{ "spore": "profile", "id": "chromate-conversion-coating", "spore_version": "0.2", "family": "coatings", "name": "Chromate conversion coating", "abbreviation": "Alodine 1200S (MIL-DTL-5541)", "role": "thin chemical conversion film on aluminium for corrosion protection, paint adhesion and low electrical contact resistance", "category": "coatings", "type": "conductive-coatings", "summary": "Chromate conversion coating is a thin film that a chromate bath grows on aluminium alloys. One finisher gives its thickness as 0.25 to 1 µm, and Wikipedia gives 200 to 300 nm as typical for a dry coating. It protects against corrosion, gives paint a base and keeps electrical contact resistance low, which is why NASA process specification PRC-5005 names a Class 3 coating for lower electrical resistance.\n", "best_for": "Corrosion protection and a paint base on aluminium structures, and low-resistance electrical contact in its Class 3 form", "weakest_at": "Hexavalent chemistry: NIOSH treats Cr(VI) compounds as potential occupational carcinogens, and unpainted parts must not go above 60 °C", "identity": { "formula": "Mainly hydrated chromium(III) oxide with some chromium(VI) bound in it, grown on the aluminium surface as an amorphous film", "designations": [ { "system": "Trade name", "code": "Alodine 1200S", "source": "conro", "where": "Cover page, text 'Known as Alodine 1200S'" }, { "system": "Trade name", "code": "BONDERITE M-CR 1200S AERO", "source": "conro", "where": "Title and product description" } ], "source": "wiki", "where": "Chemistry section: the dry aluminium coating is mostly chromium(III) oxide, with very little Al2O3" }, "tags": { "environments": [], "stresses": [ "extreme-cold" ], "applications": [ "structures", "electronics-and-chips" ] }, "properties": [ { "benchmark": "bath_ph", "label": "Operating pH of the Henkel treating solution", "value": 1.3, "value_high": 1.8, "bound": "range", "unit": "-", "scope": "material", "conditions": { "product": "BONDERITE M-CR 1200S AERO (Alodine 1200S) treating solution", "basis": "optimum bath pH stated by the manufacturer" }, "method": "Range printed in the manufacturer data sheet; the control table repeats 1.3 to 1.8", "status": "ground", "source": "conro", "where": "Control Procedure, pH Determination; Operation and Control table, row pH", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "bath_temperature", "label": "Treating bath temperature, control table range", "value": 20, "value_high": 35, "bound": "range", "unit": "°C", "scope": "material", "conditions": { "product": "BONDERITE M-CR 1200S AERO treating solution", "temperature_in_source": "68 to 95 °F" }, "method": "Range printed in the Operation and Control table of the manufacturer data sheet", "status": "ground", "note": "The Operation section prints a narrower range for the same bath, 20 to 30 °C (70 to 100 °F). Both ranges are recorded because the sheet does not reconcile them.", "source": "conro", "where": "Operation and Control table, row Temperature, °C", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "bath_temperature", "label": "Treating bath temperature, operation range", "value": 20, "value_high": 30, "bound": "range", "unit": "°C", "scope": "material", "conditions": { "product": "BONDERITE M-CR 1200S AERO treating solution", "temperature_in_source": "70 to 100 °F" }, "method": "Range printed in the Operation section of the manufacturer data sheet", "status": "ground", "note": "Narrower than the control-table range (20 to 35 °C) for the same bath.", "source": "conro", "where": "Operation section, Operation, Temperature", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "treatment_time", "label": "Immersion or spray time in the treating solution", "value": 15, "value_high": 180, "bound": "range", "unit": "s", "scope": "material", "conditions": { "product": "BONDERITE M-CR 1200S AERO treating solution", "process": "immersion or spray" }, "method": "Range printed in the Operation and Control table (Time, sec.)", "status": "ground", "note": "The Operation section gives the same range as 15 seconds to 3 minutes.", "source": "conro", "where": "Operation and Control table, row Time, sec.; Operation section, Time", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "bath_titration_points", "label": "Bath concentration as titration value (mL of titrant)", "value": 5, "value_high": 19, "bound": "range", "unit": "mL", "scope": "material", "conditions": { "product": "BONDERITE M-CR 1200S AERO treating solution", "basis": "titration of a 5 mL sample, control procedure" }, "method": "Range printed in the Operation and Control table as the concentration range in mL of titrant; the control procedure says to stay within plus or minus 1 point of the value that gives the