application: propulsion-and-tanks
device: Gasoline and fresh water tanks
example: Special Metals lists gasoline and fresh water tanks among the typical applications of alloy 400, together with crude petroleum stills, process vessels and piping.
source: sm-monel400
where: Introduction, typical applications list
- application: structures
device: Marine fixtures and fasteners
example: Special Metals lists marine fixtures and fasteners among the typical applications of alloy 400.
source: sm-monel400
where: Introduction, typical applications list
- application: thermal-control
device: Boiler feedwater heaters, heat exchangers and deaerating heaters
example: Special Metals lists boiler feedwater heaters and other heat exchangers, and deaerating heaters, among the typical applications of alloy 400.
source: sm-monel400
where: Introduction, typical applications list
- application: mechanisms
device: Valves, pumps, and pump and propeller shafts
example: Special Metals lists valves and pumps, and pump and propeller shafts, among the typical applications of alloy 400. Wikipedia says Monel is used for pump shafts and seawater valves.
source: sm-monel400
where: Introduction, typical applications list; Wikipedia, Marine applications section
- application: structures
device: Frames and skins of experimental rocket planes
example: Wikipedia says Monel metal was used in bulk in aircraft construction, including the frames and skins of experimental rocket planes such as the X-15. The article calls it Monel metal and does not name the grade.
source: wiki-monel
where: Aerospace applications section
supply:
- subject: Nickel
abundance: Globally, nickel resources have been estimated to contain more than 350 million tons of nickel (USGS)
producers:
- country: Indonesia
share_percent: 66.7
year: 2025
- country: Philippines
share_percent: 6.9
year: 2025
- country: Russia
share_percent: 5.1
year: 2025
- country: Canada
share_percent: 3.6
year: 2025
recycling: In 2025, nickel recovered from scrap accounted for approximately 60% of apparent consumption (USGS).
substitutes:
- Titanium alloys can substitute for nickel or nickel-base alloys in corrosive environments (USGS).
source: usgs-mcs2026-nickel
where: World Mine Production and Reserves table, 2025e column (world total 3,900,000 t); shares calculated by Space Mushroom from the printed tonnages; Recycling; Substitutes; World Resources
- subject: Copper
abundance: 'World resources: identified resources contain 1.5 billion tons of unextracted copper (2.1 billion tons including past production), and undiscovered resources an estimated 3.5 billion tons (USGS, 2015 assessment)'
producers:
- country: Chile
share_percent: 23
year: 2025
- country: Congo (Kinshasa)
share_percent: 13.9
year: 2025
- country: Peru
share_percent: 11.7
year: 2025
- country: China
share_percent: 7.8
year: 2025
recycling: Old scrap provided an estimated 160,000 tons of copper in 2025, and new scrap an estimated 760,000 tons; copper recovered from scrap contributed about 30% of the U.S. copper supply (USGS).
substitutes:
- Aluminum substitutes for copper in automobile radiators, cooling and refrigeration tube, electrical equipment and power cable. Titanium and steel are used in heat exchangers (USGS).
