Monel 400 Alloy 400 (UNS N04400)

Nickel-copper solid-solution alloy: 63.0 min nickel plus cobalt, 28.0 to 34.0 copper, 2.5 max iron, 2.0 max manganese, 0.5 max silicon, 0.3 max carbon, 0.024 max sulfur (wt%)

Also known as UNS N04400, EN 2.4360, EN 2.4361, EN name NiCu30Fe, DIN 17750, DIN 17751 · 26 more

Monel 400 (UNS N04400, W.Nr.

9 sources · Updated 2026-10-24 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Recipe, share of the weight

  • Ni minimum, nickel plus cobaltNickel plus cobalt
  • Cu 28 to 34%Copper
  • Fe 2.5 maximumIron
  • Mn 2.0 maximumManganese
  • Si 0.5 maximumSilicon
  • C 0.3 maximumCarbon
  • S 0.024 maximumSulfur

Best for

Seawater, hydrofluoric-acid and reducing-acid service, and marine valves, pump shafts and fasteners, where corrosion resistance matters more than high strength

Weakest at

Stagnant seawater (crevice and pitting corrosion), caustic at high temperature and stress (stress-corrosion cracking), and low strength in the annealed condition

Risk at a glance

  • People Moderate. Metal flagged by nickel and copper records; no alloy SDS
  • If it fails High. Caustic stress-corrosion cracking
  • Corrosion Severe. Not useful in highly oxidising acids such as nitric or nitrous acid (ATI).

Quick facts: Alloy 400 (UNS N04400)

Key properties of Alloy 400 (UNS N04400)
PropertyValueBasis
Density8.8 to 8.83 g/cm³2 sourced values across conditions
Yield strength172 to 345 MPa4 sourced values across conditions
Tensile strength483 to 621 MPa4 sourced values across conditions
Young's modulus179 to 180 GPa2 sourced values across conditions
Thermal conductivity22 W/(m·K)1 sourced value
Thermal expansion (CTE)13.9 to 14.2 ppm/K2 sourced values across conditions
Melting point1,300 to 1,350 °C1 sourced value
Specific heat427 to 430 J/(kg·K)2 sourced values across conditions
Electrical resistivity5.1e-7 Ω·m2 sourced values across conditions

What is the density of Monel 400?

Monel 400 has a density of 8.8 to 8.83 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the thermal conductivity of Monel 400?

Monel 400 has a thermal conductivity of 22 W/(m·K). The source and test conditions are listed in the properties table on this page.

What is the coefficient of thermal expansion of Monel 400?

Monel 400 has a coefficient of thermal expansion of 13.9 to 14.2 ppm/K. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the melting point of Monel 400?

Monel 400 has a melting point of 1,300 to 1,350 °C. The source and test conditions are listed in the properties table on this page.

What is the yield strength of Monel 400?

Monel 400 has a yield strength of 172 to 345 MPa. The range covers 4 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What are the other names and codes for Monel 400?

Monel 400 is also written as UNS N04400, EN 2.4360, EN 2.4361, EN name NiCu30Fe, DIN 17750, DIN 17751. Each code is printed in the source listed beside it in the designations table.

What is Monel 400 used for?

Uses recorded in the sources include Gasoline and fresh water tanks; Marine fixtures and fasteners; Boiler feedwater heaters, heat exchangers and deaerating heaters.

Why it exists

Monel 400 comes from a nickel-copper ore developed in the early twentieth century, whose nickel and copper were in about the ratio now specified for the alloy (ATI). Special Metals says it combines high strength and toughness with excellent resistance to many corrosive environments, and its name is a trademark now held by Special Metals (Wikipedia). Marine and chemical processing use it because it resists seawater and reducing acids (Special Metals).

Where it's used

Marine and chemical service

Special Metals names valves and pumps, pump and propeller shafts, marine fixtures and fasteners, chemical processing equipment, and crude petroleum stills, process vessels and piping as typical applications.

Heat exchangers and boiler feedwater heaters

Boiler feedwater heaters, other heat exchangers and deaerating heaters are typical applications (Special Metals).

Fuel and water tanks

Gasoline and fresh water tanks are typical applications (Special Metals).

Aircraft structures, historical

Wikipedia says Monel metal was used in bulk in aircraft construction, including the frames and skins of experimental rocket planes such as the X-15, though the article does not name the grade.

Recipe

Nickel-copper solid-solution alloy: 63.0 min nickel plus cobalt, 28.0 to 34.0 copper, 2.5 max iron, 2.0 max manganese, 0.5 max silicon, 0.3 max carbon, 0.024 max sulfur (wt%)

Monel 400 is a single-phase nickel-copper alloy. Special Metals gives the limiting composition in weight percent, with nickel plus cobalt at least 63.0, copper 28.0 to 34.0, and iron 2.5 maximum, manganese 2.0 maximum, silicon 0.5 maximum, carbon 0.3 maximum and sulfur 0.024 maximum. Nickel and copper are mutually soluble in all proportions, so the alloy is one solid-solution phase (Wikipedia). Special Metals says it is hardened only by cold working.

