Stainless steel 440C 440C (UNS S44004)
Fe balance, 0.95 to 1.20 C, 16.0 to 18.0 Cr, 0.75 max Mo (Rolled Alloys and Carpenter
Also known as UNS S44004, EN 1.4125, JIS SUS440C, JIS G4303, AISI 440C, ASTM A 276 · 2 more
440C is the highest-carbon 400-series stainless steel, a martensitic iron alloy with 0.95 to 1.20 percent carbon and 16 to 18 percent chromium.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Recipe, share of the weight
- Fe balance (the rest)Iron
- C 0.95 to 1.2%Carbon
- Cr 16 to 18%Chromium
- Mo 0 to 0.75%Molybdenum
- Mn 0 to 1%Manganese
- Si 0 to 1%Silicon
- P 0 to 0.04%Phosphorus
- S 0 to 0.03%Sulfur
Best for
Bearings and valve parts that must be hard and wear-resistant in the hardened and tempered condition (Carpenter, Aalco, Rolled Alloys)
Weakest at
Corrosion resistance in the annealed state or after tempering above about 800 F (427 C), and service above about 400 C (NASA 2018 maximum use temperature)
Risk at a glance
- People Low. Welding fume is the main human-health watch point
- If it fails High. Ball wear in unlubricated sliding contact
- Corrosion Moderate. Lower corrosion resistance than the common austenitic grades.
Quick facts: 440C (UNS S44004)
| Property | Value | Basis |
|---|---|---|
| Density | 7.61 to 7.7 g/cm³ | 3 sourced values across conditions |
| Yield strength | 1,896 MPa | 2 sourced values across conditions |
| Tensile strength | 1,965 MPa | 2 sourced values across conditions |
| Young's modulus | 200 to 210 GPa | 4 sourced values across conditions |
| Thermal conductivity | 22.8 to 24.2 W/(m·K) | 3 sourced values across conditions |
| Thermal expansion (CTE) | 10 to 10.1 ppm/K | 3 sourced values across conditions |
| Melting point | 1,371 to 1,482 °C | 1 sourced value |
| Electrical resistivity | 6.0e-7 Ω·m | 2 sourced values across conditions |
| Maximum service temperature | 400 °C | 1 sourced value |
What is the density of Stainless steel 440C?
Stainless steel 440C has a density of 7.61 to 7.7 g/cm³. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the thermal conductivity of Stainless steel 440C?
Stainless steel 440C has a thermal conductivity of 22.8 to 24.2 W/(m·K). The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the coefficient of thermal expansion of Stainless steel 440C?
Stainless steel 440C has a coefficient of thermal expansion of 10 to 10.1 ppm/K. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the melting point of Stainless steel 440C?
Stainless steel 440C has a melting point of 1,371 to 1,482 °C. The source and test conditions are listed in the properties table on this page.
What is the yield strength of Stainless steel 440C?
Stainless steel 440C has a yield strength of 1,896 MPa. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What are the other names and codes for Stainless steel 440C?
Stainless steel 440C is also written as UNS S44004, EN 1.4125, JIS SUS440C, JIS G4303, AISI 440C, ASTM A 276. Each code is printed in the source listed beside it in the designations table.
What is Stainless steel 440C used for?
Uses recorded in the sources include Rolling-element bearings (ball and roller); Valve seats and valve parts; High-pressure oxygen turbopump bearings of the Space Shuttle main engine (HPOTP).
Why it exists
440C is a high-carbon martensitic stainless steel built for hardness. It is hardened by heat treatment, and Carpenter says it is used in the hardened plus tempered condition. Its main use is bearings and valve parts, and NASA studied 440C bearings in the Space Shuttle main engine's high-pressure oxygen turbopump. The trade-off is corrosion resistance: Carpenter says it falls in the annealed state and after tempering above about 800 F (427 C), and NASA's 2018 comparison rates it marginal.
Where it's used
Bearings and valve parts
Rolled Alloys, Aalco and UPMET all list bearings and valve parts (UPMET: ball bearings and valves). Aalco also lists high-quality knife blades, surgical instruments and chisels.
Space Shuttle main engine turbopump bearings
A 1984 NASA report on the high-pressure oxygen turbopump bearings measured 440C wear and tempering. It found that wear in unlubricated contact could explain the ball wear seen in service.
Space reaction-wheel bearing comparison (2018)
NASA Glenn's 2018 slides compare 440C with 60NiTi for space bearings. They credit 60NiTi bearing races with 2x (against Rex 20) to 5x (against 440C) improvement in a reaction-wheel bearing.