critical_lists:
- list: US Final 2025 List of Critical Minerals (copper added, 90 FR 50494)
listed: true
source: usgs-mcs2026-copper
where: World Mine and Refinery Production table, mine production 2025e (world total 23,000 thousand t, rounded); shares calculated by Space Mushroom; Events, Trends, and Issues (critical minerals); Recycling; Substitutes; World Resources
media: []
documents:
- title: MONEL alloy 400 datasheet, Special Metals Corporation (publication SMC-053, February 2005)
type: datasheet
url: https://www.specialmetals.com/documents/technical-bulletins/monel-alloy-400.pdf
year: 2005
- title: ATI 400 Technical Data Sheet, version 1 (2/18/2014)
type: datasheet
url: https://www.atimaterials.com/Products/Documents/datasheets/nickel-cobalt/nickel-based/ati_400_tds_en_v1.pdf
year: 2014
- title: ATI 400 Nickel-Based Alloy product page (plate minimums and specifications)
type: datasheet
url: https://www.atimaterials.com/Products/ati-400
- title: Monel, Wikipedia English article (read in this run)
type: database
url: https://en.wikipedia.org/wiki/Monel
- title: ESPI Metals technical data, nickel-copper alloys (Alloy 400 entry)
type: datasheet
url: http://www.espimetals.com/index.php/technical-data/165-nickel-copper-monel-alloys
- title: 'USGS Mineral Commodity Summaries 2026: Nickel'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-nickel.pdf
year: 2026
- title: 'USGS Mineral Commodity Summaries 2026: Copper'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-copper.pdf
year: 2026
- title: PubChem nickel (CID 935), GHS classification (PUG View JSON)
type: database
url: https://pubchem.ncbi.nlm.nih.gov/rest/pug_view/data/compound/935/JSON?heading=GHS+Classification
- title: PubChem copper (CID 23978), GHS classification (PUG View JSON)
type: database
url: https://pubchem.ncbi.nlm.nih.gov/rest/pug_view/data/compound/23978/JSON?heading=GHS+Classification
gaps:
- No corrosion rate, critical pitting temperature, ASTM G48 result or stress-corrosion threshold was printed in the sources read. The seawater, hydrofluoric-acid and stress-corrosion entries are qualitative.
- No fatigue value is recorded. Special Metals Tables 18 and 19 (fatigue strength of rod and of sheet) and the S-N figures were not transcribed.
- Low-temperature tensile (Table 6), Charpy impact (Tables 13 to 17), torsion (Table 7), compression (Table 8), shear (Tables 9 and 10), tear (Table 11) and bearing (Table 12) data were not transcribed.
- No numeric maximum service temperature is printed. Special Metals names ASME allowable-stress ranges up to 800 F (Section III) and 900 F (Section VIII Division 1) without stress values, and ATI says creep resistance should be considered above about 650 F (343 C), so max_service_temp is left out.
- No numeric minimum service temperature is printed. Wikipedia says the alloy does not undergo a ductile-to-brittle transition even when cooled to the temperature of liquid hydrogen, but gives no number, so min_service_temp is left out.
- Special Metals Table 4 values are composite ranges for various product sizes and are not specification values (footnote a). ATI values are typical, and the ATI product-page minimums are for plate only.
- The ATI product-page bar composition table places its nickel value in a column that does not match the other tables, so no bar composition was used. Composition comes from Special Metals Table 1 and the ATI plate table.
- 'Densities differ by source: 8.80 g/cm3 (Special Metals), 8.83 g/cm3 (ATI data sheet) and 8.84 g/cm3 for plate (ATI product page). The first two are recorded; the product-page value is left out to avoid a third density row.'
- electrical_conductivity (about 34 percent IACS, Wikipedia) is not in property-canon.yaml, so it uses a snake_case name until a canonical entry exists. Wikipedia gives no temperature or condition for it.
- No product safety data sheet for solid Monel 400 was read. The hazard entries rely on the PubChem records for nickel (about 63 percent of the alloy) and copper (28.0 to 34.0 percent), which describe the metals, not the alloy.
- The USGS 2026 nickel summary mentions an executive order on seabed deposits for critical minerals such as nickel but prints no critical-mineral list status, so nickel has no critical_lists entry. Copper is on the US Final 2025 List of Critical Minerals (USGS copper summary).
- The ASTM, ASME and AMS standard texts are paywalled and were not read. Designations come from the Special Metals product list (ASTM, ASME, AMS, BS, DIN and QQ numbers), the ATI product page and data sheet, and the Wikipedia table.
- NiCu30Fe is not printed in the Special Metals or ATI datasheets. It appears in the Wikipedia citation title for Monel 400 (NiCu30Fe, 2.4360, N04400, NA13), and that citation is the only source for the EN name.
- Monel K-500 is a different, age-hardened alloy, and Monel 405 (R-405, the free-machining grade) is a different grade. Their codes are left out. The Special Metals Tables 2 and 3 values are printed for MONEL alloy 400, and footnote a says they also apply to R-405.
- The Special Metals datasheet is publication SMC-053 dated February 2005, and the ATI data sheet is version 1 dated 2/18/2014. Values may have been revised since.