What Alloy 400 (UNS N04400) is made of
IngredientShare of the weightWhat it does
Nickel plus cobalt Ni minimum, nickel plus cobalt Matrix of the single-phase solid solution, with copper
Copper Cu 28 to 34% Mutually soluble with nickel in all proportions, so the alloy is single-phase (Wikipedia)
Iron Fe 2.5 maximum Residual element, limited to 2.5 percent
Manganese Mn 2.0 maximum Residual element, limited to 2.0 percent
Silicon Si 0.5 maximum Residual element, limited to 0.5 percent
Carbon C 0.3 maximum Residual element, limited to 0.3 percent
Sulfur S 0.024 maximum Residual element, limited to 0.024 percent

Weight shares are as printed in the sources.

What it can do

Seawater

Very low corrosion rates in flowing seawater (Special Metals), and Wikipedia says it resists rapidly flowing seawater.

Hydrofluoric acid

Exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point (Special Metals).

Strength in the annealed condition

Annealed rod and bar give 75 to 90 ksi tensile and 25 to 50 ksi yield, and annealed hot-rolled plate gives 70 to 85 ksi tensile (Special Metals Table 4, composite ranges).

Stiffness

Tension modulus is 26.0 times 10^3 ksi (Special Metals Table 2), and ATI gives 180 GPa for annealed plate, sheet and strip.

Low temperature

Wikipedia says the alloy does not undergo a ductile-to-brittle transition even when cooled to the temperature of liquid hydrogen.

How it compares

Compare with [Inconel 625](/profiles/inconel-625/), the chromium-bearing nickel alloy on this site. Monel 400 has no chromium in its limiting composition, and its composition is nickel with 28.0 to 34.0 percent copper (Special Metals Table 1). Monel K-500 is a different, age-hardened alloy and is not covered by this profile.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.

