Chromate conversion coating Alodine 1200S (MIL-DTL-5541)

Mainly hydrated chromium(III) oxide with some chromium(VI) bound in it, grown on the aluminium surface as an amorphous film

Also known as Alodine 1200S, BONDERITE M-CR 1200S AERO

Chromate conversion coating is a thin film that a chromate bath grows on aluminium alloys.

8 sources · Updated 2026-11-01 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Corrosion barrier

0.25 to 1 µm

Paint base

Within 48 hours

Self-repair

Cr(VI) migrates

Process speed

15 s to 3 min

Heat limit

60 °C

Recipe, share of the weight

  • Cr not statedChromium
  • O not statedOxygen
  • Al not statedAluminium

Best for

Corrosion protection and a paint base on aluminium structures, and low-resistance electrical contact in its Class 3 form

Weakest at

Hexavalent chemistry: NIOSH treats Cr(VI) compounds as potential occupational carcinogens, and unpainted parts must not go above 60 °C

Risk at a glance

  • People Low. Hexavalent chromium is the concern
  • If it fails Moderate. Loss of corrosion protection on unpainted parts above 60 °C
  • Corrosion Moderate. Unpainted chromate coatings lose corrosion resistance above 60 °C.

Why it exists

Chromate conversion coating is a long-standing aluminium pre-treatment. It puts a thin film on the metal that protects it from corrosion and gives paint a base. Grilli describes the film as low in surface electrical resistance, which the thesis calls an important feature for the space industry. NASA PRC-5005 uses Class 3 for coatings where lower electrical resistance is required, and Class 1A for maximum corrosion protection. Type I, the hexavalent version, is recommended for most flight hardware.

Where it's used

Structures

Henkel lists its powder on Qualified Product List QPL-81706 for Class 1A and Class 3 coatings, bare or painted, to MIL-DTL-5541. NASA lets MIL-DTL-5541 coatings serve as a primer base or a temporary fabrication coating.

Electrical grounding

PRC-5005 names Class 3 for protection where lower electrical resistance is required. The sources opened give no numeric resistance value for it.

Paint and bonding preparation

The coating is a good base for paint primers and only a fair base for bonding. The standard bonding method removes it during surface preparation, and the primer or adhesive should go on within 48 hours.

Recipe

Mainly hydrated chromium(III) oxide with some chromium(VI) bound in it, grown on the aluminium surface as an amorphous film

Chromate conversion coating is a thin film formed on aluminium by reaction with an acidic chromate bath. The dry film is mostly chromium(III) oxide with very little aluminium oxide, and it holds some chromium(VI) within it (Wikipedia). Process: clean, rinse, deoxidise if the surface is heavily oxidised, rinse, treat, rinse, then dry (Henkel). The Henkel bath is acidic, at pH 1.3 to 1.8.

What Alodine 1200S (MIL-DTL-5541) is made of
IngredientShare of the weightWhat it does
Chromium Cr not stated The film-forming metal. Chromium(VI) in the bath is reduced to chromium(III), which forms the hydrated oxide; some chromium(VI) stays bound and can migrate to defects.
Oxygen O not stated Bound to chromium in the oxide film. Chromium(III) oxide is the main constituent of the dry coating.
Aluminium Al not stated The substrate. Aluminium is oxidised as the chromium is reduced, and very little aluminium oxide remains in the final film (Wikipedia; Grilli 2010).

Weight shares are as printed in the sources.

What it can do

Corrosion barrier

0.25 to 1 µm

One finisher gives the film thickness as 0.25 to 1 µm. Wikipedia gives 200 to 300 nm as the typical dry coating, and 200 to 1000 nm as the average for Alodine 1200s on aluminium.

Paint base

Within 48 hours

PRC-5005 says primer or adhesive must go on in less than 48 hours after the conversion treatment for adequate adhesion.

Self-repair

Cr(VI) migrates

Chromium(VI) in the film migrates to defects, where it can repassivate pits. Grilli notes that ageing and water loss may limit this action.

Process speed

15 s to 3 min

The Henkel sheet gives 15 seconds to 3 minutes of treatment time, at a bath temperature of 20 to 30 °C in the operation section.

Heat limit

60 °C

Unpainted hexavalent chromate parts should not exceed 60 °C (140 °F), according to NASA-STD-6012A section 4.6.2.