desired result", "status": "ground", "source": "conro", "where": "Operation and Control table, row Concentration range, mL; Control Procedure, Concentration", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "shelf_life", "label": "Shelf life of unopened powder", "value": 48, "bound": "exact", "unit": "months", "scope": "material", "conditions": { "form": "powder as supplied", "packaging": "unopened original packaging" }, "method": "Value printed in the storage table of the manufacturer data sheet", "status": "ground", "source": "conro", "where": "Storage table, row Shelf-life", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "storage_temperature", "label": "Storage temperature of the powder", "value": -10, "value_high": 40, "bound": "range", "unit": "°C", "scope": "material", "conditions": { "form": "powder as supplied" }, "method": "Range printed in the storage table of the manufacturer data sheet", "status": "ground", "source": "conro", "where": "Storage table, row Temperature, °C", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "max_drying_temperature", "label": "Maximum metal surface temperature when drying in an oven", "value": 60, "bound": "upper", "unit": "°C", "scope": "material", "conditions": { "basis": "metal surface temperature when an oven or other heat source is used", "temperature_in_source": "150 °F" }, "method": "Limit printed in the Drying section of the manufacturer data sheet, to maintain optimum corrosion resistance", "status": "ground", "source": "conro", "where": "Drying section", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "hexavalent_chromium_per_titrant", "label": "Hexavalent chromium per unit of bath titrant", "value": 1.73, "bound": "exact", "unit": "mg/mL", "scope": "material", "conditions": { "basis": "1 mL of titrant equals 1.73 mg/mL of hexavalent chrome in BONDERITE M-CR 1200S AERO" }, "method": "Conversion factor printed in the Concentration part of the Control Procedure", "status": "ground", "source": "conro", "where": "Control Procedure, Concentration", "source_detail": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" } }, { "benchmark": "coating_thickness", "label": "Coating thickness, typical dry aluminium coating", "value": 200, "value_high": 300, "bound": "range", "unit": "nm", "scope": "material", "conditions": { "basis": "typical dry coating when process variables are adjusted to give it" }, "method": "Range printed in the Chemistry section of the Wikipedia article", "status": "ground", "note": "Wikipedia gives a typical dry film of 200 to 300 nm; the finisher page gives 0.25 to 1 µm. Both are kept.", "source": "wiki", "where": "Chemistry section, Typical thickness", "source_detail": { "title": "Wikipedia: Chromate conversion coating", "url": "https://en.wikipedia.org/wiki/Chromate_conversion_coating", "kind": "web", "license": "CC BY-SA 4.0 (cited, not reproduced)" } }, { "benchmark": "coating_thickness", "label": "Coating thickness, Alodine 1200s on aluminium, average", "value": 200, "value_high": 1000, "bound": "range", "unit": "nm", "scope": "material", "conditions": { "product": "Alodine 1200s", "substrate": "aluminium", "basis": "average" }, "method": "Range printed in the Aluminium section of the Wikipedia article", "status": "ground", "source": "wiki", "where": "Aluminium section, Thickness", "source_detail": { "title": "Wikipedia: Chromate conversion coating", "url": "https://en.wikipedia.org/wiki/Chromate_conversion_coating", "kind": "web", "license": "CC BY-SA 4.0 (cited, not reproduced)" } }, { "benchmark": "hexavalent_chromium_fraction", "label": "Share of chromium atoms that are hexavalent in a commercial coating", "value": 23, "bound": "exact", "unit": "%", "scope": "material", "conditions": { "coating": "commercial aluminium chromate coating", "region": "except in a region close to the metal" }, "method": "Value stated in the Chemistry section of the Wikipedia article; the primary study was not opened", "status": "ground", "source": "wiki", "where": "Chemistry section, Hexavalent chromium residues", "source_detail": { "title": "Wikipedia: Chromate conversion coating", "url": "https://en.wikipedia.org/wiki/Chromate_conversion_coating", "kind": "web", "license": "CC BY-SA 4.0 (cited, not reproduced)" } }, { "benchmark": "unpainted_coating_max_temperature", "label": "Upper temperature limit for unpainted hexavalent chromate parts", "value": 60, "bound": "upper", "unit": "°C", "scope": "material", "conditions": { "coating": "unpainted hexavalent chromate conversion coated parts", "temperature_in_source": "140 °F" }, "method": "Requirement stated in NASA-STD-6012A section 4.6.2", "status": "ground", "source": "std6012", "where": "Section 4.6.2, requirement CPR 24", "source_detail": { "title": "NASA-STD-6012A, Corrosion