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Refractory metals and carbides
refractory-metalsAbout refractory metals and carbides
Tungsten, tantalum and tungsten carbide: high-temperature and wear data with sources.
Refractory metals melt at very high temperatures and keep their strength when hot. Cemented tungsten carbide gets its hardness from tungsten carbide grains in a cobalt binder; its properties depend on the cobalt content and grain size.
At a glance
- Highest yield strength: Zirconium alloys (Zr alloys) reaches 998 MPa. Lowest: Hafnium (Hf) starts at 151 MPa. (12 of 22 grades have a sourced value.)
- Highest tensile strength: Zirconium alloys (Zr alloys) reaches 1,069 MPa. Lowest: Mo-30W starts at 170 MPa. (14 of 22 grades have a sourced value.)
- Highest density: Rhenium (Re) reaches 21 g/cm³. Lowest: Beryllium starts at 1.85 g/cm³. (22 of 22 grades have a sourced value.)
Ranges run across the conditions each source reports (temper, heat treatment, form), measured at room temperature where the source says so.
How they compare
The same measurements for every material in the collection. A range means the grade has values under several conditions; "at least" means the source gives a specified minimum. "no data" means no sourced value yet. For ranked tables, open a benchmark.
| Material | Yield strength | Tensile strength | Density | Young's modulus | Thermal conductivity | Melting point |
|---|---|---|---|---|---|---|
| Tungsten (W)refractory metal | no data | no data | 19.3 g/cm³ | 411 GPa | 174 W/(m·K) | 3,422 °C |
| Tungsten carbide (WC)wear-resistant hard phase, held together by a cobalt binder | no data | no data | 14.4 to 15.6 g/cm³ | 530 to 700 GPa | 110 W/(m·K) | no data |
| Tantalumdense refractory metal (radiation spot shielding, capacitor anodes) | no data | no data | 16.6 g/cm³ | no data | 57 W/(m·K) | 3,017 °C |
| Hafnium (Hf)nuclear control rod material and superalloy additive | at least 151 MPa | at least 400 MPa | 13.1 to 13.3 g/cm³ | 137 GPa | 23 W/(m·K) | 2,233 °C |
| Molybdenumrefractory structural and alloying metal | 265 MPa | 411 MPa | 10.2 g/cm³ | no data | 142 W/(m·K) | 2,623 °C |
| Mo-Reductile refractory alloy for space reactor cladding and structures, and for high-temperature thermoelements | 557 MPa | 719 MPa | 14.6 g/cm³ | no data | no data | at least 2,610 °C |
| Mo-30Whigh-temperature molybdenum-tungsten alloy for furnace hot zones, crucibles, zinc-bath heaters and sputtering targets | no data | 170 to 385 MPa | 10.9 to 11.2 g/cm³ | no data | no data | 2,829 °C |
| TZM molybdenum alloyhigh-temperature molybdenum alloy for furnace and hot-tool parts | 750 to 900 MPa | 800 to 1,000 MPa | 10.2 g/cm³ | 300 GPa | 130 W/(m·K) | no data |
| Niobium (Nb)refractory metal for high-temperature rocket nozzles, steel microalloying and superconducting wire | 276 MPa | 386 MPa | 8.58 to 8.86 g/cm³ | 90 to 105 GPa | 53.7 W/(m·K) | 2,350 to 2,477 °C |
| Niobium alloys (Nb alloys)refractory niobium alloys for rocket and thruster nozzles, load-free thermal shields and alkali-metal containment | 276 MPa | 386 MPa | 8.57 to 8.85 g/cm³ | 90 GPa | 38.1 to 44.7 W/(m·K) | 2,350 to 2,410 °C |
| Rhenium (Re)high-temperature structural metal for thruster chambers and superalloys | 200 to 500 MPa | 400 to 700 MPa | 21 g/cm³ | 460 GPa | 48 W/(m·K) | 3,186 °C |
| Tungsten-rhenium alloys (W-Re)refractory alloy for high-temperature thermocouples, X-ray target tracks and nuclear-space design studies | no data | 200 to 220 x 10^3 psi | 19.3 to 19.7 g/cm³ | no data | no data | 3,120 to 3,350 °C |