How it compares

Anodize, covered by the anodized aluminium profile, grows an oxide skin that the profile describes as electrically insulating. Chromate conversion coating is a thin chemical film and is chosen where lower electrical resistance is needed, as NASA PRC-5005 describes for Class 3. Type II coatings avoid hexavalent chromium, but PRC-5005 says Type I consistently outperforms Type II in corrosion tests, and Grilli reviews chromium-free alternatives for aluminium without giving a single replacement value. The table below compares film thickness, the heat limit for unpainted parts and the bath pH.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details.

Benchmarks
MeasurementAlodine 1200S (MIL-DTL-5541)
Lifetime and stability
Shelf life of unopened powder48 months6
Physical and electrical
Coating thickness, typical dry aluminium coating200 to 300 nm10
Coating thickness, Alodine 1200s on aluminium, average200 to 1000 nm11
Temperature behavior
Treating bath temperature, control table range20 to 35 °C2
Treating bath temperature, operation range20 to 30 °C3
Storage temperature of the powder-10 to 40 °C7
Maximum metal surface temperature when drying in an oven< 60 °C8
Upper temperature limit for unpainted hexavalent chromate parts< 60 °C13
Lower temperature limit for unpainted parts, time-limited> 0 °C16
Other measurements
Operating pH of the Henkel treating solution1.3 to 1.8 -1
Immersion or spray time in the treating solution15 to 180 s4
Bath concentration as titration value (mL of titrant)5 to 19 mL5
Hexavalent chromium per unit of bath titrant1.73 mg/mL9
Share of chromium atoms that are hexavalent in a commercial coating23 %12
Guidance exposure time at 60 °C for unpainted parts1 min14
Guidance exposure time at 21 °C for unpainted parts168 h15
Maximum time from conversion treatment to primer or adhesive< 48 h17

Why choose it, and why not

Good for

  • Corrosion protection with a paint base, in a film of 0.25 to 1 µm according to one finisher.
  • Low electrical contact resistance in its Class 3 form, as PRC-5005 describes, with no numeric value in the sources read.
  • Self-repair of small defects, because Cr(VI) migrates to defects, as Wikipedia and Grilli describe.

Watch out for

  • Hexavalent chromium: NIOSH treats all Cr(VI) compounds as potential occupational carcinogens.
  • Unpainted parts lose corrosion resistance above 60 °C (140 °F), and the loss increases with temperature and time.
  • NASA-STD-6012A says MIL-DTL-5541 coatings alone would generally fail its environment Class 1 and Class 2 requirements on aluminium alloys. Those are the standard's environment classes, not the coating classes.
  • The Henkel sheet gives two bath temperature ranges, 20 to 35 °C and 20 to 30 °C, and does not say which applies.

Chromate conversion coating is a long-standing aluminium pre-treatment that gives corrosion protection, a paint base and low electrical resistance in its Class 3 form. Its hexavalent chemistry brings a carcinogen concern, a 60 °C limit for unpainted parts, and no numeric electrical value in the sources read here.

Used in space products

Space hardware whose maker names Alodine 1200S (MIL-DTL-5541), with the part it is used for.

Space products that use Alodine 1200S (MIL-DTL-5541)
ProductWhere it is used
OreSatPSAS / Oregon State Electrical-ground contact patches on frames

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Other names and standards

The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.

Other names and standards
SystemCodes
Trade nameAlodine 1200S, BONDERITE M-CR 1200S AERO