Recipe
Fe balance, 0.95 to 1.20 C, 16.0 to 18.0 Cr, 0.75 max Mo (Rolled Alloys and Carpenter; EN 10088-3 gives 0.40 to 0.80 Mo), 1.00 max Mn, 1.00 max Si, 0.04 max P, 0.03 max S (wt%)
440C is an iron-based martensitic stainless steel. Carbon (0.95 to 1.20 percent) is the highest of the 400 series, and chromium (16 to 18 percent) gives the stainless film. Rolled Alloys, Carpenter and Aalco print the same carbon and chromium limits, and Wikipedia gives the same ranges. Molybdenum is 0.75 percent maximum in Rolled Alloys and Carpenter, while EN 10088-3 (Aalco) allows 0.40 to 0.80 percent. The record gives limits, not a single analysis.
| Ingredient | Share of the weight | What it does |
|---|---|---|
| Iron Fe | balance (the rest) | The matrix. As a martensitic stainless steel it can be hardened by heat treatment (Rolled Alloys). |
| Carbon C | 0.95 to 1.2% | Gives the high hardness; Rolled Alloys calls 440C the highest carbon content of the 400 series stainless steels. |
| Chromium Cr | 16 to 18% | Keeps the stainless characteristics despite the high carbon (Rolled Alloys). |
| Molybdenum Mo | 0 to 0.75% | Maximum 0.75 (Rolled Alloys and Carpenter); EN 10088-3 allows 0.40 to 0.80 (Aalco). |
| Manganese Mn | 0 to 1% | Residual element, held to a maximum. |
| Silicon Si | 0 to 1% | Residual element, held to a maximum. |
| Phosphorus P | 0 to 0.04% | Impurity held to a maximum. |
| Sulfur S | 0 to 0.03% | Impurity held to a maximum. |
Weight shares are as printed in the sources.
What it can do
Hardness
Hardened and tempered, 440C reaches about HRC 60, the highest hardness of any stainless steel (Carpenter, Rolled Alloys). The temper sets it: 60 HRC after a one-hour temper at 300 F, and 56 HRC after tempering at 600 to 800 F (Rolled Alloys).
Strength
At the 600 F temper, Aircraft Materials gives 1965 MPa tensile and 1896 MPa yield, and Rolled Alloys gives 285 ksi and 275 ksi for the same heat treatment, with 2 percent elongation.
Stiffness
Young's modulus is 200 GPa in the Aalco, UPMET and NASA 2018 records.
Heat tolerance
In NASA's 1984 tests, tempering at 540 C (1000 F) for 10 to 945 s dropped hardness from HRC 60 only to HRC 57 to 58. Bulk bearing temperatures of 480 C (900 F) or more could not be tolerated in the turbopump bearings.
Service temperature
NASA Glenn gives about 400 C as the maximum use temperature of 440C in its 2018 comparison.
How it compares
Against common stainless steels, 440C trades corrosion resistance for hardness. Aalco says its corrosion resistance approximates that of 304 in many environments, and that martensitic grades resist corrosion less than the common austenitic grades. NASA's 2018 comparison rates 440C corrosion resistance as marginal and calls the austenitic 304 soft, while it lists 60NiTi, a superelastic bearing alloy, as excellent in aqueous and acidic service.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.
