Materials/Metals and alloys/Collections

Refractory metals and carbides

refractory-metals

About refractory metals and carbides

Tungsten, tantalum and tungsten carbide: high-temperature and wear data with sources.

Refractory metals melt at very high temperatures and keep their strength when hot. Cemented tungsten carbide gets its hardness from tungsten carbide grains in a cobalt binder; its properties depend on the cobalt content and grain size.

At a glance

  • Highest yield strength: Zirconium alloys (Zr alloys) reaches 998 MPa. Lowest: Hafnium (Hf) starts at 151 MPa. (12 of 22 grades have a sourced value.)
  • Highest tensile strength: Zirconium alloys (Zr alloys) reaches 1,069 MPa. Lowest: Mo-30W starts at 170 MPa. (14 of 22 grades have a sourced value.)
  • Highest density: Rhenium (Re) reaches 21 g/cm³. Lowest: Beryllium starts at 1.85 g/cm³. (22 of 22 grades have a sourced value.)

Ranges run across the conditions each source reports (temper, heat treatment, form), measured at room temperature where the source says so.

How they compare

The same measurements for every material in the collection. A range means the grade has values under several conditions; "at least" means the source gives a specified minimum. "no data" means no sourced value yet. For ranked tables, open a benchmark.

Refractory metals and carbides: how the grades compare
MaterialYield strengthTensile strengthDensityYoung's modulusThermal conductivityMelting point
Tungsten (W)refractory metal no datano data19.3 g/cm³411 GPa174 W/(m·K)3,422 °C
Tungsten carbide (WC)wear-resistant hard phase, held together by a cobalt binder no datano data14.4 to 15.6 g/cm³530 to 700 GPa110 W/(m·K)no data
Tantalumdense refractory metal (radiation spot shielding, capacitor anodes) no datano data16.6 g/cm³no data57 W/(m·K)3,017 °C
Hafnium (Hf)nuclear control rod material and superalloy additive at least 151 MPaat least 400 MPa13.1 to 13.3 g/cm³137 GPa23 W/(m·K)2,233 °C
Molybdenumrefractory structural and alloying metal 265 MPa411 MPa10.2 g/cm³no data142 W/(m·K)2,623 °C
Mo-Reductile refractory alloy for space reactor cladding and structures, and for high-temperature thermoelements 557 MPa719 MPa14.6 g/cm³no datano dataat least 2,610 °C
Mo-30Whigh-temperature molybdenum-tungsten alloy for furnace hot zones, crucibles, zinc-bath heaters and sputtering targets no data170 to 385 MPa10.9 to 11.2 g/cm³no datano data2,829 °C
TZM molybdenum alloyhigh-temperature molybdenum alloy for furnace and hot-tool parts 750 to 900 MPa800 to 1,000 MPa10.2 g/cm³300 GPa130 W/(m·K)no data
Niobium (Nb)refractory metal for high-temperature rocket nozzles, steel microalloying and superconducting wire 276 MPa386 MPa8.58 to 8.86 g/cm³90 to 105 GPa53.7 W/(m·K)2,350 to 2,477 °C
Niobium alloys (Nb alloys)refractory niobium alloys for rocket and thruster nozzles, load-free thermal shields and alkali-metal containment 276 MPa386 MPa8.57 to 8.85 g/cm³90 GPa38.1 to 44.7 W/(m·K)2,350 to 2,410 °C
Rhenium (Re)high-temperature structural metal for thruster chambers and superalloys 200 to 500 MPa400 to 700 MPa21 g/cm³460 GPa48 W/(m·K)3,186 °C
Tungsten-rhenium alloys (W-Re)refractory alloy for high-temperature thermocouples, X-ray target tracks and nuclear-space design studies no data200 to 220 x 10^3 psi19.3 to 19.7 g/cm³no datano data3,120 to 3,350 °C
Tungsten heavy alloy (WHA)dense radiation shield, counterweight and mass material 517 MPa689 to 758 MPa16.9 to 18.9 g/cm³330 to 385 GPano datano data
Tungsten-copper (W-Cu)heat sink and electrical contact composite no data620 to 689 MPa14.5 to 15.5 g/cm³280 GPa180 to 235 W/(m·K)no data
Silver-tungsten (W-Ag)electrical contact and electrode composite no datano data11.8 to 16.1 g/cm³no datano datano data
Thoriated tungsten (WT20)TIG welding electrode and cathode material no datano data11.7 g/cm³411 GPa174 W/(m·K)3,422 °C
Vanadiumrefractory metal used mainly as an alloying element in steel and aerospace titanium alloys, and as the electrolyte element of vanadium redox flow batteries no datano data6.11 g/cm³128 GPa30.7 W/(m·K)1,900 to 1,910 °C
Vanadium alloys (V alloys)fusion first-wall and blanket structural alloys, and vanadium-based hydrogen-permeation membranes 402 MPa488 MPa6.05 g/cm³126 GPano data1,900 °C
Zirconium and Zircaloy (Zr)corrosion-resistant structural metal and nuclear cladding alloy 207 to 506 MPa379 to 615 MPa6.51 to 6.64 g/cm³94.7 to 99.3 GPa21.5 W/(m·K)1,840 to 1,852 °C
Zirconium alloys (Zr alloys)corrosion-resistant structural alloys for nuclear fuel cladding, reactor pressure tubes and chemical-process equipment 468 to 998 MPa515 to 1,069 MPa6.55 g/cm³99.3 GPa21.5 W/(m·K)1,850 °C
Titanium hydride (TiH2)hydrogen reservoir, foaming agent and neutron moderator (titanium, zirconium and hafnium hydrides) no datano data3.78 to 11.4 g/cm³no datano dataat least 400 °C
Berylliumstructural and optical metal at least 207 MPaat least 290 MPa1.85 g/cm³290 GPa216 W/(m·K)1,287 °C