Benchmarks
MeasurementAlloy 400 (UNS N04400)IN718 (UNS N07718)IN625 (UNS N06625)FeNi36Ni-MoC-22C-276 (UNS N10276)X (UNS N06002)UNS N07214H230 (UNS N06230)UNS N08800Alloy 825 (UNS N08825)Alloy 600 (UNS N06600, W.Nr. 2.4816)Alloy 601Alloy 617X-750 (UNS N07750)Fe-Ni-CoK-500NiNi3Al, NiAlNiBe2Ni-alloysUNS N07090 (W. Nr. 2.4632)UNS N07001
Thermal behavior and safety
melting point1300 to 1350 °C31260 °C1290 to 1350 °C1427 °C1370 to 1418 °C1357 to 1399 °C1323 to 1371 °C1260 to 1355 °C1355 to 1400 °C1301 to 1371 °C1357 to 1385 °C1370 to 1400 °C1354 to 1413 °C1360 to 1411 °C1330 to 1380 °C1393 to 1427 °C1450 °C1315 to 1350 °C1455 °Cno data1195 to 1325 °C1425 °C1370 °C1330 to 1360 °C
Thermal conductivity22 W/m°C779 BTU·in/ft²·h·°F9.8 W/m°C72.85 Btu·in/(hr·ft²·°F)11.2 W/m.°C10.1 W/(m·K)10.5 W/m.°C9.2 W/(m·K)12 W/m-°C8.9 W/(m·°C)11.5 W/m°C11.1 W/(m·K)14.9 W/(m·K)11.2 W/(m·K)13.4 W/(m·K)83 Btu/in./hr/sq ft/°F17.5 W/m °K17.5 W/m °C70.3 W/(m·K)no data48 W/(m·K)13 W/(m·K)11.47 W/(m·K)19.1 W/(m·°C)
specific heat427 J/kg°C8435 J/kg °C410 J/(kg·K)515 J/(kg·K)373 J/kg.°C410 J/(kg·K)427 J/kg.°C486 J/(kg·K)452 J/kg-°C397 J/kg·°C460 J/kg·°C440 J/(kg·K)444 J/kg °C448 J/(kg·K)419 J/(kg·K)0.103 Btu/lb/°F500 J/(kg. K)419 J/kg °C456 J/(kg·K)no datano data500 J/(kg·K)446 J/(kg·K)no data
specific heat430 J/kg·K11435 J/kg °C410 J/(kg·K)515 J/(kg·K)373 J/kg.°C410 J/(kg·K)427 J/kg.°C486 J/(kg·K)452 J/kg-°C397 J/kg·°C460 J/kg·°C440 J/(kg·K)444 J/kg °C448 J/(kg·K)419 J/(kg·K)0.103 Btu/lb/°F500 J/(kg. K)419 J/kg °C456 J/(kg·K)no datano data500 J/(kg·K)446 J/(kg·K)no data
Physical and electrical
Density8.8 g/cm³10.297 lb/in38.44 g/cm³8.05 g/cm³9.22 g/cm³8.69 g/cm³8.89 g/cm³8.22 g/cm³8.05 g/cm³8.97 g/cm³7.94 g/cm³8.14 g/cm³0.306 lb/in38.11 Mg/m38.36 g/cm³8.28 g/cm³8.36 g/cm³8.45 g/cm³8.89 g/cm³7.5 g/cm³8.27 g/cm³8.2 g/cm³8.18 g/cm³8.19 g/cm³
Density8.83 g/cm³20.297 lb/in38.44 g/cm³8.05 g/cm³9.22 g/cm³8.69 g/cm³8.89 g/cm³8.22 g/cm³8.05 g/cm³8.97 g/cm³7.94 g/cm³8.14 g/cm³0.306 lb/in38.11 Mg/m38.36 g/cm³8.28 g/cm³8.36 g/cm³8.45 g/cm³8.89 g/cm³7.5 g/cm³8.27 g/cm³8.2 g/cm³8.18 g/cm³8.19 g/cm³
electrical resistivity0.511 µΩ·m9725 ohm circ mil/ft129 µΩ-cm84 µΩ·cm1.37 μohm.m1.14 µΩ·m1.23 μohm.m114.8 µohm-cm135.9 µohm-cm125 µohm-m0.989 µΩ·m112 µΩ·cm1.03 µΩ·m1.18 µΩ·m1.22×10^-4 Ω·cm731 ohm circ mil/ft49 μΩcm0.615 µΩ·m0.096 µΩ·mno data< 28.7 µΩ·cm45 µΩ·cm1.18 µΩ·m1.24 µΩ·m
electrical resistivity51 µΩ-cm12725 ohm circ mil/ft129 µΩ-cm84 µΩ·cm1.37 μohm.m1.14 µΩ·m1.23 μohm.m114.8 µohm-cm135.9 µohm-cm125 µohm-m0.989 µΩ·m112 µΩ·cm1.03 µΩ·m1.18 µΩ·m1.22×10^-4 Ω·cm731 ohm circ mil/ft49 μΩcm0.615 µΩ·m0.096 µΩ·mno data< 28.7 µΩ·cm45 µΩ·cm1.18 µΩ·m1.24 µΩ·m
electrical conductivity34 % IACS27no datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano datano data> 6 %IACSno datano datano data
Temperature behavior
curie temperature21 to 49 °C4-112 °C< -196 °C279 °Cno datano datano datano datano datano data-115 °C< -196 °C-124 °Cno datano datano data435 °C-65 °C360 °Cno datano data450 °Cno datano data
Other measurements
elastic modulus26 10^3 ksi529 ksi x 10^3207.5 GPa140 GPa216 GPa206 GPa205 GPa205 GPa218 GPa209 GPa196.5 GPa196 GPa214 GPa206.5 GPa211 GPa31 10^3 ksi138 kN/mm2179 GPa205 GPa200 GPa195 to 210 GPano data204 GPa211 GPa
elastic modulus180 GPa629 ksi x 10^3207.5 GPa140 GPa216 GPa206 GPa205 GPa205 GPa218 GPa209 GPa196.5 GPa196 GPa214 GPa206.5 GPa211 GPa31 10^3 ksi138 kN/mm2179 GPa205 GPa200 GPa195 to 210 GPano data204 GPa211 GPa
poissons ratioTable 2, Poisson's Ratio row, printed as 0.320.32 -0.294 -0.278 -no datano datano data0.31 -0.32 -no data0.31 -0.339 -no data0.324 -0.272 -no data0.29 -no datano datano datano data0.3 -no datano datano data