| Measurement | 440C (UNS S44004) | 410 (UNS S41000) | S41500 (F6NM forged, CA6NM cast) | 410S (UNS S41008) | 416 | 420 | 431 (UNS S43100, EN 1.4057) | 1.4418 (X4CrNiMo16-5-1) |
|---|---|---|---|---|---|---|---|---|
| Thermal behavior and safety | ||||||||
| Thermal conductivity | 24.2 W/m.K9 | 24.9 W/m-K | 25 W/(m K) | 26.9 W/m-K | 30 W/m K | 24.9 W/(m·K) | 25 W/(m·K) | 15 W/m K |
| Thermal conductivity | 24 W/m-°K10 | 24.9 W/m-K | 25 W/(m K) | 26.9 W/m-K | 30 W/m K | 24.9 W/(m·K) | 25 W/(m·K) | 15 W/m K |
| Thermal conductivity | 13.2 Btu·ft/ft2·hr·°F11 | 24.9 W/m-K | 25 W/(m K) | 26.9 W/m-K | 30 W/m K | 24.9 W/(m·K) | 25 W/(m·K) | 15 W/m K |
| melting point | 2500 to 2700 °F15 | 1482 to 1532 °C | no data | 1480 to 1530 °C | 2714 °F | 2650 to 2750 °F | no data | no data |
| Physical and electrical | ||||||||
| Density | 0.275 lb/in31 | 7.73 g/cm³ | 7.61 to 8.1 kg/dm3 | 7.73 g/cm³ | 7.7 kg/dm3 | 7.75 g/cm³ | 7800 kg/m3 | 7.7 kg/dm3 |
| Density | 7.65 g/cm³2 | 7.73 g/cm³ | 7.61 to 8.1 kg/dm3 | 7.73 g/cm³ | 7.7 kg/dm3 | 7.75 g/cm³ | 7800 kg/m3 | 7.7 kg/dm3 |
| Density | 7.7 g/cc3 | 7.73 g/cm³ | 7.61 to 8.1 kg/dm3 | 7.73 g/cm³ | 7.7 kg/dm3 | 7.75 g/cm³ | 7800 kg/m3 | 7.7 kg/dm3 |
| electrical resistivity | 0.6 10-6 ohm.m16 | 57 µohm-cm | no data | 60 µohm-cm | 0.6 Ω mm2/m | 0.55 µΩ·m | 0.7 ohm mm2/m | no data |
| electrical resistivity | 0.6 10-6 ohm.m17 | 57 µohm-cm | no data | 60 µohm-cm | 0.6 Ω mm2/m | 0.55 µΩ·m | 0.7 ohm mm2/m | no data |
| Rockwell C after a one-hour temper at 300 F | 60 HRC20 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Rockwell C after a one-hour temper at 400 F | 59 HRC21 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Rockwell C after a one-hour temper at 500 F | 57 HRC22 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Rockwell C after a one-hour temper at 600 F | 56 HRC23 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Rockwell C after a one-hour temper at 700 F | 56 HRC24 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Rockwell C after a one-hour temper at 800 F | 56 HRC25 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Annealed hardness (approximate) | 223 HB26 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Brinell hardness at the 600 F temper | 580 HB27 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| As heat treated, before any tempering | 60 HRC28 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| After tempering at 540 C for 10 to 945 s, from HRC 60 | 57 to 58 HRC29 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| After tempering at 650 C for 105 s, from HRC 60 | 50.5 HRC30 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| After tempering at 650 C for 420 s, from HRC 60 | 46.5 HRC31 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| After tempering at 760 C for 10 s, from HRC 60 | 44 HRC32 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| After tempering at 760 C for 105 s, from HRC 60 | 40 HRC33 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Hot hardness at 540 C, used HPOTP race | < 30 HRC34 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Hardness range as compared by NASA Glenn | 58 to 62 HRC35 | < 217 HB | < 320 HB | < 89 HRB | no data | no data | no data | < 320 HB |
| Other measurements | ||||||||
| elastic modulus | 200 GPa4 | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 215 kN/mm2 | 200 GPa |
| elastic modulus | 200 GPa5 | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 215 kN/mm2 | 200 GPa |
| elastic modulus | 200 GPa6 | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 215 kN/mm2 | 200 GPa |
| elastic modulus | 30.4 psi x 10^67 | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 200 GPa | 215 kN/mm2 | 200 GPa |
| poissons ratio | 0.3 -8 | 0.28 - | 0.27 to 0.3 - | no data | no data | 0.28 - | no data | no data |
| Thermal expansion (CTE) | 10.1 10-6/K12 | 9.9 µm/m-°C | no data | 10.8 µm/m·K | 10.5 10^-6/K | 10.3 10^-6/K | 10 ppm/K | 10.8 10-6 K-1 |
| Thermal expansion (CTE) | 10 10-6/°C13 | 9.9 µm/m-°C | no data | 10.8 µm/m·K | 10.5 10^-6/K | 10.3 10^-6/K | 10 ppm/K | 10.8 10-6 K-1 |
| Thermal expansion (CTE) | 5.6 in/in°F x 10^-614 | 9.9 µm/m-°C | no data | 10.8 µm/m·K | 10.5 10^-6/K | 10.3 10^-6/K | 10 ppm/K | 10.8 10-6 K-1 |
| Maximum service temperature | 400 °C18 | < 649 °C | 300 °C | < 705 °C | 675 °C | < 675 °C | 400 °C | 300 °C |
| fracture toughness | 22 MPa/√m19 | no data | no data | no data | no data | no data | no data | no data |
| ultimate tensile strength | 1965 MPa36 | 450 to 510 MPa | < 1100 MPa | > 60 ksi | 650 to 850 N/mm2 | 85.8 ksi | 862 MPa | 760 to 960 MPa |
| ultimate tensile strength | 285 ksi37 | 450 to 510 MPa | < 1100 MPa | > 60 ksi | 650 to 850 N/mm2 | 85.8 ksi | 862 MPa | 760 to 960 MPa |
| yield strength | 1896 MPa38 | 205 to 290 MPa | > 520 MPa | > 30 ksi | > 450 MPa | 51.5 ksi | 600 MPa | > 550 MPa |
| yield strength | 275 ksi39 | 205 to 290 MPa | > 520 MPa | > 30 ksi | > 450 MPa | 51.5 ksi | 600 MPa | > 550 MPa |
| elongation | 2 %40 | 20 to 34 % | 15 % | > 22 % | > 12 % | 12 to 13 % | 20 % | > 16 % |
| elongation | 2 %41 | 20 to 34 % | 15 % | > 22 % | > 12 % | 12 to 13 % | 20 % | > 16 % |
Why choose it, and why not
Good for
- Bearings, where hardness and wear resistance matter (Carpenter, Aalco, Rolled Alloys).