| Tungsten heavy alloy (WHA)dense radiation shield, counterweight and mass material | 517 MPa | 689 to 758 MPa | 16.9 to 18.9 g/cm³ | 330 to 385 GPa | no data | no data |
| Tungsten-copper (W-Cu)heat sink and electrical contact composite | no data | 620 to 689 MPa | 14.5 to 15.5 g/cm³ | 280 GPa | 180 to 235 W/(m·K) | no data |
| Silver-tungsten (W-Ag)electrical contact and electrode composite | no data | no data | 11.8 to 16.1 g/cm³ | no data | no data | no data |
| Thoriated tungsten (WT20)TIG welding electrode and cathode material | no data | no data | 11.7 g/cm³ | 411 GPa | 174 W/(m·K) | 3,422 °C |
| Vanadiumrefractory metal used mainly as an alloying element in steel and aerospace titanium alloys, and as the electrolyte element of vanadium redox flow batteries | no data | no data | 6.11 g/cm³ | 128 GPa | 30.7 W/(m·K) | 1,900 to 1,910 °C |
| Vanadium alloys (V alloys)fusion first-wall and blanket structural alloys, and vanadium-based hydrogen-permeation membranes | 402 MPa | 488 MPa | 6.05 g/cm³ | 126 GPa | no data | 1,900 °C |
| Zirconium and Zircaloy (Zr)corrosion-resistant structural metal and nuclear cladding alloy | 207 to 506 MPa | 379 to 615 MPa | 6.51 to 6.64 g/cm³ | 94.7 to 99.3 GPa | 21.5 W/(m·K) | 1,840 to 1,852 °C |
| Zirconium alloys (Zr alloys)corrosion-resistant structural alloys for nuclear fuel cladding, reactor pressure tubes and chemical-process equipment | 468 to 998 MPa | 515 to 1,069 MPa | 6.55 g/cm³ | 99.3 GPa | 21.5 W/(m·K) | 1,850 °C |
| Titanium hydride (TiH2)hydrogen reservoir, foaming agent and neutron moderator (titanium, zirconium and hafnium hydrides) | no data | no data | 3.78 to 11.4 g/cm³ | no data | no data | at least 400 °C |
| Berylliumstructural and optical metal | at least 207 MPa | at least 290 MPa | 1.85 g/cm³ | 290 GPa | 216 W/(m·K) | 1,287 °C |
What these materials are made of
Composition by weight, as printed in the sources for each grade (the first constituents listed).
| Material | Main constituents |
|---|---|
| Tungsten (W) | W 100.0% |
| Tungsten carbide (WC) | WC 90 to 94% · Co 6 to 10% |
| Tantalum | Ta 100.0% |
| Hafnium (Hf) | Hf 100.0% |
| Molybdenum | Mo 100.0% |
| Mo-Re | Mo 59% · Re 41% |
| Mo-30W | Mo balance · W 28 to 32% |
| TZM molybdenum alloy | Mo balance · Ti 0.5% · Zr 0.08% · C 0.01 to 0.04% |
| Rhenium (Re) | Re 100.0% |
| Vanadium alloys (V alloys) | V balance |
| Zirconium and Zircaloy (Zr) | Sn 1.2 to 1.7% · Fe 0.18 to 0.24% · Cr 0.07 to 0.13% |
| Zirconium alloys (Zr alloys) | Zr 95% · Sn 1.2 to 1.7% · Fe 0.18 to 0.24% · Cr 0.07 to 0.13% · Nb 2.4 to 2.8% |
| Titanium hydride (TiH2) | Ti 15.0% · Zr 28.5% · Hf 55.8% · H 0.6% |
| Beryllium | Be 99.2% · BeO 0.9% · C 0.09% · Fe 0.08% · Al 0.05% |
Where they are used
| Use | Grades |
|---|---|
| Rocket nozzle throat inserts | Tungsten (W) |
| Gamma shield near a space nuclear reactor | Tungsten (W) |
| Heavy-alloy counterweights and vibration damping | Tungsten (W) |
| Metal-machining cutting tools | Tungsten carbide (WC) |
| Mining drill bits and rock drilling tools | Tungsten carbide (WC) |
| Wear parts for tunnel boring, road construction and agriculture | Tungsten carbide (WC) |
| Spot shield on spacecraft electronics vault | Tantalum |
| Tantalum capacitor anode | Tantalum |
| Spot shield (NIST attenuation context) | Tantalum |
| Control rods in nuclear reactors | Hafnium (Hf) |
| Nickel-based superalloys for hot-end parts of jet engines | Hafnium (Hf) |
| Liquid-rocket thruster nozzles (C103 alloy) | Hafnium (Hf) |
| Alloying agent in steel, cast iron and superalloys | Molybdenum |
| Conductive metal layers in thin-film transistors | Molybdenum |
| Resistance elements in electric furnaces | Molybdenum |