Thermal expansion (CTE)14.2 µm/m°C108.91 ppm/°F12.8 ppm/°C1.3 ppm/K10.6 μm/m.°C12.4 ppm/K11.2 μm/m.°C13.9 µm/(m·K)14.6 µm/m-°C11.8 ppm/K14.4 µm/m/°C13.9 ppm/K10.4 ppm/K13.75 µm/m/°C11.6 µm/(m·K)7 10-6 in./in./°F5.86 10-6/°C13.7 10-6/°C13.3 ppm/Kno data14.5 ppm/K8 ppm/K12.7 µm/(m·K)14.3 µm/m·°C
Thermal expansion (CTE)13.9 10^-6/°C138.91 ppm/°F12.8 ppm/°C1.3 ppm/K10.6 μm/m.°C12.4 ppm/K11.2 μm/m.°C13.9 µm/(m·K)14.6 µm/m-°C11.8 ppm/K14.4 µm/m/°C13.9 ppm/K10.4 ppm/K13.75 µm/m/°C11.6 µm/(m·K)7 10-6 in./in./°F5.86 10-6/°C13.7 10-6/°C13.3 ppm/Kno data14.5 ppm/K8 ppm/K12.7 µm/(m·K)14.3 µm/m·°C
ultimate tensile strength75 to 90 ksi14201 ksi120 to 150 ksi65 ksi862 MPa690 to 950 MPa792 MPa760 MPa975 MPa837 MPa590 MPa662 MPa550 to 690 MPa675 MPa710 MPa> 165 ksi450 to 585 N/mm2621 to 758 MPa380 to 520 MPa2300 MPa660 to 900 MPa500 MPa1175 MPa1027 MPa
yield strength25 to 50 ksi15171 ksi60 to 95 ksi40 ksi421 MPa> 310 MPa356 MPa340 MPa577 MPa417 MPa250 MPa338 MPa170 to 345 MPa292 MPa340 MPa> 105 ksi> 200 N/mm2276 to 414 MPa105 to 210 MPano data280 to 480 MPa280 MPa752 MPa586 MPa
elongation35 to 60 %1626 %30 to 60 %35 %53 %> 45 %61 %48.9 %37.3 %47.3 %17 %45 %35 to 55 %46 %62 %> 20 %> 25 %20 to 35 %40 to 55 %no data> 30 %35 %30 %43 %
ultimate tensile strength70 to 85 ksi17201 ksi120 to 150 ksi65 ksi862 MPa690 to 950 MPa792 MPa760 MPa975 MPa837 MPa590 MPa662 MPa550 to 690 MPa675 MPa710 MPa> 165 ksi450 to 585 N/mm2621 to 758 MPa380 to 520 MPa2300 MPa660 to 900 MPa500 MPa1175 MPa1027 MPa
yield strength28 to 50 ksi18171 ksi60 to 95 ksi40 ksi421 MPa> 310 MPa356 MPa340 MPa577 MPa417 MPa250 MPa338 MPa170 to 345 MPa292 MPa340 MPa> 105 ksi> 200 N/mm2276 to 414 MPa105 to 210 MPano data280 to 480 MPa280 MPa752 MPa586 MPa
ultimate tensile strength70 to 85 ksi19201 ksi120 to 150 ksi65 ksi862 MPa690 to 950 MPa792 MPa760 MPa975 MPa837 MPa590 MPa662 MPa550 to 690 MPa675 MPa710 MPa> 165 ksi450 to 585 N/mm2621 to 758 MPa380 to 520 MPa2300 MPa660 to 900 MPa500 MPa1175 MPa1027 MPa
yield strength> 28 ksi20171 ksi60 to 95 ksi40 ksi421 MPa> 310 MPa356 MPa340 MPa577 MPa417 MPa250 MPa338 MPa170 to 345 MPa292 MPa340 MPa> 105 ksi> 200 N/mm2276 to 414 MPa105 to 210 MPano data280 to 480 MPa280 MPa752 MPa586 MPa
elongation> 35 %2126 %30 to 60 %35 %53 %> 45 %61 %48.9 %37.3 %47.3 %17 %45 %35 to 55 %46 %62 %> 20 %> 25 %20 to 35 %40 to 55 %no data> 30 %35 %30 %43 %
ultimate tensile strength75000 psi22201 ksi120 to 150 ksi65 ksi862 MPa690 to 950 MPa792 MPa760 MPa975 MPa837 MPa590 MPa662 MPa550 to 690 MPa675 MPa710 MPa> 165 ksi450 to 585 N/mm2621 to 758 MPa380 to 520 MPa2300 MPa660 to 900 MPa500 MPa1175 MPa1027 MPa
yield strength35000 psi23171 ksi60 to 95 ksi40 ksi421 MPa> 310 MPa356 MPa340 MPa577 MPa417 MPa250 MPa338 MPa170 to 345 MPa292 MPa340 MPa> 105 ksi> 200 N/mm2276 to 414 MPa105 to 210 MPano data280 to 480 MPa280 MPa752 MPa586 MPa
elongation45 %2426 %30 to 60 %35 %53 %> 45 %61 %48.9 %37.3 %47.3 %17 %45 %35 to 55 %46 %62 %> 20 %> 25 %20 to 35 %40 to 55 %no data> 30 %35 %30 %43 %
yield strength21000 psi25171 ksi60 to 95 ksi40 ksi421 MPa> 310 MPa356 MPa340 MPa577 MPa417 MPa250 MPa338 MPa170 to 345 MPa292 MPa340 MPa> 105 ksi> 200 N/mm2276 to 414 MPa105 to 210 MPano data280 to 480 MPa280 MPa752 MPa586 MPa
ultimate tensile strength53000 psi26201 ksi120 to 150 ksi65 ksi862 MPa690 to 950 MPa792 MPa760 MPa975 MPa837 MPa590 MPa662 MPa550 to 690 MPa675 MPa710 MPa> 165 ksi450 to 585 N/mm2621 to 758 MPa380 to 520 MPa2300 MPa660 to 900 MPa500 MPa1175 MPa1027 MPa