Protection for Space Flight Hardware", "id": "NASA-STD-6012A, approved 2022-03-23", "url": "https://standards.nasa.gov/sites/default/files/standards/NASA/A/2022-01-11-NASA-STD-6012A-Approved.pdf", "year": 2022, "kind": "standard", "license": "NASA technical standard, approved for public release" } }, { "benchmark": "unpainted_exposure_time", "label": "Guidance exposure time at 60 °C for unpainted parts", "value": 1, "bound": "exact", "unit": "min", "scope": "material", "conditions": { "temperature": "60 °C (140 °F)", "coating": "unpainted hexavalent chromate conversion coating" }, "method": "Guidance row in the Appendix E table of NASA-STD-6012A; the appendix says no literature supports exposure time limits", "status": "ground", "source": "std6012", "where": "Appendix E, guidance table, first row", "source_detail": { "title": "NASA-STD-6012A, Corrosion Protection for Space Flight Hardware", "id": "NASA-STD-6012A, approved 2022-03-23", "url": "https://standards.nasa.gov/sites/default/files/standards/NASA/A/2022-01-11-NASA-STD-6012A-Approved.pdf", "year": 2022, "kind": "standard", "license": "NASA technical standard, approved for public release" } }, { "benchmark": "unpainted_exposure_time", "label": "Guidance exposure time at 21 °C for unpainted parts", "value": 168, "bound": "exact", "unit": "h", "scope": "material", "conditions": { "temperature": "21 °C (70 °F)", "coating": "unpainted hexavalent chromate conversion coating" }, "method": "Guidance row in the Appendix E table of NASA-STD-6012A", "status": "ground", "source": "std6012", "where": "Appendix E, guidance table, last row", "source_detail": { "title": "NASA-STD-6012A, Corrosion Protection for Space Flight Hardware", "id": "NASA-STD-6012A, approved 2022-03-23", "url": "https://standards.nasa.gov/sites/default/files/standards/NASA/A/2022-01-11-NASA-STD-6012A-Approved.pdf", "year": 2022, "kind": "standard", "license": "NASA technical standard, approved for public release" } }, { "benchmark": "unpainted_cold_exposure_limit", "label": "Lower temperature limit for unpainted parts, time-limited", "value": 0, "bound": "lower", "unit": "°C", "scope": "material", "conditions": { "coating": "unpainted hexavalent chromate conversion coated parts", "duration_limit": "not longer than 1 minute below this temperature" }, "method": "Guidance in Appendix E of NASA-STD-6012A, which says water in the coating may freeze or sublime as the structure cracks", "status": "ground", "source": "std6012", "where": "Appendix E, paragraph after the guidance table", "source_detail": { "title": "NASA-STD-6012A, Corrosion Protection for Space Flight Hardware", "id": "NASA-STD-6012A, approved 2022-03-23", "url": "https://standards.nasa.gov/sites/default/files/standards/NASA/A/2022-01-11-NASA-STD-6012A-Approved.pdf", "year": 2022, "kind": "standard", "license": "NASA technical standard, approved for public release" } }, { "benchmark": "coating_to_primer_time", "label": "Maximum time from conversion treatment to primer or adhesive", "value": 48, "bound": "upper", "unit": "h", "scope": "material", "conditions": { "requirement": "primer or adhesive must be applied in less than 48 hours after the conversion coating process for adequate adhesion" }, "method": "Process requirement stated in NASA PRC-5005 Rev. D, section 3.0", "status": "ground", "source": "prc", "where": "Section 3.0, paragraph on adhesion", "source_detail": { "title": "NASA/JSC PRC-5005 Rev. D, Process Specification for the Chemical Conversion Coating of Aluminum Alloys", "id": "PRC-5005 Rev. D, July 2020", "url": "https://nasa.gov/wp-content/uploads/2023/03/prc-5005-current.pdf", "year": 2020, "kind": "standard", "license": "NASA process specification (public)" } } ], "corrosion": [ { "environment": "Self-healing in service, after scratches or pits form in the film", "headline": "Cr(VI) in the film migrates to defects and helps repassivate pits.", "effect": "The coating is a mix of Cr(III) and Cr(VI) oxides. When it contacts an electrolyte, the Cr(VI) migrates to defects in the layer, where it can repassivate corrosion pits. Grilli notes that it is unclear how ageing and the loss of water affect this self-healing. The mechanism is described from the literature in a thesis, not measured in the sources read here.", "rating": "low", "conditions": { "basis": "mechanism summarised in a PhD thesis chapter, no test conditions given" }, "source": "grilli2010", "where": "Section 2.3, Chromate Conversion Coatings" }, { "environment": "Unpainted parts above 60 °C (140 °F) during drying, fabrication or service", "headline": "Unpainted chromate coatings lose corrosion resistance above 60 °C.", "effect": "NASA quotes MIL-DTL-5541F: unpainted conversion coatings start to lose