| Fuel cladding and core structural material for spacecraft reactors | Mo-Re |
When each grade fits
| Material | Best for | Weakest at |
|---|---|---|
| Tungsten (W) | Very high temperature parts, dense counterweights and gamma shielding where weight per unit of shielding matters more than cost | Brittle and hard to form or machine; oxidises in air when hot, so it needs protection above room temperature |
| Tungsten carbide (WC) | Cutting and wear parts where hardness matters most (less cobalt, fine grain), and mining drill bits and crusher parts, which Hyperion's mining table lists in 6 percent cobalt grades | Toughness: Hyperion ties high toughness to 10 to 20 percent binder and high hardness to sub-micron grains with 3 to 15 percent binder. The dust carries a cobalt and hardmetal health hazard and a rare fire risk (Sandvik SDS). |
| Tantalum | Dense, high-melting spot shielding in thin sheet, such as the approximately 1 mm tantalum vault plate on NASA's Europa Clipper | Mass: the 16650 kg/m3 density makes it heavy for large areas, and the vault plate is only a local shield, not a full enclosure |
| Hafnium (Hf) | Absorbing neutrons in reactor control rods (104 barns thermal neutron cross-section) and strengthening nickel superalloys (ATI) | Fine powder and chips, which ignite in air (ATI, ESPI), and strength that depends strongly on oxygen, nitrogen and carbon pickup (ATI) |
| Molybdenum | High-temperature strength and heat conduction: 2623 °C melting point and 142 W/(m·K) thermal conductivity at 20 °C, in vacuum or inert service | Oxidation in air above about 400 °C, where it forms volatile MoO3, and toughness at room temperature in as-rolled sheet (ductile-brittle transition above 25 °C in the NASA study) |
| Mo-Re | Structural and cladding use at high temperature in vacuum or inert gas, for example fuel cladding and core structures in space reactors, where ductility must survive welding | Oxidation in air above about 600 °C, and embrittlement by the sigma phase in Mo-47.5Re and by irradiation above about 1100 K |
| Mo-30W | Refractory parts that must hold shape at high temperature in vacuum or inert furnaces, where the 2829 °C melting point and the 10.9 g/cm3 sintered minimum density are the reference figures | Strength falls off above about 1500 °C in the powder-metallurgy bar tested by Wang et al., and the zinc-bath factory test found aluminium in the bath attacks the alloy |
| TZM molybdenum alloy | High-temperature strength in vacuum and inert furnaces: recrystallisation at 1400 °C and a reference yield strength of 750 to 900 MPa, against 1100 °C for pure molybdenum | Oxygen and water vapour. TZM loses ductility at 500 ppm oxygen and is embrittled within hours at 1150 °C in low-pressure oxygen (ORNL-5431), so it is kept below 825 °C in oxidising service |
| Niobium (Nb) | Hot structures that must hold stress above 1000 °C: C-103 keeps a minimum yield strength of 124 MPa at 1093 °C in vacuum (Smiths datasheet, minimum values) | Oxidation in air: niobium begins to oxidise at 200 °C, and unprotected C-103 needs a coating above 800 °C. C103 is expensive because of its hafnium content (NASA Glenn), and the USGS reports 100 % net import reliance for the United States. |
| Niobium alloys (Nb alloys) | Hot load-bearing nozzles: C-103 keeps a minimum yield strength of 124 MPa at 1093 °C in vacuum (Smiths datasheet, minimum values) | Oxidation in air: all three need a protective coating above about 400 °C (Wikipedia). Niobium supply is concentrated in Brazil, which mines about 93 % of world niobium (USGS 2026). |