What these materials are made of

Composition by weight, as printed in the sources for each grade (the first constituents listed).

Composition of each grade
MaterialMain constituents
Tungsten (W)W 100.0%
Tungsten carbide (WC)WC 90 to 94% · Co 6 to 10%
TantalumTa 100.0%
Hafnium (Hf)Hf 100.0%
MolybdenumMo 100.0%
Mo-ReMo 59% · Re 41%
Mo-30WMo balance · W 28 to 32%
TZM molybdenum alloyMo balance · Ti 0.5% · Zr 0.08% · C 0.01 to 0.04%
Rhenium (Re)Re 100.0%
Vanadium alloys (V alloys)V balance
Zirconium and Zircaloy (Zr)Sn 1.2 to 1.7% · Fe 0.18 to 0.24% · Cr 0.07 to 0.13%
Zirconium alloys (Zr alloys)Zr 95% · Sn 1.2 to 1.7% · Fe 0.18 to 0.24% · Cr 0.07 to 0.13% · Nb 2.4 to 2.8%
Titanium hydride (TiH2)Ti 15.0% · Zr 28.5% · Hf 55.8% · H 0.6%
BerylliumBe 99.2% · BeO 0.9% · C 0.09% · Fe 0.08% · Al 0.05%

Where they are used

Uses
UseGrades
Rocket nozzle throat insertsTungsten (W)
Gamma shield near a space nuclear reactorTungsten (W)
Heavy-alloy counterweights and vibration dampingTungsten (W)
Metal-machining cutting toolsTungsten carbide (WC)
Mining drill bits and rock drilling toolsTungsten carbide (WC)
Wear parts for tunnel boring, road construction and agricultureTungsten carbide (WC)
Spot shield on spacecraft electronics vaultTantalum
Tantalum capacitor anodeTantalum
Spot shield (NIST attenuation context)Tantalum
Control rods in nuclear reactorsHafnium (Hf)
Nickel-based superalloys for hot-end parts of jet enginesHafnium (Hf)
Liquid-rocket thruster nozzles (C103 alloy)Hafnium (Hf)
Alloying agent in steel, cast iron and superalloysMolybdenum
Conductive metal layers in thin-film transistorsMolybdenum
Resistance elements in electric furnacesMolybdenum
Fuel cladding and core structural material for spacecraft reactorsMo-Re