corrosion resistance at 60 °C (140 °F) or higher. The coating dehydrates and its chromates become insoluble. Protection falls as temperature and exposure time rise, and dew point also changes how long a coating tolerates heat.", "rating": "moderate", "conditions": { "temperatures": "60 °C (140 °F) and above", "exposure_time": "Appendix E table: 1 minute at 60 °C down to 168 hours at 21 °C" }, "source": "std6012", "where": "Section 4.6.2 and Appendix E" }, { "environment": "Ageing in air", "headline": "Long ageing produces microcracks that a limited Cr(VI) supply is unlikely to repair.", "effect": "Grilli reports that ageing in air causes the loss of water from the film and a developing network of microcracks. These cracks may be pathways to the aluminium, and a limited Cr(VI) reservoir is unlikely to repair them. The ageing rate and crack growth were not measured in the sources read.", "rating": "moderate", "conditions": { "basis": "literature summarised in a thesis chapter, no ageing time or humidity given" }, "source": "grilli2010", "where": "Section 2.3, Chromate Conversion Coatings" }, { "environment": "Alloys with copper or intermetallic particles", "headline": "The film is thinner over intermetallic particles, so it is less even on some alloys.", "effect": "Juffs and co-workers, cited by Grilli, found the coating on the aluminium matrix about 10 times thicker than on an intermetallic phase. The coating is therefore uneven on alloys with second-phase particles, and copper-rich alloys can change its composition.", "rating": "moderate", "conditions": { "basis": "macroscopic intermetallic phases coupled to aluminium, as cited in the thesis" }, "source": "grilli2010", "where": "Section 2.3, paragraph citing Juffs et al." }, { "environment": "Below freezing, unpainted parts", "headline": "Below 0 °C for more than 1 minute, the coating can crack and expose the metal.", "effect": "NASA says water molecules in the coating may freeze or sublime as its structure cracks, possibly exposing the base metal. The guidance is that unpainted parts should not be exposed below 0 °C for longer than 1 minute.", "rating": "moderate", "conditions": { "temperature": "below 0 °C (32 °F)", "duration": "longer than 1 minute" }, "source": "std6012", "where": "Appendix E, paragraph after the guidance table" } ], "risks": { "hazards": [ { "text": "NIOSH considers all Cr(VI) compounds to be potential occupational carcinogens.", "ghs": [], "source": "niosh-cr6", "where": "What this means to you section, Engineering Controls Database" }, { "text": "Wikipedia says hexavalent chromium compounds have been the topic of intense workplace and public health concern over carcinogenicity, and that they are highly regulated.", "ghs": [], "source": "wiki", "where": "Safety section" }, { "text": "The Henkel data sheet says the powder's hazards are in its material safety data sheet and does not name the hexavalent compound. The safety data sheet was not opened, so no GHS codes are recorded for this product.", "ghs": [], "source": "conro", "where": "Classification section" } ], "failure_risks": [ { "mode": "Loss of corrosion protection on unpainted parts above 60 °C", "trigger": "Drying, fabrication or service above 60 °C (140 °F)", "consequence": "The coating dehydrates and its chromates become insoluble, so corrosion resistance falls. The effect grows with temperature and exposure time.", "severity": "moderate", "source": "std6012", "where": "Section 4.6.2; Appendix E" }, { "mode": "Cracking of the film in the cold", "trigger": "Unpainted parts below 0 °C (32 °F) for more than 1 minute", "consequence": "Water in the coating may freeze or sublime as the structure cracks, possibly exposing the base metal.", "severity": "moderate", "source": "std6012", "where": "Appendix E, paragraph after the guidance table" }, { "mode": "Microcracks from long ageing", "trigger": "Ageing of the coating in air, which removes water from the film", "consequence": "A network of microcracks develops that a limited Cr(VI) reservoir is unlikely to repair, so the self-healing action may weaken.", "severity": "moderate", "source": "grilli2010", "where": "Section 2.3, Chromate Conversion Coatings" }, { "mode": "Poor paint or bond adhesion after delay", "trigger": "Primer or adhesive applied 48 hours or more after the conversion treatment", "consequence": "NASA PRC-5005 says adequate adhesion needs application in less than 48 hours.", "severity": "moderate", "source": "prc", "where": "Section 3.0, paragraph on adhesion" } ], "side_effects": [ { "text": "About 23% of chromium atoms in a commercial aluminium coating are hexavalent, except near the metal, and these residues can migrate when the coating is wetted.", "affects": "Workers handling