| Rhenium (Re) | Structures that must hold strength above 2000 °C: iridium-coated rhenium thrust chambers tested up to about 2200 °C | Oxidation in air or oxygen-rich gas above about 300 °C, which makes uncoated rhenium unusable without a protective coating |
| Tungsten-rhenium alloys (W-Re) | High-temperature thermocouples and X-ray target tracks, used in reducing, inert or vacuum conditions where pure tungsten is too brittle | Rapid oxidation at high temperature in air or other oxidising gas (the data sheet says not recommended there) |
| Tungsten heavy alloy (WHA) | Dense, stiff parts that must absorb X-rays and gamma rays, or sit as counterweights in a small volume (density 16.85 to 18.85 g/cc across ASTM B777 classes 1 to 4) | Ductility falls as tungsten rises: minimum elongation is 2 % in class 4. The binder contains nickel, a hazardous substance. No vacuum or flight result was found. |
| Tungsten-copper (W-Cu) | Heat sinks and electrical contacts: a thermal conductivity of 235 W/(m·K) at 20 °C with a low thermal expansion of 8.3 ppm/K in the Plansee WCu20 grade | Heavy, and it oxidises in hot air: density 15.15 g/cm3 for W80Cu20, and strong oxidation in air beginning around 400 °C |
| Silver-tungsten (W-Ag) | Electrical contacts for switchgear, relays and circuit breakers (uses listed by Goodfellow) | Tarnish in sulfur-containing air, and few sourced numbers: no thermal, flight or vacuum data for the composite was found in a readable source |
| Thoriated tungsten (WT20) | Direct-current TIG welding with constant-current transformer power sources (EWS) | Radioactive oxide content: the thorium needs dust control when the tip is ground, and the electrode is handled as a radioactive material |
| Vanadium | Alloying steel and aerospace titanium: no acceptable substitute exists for vanadium in aerospace titanium alloys (USGS 2026) | Fire and oxidation: fine powder is pyrophoric and bulk metal ignites above about 600 °C in air, and the oxide V2O5 is toxic (Goodfellow) |
| Vanadium alloys (V alloys) | Fusion first-wall and blanket structures that must carry load at high temperature with low activation (Argonne) | Oxygen and hydrogen pickup: the alloy embrittles after exposure to oxygen at 500 to 700 C, and vanadium-based membranes are highly susceptible to hydrogen embrittlement |
| Zirconium and Zircaloy (Zr) | Corrosion resistance in acids, especially hot nitric acid: 0.0 mpy for Zr 702 in 65 % nitric acid at 204 °C (ATI nitric acid sheet, Table 1) | Dry powder fire risk, delayed hydride cracking of Zircaloy cladding, and loss of strength when hot (Zr 702 yield 97.2 MPa at 316 °C) |
| Zirconium alloys (Zr alloys) | Nuclear fuel cladding and reactor pressure tubes, where low thermal neutron absorption (0.22 barns for Zircaloy-4) and corrosion resistance in water and steam both matter (ATI reactor-grade sheet) | Hydride embrittlement: hydrogen from water oxidation forms hydrides that blister and crack the cladding (Wikipedia), and hot hydrochloric acid still attacks Zircaloy-4 at 0.36 mm/a |
| Titanium hydride (TiH2) | Hydrogen reservoirs and foaming agents for metal powder processing (Albemarle grade N and the KTU aluminium foam paper), and zirconium hydride as a moderator with a high moderating ratio (ORNL Table 1) | Hydrogen loss on heating: TiH2 releases hydrogen from about 763 K, ZrH2 evolves hydrogen above 300 °C (ATI), and all three powders are flammable with a dust-explosion risk |
| Beryllium | Stiff, light structures and mirrors that must hold their shape when cold: 290 GPa modulus at 1.85 g/cm3 in the pure S-65 grade | Toxicity: inhaled dust or fume causes chronic beryllium disease, and the metal is hard and brittle with 3.0 % minimum elongation |