- Valve seats and valve parts (Aalco, Rolled Alloys, UPMET).
- Knife blades, surgical instruments and chisels (Aalco, UPMET).
Watch out for
- Corrosion. NASA rates it marginal, and Aalco says it is less corrosion resistant than the common austenitic grades.
- Tempering between 425 and 565 C, which reduces impact and corrosion resistance (Aalco).
- Long holds at 540 C (1000 F), or bulk temperatures of 480 C (900 F) and above, which take bearing hardness to unusable levels (NASA 1984).
- Welding, which is seldom done. Filler choice changes the weld hardness (Aalco, Rolled Alloys).
Of the stainless steels in these sources, 440C is the hardest when heat-treated, so it is the bearing and valve choice when hardness matters most. Accept its marginal corrosion resistance, keep the temper at or below about 800 F (427 C), and keep service below about 400 C.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Other names and standards
The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.
| System | Codes |
|---|---|
| UNS | S44004 |
| EN | 1.4125 |
| JIS | SUS440C, G4303 |
| AISI | 440C |
| ASTM | A 276 |
| AMS | 5630, 5880 |
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Density | Physical properties table as printed (Density: 0.275 lb/in3); the bulletin gives no SI value | temperature not statedheat treatment not stated | — |
| 2 | Density | Physical properties table as printed (Density 7.65 g/cm3) | standard EN 10088-3:2005 bartemperature not statedheat treatment not stated | — |
| 3 | Density | NASA Glenn 2018 comparison table, 440C column, printed as 7.7 g/cc | temperature not statedheat treatment not stated on the slide | — |
| 4 | elastic modulus | Physical properties table as printed (Modulus of Elasticity 200 GPa) | temperature not statedheat treatment not stated | — |
| 5 | elastic modulus | UPMET datasheet, Physical Properties table, printed as 200 GPa | temperature not statedheat treatment not printed on the datasheet | — |
| 6 | elastic modulus | NASA Glenn 2018 comparison table, printed as 200 GPa (Young's Modulus row) | temperature not statedheat treatment not stated on the slide | — |
| 7 | elastic modulus | Physical properties table, Modulus of Elasticity, Dynamic, printed as 30.4 psi x 10^6 at 70 F; dynamic, not the static value | temperature 70 Fheat treatment not statedbasis dynamic modulus, as printed | — |
| 8 | poissons ratio | NASA Glenn 2018 comparison table, printed as 0.3 for 440C | heat treatment not stated on the slide | — |
| 9 | Thermal conductivity | Physical properties table as printed (Thermal Conductivity 24.2 W/m.K) | temperature not stated | — |
| 10 | Thermal conductivity | NASA Glenn 2018 comparison table, printed as 24 W/m-°K for 440C | temperature not statedheat treatment not stated on the slide | — |
| 11 | Thermal conductivity | Physical properties table at 70 F, printed as 13.2 Btu ft/ft2 hr F (unit printed with bullets) | temperature 70 Fheat treatment not stated | — |
| 12 | Thermal expansion (CTE) | Physical properties table as printed (Thermal Expansion 10.1 x10^-6 /K); same unit written in short form | temperature not statedunit in source x10^-6 /K | — |
| 13 | Thermal expansion (CTE) | NASA Glenn 2018 comparison table, printed as 10x10^-6/°C for 440C | temperature not statedheat treatment not stated on the slide | — |
| 14 | Thermal expansion (CTE) | Physical properties table, coefficient marked with footnote: 70 F to indicated temperature; printed in inches per inch per F | temperature 70 F to the indicated temperature (table column at 70 F)heat treatment not stated | — |
| 15 | melting point | Physical properties table as printed (Melting Range 2500 - 2700 F) | temperature melting range as printedheat treatment not stated | — |
| 16 | electrical resistivity | Physical properties table as printed (Electrical Resistivity 0.6 x10^-6 Ω.m) | temperature not statedunit in source x10^-6 Ω.m | — |
| 17 | electrical resistivity | NASA Glenn 2018 comparison table, first table, printed as ~0.60x10^-6 Ω-m for 440C | temperature not statedheat treatment not stated on the slidebasis approximate, printed with a tilde | The second 440C table on the same slide prints about 36 x10^-6 Ω-cm, which conflicts; the first table is used. |