- Copper and nickel shares are calculated by Space Mushroom from the printed USGS tonnages, not printed as shares.
- The ESPI Metals technical data page is a supplier summary and is used only for a qualitative corrosion statement.
sources:
sm-monel400:
title: MONEL alloy 400 datasheet, Special Metals Corporation
id: Special Metals Corporation, publication SMC-053 (Feb 2005)
url: https://www.specialmetals.com/documents/technical-bulletins/monel-alloy-400.pdf
year: 2005
kind: datasheet
license: Special Metals terms (cited, not reproduced)
ati-tds:
title: ATI 400 Technical Data Sheet (UNS N04400)
id: ATI Allegheny Technologies, version 1 (2/18/2014)
url: https://www.atimaterials.com/Products/Documents/datasheets/nickel-cobalt/nickel-based/ati_400_tds_en_v1.pdf
year: 2014
kind: datasheet
license: ATI terms (cited, not reproduced)
ati-page:
title: ATI 400 Nickel-Based Alloy product page
id: ATI product page, read in this run (2026-10-24)
url: https://www.atimaterials.com/Products/ati-400
kind: web
license: ATI terms (cited, not reproduced)
wiki-monel:
title: Monel
id: Wikipedia, English article (read in this run, 2026-10-24)
url: https://en.wikipedia.org/wiki/Monel
kind: web
license: CC BY-SA 4.0
espi-alloy400:
title: ESPI Metals technical data, nickel-copper alloys
id: ESPI Metals, Alloy 400 entry, read in this run (2026-10-24)
url: http://www.espimetals.com/index.php/technical-data/165-nickel-copper-monel-alloys
kind: web
license: Supplier page (cited, not reproduced)
usgs-mcs2026-nickel:
title: 'Mineral Commodity Summaries 2026: Nickel'
id: USGS, Mineral Commodity Summaries 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-nickel.pdf
year: 2026
kind: report
license: US Government work (public domain)
usgs-mcs2026-copper:
title: 'Mineral Commodity Summaries 2026: Copper'
id: USGS, Mineral Commodity Summaries 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-copper.pdf
year: 2026
kind: report
license: US Government work (public domain)
pubchem-nickel:
title: Nickel, PubChem CID 935, GHS classification (aggregated ECHA C&L notifications)
id: PubChem CID 935
url: https://pubchem.ncbi.nlm.nih.gov/rest/pug_view/data/compound/935/JSON?heading=GHS+Classification
kind: database
license: PubChem (NIH, public domain)
pubchem-copper:
title: Copper, PubChem CID 23978, GHS classification (aggregated ECHA C&L notifications)
id: PubChem CID 23978
url: https://pubchem.ncbi.nlm.nih.gov/rest/pug_view/data/compound/23978/JSON?heading=GHS+Classification
kind: database
license: PubChem (NIH, public domain)
license: CC-BY-4.0
updated: '2026-10-24'
review:
status: draft
method: assistant
checked_values: 28
unreachable: 0
caveats: 17
note: Written by an AI assistant on 2026-10-24 from the Special Metals MONEL alloy 400 datasheet (SMC-053, 2005), the ATI 400 data sheet (2014) and product page, the Wikipedia Monel article, ESPI Metals technical data, USGS MCS 2026 nickel and copper, and PubChem GHS records for nickel and copper. Every number was read from a page fetched in this run. Web search was unavailable in this run, so the pages were fetched directly. The compare link points to the Inconel 625 profile, and no value from that file was used.
story:
recipe:
line: Monel 400 is a single-phase nickel-copper alloy. Special Metals gives the limiting composition in weight percent, with nickel plus cobalt at least 63.0, copper 28.0 to 34.0, and iron 2.5 maximum, manganese 2.0 maximum, silicon 0.5 maximum, carbon 0.3 maximum and sulfur 0.024 maximum. Nickel and copper are mutually soluble in all proportions, so the alloy is one solid-solution phase (Wikipedia). Special Metals says it is hardened only by cold working.