wet parts, and waste from the process", "source": "wiki", "where": "Chemistry section, Hexavalent chromium residues; Safety section" } ], "handling": [ { "text": "The Henkel sheet says dried, unfinished parts should not be handled bare-handed; use plastic or clean cotton gloves.", "source": "conro", "where": "Drying section" }, { "text": "Storing the working solution in mild steel containers slowly decomposes it. Process tanks should be 300 series stainless steel, with 316L preferred.", "source": "conro", "where": "Equipment section" }, { "text": "Rinse the coating after application so the acids and salts in the process solution are removed before the coating dries.", "source": "prc", "where": "Section 6.0" } ], "mitigations": [ { "text": "Type II coatings have no hexavalent chromium, but PRC-5005 says Type I outperforms Type II in corrosion tests, especially in filiform and deep scratch tests, and recommends Type I for most flight hardware.", "source": "prc", "where": "Section 3.0, Usage" }, { "text": "Wikipedia says trivalent chromium alternatives have been developed because they are considerably less toxic than hexavalent chromium.", "source": "wiki", "where": "Safety section" } ] }, "uses": [ { "application": "structures", "device": "Aluminium parts that are painted or left bare (Class 1A coating)", "example": "Henkel lists BONDERITE M-CR 1200S AERO on Qualified Product List QPL-81706 for Class 1A and Class 3 coatings, bare or painted, to MIL-DTL-5541.", "source": "conro", "where": "Application Areas" }, { "application": "electronics-and-chips", "device": "Aluminium parts where lower electrical contact resistance is required (Class 3 coating)", "example": "PRC-5005 defines Class 3 as protection against corrosion where lower electrical resistance is required.", "source": "prc", "where": "Section 2.0, classes" }, { "application": "structures", "device": "Aluminium surfaces to be painted or bonded", "example": "PRC-5005 says the coating is a good base for paint primers and only a fair base for bonding, and that the standard bonding method removes it during surface preparation.", "source": "prc", "where": "Section 3.0" } ], "supply": [ { "subject": "Chromium (mine production, the source of chromium chemicals)", "producers": [ { "country": "South Africa", "share_percent": 45.1, "year": 2025 }, { "country": "Turkey", "share_percent": 17.6, "year": 2025 }, { "country": "Kazakhstan", "share_percent": 13.7, "year": 2025 }, { "country": "India", "share_percent": 5.9, "year": 2025 } ], "critical_lists": [], "recycling": "USGS: recycled chromium in stainless-steel scrap accounted for 21% of US apparent consumption in 2025.", "substitutes": [ "USGS: chromium has no substitute in stainless steel or in superalloys. The chapter does not discuss chromate conversion coatings." ], "source": "usgs-mcs2026-chromium", "where": "World Mine Production and Reserves table, 2025e (world total 51,000 thousand t as printed; shares calculated by Space Mushroom from South Africa 23,000, Turkey 9,000, Kazakhstan 7,000 and India 3,000 thousand t); Recycling; Substitutes" }, { "subject": "Chromium-containing chemicals (US import sources)", "producers": [ { "country": "Kazakhstan", "share_percent": 25 }, { "country": "China", "share_percent": 19 }, { "country": "Germany", "share_percent": 14 }, { "country": "India", "share_percent": 13 } ], "critical_lists": [], "recycling": "Not stated in the chromium chapter for chemicals.", "substitutes": [], "source": "usgs-mcs2026-chromium", "where": "Domestic Production and Use, Import Sources (2021 to 2024) paragraph; the share for the chemicals is the US import share, not the world share" } ], "media": [], "documents": [ { "title": "BONDERITE M-CR 1200S AERO (Alodine 1200S) Technical Data Sheet, Henkel, November 2019", "type": "datasheet", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019 }, { "title": "NASA/JSC PRC-5005 Rev. D, Process Specification for the Chemical Conversion Coating of Aluminum Alloys (July 2020)", "type": "standard", "url": "https://nasa.gov/wp-content/uploads/2023/03/prc-5005-current.pdf", "year": 2020 }, { "title": "NASA-STD-6012A, Corrosion Protection for Space Flight Hardware (approved 2022-03-23)", "type": "standard", "url": "https://standards.nasa.gov/sites/default/files/standards/NASA/A/2022-01-11-NASA-STD-6012A-Approved.pdf", "year": 2022 }, { "title": "Grilli, Conversion coatings for aluminium alloys: a surface investigation for corrosion mechanisms (PhD thesis, University of Surrey, 2010)", "type": "paper", "url": "http://esmat.esa.int/Publications/Published_papers/Conversion_coatings_for_aluminium_alloys.pdf", "year": 2010 }, { "title": "USGS Mineral Commodity Summaries 2026: Chromium", "type": "report", "url": "https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-chromium.pdf", "year": 2026 }, { "title": "NIOSH Engineering Controls Database: Control of Hexavalent Chromium Exposures", "type": "database", "url": "https://www.cdc.gov/niosh/engcontrols/ecd/detail7.html" }, { "title": "Wikipedia: Chromate conversion coating", "type": "database", "url": "https://en.wikipedia.org/wiki/Chromate_conversion_coating" }, { "title": "Fictiv: Alodine chromate conversion coating finish page", "type": "datasheet", "url": "https://fictiv.com/finishes/alodine-chromate-conversion-coating" } ], "gaps": [ "No electrical contact resistance or surface resistance value for the Class 3 coating was found in any source opened. PRC-5005 names Class 3 for lower electrical resistance but gives no number. A forum thread on finishing.com quotes 5,000 microohms per square inch, but that is a second-hand forum quote and is not recorded as a property.", "MIL-DTL-5541 itself was not opened. Its Class 1A and Class 3 test requirements, salt spray hours and filiform test results are therefore not recorded.", "No salt spray, humidity or filiform corrosion test hours for this coating were found in the sources read.", "No flight, vacuum, outgassing or atomic-oxygen result for the coating was found. NASA-STD-6012A gives only temperature and exposure limits, and the outgassing and erosion data are not in any source opened.", "Coating mass (coating weight) per area was not found as a number. The Fictiv page and forum thread give it only in general terms.", "Bath temperature conflicts in the Henkel sheet (20 to 35 °C in the control table, 20 to 30 °C in the operation section). Both are recorded; the sheet does not reconcile them.", "Thickness conflicts across sources: 0.25 to 1 µm (Fictiv) against 200 to 300 nm typical (Wikipedia). Both are recorded; the thickness for a given drawing should come from the drawing or the work instruction.", "The hazard data rest on the NIOSH engineering controls page and the Wikipedia safety section. The Henkel powder's safety data sheet was not opened, and the hexavalent compound in the powder is not named in the sheet, so no GHS codes are recorded.", "The 23% hexavalent figure comes from a Wikipedia summary; the primary study was not opened.", "Atomic weights were not read in this run, so the recipe parts carry atom counts only.", "The chromium chapter in USGS MCS 2026 was read for supply, but the USGS 2025 critical minerals list was not opened, so no critical-list status is recorded for chromium.", "The aluminium substrate is not profiled here. Its supply and corrosion behaviour belong to the aluminium profiles.", "No environment tags: none of the sources opened ties this coating to a specific space environment such as low Earth orbit or the lunar surface.", "The Henkel bath make-up figures (6.3 pounds per 100 gallons, and the metric equivalent printed as 7,5 kg per 1000 liters) were not recorded because the printed metric figure is ambiguous.", "No media images were selected for this profile." ], "story": { "why": "Chromate conversion coating is a long-standing aluminium pre-treatment. It puts a thin film on the metal that protects it from corrosion and gives paint a base. Grilli describes the film as low in surface electrical resistance, which the thesis calls an important feature for the space industry. NASA PRC-5005 uses Class 3 for coatings where lower electrical resistance is required, and Class 1A for maximum corrosion protection. Type I, the hexavalent version, is recommended for most flight hardware.", "uses": [ { "where": "Structures", "line": "Henkel lists its powder on Qualified Product List QPL-81706 for Class 1A and Class 3 coatings, bare or painted, to MIL-DTL-5541. NASA lets MIL-DTL-5541 coatings serve as a primer base or a temporary fabrication coating." }, { "where": "Electrical grounding", "line": "PRC-5005 names Class 3 for protection where lower electrical resistance is required. The sources opened give no numeric resistance value for it." }, { "where": "Paint and bonding preparation", "line": "The coating is a good base for paint primers and only a fair base for bonding. The standard bonding method removes it during surface preparation, and the primer or adhesive should go on within 48 hours." } ], "can_do": [ { "label": "Corrosion barrier", "line": "One finisher gives the film thickness as 0.25 to 1 µm. Wikipedia gives 200 to 300 nm as the typical dry coating, and 200 to 1000 nm as the average for Alodine 1200s on aluminium.", "scope": "material", "value": "0.25 to 1 µm" }, { "label": "Paint base", "line": "PRC-5005 says primer or adhesive must go on in less than 48 hours after the conversion treatment for adequate adhesion.", "scope": "material", "value": "Within 48 