Why choose it, and why not

Good for

  • Seawater and marine parts that need strength with corrosion resistance, such as valves, pump and propeller shafts and fasteners (Special Metals).
  • Hydrofluoric-acid service, including the reacting section of alkylation units (Wikipedia; Special Metals).
  • Chemical processing in reducing acids, and heat exchangers and boiler feedwater heaters (Special Metals).

Watch out for

  • Stagnant seawater can cause crevice and pitting corrosion, although flowing seawater gives very low corrosion rates (Special Metals).
  • Caustic stress-corrosion cracking can occur at high temperature, high stress and high caustic concentration (ATI).
  • Strength ranges are composites for various product sizes and are not specification values (Special Metals Table 4).
  • Some heats are magnetic at room temperature and others are not, because the Curie temperature sits near room temperature (Special Metals Table 2).
  • Galvanic attack on steel in salt water (Wikipedia).
  • The corrosion entries are qualitative. No corrosion rate or test number was read in this run.

Monel 400 is a nickel-copper alloy for seawater, chemical and hydrofluoric-acid service. Its annealed strength is modest, so state the temper on every design, design for flowing rather than stagnant seawater, and stress-relieve where stress-corrosion cracking is a concern.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Other names and standards

The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.

Other names and standards
SystemCodes
UNSN04400
EN2.4360, 2.4361 (printed with 2.4360)
EN nameNiCu30Fe
DIN17750 (plate, strip and sheet), 17751 (pipe and tube), 17752 (rod and bar), 17753 (wire), 17754 (forgings)
BS3072 NA13 (sheet and plate), 3073 NA13 (strip), 3074 NA13 (tube), 3075 NA13 (wire), 3076 NA13 (bar)
ASTMB127 (plate, sheet and strip), B163 (condenser and heat exchanger tube), B164 (rod, bar and wire), B165 (seamless pipe and tube), B564 (forgings)
ASMESB 127 (plate, sheet and strip), SB 164 (rod, bar and wire), SB 165 (seamless pipe and tube)
AMS4544 (sheet, strip and plate), 4574 (seamless tubing), 4675 (bars and forgings), 4730 (wire), 4731 (wire and ribbon)
FederalQQ-N-281 (plate, sheet, strip, bar, rod, wire and forgings)
Trade nameMONEL alloy 400, Monel 400, Alloy 400, ATI 400