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Operating pH of the Henkel treating solutionRange printed in the manufacturer data sheet; the control table repeats 1.3 to 1.8product BONDERITE M-CR 1200S AERO (Alodine 1200S) treating solutionbasis optimum bath pH stated by the manufacturer—
2Treating bath temperature, control table rangeRange printed in the Operation and Control table of the manufacturer data sheetproduct BONDERITE M-CR 1200S AERO treating solutiontemperature in source 68 to 95 °FThe Operation section prints a narrower range for the same bath, 20 to 30 °C (70 to 100 °F). Both ranges are recorded because the sheet does not reconcile them.
3Treating bath temperature, operation rangeRange printed in the Operation section of the manufacturer data sheetproduct BONDERITE M-CR 1200S AERO treating solutiontemperature in source 70 to 100 °FNarrower than the control-table range (20 to 35 °C) for the same bath.
4Immersion or spray time in the treating solutionRange printed in the Operation and Control table (Time, sec.)product BONDERITE M-CR 1200S AERO treating solutionprocess immersion or sprayThe Operation section gives the same range as 15 seconds to 3 minutes.
5Bath concentration as titration value (mL of titrant)Range printed in the Operation and Control table as the concentration range in mL of titrant; the control procedure says to stay within plus or minus 1 point of the value that gives the desired resultproduct BONDERITE M-CR 1200S AERO treating solutionbasis titration of a 5 mL sample, control procedure—
6Shelf life of unopened powderValue printed in the storage table of the manufacturer data sheetform powder as suppliedpackaging unopened original packaging—
7Storage temperature of the powderRange printed in the storage table of the manufacturer data sheetform powder as supplied—
8Maximum metal surface temperature when drying in an ovenLimit printed in the Drying section of the manufacturer data sheet, to maintain optimum corrosion resistancebasis metal surface temperature when an oven or other heat source is usedtemperature in source 150 °F—
9Hexavalent chromium per unit of bath titrantConversion factor printed in the Concentration part of the Control Procedurebasis 1 mL of titrant equals 1.73 mg/mL of hexavalent chrome in BONDERITE M-CR 1200S AERO—
10Coating thickness, typical dry aluminium coatingRange printed in the Chemistry section of the Wikipedia articlebasis typical dry coating when process variables are adjusted to give itWikipedia gives a typical dry film of 200 to 300 nm; the finisher page gives 0.25 to 1 µm. Both are kept.
11Coating thickness, Alodine 1200s on aluminium, averageRange printed in the Aluminium section of the Wikipedia articleproduct Alodine 1200ssubstrate aluminiumbasis average—
12Share of chromium atoms that are hexavalent in a commercial coatingValue stated in the Chemistry section of the Wikipedia article; the primary study was not openedcoating commercial aluminium chromate coatingregion except in a region close to the metal—
13Upper temperature limit for unpainted hexavalent chromate partsRequirement stated in NASA-STD-6012A section 4.6.2coating unpainted hexavalent chromate conversion coated partstemperature in source 140 °F—
14Guidance exposure time at 60 °C for unpainted partsGuidance row in the Appendix E table of NASA-STD-6012A; the appendix says no literature supports exposure time limitstemperature 60 °C (140 °F)coating unpainted hexavalent chromate conversion coating—
15Guidance exposure time at 21 °C for unpainted partsGuidance row in the Appendix E table of NASA-STD-6012Atemperature 21 °C (70 °F)coating unpainted hexavalent chromate conversion coating—
16Lower temperature limit for unpainted parts, time-limitedGuidance in Appendix E of NASA-STD-6012A, which says water in the coating may freeze or sublime as the structure crackscoating unpainted hexavalent chromate conversion coated partsduration limit not longer than 1 minute below this temperature—
17Maximum time from conversion treatment to primer or adhesiveProcess requirement stated in NASA PRC-5005 Rev. D, section 3.0requirement primer or adhesive must be applied in less than 48 hours after the conversion coating process for adequate adhesion—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Self-healing in service, after scratches or pits form in the film low Cr(VI) in the film migrates to defects and helps repassivate pits.1
Unpainted parts above 60 °C (140 °F) during drying, fabrication or service moderate Unpainted chromate coatings lose corrosion resistance above 60 °C.2
Ageing in air moderate Long ageing produces microcracks that a limited Cr(VI) supply is unlikely to repair.3
Alloys with copper or intermetallic particles moderate The film is thinner over intermetallic particles, so it is less even on some alloys.4
Below freezing, unpainted parts moderate Below 0 °C for more than 1 minute, the coating can crack and expose the metal.5
Corrosion details
#EnvironmentDetailsTest conditions
1 Self-healing in service, after scratches or pits form in the film The coating is a mix of Cr(III) and Cr(VI) oxides. When it contacts an electrolyte, the Cr(VI) migrates to defects in the layer, where it can repassivate corrosion pits. Grilli notes that it is unclear how ageing and the loss of water affect this self-healing. The mechanism is described from the literature in a thesis, not measured in the sources read here. basis mechanism summarised in a PhD thesis chapter, no test conditions given
2 Unpainted parts above 60 °C (140 °F) during drying, fabrication or service NASA quotes MIL-DTL-5541F: unpainted conversion coatings start to lose corrosion resistance at 60 °C (140 °F) or higher. The coating dehydrates and its chromates become insoluble. Protection falls as temperature and exposure time rise, and dew point also changes how long a coating tolerates heat. temperatures 60 °C (140 °F) and aboveexposure time Appendix E table: 1 minute at 60 °C down to 168 hours at 21 °C
3 Ageing in air Grilli reports that ageing in air causes the loss of water from the film and a developing network of microcracks. These cracks may be pathways to the aluminium, and a limited Cr(VI) reservoir is unlikely to repair them. The ageing rate and crack growth were not measured in the sources read. basis literature summarised in a thesis chapter, no ageing time or humidity given
4 Alloys with copper or intermetallic particles Juffs and co-workers, cited by Grilli, found the coating on the aluminium matrix about 10 times thicker than on an intermetallic phase. The coating is therefore uneven on alloys with second-phase particles, and copper-rich alloys can change its composition. basis macroscopic intermetallic phases coupled to aluminium, as cited in the thesis
5 Below freezing, unpainted parts NASA says water molecules in the coating may freeze or sublime as its structure cracks, possibly exposing the base metal. The guidance is that unpainted parts should not be exposed below 0 °C for longer than 1 minute. temperature below 0 °C (32 °F)duration longer than 1 minute