hours" }, { "label": "Self-repair", "line": "Chromium(VI) in the film migrates to defects, where it can repassivate pits. Grilli notes that ageing and water loss may limit this action.", "scope": "material", "value": "Cr(VI) migrates" }, { "label": "Process speed", "line": "The Henkel sheet gives 15 seconds to 3 minutes of treatment time, at a bath temperature of 20 to 30 °C in the operation section.", "scope": "material", "value": "15 s to 3 min" }, { "label": "Heat limit", "line": "Unpainted hexavalent chromate parts should not exceed 60 °C (140 °F), according to NASA-STD-6012A section 4.6.2.", "scope": "material", "value": "60 °C" } ], "compare": "Anodize, covered by the anodized aluminium profile, grows an oxide skin that the profile describes as electrically insulating. Chromate conversion coating is a thin chemical film and is chosen where lower electrical resistance is needed, as NASA PRC-5005 describes for Class 3. Type II coatings avoid hexavalent chromium, but PRC-5005 says Type I consistently outperforms Type II in corrosion tests, and Grilli reviews chromium-free alternatives for aluminium without giving a single replacement value. The table below compares film thickness, the heat limit for unpainted parts and the bath pH.", "compare_rows": [ { "label": "Film thickness", "benchmark": "coating_thickness", "scope": "material" }, { "label": "Upper temperature for unpainted parts", "benchmark": "unpainted_coating_max_temperature", "scope": "material" }, { "label": "Bath pH", "benchmark": "bath_ph", "scope": "material" } ], "handling": [ "Specify the type and class on the drawing. PRC-5005 uses Type I unless the drawing says otherwise, and Class 3 where lower electrical resistance is needed.", "Keep unpainted parts at or below 60 °C (140 °F), and do not expose them below 0 °C for more than 1 minute.", "Apply primer or adhesive within 48 hours of the conversion treatment.", "Wear plastic or clean cotton gloves on dried, unfinished parts.", "Store the unopened powder between -10 and 40 °C. The shelf life is 48 months." ], "good_for": [ "Corrosion protection with a paint base, in a film of 0.25 to 1 µm according to one finisher.", "Low electrical contact resistance in its Class 3 form, as PRC-5005 describes, with no numeric value in the sources read.", "Self-repair of small defects, because Cr(VI) migrates to defects, as Wikipedia and Grilli describe." ], "watch_out": [ "Hexavalent chromium: NIOSH treats all Cr(VI) compounds as potential occupational carcinogens.", "Unpainted parts lose corrosion resistance above 60 °C (140 °F), and the loss increases with temperature and time.", "NASA-STD-6012A says MIL-DTL-5541 coatings alone would generally fail its environment Class 1 and Class 2 requirements on aluminium alloys. Those are the standard's environment classes, not the coating classes.", "The Henkel sheet gives two bath temperature ranges, 20 to 35 °C and 20 to 30 °C, and does not say which applies." ], "verdict": "Chromate conversion coating is a long-standing aluminium pre-treatment that gives corrosion protection, a paint base and low electrical resistance in its Class 3 form. Its hexavalent chemistry brings a carcinogen concern, a 60 °C limit for unpainted parts, and no numeric electrical value in the sources read here.", "recipe": { "line": "Chromate conversion coating is a thin film formed on aluminium by reaction with an acidic chromate bath. The dry film is mostly chromium(III) oxide with very little aluminium oxide, and it holds some chromium(VI) within it (Wikipedia). Process: clean, rinse, deoxidise if the surface is heavily oxidised, rinse, treat, rinse, then dry (Henkel). The Henkel bath is acidic, at pH 1.3 to 1.8.", "parts": [ { "name": "Chromium", "symbol": "Cr", "role": "The film-forming metal. Chromium(VI) in the bath is reduced to chromium(III), which forms the hydrated oxide; some chromium(VI) stays bound and can migrate to defects." }, { "name": "Oxygen", "symbol": "O", "role": "Bound to chromium in the oxide film. Chromium(III) oxide is the main constituent of the dry coating." }, { "name": "Aluminium", "symbol": "Al", "role": "The substrate. Aluminium is oxidised as the chromium is reduced, and very little aluminium oxide remains in the final film (Wikipedia; Grilli 2010)." } ] }, "risk_groups": [ { "title": "For people", "lead": "The coating is made in a hexavalent chromium bath, and hexavalent chromium compounds are a recognised occupational hazard. The sources do not give toxicity numbers for this product.", "points": [ { "label": "The chemistry", "line": "NIOSH considers all Cr(VI) compounds to be potential occupational carcinogens. The Henkel sheet's titration factor shows the bath contains hexavalent chrome: 1 mL of titrant equals 1.73 mg/mL