When each grade fits

Best use and weak spots of each grade
MaterialBest forWeakest at
Tungsten (W)Very high temperature parts, dense counterweights and gamma shielding where weight per unit of shielding matters more than costBrittle and hard to form or machine; oxidises in air when hot, so it needs protection above room temperature
Tungsten carbide (WC)Cutting and wear parts where hardness matters most (less cobalt, fine grain), and mining drill bits and crusher parts, which Hyperion's mining table lists in 6 percent cobalt gradesToughness: Hyperion ties high toughness to 10 to 20 percent binder and high hardness to sub-micron grains with 3 to 15 percent binder. The dust carries a cobalt and hardmetal health hazard and a rare fire risk (Sandvik SDS).
TantalumDense, high-melting spot shielding in thin sheet, such as the approximately 1 mm tantalum vault plate on NASA's Europa ClipperMass: the 16650 kg/m3 density makes it heavy for large areas, and the vault plate is only a local shield, not a full enclosure
Hafnium (Hf)Absorbing neutrons in reactor control rods (104 barns thermal neutron cross-section) and strengthening nickel superalloys (ATI)Fine powder and chips, which ignite in air (ATI, ESPI), and strength that depends strongly on oxygen, nitrogen and carbon pickup (ATI)
MolybdenumHigh-temperature strength and heat conduction: 2623 °C melting point and 142 W/(m·K) thermal conductivity at 20 °C, in vacuum or inert serviceOxidation in air above about 400 °C, where it forms volatile MoO3, and toughness at room temperature in as-rolled sheet (ductile-brittle transition above 25 °C in the NASA study)
Mo-ReStructural and cladding use at high temperature in vacuum or inert gas, for example fuel cladding and core structures in space reactors, where ductility must survive weldingOxidation in air above about 600 °C, and embrittlement by the sigma phase in Mo-47.5Re and by irradiation above about 1100 K
Mo-30WRefractory parts that must hold shape at high temperature in vacuum or inert furnaces, where the 2829 °C melting point and the 10.9 g/cm3 sintered minimum density are the reference figuresStrength falls off above about 1500 °C in the powder-metallurgy bar tested by Wang et al., and the zinc-bath factory test found aluminium in the bath attacks the alloy
TZM molybdenum alloyHigh-temperature strength in vacuum and inert furnaces: recrystallisation at 1400 °C and a reference yield strength of 750 to 900 MPa, against 1100 °C for pure molybdenumOxygen and water vapour. TZM loses ductility at 500 ppm oxygen and is embrittled within hours at 1150 °C in low-pressure oxygen (ORNL-5431), so it is kept below 825 °C in oxidising service
Niobium (Nb)Hot structures that must hold stress above 1000 °C: C-103 keeps a minimum yield strength of 124 MPa at 1093 °C in vacuum (Smiths datasheet, minimum values)Oxidation in air: niobium begins to oxidise at 200 °C, and unprotected C-103 needs a coating above 800 °C. C103 is expensive because of its hafnium content (NASA Glenn), and the USGS reports 100 % net import reliance for the United States.
Niobium alloys (Nb alloys)Hot load-bearing nozzles: C-103 keeps a minimum yield strength of 124 MPa at 1093 °C in vacuum (Smiths datasheet, minimum values)Oxidation in air: all three need a protective coating above about 400 °C (Wikipedia). Niobium supply is concentrated in Brazil, which mines about 93 % of world niobium (USGS 2026).
Rhenium (Re)Structures that must hold strength above 2000 °C: iridium-coated rhenium thrust chambers tested up to about 2200 °COxidation in air or oxygen-rich gas above about 300 °C, which makes uncoated rhenium unusable without a protective coating
Tungsten-rhenium alloys (W-Re)High-temperature thermocouples and X-ray target tracks, used in reducing, inert or vacuum conditions where pure tungsten is too brittleRapid oxidation at high temperature in air or other oxidising gas (the data sheet says not recommended there)
Tungsten heavy alloy (WHA)Dense, stiff parts that must absorb X-rays and gamma rays, or sit as counterweights in a small volume (density 16.85 to 18.85 g/cc across ASTM B777 classes 1 to 4)Ductility falls as tungsten rises: minimum elongation is 2 % in class 4. The binder contains nickel, a hazardous substance. No vacuum or flight result was found.
Tungsten-copper (W-Cu)Heat sinks and electrical contacts: a thermal conductivity of 235 W/(m·K) at 20 °C with a low thermal expansion of 8.3 ppm/K in the Plansee WCu20 gradeHeavy, and it oxidises in hot air: density 15.15 g/cm3 for W80Cu20, and strong oxidation in air beginning around 400 °C
Silver-tungsten (W-Ag)Electrical contacts for switchgear, relays and circuit breakers (uses listed by Goodfellow)Tarnish in sulfur-containing air, and few sourced numbers: no thermal, flight or vacuum data for the composite was found in a readable source
Thoriated tungsten (WT20)Direct-current TIG welding with constant-current transformer power sources (EWS)Radioactive oxide content: the thorium needs dust control when the tip is ground, and the electrode is handled as a radioactive material
VanadiumAlloying steel and aerospace titanium: no acceptable substitute exists for vanadium in aerospace titanium alloys (USGS 2026)Fire and oxidation: fine powder is pyrophoric and bulk metal ignites above about 600 °C in air, and the oxide V2O5 is toxic (Goodfellow)
Vanadium alloys (V alloys)Fusion first-wall and blanket structures that must carry load at high temperature with low activation (Argonne)Oxygen and hydrogen pickup: the alloy embrittles after exposure to oxygen at 500 to 700 C, and vanadium-based membranes are highly susceptible to hydrogen embrittlement
Zirconium and Zircaloy (Zr)Corrosion resistance in acids, especially hot nitric acid: 0.0 mpy for Zr 702 in 65 % nitric acid at 204 °C (ATI nitric acid sheet, Table 1)Dry powder fire risk, delayed hydride cracking of Zircaloy cladding, and loss of strength when hot (Zr 702 yield 97.2 MPa at 316 °C)
Zirconium alloys (Zr alloys)Nuclear fuel cladding and reactor pressure tubes, where low thermal neutron absorption (0.22 barns for Zircaloy-4) and corrosion resistance in water and steam both matter (ATI reactor-grade sheet)Hydride embrittlement: hydrogen from water oxidation forms hydrides that blister and crack the cladding (Wikipedia), and hot hydrochloric acid still attacks Zircaloy-4 at 0.36 mm/a
Titanium hydride (TiH2)Hydrogen reservoirs and foaming agents for metal powder processing (Albemarle grade N and the KTU aluminium foam paper), and zirconium hydride as a moderator with a high moderating ratio (ORNL Table 1)Hydrogen loss on heating: TiH2 releases hydrogen from about 763 K, ZrH2 evolves hydrogen above 300 °C (ATI), and all three powders are flammable with a dust-explosion risk
BerylliumStiff, light structures and mirrors that must hold their shape when cold: 290 GPa modulus at 1.85 g/cm3 in the pure S-65 gradeToxicity: inhaled dust or fume causes chronic beryllium disease, and the metal is hard and brittle with 3.0 % minimum elongation