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1DensityTable 2, Physical Constants, Density g/cm3 row, printed as 8.80; the lb/in3 row prints 0.318basis Table 2 physical constant; no test temperature or condition printed—
2DensityDensity section, printed as 0.319 lb/in3 and 8.83 g/cm3; the specific gravity is also printed as 8.83basis typical value on the ATI data sheet; no temperature or condition stated—
3melting pointTable 2, Melting Range, °C row, printed as 1300-1350; the F row prints 2370-2460basis melting range as printed in Table 2 (2370 to 2460 F)—
4curie temperatureTable 2, Curie Temperature, °C row, printed as 21-49basis Curie range as printed in Table 2 (70 to 120 F); some heats are magnetic at room temperature and others are not—
5elastic modulusTable 2, Modulus of Elasticity, Tension row, printed as 26.0 (10^3 ksi); the compression row also prints 26.0basis tension modulus; no test temperature printed (Figure 1 gives the temperature effect and was not read)—
6elastic modulusMechanical Properties, Elastic Modulus column, annealed plate, sheet and strip row, printed as 26x10^6 psi (180 GPa)condition annealedproduct plate, sheet and striptemperature room temperaturebasis typical value on the ATI data sheet—
7Thermal conductivityTable 3, Thermal Conductivity W/m°C column, row 70 F (21 C), printed as 22.0; the Btu-in/h/ft2/F column prints 151 for the same rowtemperature 70 F (21 C)basis Table 3 row 70 F (21 C); footnote a says the values also apply to R-405, the free-machining version of this alloy—
8specific heatTable 3, Specific Heat J/kg°C column, row 70 F (21 C), printed as 427; the Btu/lb/F column prints 0.102temperature 70 F (21 C)basis Table 3 row 70 F (21 C); footnote a also applies to R-405—
9electrical resistivityTable 3, Electrical Resistivity µΩ·m column, row 70 F (21 C), printed as 0.511temperature 70 F (21 C)condition annealed material (footnote c)basis Table 3 row 70 F (21 C)—
10Thermal expansion (CTE)Table 3, Mean Linear Expansion µm/m°C column, row 200 F (100 C), printed as 14.2; the in/in/F column prints 7.7 x 10^-6condition annealed material (footnote b)temperature 70 F (21 C) to 200 F (100 C)basis mean linear expansion from 70 F to the row temperature, as printed in Table 3—
11specific heatPhysical Properties, Specific Heat, room temperature values, printed as 430 Joules/kg Ktemperature room temperaturebasis room-temperature value printed on the ATI data sheet; condition not stated—
12electrical resistivityPhysical Properties, Electrical Resistivity, printed as 51.0 Microhm-cmbasis value printed on the ATI data sheet with no temperature or condition stated—
13Thermal expansion (CTE)Linear Coefficient of Thermal Expansion table, row 200 F (93 C), 10^-6/C column, printed as 13.9; the 10^-6/F column prints 7.7temperature 70 F (21 C) to 200 F (93 C)basis mean linear expansion, typical value on the ATI data sheet—
14ultimate tensile strengthTable 4, Rod and Bar, Annealed row, tensile strength column, printed as 75-90 ksi (517-620 MPa)condition annealedproduct rod and bartemperature room temperaturebasis composite range for various product sizes, not for specification (footnote a)—
15yield strengthTable 4, Rod and Bar, Annealed row, yield strength (0.2% offset) column, printed as 25-50 ksi (172-345 MPa)condition annealedproduct rod and bartemperature room temperature, 0.2 percent offsetbasis composite range for various product sizes, not for specification (footnote a)—
16elongationTable 4 prints 60-35 percent for the annealed row; recorded here low to highcondition annealedproduct rod and bartemperature room temperature—
17ultimate tensile strengthTable 4, Plate, Hot-Rolled Annealed row, tensile strength column, printed as 70-85 ksi (482-586 MPa)condition hot-rolled, annealedproduct platetemperature room temperaturebasis composite range for various product sizes, not for specification (footnote a)—
18yield strengthTable 4, Plate, Hot-Rolled Annealed row, yield strength column, printed as 28-50 ksi (193-345 MPa)condition hot-rolled, annealedproduct platetemperature room temperature, 0.2 percent offsetbasis composite range for various product sizes, not for specification (footnote a)—
19ultimate tensile strengthATI product page, plate table, annealed, printed as 70 min - 85 max ksi (485 min - 585 max MPa)condition annealedproduct plate (ASTM B127, ASME SB-127, AMS 4544)temperature room temperaturebasis minimum and maximum printed on the ATI product page—
20yield strengthATI product page, plate table, annealed, printed as 28 min ksi (195 min MPa)condition annealedproduct plate (ASTM B127, ASME SB-127, AMS 4544)temperature room temperature, 0.2 percent offsetbasis minimum printed on the ATI product page—
21elongationATI product page, plate table, annealed, printed as 35% mincondition annealedproduct plate (ASTM B127, ASME SB-127, AMS 4544)temperature room temperaturebasis minimum printed on the ATI product page—
22ultimate tensile strengthProperties Applicable to Plate, Sheet and Strip, annealed row, ultimate tensile strength column, printed as 75,000 psi (520 MPa)condition annealedproduct plate, sheet and striptemperature room temperaturebasis typical value on the ATI data sheet—
23yield strengthProperties Applicable to Plate, Sheet and Strip, annealed row, yield strength column, printed as 35,000 psi (240 MPa)condition annealedproduct plate, sheet and striptemperature room temperature, 0.2 percent offsetbasis typical value on the ATI data sheet—
24elongationProperties Applicable to Plate, Sheet and Strip, annealed row, elongation column, printed as 45 percent in 2 in (51 mm)condition annealedproduct plate, sheet and striptemperature room temperaturebasis typical value in 2 in (51 mm) on the ATI data sheet—
25yield strengthShort Time Elevated Temperature Properties table, row 1000 F (538 C), printed as 21,000 psi (145 MPa)condition annealedtemperature 1000 F (538 C)basis short-time test, 0.2 percent offset yield strength, typical value on the ATI data sheet—
26ultimate tensile strengthShort Time Elevated Temperature Properties table, row 1000 F (538 C), printed as 53,000 psi (370 MPa)condition annealedtemperature 1000 F (538 C)basis short-time test, typical value on the ATI data sheet—