| 18 | Maximum service temperature | NASA Glenn 2018 comparison table, Maximum use temp row, printed as ~400 °C for 440C | basis maximum use temperature, printed as about 400 C (approximate)heat treatment not stated on the slide | Printed with a tilde (about 400 C); the slide does not give the basis or the temper. |
| 19 | fracture toughness | NASA Glenn 2018 comparison table, printed as 22 MPa/√m for 440C (Fracture toughness row); benchmark name is not in property-canon.yaml | heat treatment not stated on the slide | — |
| 20 | Rockwell C after a one-hour temper at 300 F | Typical Hardness table, Rockwell C row, as printed | heat treatment hardened 1900 F, oil quench, tempered one hour at 300 Fspecimen 1 in round | — |
| 21 | Rockwell C after a one-hour temper at 400 F | Typical Hardness table, Rockwell C row, as printed | heat treatment hardened 1900 F, oil quench, tempered one hour at 400 Fspecimen 1 in round | — |
| 22 | Rockwell C after a one-hour temper at 500 F | Typical Hardness table, Rockwell C row, as printed | heat treatment hardened 1900 F, oil quench, tempered one hour at 500 Fspecimen 1 in round | — |
| 23 | Rockwell C after a one-hour temper at 600 F | Typical Hardness table, Rockwell C row, as printed | heat treatment hardened 1900 F, oil quench, tempered one hour at 600 Fspecimen 1 in round | — |
| 24 | Rockwell C after a one-hour temper at 700 F | Typical Hardness table, Rockwell C row, as printed | heat treatment hardened 1900 F, oil quench, tempered one hour at 700 Fspecimen 1 in round | — |
| 25 | Rockwell C after a one-hour temper at 800 F | Typical Hardness table, Rockwell C row, as printed | heat treatment hardened 1900 F, oil quench, tempered one hour at 800 Fspecimen 1 in round | — |
| 26 | Annealed hardness (approximate) | Annealing paragraph, printed as Brinell hardness should be approximately 223 | heat treatment annealed: heat to 1550 to 1600 F, slow cool in the furnace | Approximate value, as printed. |
| 27 | Brinell hardness at the 600 F temper | Typical Mechanical Properties table, Brinell Hardness column, as printed | heat treatment hardened 1900 F, oil quench, tempered 600 Ftest temperature not printed | — |
| 28 | As heat treated, before any tempering | Tempering section, text: as-heat-treated material (HRC 60) | heat treatment heat treated to HRC 60 per the HPOTP bearing procedure, not tempered in this rowspecimen AISI 440C rods 7.9 mm diameter | — |
| 29 | After tempering at 540 C for 10 to 945 s, from HRC 60 | Short-term tempering results, printed as reduced the hardness from the initial value of HRC 60 to HRC 57-58 | heat treatment from HRC 60, tempered at 540 C (1000 F) for 10 to 945 stemperature 540 C (1000 F)time 10, 105 and 945 s | — |
| 30 | After tempering at 650 C for 105 s, from HRC 60 | Results text, printed as the hardness was reduced to HRC 50.5 at 105 seconds | heat treatment from HRC 60, tempered at 650 C (1200 F) for 105 stemperature 650 C (1200 F)time 105 s | — |
| 31 | After tempering at 650 C for 420 s, from HRC 60 | Results text, printed as the hardness was reduced to HRC 46.5 at 420 seconds | heat treatment from HRC 60, tempered at 650 C (1200 F) for 420 stemperature 650 C (1200 F)time 420 s | — |
| 32 | After tempering at 760 C for 10 s, from HRC 60 | Results text, printed as the hardness was reduced to HRC 44 in 10 seconds at 760 C | heat treatment from HRC 60, tempered at 760 C (1400 F) for 10 stemperature 760 C (1400 F)time 10 s | — |
| 33 | After tempering at 760 C for 105 s, from HRC 60 | Results text, printed as HRC 40 in 105 seconds at 760 C | heat treatment from HRC 60, tempered at 760 C (1400 F) for 105 stemperature 760 C (1400 F)time 105 s | The Figure 14 caption prints HRC 58 for 760 C at 105 s; the text value of HRC 40 is used. |
| 34 | Hot hardness at 540 C, used HPOTP race | Hot-Hardness Measurements section, printed as less than DPHN 300 (HRC 30) at 540 C (1000 F) | temperature 540 C (1000 F)specimen cut from a used HPOTP bearing race that measured HRC 50 at room temperaturetest hot-hardness apparatus; diamond pyramid hardness numbers converted in the text | — |
| 35 | Hardness range as compared by NASA Glenn | NASA Glenn 2018 comparison table, Hardness row, printed as 58 to 62 HRC for 440C | heat treatment not stated on the slide | — |