Materials

refractory-metals/be
Refractory metals • 16 sourced entries • 8 sources • 2026
refractory-metals/hf
Refractory metals • 21 sourced entries • 8 sources • 2026
refractory-metals/mo-re
Refractory metals • 21 sourced entries • 13 sources • 2026
refractory-metals/mo-30w
Refractory metals • 9 sourced entries • 10 sources • 2026
refractory-metals/mo
Refractory metals • 16 sourced entries • 8 sources • 2026
refractory-metals/nb-alloys
Refractory metals • 20 sourced entries • 8 sources • 2026
refractory-metals/nb
Refractory metals • 24 sourced entries • 10 sources • 2026
refractory-metals/re
Refractory metals • 20 sourced entries • 8 sources • 2026
refractory-metals/w-ag
Refractory metals • 9 sourced entries • 8 sources • 2026
refractory-metals/ta
Spot shields • 24 sourced entries • 10 sources • 2026
refractory-metals/wt20
Refractory metals • 17 sourced entries • 6 sources • 2026
refractory-metals/tih2
Refractory metals • 37 sourced entries • 16 sources • 2026
refractory-metals/wc
Refractory metals • 26 sourced entries • 15 sources • 2026
refractory-metals/w-cu
Refractory metals • 19 sourced entries • 11 sources • 2026
refractory-metals/wha
Refractory metals • 27 sourced entries • 9 sources • 2026
refractory-metals/w-re
Refractory metals • 22 sourced entries • 15 sources • 2026
refractory-metals/w
Refractory metals • 21 sourced entries • 9 sources • 2026
refractory-metals/tzm
Refractory metals • 18 sourced entries • 9 sources • 2026
refractory-metals/v-alloys
Refractory metals • 14 sourced entries • 11 sources • 2026
refractory-metals/v
Refractory metals • 19 sourced entries • 8 sources • 2026
refractory-metals/zr-alloys
Refractory metals • 34 sourced entries • 8 sources • 2026
refractory-metals/zr
Refractory metals • 41 sourced entries • 8 sources • 2026