27electrical conductivityProperties section, first paragraph on Monel alloy 400, printed as approximately 34% IACSbasis approximate value in the Properties section; no temperature or condition printed—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Flowing seawater low Very low corrosion rates in flowing seawater (Special Metals); Wikipedia says it resists rapidly flowing seawater.1
Stagnant seawater moderate Crevice and pitting corrosion in stagnant seawater (Special Metals).2
Hydrofluoric acid, all concentrations up to the boiling point low Exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point (Special Metals).3
Range of media, including seawater, hydrofluoric acid, sulfuric acid and alkalies low ESPI Metals lists seawater, hydrofluoric acid, sulfuric acid and alkalies among the media in which Alloy 400 resists corrosion.4
Stress-corrosion cracking in fresh and industrial waters low Resistant to stress-corrosion cracking and pitting in most fresh and industrial waters (Special Metals).5
Chloride stress-corrosion cracking low Exceptionally resistant to chloride stress-corrosion cracking (ATI).6
Caustic at high temperature and high stress moderate Caustic stress-corrosion cracking can occur at high temperature, high stress and high caustic concentration (ATI).7
Sulfur-bearing gases and molten sulfur moderate Attacked by sulfur-bearing gases above about 700 F (371 C); molten sulfur attacks it above about 500 F (260 C) (ATI).8
Sulfuric and hydrochloric acids under reducing conditions low Resists many forms of sulfuric and hydrochloric acid under reducing conditions (Special Metals; ATI).9
Highly oxidising acids, nitric and nitrous severe Not useful in highly oxidising acids such as nitric or nitrous acid (ATI).10
Galvanic contact with steel in salt water moderate Galvanic attack on steel in salt water, so Monel must be insulated from steel in shipbuilding (Wikipedia).11
Sour oil and gas service (NACE MR-01-75) not rated Listed in NACE MR-01-75 for oil and gas service; no sour-service test result was read.12
Creep and long-term high temperature not rated ATI says creep resistance should be considered above about 650 F (343 C).13
Corrosion details
#EnvironmentDetailsTest conditions
1 Flowing seawater Special Metals says alloy 400 products exhibit very low corrosion rates in flowing seawater. No corrosion rate or exposure time is printed. condition flowing seawaterbasis qualitative statement, no corrosion rate or exposure time printed
2 Stagnant seawater Special Metals says stagnant conditions have been shown to induce crevice and pitting corrosion. No test result is printed. condition stagnant seawaterbasis qualitative statement, no test result printed
3 Hydrofluoric acid, all concentrations up to the boiling point Special Metals says alloy 400 offers exceptional resistance to hydrofluoric acid in all concentrations up to the boiling point, and that it is perhaps the most resistant of all commonly used engineering alloys. No corrosion rate is printed. temperature up to the boiling pointbasis qualitative statement, no corrosion rate printed
4 Range of media, including seawater, hydrofluoric acid, sulfuric acid and alkalies ESPI Metals describes Alloy 400 as having high strength and excellent corrosion resistance in a range of media, including seawater, hydrofluoric acid, sulfuric acid, and alkalies. This is a supplier summary, so it supports the Special Metals statements and gives no numbers. basis qualitative supplier summary, no numbers
5 Stress-corrosion cracking in fresh and industrial waters Special Metals says alloy 400 is also resistant to stress corrosion cracking and pitting in most fresh and industrial waters, and it recommends stress relief as a precaution against stress-corrosion cracking in certain environments. basis qualitative statement; no test stress or medium printed
6 Chloride stress-corrosion cracking ATI says the alloy is exceptionally resistant to chloride stress corrosion cracking. No test stress, medium or time is printed. basis qualitative statement; no test stress or medium printed
7 Caustic at high temperature and high stress ATI says the alloy is a consideration for cooler alkaline caustic conditions, but high temperature, high stress and high concentrations of caustic have produced caustic stress corrosion cracking in the material. condition high temperature, high stress and high caustic concentrationbasis qualitative statement; no temperatures or concentrations printed
8 Sulfur-bearing gases and molten sulfur ATI says the alloy is attacked in sulfur-bearing gases above about 700 F (371 C), and that molten sulfur attacks the alloy at temperatures over about 500 F (260 C). temperature above about 700 F (371 C) in sulfur-bearing gases; over about 500 F (260 C) for molten sulfurbasis printed temperatures, no exposure time
9 Sulfuric and hydrochloric acids under reducing conditions Special Metals says alloy 400 is resistant to many forms of sulfuric and hydrochloric acids under reducing conditions. ATI says it is used in reducing acids such as sulfuric and hydrochloric, especially in the absence of aeration and oxidising species. basis qualitative statements; no concentrations or temperatures printed
10 Highly oxidising acids, nitric and nitrous ATI says the alloy is not useful in highly oxidising acids such as nitric or nitrous acids, and points to high-chromium stainless steels for those environments. basis qualitative statement
11 Galvanic contact with steel in salt water Wikipedia says electrolytic action in salt water means Monel must be carefully insulated from other metals such as steel, and it records a yacht whose steel skeleton deteriorated through electrolytic interaction with Monel. condition direct contact with steel in salt waterbasis qualitative account, no rate printed
12 Sour oil and gas service (NACE MR-01-75) Special Metals says the alloy is listed in NACE MR-01-75 for oil and gas service. No sour-service test data were read in this run. standard NACE MR-01-75 (listed)
13 Creep and long-term high temperature ATI says creep resistance should be a consideration above about 650 F (343 C). No creep or rupture data were read. temperature above about 650 F (343 C)basis qualitative statement; no creep data printed