parts:
- name: Nickel plus cobalt
symbol: Ni
share_percent: 63
share_note: minimum, nickel plus cobalt
role: Matrix of the single-phase solid solution, with copper
source: sm-monel400
where: Table 1, Limiting Chemical Composition, Nickel (plus Cobalt) 63.0 min
- name: Copper
symbol: Cu
share_percent: 28
share_high: 34
role: Mutually soluble with nickel in all proportions, so the alloy is single-phase (Wikipedia)
source: sm-monel400
where: Table 1, Limiting Chemical Composition, Copper 28.0 to 34.0
- name: Iron
symbol: Fe
share_percent: 2.5
share_note: 2.5 maximum
role: Residual element, limited to 2.5 percent
source: sm-monel400
where: Table 1, Iron 2.5 max
- name: Manganese
symbol: Mn
share_percent: 2
share_note: 2.0 maximum
role: Residual element, limited to 2.0 percent
source: sm-monel400
where: Table 1, Manganese 2.0 max
- name: Silicon
symbol: Si
share_percent: 0.5
share_note: 0.5 maximum
role: Residual element, limited to 0.5 percent
source: sm-monel400
where: Table 1, Silicon 0.5 max
- name: Carbon
symbol: C
share_percent: 0.3
share_note: 0.3 maximum
role: Residual element, limited to 0.3 percent
source: sm-monel400
where: Table 1, Carbon 0.3 max
- name: Sulfur
symbol: S
share_percent: 0.024
share_note: 0.024 maximum
role: Residual element, limited to 0.024 percent
source: sm-monel400
where: Table 1, Sulfur 0.024 max
risk_groups:
- title: For people
level: 2
verdict: Metal flagged by nickel and copper records; no alloy SDS
lead: No safety data sheet for solid Monel 400 was read. The flags come from PubChem records for nickel (about 63 percent of the alloy) and copper (28.0 to 34.0 percent).
points:
- label: Nickel record
line: PubChem aggregated nickel GHS lists skin sensitisation (H317, 99.9 percent of reports), suspected cancer (H351, 72.9 percent) and organ damage from prolonged exposure (H372, 99.7 percent).
- label: Copper record
line: PubChem aggregated copper GHS lists very toxic to aquatic life (H400, 43.1 percent) and very toxic with long-lasting effects (H410, 18.8 percent).
- title: If a part sees the wrong conditions
lead: These results come from the datasheets and the Wikipedia article, not from field incidents.
points:
- label: Stagnant seawater
line: Special Metals says stagnant seawater induces crevice and pitting corrosion, although flowing seawater gives very low corrosion rates.
- label: Caustic at high stress
line: ATI says high temperature, high stress and high caustic concentration have produced caustic stress-corrosion cracking.
- label: Overheating
line: Special Metals says the alloy must not be heated above 2150 F, where permanent damage may result.
- title: Handling and heat treatment
points:
- label: Stress relief
line: Stress relief at 1000 to 1200 F for 1 hour, then slow cooling, is strongly recommended against stress-corrosion cracking in certain environments (Special Metals).
- label: Hot forming
line: Hot forming runs from 1200 to 2150 F, with heavy reductions at 1700 to 2150 F (Special Metals).
why: Monel 400 comes from a nickel-copper ore developed in the early twentieth century, whose nickel and copper were in about the ratio now specified for the alloy (ATI). Special Metals says it combines high strength and toughness with excellent resistance to many corrosive environments, and its name is a trademark now held by Special Metals (Wikipedia). Marine and chemical processing use it because it resists seawater and reducing acids (Special Metals).
uses:
- where: Marine and chemical service
line: Special Metals names valves and pumps, pump and propeller shafts, marine fixtures and fasteners, chemical processing equipment, and crude petroleum stills, process vessels and piping as typical applications.
- where: Heat exchangers and boiler feedwater heaters
line: Boiler feedwater heaters, other heat exchangers and deaerating heaters are typical applications (Special Metals).
- where: Fuel and water tanks
line: Gasoline and fresh water tanks are typical applications (Special Metals).
- where: Aircraft structures, historical
line: Wikipedia says Monel metal was used in bulk in aircraft construction, including the frames and skins of experimental rocket planes such as the X-15, though the article does not name the grade.
can_do:
- label: Seawater
line: Very low corrosion rates in flowing seawater (Special Metals), and Wikipedia says it resists rapidly flowing seawater.