of hexavalent chrome." }, { "label": "Wet parts and residues", "line": "About 23% of the chromium atoms in a commercial aluminium coating are hexavalent, except near the metal. These residues can migrate when the coating is wetted." }, { "label": "Alternatives", "line": "Wikipedia says trivalent chromium alternatives are considerably less toxic. RoHS and REACH encourage the elimination of hexavalent chromium, including in chromate processes." } ], "level": 1, "verdict": "Hexavalent chromium is the concern" }, { "title": "If the coating overheats or freezes", "lead": "These are limits in NASA-STD-6012A for unpainted parts, not failure test results.", "points": [ { "label": "Heat", "line": "Unpainted parts should not be exposed above 60 °C (140 °F). At 60 °C the guidance allows about 1 minute, and at 21 °C about 168 hours." }, { "label": "Cold", "line": "Unpainted parts should not be exposed below 0 °C for more than 1 minute, because the water in the coating may freeze and crack the film." }, { "label": "Drying", "line": "The Henkel sheet limits the metal surface temperature in a drying oven to 60 °C (150 °F), to maintain corrosion resistance." } ] }, { "title": "Handling and storage", "points": [ { "label": "Powder", "line": "The powder is brown and should be stored unopened between -10 and 40 °C. Its shelf life in unopened packaging is 48 months." }, { "label": "Bath", "line": "Mild steel containers slowly decompose the working solution. The sheet recommends 300 series stainless steel tanks, with 316L preferred." } ] } ] }, "updated": "2026-11-01", "review": { "status": "draft", "method": "assistant", "checked_values": 17, "unreachable": 2, "caveats": 4, "note": "Written by an AI assistant on 2026-11-01 from the pages and PDFs named in each entry (Henkel data sheet and NASA PRC-5005 and NASA-STD-6012A extracted from PDF text). Not used: the PubChem chromium trioxide record (returned a browser verification page) and the NIOSH Pocket Guide entry for chromium (VI) (the link opened a different chemical). Caveats: the Henkel sheet gives two bath temperature ranges; the finisher and Wikipedia thickness ranges differ; the 23% figure is from a Wikipedia summary; the forum quote for contact resistance is not recorded as a value." }, "sources": { "conro": { "title": "Technical Data Sheet, BONDERITE M-CR 1200S AERO (Known as Alodine 1200S), Henkel", "id": "Henkel technical data sheet, reference 1.0, November 2019; MIL-DTL-5541 Class 1A and Class 3, QPL-81706", "url": "https://conro.com/downloads/Manuals/BONDERITE-M-CR-1200S-AERO-TDS.pdf", "year": 2019, "kind": "datasheet", "license": "Manufacturer data sheet (cited, not reproduced)" }, "prc": { "title": "NASA/JSC PRC-5005 Rev. D, Process Specification for the Chemical Conversion Coating of Aluminum Alloys", "id": "PRC-5005 Rev. D, July 2020", "url": "https://nasa.gov/wp-content/uploads/2023/03/prc-5005-current.pdf", "year": 2020, "kind": "standard", "license": "NASA process specification (public)" }, "std6012": { "title": "NASA-STD-6012A, Corrosion Protection for Space Flight Hardware", "id": "NASA-STD-6012A, approved 2022-03-23", "url": "https://standards.nasa.gov/sites/default/files/standards/NASA/A/2022-01-11-NASA-STD-6012A-Approved.pdf", "year": 2022, "kind": "standard", "license": "NASA technical standard, approved for public release" }, "grilli2010": { "title": "Conversion coatings for aluminium alloys: a surface investigation for corrosion mechanisms (PhD thesis, University of Surrey)", "id": "Rossana Grilli, March 2010, hosted by ESA ESMAT", "url": "http://esmat.esa.int/Publications/Published_papers/Conversion_coatings_for_aluminium_alloys.pdf", "year": 2010, "kind": "paper", "license": "Thesis (cited, not reproduced)" }, "usgs-mcs2026-chromium": { "title": "Mineral Commodity Summaries 2026, Chromium", "id": "USGS MCS 2026, February 2026", "url": "https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-chromium.pdf", "year": 2026, "kind": "report", "license": "public domain (USGS)" }, "niosh-cr6": { "title": "NIOSH Engineering Controls Database: Control of Hexavalent Chromium Exposures", "url": "https://www.cdc.gov/niosh/engcontrols/ecd/detail7.html", "kind": "web", "license": "public domain (CDC NIOSH)" }, "wiki": { "title": "Wikipedia: Chromate conversion coating", "url": "https://en.wikipedia.org/wiki/Chromate_conversion_coating", "kind": "web", "license": "CC BY-SA 4.0 (cited, not reproduced)" }, "fictiv": { "title": "Fictiv finishes: Alodine chromate conversion coating", "url": "https://fictiv.com/finishes/alodine-chromate-conversion-coating", "kind": "web", "license": "Supplier web page (cited, not reproduced)" } }, "license": "CC-BY-4.0", "url": "https://spacemushroom.com/profiles/chromate-conversion-coating/" }