| 36 | ultimate tensile strength | Typical Mechanical Properties table, Ultimate Tensile Strength column (MPa), as printed | heat treatment hardened 1900 F, oil quench, tempered 600 Ftest temperature not printed | — |
| 37 | ultimate tensile strength | Representative Tensile Properties table, Ultimate Tensile Strength row, printed as 285 ksi | heat treatment hardened 1900 F, oil quench, tempered 600 Ftemperature 70 F | — |
| 38 | yield strength | Typical Mechanical Properties table, Yield Strength 0.2% (MPa) column, as printed | heat treatment hardened 1900 F, oil quench, tempered 600 Ftest temperature not printedbasis 0.2 percent offset yield, as printed | — |
| 39 | yield strength | Representative Tensile Properties table, 0.2% Yield Strength row, printed as 275 ksi | heat treatment hardened 1900 F, oil quench, tempered 600 Ftemperature 70 Fbasis 0.2 percent offset yield, as printed | — |
| 40 | elongation | Typical Mechanical Properties table, Elongation column, as printed | heat treatment hardened 1900 F, oil quench, tempered 600 Fgauge 2 in, as printed in the Elongation column | — |
| 41 | elongation | Representative Tensile Properties table, Elongation row, printed as 2 % | heat treatment hardened 1900 F, oil quench, tempered 600 Ftemperature 70 F | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Atmosphere, fresh water, foods, alkalies and mild acids | low | Good general resistance, best when hardened, tempered and passivated.1 |
| Compared with the common austenitic grades | moderate | Lower corrosion resistance than the common austenitic grades.2 |
| Many environments, compared with 304 | low | About the same as 304 in many environments.3 |
| Annealed condition, or hardened and tempered above about 800 F (427 C) | moderate | Corrosion resistance is reduced when annealed or tempered above 800 F.4 |
| Tempering between 425 and 565 C | moderate | Avoid this tempering range.5 |
| General corrosion, rated Marginal by NASA | moderate | NASA rates 440C corrosion resistance Marginal, and hard steels rust.6 |
| Overheating during grinding | moderate | Grinding heat lowers hardness and corrosion resistance.7 |
| Above the tempering temperature | not rated | Not recommended above the tempering temperature, because of over-tempering.8 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Atmosphere, fresh water, foods, alkalies and mild acids | Aalco: good resistance to the atmosphere, fresh water, foods, alkalies and mild acids, with the best resistance in the hardened, tempered and passivated condition. A smooth polished surface also helps. | best case hardened, tempered and passivated, polished |
| 2 | Compared with the common austenitic grades | Aalco: corrosion resistance is lower than the common austenitic grades, and the useful temperature range is limited by loss of ductility below zero and loss of strength by over-tempering at elevated temperatures. | — |
| 3 | Many environments, compared with 304 | Aalco: the corrosion resistance of 440C approximates that of 304 in many environments. | — |
| 4 | Annealed condition, or hardened and tempered above about 800 F (427 C) | Carpenter: 440C is not usually recommended for elevated temperature applications, since corrosion resistance is reduced when used in the annealed condition or hardened and tempered above about 800 F (427 C). | temperature above about 800 F (427 C) temper, or annealed |
| 5 | Tempering between 425 and 565 C | Aalco: tempering in the range 425 to 565 C is to be avoided because of reduced impact resistance and corrosion resistance. | temperature 425 to 565 C tempering |
| 6 | General corrosion, rated Marginal by NASA | NASA Glenn's 2018 comparison rates the corrosion resistance of 440C as Marginal, against Excellent for 60NiTi in aqueous and acidic service, and says hard steels are prone to rusting, even stainless steels like 440C. | — |
| 7 | Overheating during grinding | Rolled Alloys: do not overheat while grinding, since both the hardness and corrosion resistance may be lowered. | — |
| 8 | Above the tempering temperature | Aalco: not recommended for use in temperatures above the relevant tempering temperature, because mechanical properties are reduced by over-tempering. | — |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
No safety data sheet for 440C was reached. The hazard source found is a NIOSH-authored study of stainless steel welding fume.