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

No safety data sheet for solid Monel 400 was read. The flags come from PubChem records for nickel (about 63 percent of the alloy) and copper (28.0 to 34.0 percent).

Nickel record
PubChem aggregated nickel GHS lists skin sensitisation (H317, 99.9 percent of reports), suspected cancer (H351, 72.9 percent) and organ damage from prolonged exposure (H372, 99.7 percent).
Copper record
PubChem aggregated copper GHS lists very toxic to aquatic life (H400, 43.1 percent) and very toxic with long-lasting effects (H410, 18.8 percent).

If a part sees the wrong conditions

These results come from the datasheets and the Wikipedia article, not from field incidents.

Stagnant seawater
Special Metals says stagnant seawater induces crevice and pitting corrosion, although flowing seawater gives very low corrosion rates.
Caustic at high stress
ATI says high temperature, high stress and high caustic concentration have produced caustic stress-corrosion cracking.
Overheating
Special Metals says the alloy must not be heated above 2150 F, where permanent damage may result.

Handling and heat treatment

Stress relief
Stress relief at 1000 to 1200 F for 1 hour, then slow cooling, is strongly recommended against stress-corrosion cracking in certain environments (Special Metals).
Hot forming
Hot forming runs from 1200 to 2150 F, with heavy reductions at 1700 to 2150 F (Special Metals).

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Crevice and pitting corrosion in stagnant seawatermoderate severityStagnant seawater, rather than flowing seawaterSpecial Metals says stagnant conditions have been shown to induce crevice and pitting corrosion.
Caustic stress-corrosion crackinghigh severityHigh temperature, high stress and high concentrations of causticATI says these conditions have produced caustic stress corrosion cracking in the material.
Attack by sulfur-bearing gases and molten sulfurmoderate severitySulfur-bearing gases above about 700 F (371 C); molten sulfur above about 500 F (260 C)ATI says the alloy is attacked in these environments.
Sulfur embrittlement during annealingmoderate severityAnnealing in an atmosphere with sulfur compounds, held for an extended time at the anneal temperature rangeATI says sulfur will embrittle the material with extended exposure at the anneal temperature range.
Overheating during hot workinghigh severityHeating above 2150 F, or prolonged soaking at hot-working temperaturesSpecial Metals says in no case should the alloy be heated above 2150 F, where permanent damage may result, and that prolonged soaking at hot-working temperatures is detrimental.
Galvanic attack on steel in salt waterhigh severityDirect contact with steel in salt waterWikipedia says electrolytic action in salt water attacked a steel skeleton in contact with Monel, so the metals must be insulated.
Work hardening during machininglow severityMachining at fast speeds or high feed ratesWikipedia says Monel is very difficult to machine because it work-hardens very quickly and must be turned at slow speeds and low feed rates.

Handling and storage

  • Anneal in the range of 1400 to 1800 F for short times, in an atmosphere as free of sulfur compounds as possible (ATI).
  • Stress relief at 1000 to 1200 F for 1 hour, followed by slow cooling, is strongly recommended as a precaution against stress-corrosion cracking in certain environments (Special Metals).
  • ATI gives a low-temperature stress relief of about 575 F (300 C) for 1 to 3 hours on cold-deformed material.
  • Stress equalizing holds cold-worked material at about 575 F for about 3 hours (Special Metals).
  • Hot form at 1200 to 2150 F, with heavy reductions at 1700 to 2150 F, and never heat above 2150 F (Special Metals).
  • Weld with MONEL Filler Metal 60 (AWS A5.14/ERNiCu-7) or MONEL Welding Electrode 190 (AWS A5.11/ENiCu-7) (Special Metals).
  • ATI says no preheat or post-weld heat treatment is generally required, and the joint must be free of lubricants, paint and scale.
  • Machine at slow speeds and low feed rates, because the alloy work-hardens quickly (Wikipedia).

Mitigations

  • Stress relieve after cold working, as Special Metals recommends, as a precaution against stress-corrosion cracking in certain environments.
  • Design for flowing rather than stagnant seawater, since Special Metals reports very low corrosion rates in flowing seawater and crevice and pitting in stagnant conditions.
  • Insulate Monel from steel in salt water to avoid galvanic attack (Wikipedia).
  • Anneal in a sulfur-free atmosphere, since sulfur embrittles the alloy during extended annealing (ATI).

Supply and geography

How common the raw materials are and where they come from.

Nickel

Globally, nickel resources have been estimated to contain more than 350 million tons of nickel (USGS)

Top producers (2025)
Indonesia 66.7%, Philippines 6.9%, Russia 5.1%, Canada 3.6%
Recycling
In 2025, nickel recovered from scrap accounted for approximately 60% of apparent consumption (USGS).
Substitutes
Titanium alloys can substitute for nickel or nickel-base alloys in corrosive environments (USGS).

Copper

World resources: identified resources contain 1.5 billion tons of unextracted copper (2.1 billion tons including past production), and undiscovered resources an estimated 3.5 billion tons (USGS, 2015 assessment)

Top producers (2025)
Chile 23%, Congo (Kinshasa) 13.9%, Peru 11.7%, China 7.8%
Critical mineral lists
US: listed
Recycling
Old scrap provided an estimated 160,000 tons of copper in 2025, and new scrap an estimated 760,000 tons; copper recovered from scrap contributed about 30% of the U.S. copper supply (USGS).
Substitutes
Aluminum substitutes for copper in automobile radiators, cooling and refrigeration tube, electrical equipment and power cable. Titanium and steel are used in heat exchangers (USGS).