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

The coating is made in a hexavalent chromium bath, and hexavalent chromium compounds are a recognised occupational hazard. The sources do not give toxicity numbers for this product.

The chemistry
NIOSH considers all Cr(VI) compounds to be potential occupational carcinogens. The Henkel sheet's titration factor shows the bath contains hexavalent chrome: 1 mL of titrant equals 1.73 mg/mL of hexavalent chrome.
Wet parts and residues
About 23% of the chromium atoms in a commercial aluminium coating are hexavalent, except near the metal. These residues can migrate when the coating is wetted.
Alternatives
Wikipedia says trivalent chromium alternatives are considerably less toxic. RoHS and REACH encourage the elimination of hexavalent chromium, including in chromate processes.

If the coating overheats or freezes

These are limits in NASA-STD-6012A for unpainted parts, not failure test results.

Heat
Unpainted parts should not be exposed above 60 °C (140 °F). At 60 °C the guidance allows about 1 minute, and at 21 °C about 168 hours.
Cold
Unpainted parts should not be exposed below 0 °C for more than 1 minute, because the water in the coating may freeze and crack the film.
Drying
The Henkel sheet limits the metal surface temperature in a drying oven to 60 °C (150 °F), to maintain corrosion resistance.

Handling and storage

Powder
The powder is brown and should be stored unopened between -10 and 40 °C. Its shelf life in unopened packaging is 48 months.
Bath
Mild steel containers slowly decompose the working solution. The sheet recommends 300 series stainless steel tanks, with 316L preferred.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Loss of corrosion protection on unpainted parts above 60 °Cmoderate severityDrying, fabrication or service above 60 °C (140 °F)The coating dehydrates and its chromates become insoluble, so corrosion resistance falls. The effect grows with temperature and exposure time.
Cracking of the film in the coldmoderate severityUnpainted parts below 0 °C (32 °F) for more than 1 minuteWater in the coating may freeze or sublime as the structure cracks, possibly exposing the base metal.
Microcracks from long ageingmoderate severityAgeing of the coating in air, which removes water from the filmA network of microcracks develops that a limited Cr(VI) reservoir is unlikely to repair, so the self-healing action may weaken.
Poor paint or bond adhesion after delaymoderate severityPrimer or adhesive applied 48 hours or more after the conversion treatmentNASA PRC-5005 says adequate adhesion needs application in less than 48 hours.

Side effects on surrounding parts

Side effects on surrounding parts
AffectsEffect
Workers handling wet parts, and waste from the processAbout 23% of chromium atoms in a commercial aluminium coating are hexavalent, except near the metal, and these residues can migrate when the coating is wetted.

Handling and storage

  • The Henkel sheet says dried, unfinished parts should not be handled bare-handed; use plastic or clean cotton gloves.
  • Storing the working solution in mild steel containers slowly decomposes it. Process tanks should be 300 series stainless steel, with 316L preferred.
  • Rinse the coating after application so the acids and salts in the process solution are removed before the coating dries.

Mitigations

  • Type II coatings have no hexavalent chromium, but PRC-5005 says Type I outperforms Type II in corrosion tests, especially in filiform and deep scratch tests, and recommends Type I for most flight hardware.
  • Wikipedia says trivalent chromium alternatives have been developed because they are considerably less toxic than hexavalent chromium.

Supply and geography

How common the raw materials are and where they come from.

Chromium (mine production, the source of chromium chemicals)

Top producers (2025)
South Africa 45.1%, Turkey 17.6%, Kazakhstan 13.7%, India 5.9%
Recycling
USGS: recycled chromium in stainless-steel scrap accounted for 21% of US apparent consumption in 2025.
Substitutes
USGS: chromium has no substitute in stainless steel or in superalloys. The chapter does not discuss chromate conversion coatings.

Chromium-containing chemicals (US import sources)

Top producers
Kazakhstan 25%, China 19%, Germany 14%, India 13%
Recycling
Not stated in the chromium chapter for chemicals.

Updated