- Welding fume
- In the NIOSH-authored study, the hexavalent chromium fraction of stainless steel welding fume ranged from 2800 to 34,000 ppm across eight process and shielding-gas combinations.
- Scope
- The study covers welding fume in general, not 440C alone, so treat it as a guide until a 440C safety data sheet is checked.
In service
NASA's 1984 study of turbopump bearings found that 440C softens with heat and wears fast when unlubricated.
- Heat
- Bulk bearing temperatures of 480 C (900 F) or more could not be tolerated, and hot hardness falls rapidly from 540 C (1000 F).
- Wear
- Unlubricated 440C wear rates were high enough to explain the ball wear seen in service.
Corrosion and temper
Corrosion resistance is best in the hardened, tempered and passivated condition (Aalco).
- Avoid
- Tempering between 425 and 565 C reduces impact and corrosion resistance (Aalco).
- Above 800 F
- Hardened and tempered above about 800 F (427 C), or annealed, the corrosion resistance is reduced (Carpenter).
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Ball wear in unlubricated sliding contacthigh severity | 440C in self-mated sliding contact without lubrication (liquid-nitrogen test rig)Wear rates were high enough to explain the ball wear sometimes seen in HPOTP bearings. |
| Softening from heathigh severity | Bulk bearing temperatures of 480 C (900 F) or more, or extended time at 540 C (1000 F)NASA 1984: hot hardness falls rapidly at 540 C (1000 F) and above, and at 760 C (1400 F) hardness fell from HRC 60 to HRC 44 in 10 s and HRC 40 in 105 s. |
| Over-temperingmoderate severity | Service or tempering above the tempering temperatureAalco: mechanical properties are reduced by over-tempering at elevated temperatures, so use above the tempering temperature is not recommended. |
| Rusting in moist or wet servicemoderate severity | Moisture or wet serviceNASA Glenn says hard steels are prone to rusting, even stainless steels such as 440C. |
| Soft or hard welds from the wrong fillermoderate severity | Choice of welding filler (Aalco lists 420, 309 and 310 fillers)Aalco: a grade 420 filler gives a high-hardness weld, while 309 or 310 gives soft welds with higher ductility. |
Handling and storage
- Machine in the annealed condition; once hardened, machining becomes much harder and probably impossible (Aalco). Chips are tough and stringy, so chip breakers matter (Aalco, Rolled Alloys).
- Do not overheat when grinding, since hardness and corrosion resistance can be lowered (Rolled Alloys).
- Hardening: heat to 1010 to 1065 C, then quench in warm oil or air, with oil for heavy sections (Aalco).
- Hardening: heat to 1850 to 1950 F, quench in warm oil or air, and temper immediately between 300 and 800 F, depending on the hardness wanted (Rolled Alloys).
- Weldability: if welding is needed, preheat to about 250 C and follow with a full anneal (Aalco).
- Weldability: Rolled Alloys preheats to about 500 F, welds, then anneals at 1350 to 1400 F for 6 to 8 hours, cooling slowly in the furnace.
Mitigations
- Keep the temper at or below about 800 F (427 C) where corrosion resistance matters (Carpenter).
- Avoid tempering between 425 and 565 C, the range that lowers impact and corrosion resistance; 590 to 675 C gives lower hardness and high impact resistance (Aalco).
- Short overheats are tolerable: tempering times of 10 seconds or less can be taken up to 650 C (1200 F) without significant hardness loss (NASA 1984).
- Weld with 309 or 310 filler when soft, ductile welds are wanted, since 420 gives a high-hardness weld (Aalco).
Supply and geography
How common the raw materials are and where they come from.
Chromium
World mine production about 51,000 thousand metric tons, gross weight, in 2025 (estimated). World resources are greater than 12 billion tons of shipping-grade chromite, 95 percent in Kazakhstan and southern Africa (USGS 2026).
- Top producers (2025)
- South Africa 45.1%, Turkey 17.6%, Kazakhstan 13.7%, India 5.9%, Brazil 3.9%, Zimbabwe 3.9%, Finland 3.7%
- Recycling
- Recycled chromium in reported stainless-steel scrap receipts was 21 percent of US apparent consumption in 2025 (USGS 2026).