- label: Hydrofluoric acid
line: Exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point (Special Metals).
- label: Strength in the annealed condition
line: Annealed rod and bar give 75 to 90 ksi tensile and 25 to 50 ksi yield, and annealed hot-rolled plate gives 70 to 85 ksi tensile (Special Metals Table 4, composite ranges).
- label: Stiffness
line: Tension modulus is 26.0 times 10^3 ksi (Special Metals Table 2), and ATI gives 180 GPa for annealed plate, sheet and strip.
- label: Low temperature
line: Wikipedia says the alloy does not undergo a ductile-to-brittle transition even when cooled to the temperature of liquid hydrogen.
compare: Compare with [Inconel 625](/profiles/inconel-625/), the chromium-bearing nickel alloy on this site. Monel 400 has no chromium in its limiting composition, and its composition is nickel with 28.0 to 34.0 percent copper (Special Metals Table 1). Monel K-500 is a different, age-hardened alloy and is not covered by this profile.
compare_rows:
- label: Density
benchmark: density
scope: material
- label: Stiffness
benchmark: elastic_modulus
scope: material
- label: Melting range
benchmark: melting_point
scope: material
handling:
- Anneal in the range of 1400 to 1800 F for short times, in an atmosphere as free of sulfur compounds as possible (ATI).
- Stress-relieve at 1000 to 1200 F for 1 hour and cool slowly, which Special Metals strongly recommends as a precaution against stress-corrosion cracking in certain environments.
- Hot form at 1200 to 2150 F, with heavy reductions at 1700 to 2150 F, and never heat above 2150 F (Special Metals).
- Weld with MONEL Filler Metal 60 or MONEL Welding Electrode 190 (Special Metals). ATI says no preheat or post-weld heat treatment is generally needed.
- Machine at slow speeds and low feed rates, because the alloy work-hardens quickly (Wikipedia).
good_for:
- Seawater and marine parts that need strength with corrosion resistance, such as valves, pump and propeller shafts and fasteners (Special Metals).
- Hydrofluoric-acid service, including the reacting section of alkylation units (Wikipedia; Special Metals).
- Chemical processing in reducing acids, and heat exchangers and boiler feedwater heaters (Special Metals).
watch_out:
- Stagnant seawater can cause crevice and pitting corrosion, although flowing seawater gives very low corrosion rates (Special Metals).
- Caustic stress-corrosion cracking can occur at high temperature, high stress and high caustic concentration (ATI).
- Strength ranges are composites for various product sizes and are not specification values (Special Metals Table 4).
- Some heats are magnetic at room temperature and others are not, because the Curie temperature sits near room temperature (Special Metals Table 2).
- Galvanic attack on steel in salt water (Wikipedia).
- The corrosion entries are qualitative. No corrosion rate or test number was read in this run.
verdict: Monel 400 is a nickel-copper alloy for seawater, chemical and hydrofluoric-acid service. Its annealed strength is modest, so state the temper on every design, design for flowing rather than stagnant seawater, and stress-relieve where stress-corrosion cracking is a concern.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
| # | Source | Type | Year | Used for |
|---|---|---|---|---|
| MONEL alloy 400 datasheet, Special Metals Corporation | datasheet | 2005 | 33 values | |
| ATI 400 Technical Data Sheet (UNS N04400) | datasheet | 2014 | 22 values | |
| ATI 400 Nickel-Based Alloy product page | web | 3 values | ||
| Monel | web | 7 values | ||
| ESPI Metals technical data, nickel-copper alloys | web | 1 value | ||
| Mineral Commodity Summaries 2026: Nickel | report | 2026 | 1 value | |
| Mineral Commodity Summaries 2026: Copper | report | 2026 | 1 value | |
| Nickel, PubChem CID 935, GHS classification (aggregated ECHA C&L notifications) | database | 1 value | ||
| Copper, PubChem CID 23978, GHS classification (aggregated ECHA C&L notifications) | database | 1 value |