- Substitutes
- Chromium has no substitute in stainless steel, the leading end use, or in superalloys (USGS 2026)
Chromium import reliance (United States)
US net import reliance was 79 percent of apparent consumption in 2025 (estimated). Chromite imports for 2021 to 2024 came from South Africa (96 percent) and Turkey (3 percent).
- Recycling
- Recycled chromium was 21 percent of US apparent consumption in 2025.
Molybdenum
World mine production 260,000 t of molybdenum content in 2025 (estimated). Identified resources are about 5.4 million tons in the United States and about 20 million tons in the rest of the world (USGS 2026).
- Top producers (2025)
- China 37.3%, Chile 16.2%, United States 15.4%, Peru 15%, Mexico 6.5%
- Recycling
- Molybdenum recycled from steel, superalloy and catalyst scrap may be as much as 30 percent of apparent supply (USGS 2026).
- Substitutes
- Little substitution in its main use in steels and cast irons; potential substitutes in alloy steels include boron, chromium, niobium and vanadium (USGS 2026)
Molybdenum trade and policy
The United States is a net exporter of molybdenum (USGS 2026), with 40,000 t of molybdenum content mine production in 2025 (estimated). China imposed export controls on molybdenum powders in February 2025.
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
Show the full YAML
spore: profile
id: stainless-440c
spore_version: 0.2
family: stainless-martensitic
name: Stainless steel 440C
abbreviation: 440C (UNS S44004)
role: high-carbon martensitic stainless steel for bearings and valve parts
category: metals
type: steels-and-stainless
summary: 440C is the highest-carbon 400-series stainless steel, a martensitic iron alloy with 0.95 to 1.20 percent carbon and 16 to 18 percent chromium. Heat-treated, it reaches about HRC 60, the highest hardness of any stainless steel in these sources, and its hardness depends on the temper. It is used mainly for ball and roller bearings and valve parts.
best_for: Bearings and valve parts that must be hard and wear-resistant in the hardened and tempered condition (Carpenter, Aalco, Rolled Alloys)
weakest_at: Corrosion resistance in the annealed state or after tempering above about 800 F (427 C), and service above about 400 C (NASA 2018 maximum use temperature)
identity:
formula: Fe balance, 0.95 to 1.20 C, 16.0 to 18.0 Cr, 0.75 max Mo (Rolled Alloys and Carpenter; EN 10088-3 gives 0.40 to 0.80 Mo), 1.00 max Mn, 1.00 max Si, 0.04 max P, 0.03 max S (wt%)
source: rolled-440c
where: Chemical composition table, Min and Max columns (Rolled Alloys bulletin 1142); EN 10088-3 Mo range from the Aalco datasheet
designations:
- system: UNS
code: S44004
source: rolled-440c
where: 'Specifications line (UNS: S44004); also UNS #S44004 on the Carpenter page'
- system: EN
code: '1.4125'
source: rolled-440c
where: 'Specifications line (W. Nr./EN: 1.4125); also 1.4125 in the Aalco datasheet title'
- system: JIS
code: SUS440C
source: patent-jp6207408
where: 'Background text: SUS440C (C: specified in JIS G4303 as martensitic stainless steel)'
- system: JIS
code: G4303
source: patent-jp6207408
where: Same background sentence; JIS G4303 cited as the standard for martensitic grades
- system: ASTM
code: A 276
source: rolled-440c
where: 'Specifications line (ASTM: A 276); printed as ASTM A276 on the Carpenter page and in the Aircraft Materials specification list'
- system: AMS
code: '5630'
source: rolled-440c
where: 'Specifications line (AMS: 5630, 5880)'
- system: AMS
code: '5880'
source: rolled-440c
where: 'Specifications line (AMS: 5630, 5880)'
- system: AISI
code: 440C
source: aircraft-materials-440c
where: Title line (Alloy 440C / AISI 440C / AMS 5630)
tags:
environments: []
stresses: []
applications:
- mechanisms
- propulsion-and-tanks
properties:
- benchmark: density
value: 0.275
unit: lb/in3
scope: material
conditions:
temperature: not stated
heat_treatment: not stated
method: 'Physical properties table as printed (Density: 0.275 lb/in3); the bulletin gives no SI value'
status: ground
source: rolled-440c
where: Physical Properties table (Density row)
- benchmark: density
value: 7.65
unit: g/cm3
scope: material
conditions:
standard: EN 10088-3:2005 bar
temperature: not stated
heat_treatment: not stated
method: Physical properties table as printed (Density 7.65 g/cm3)
status: ground
source: aalco-440c-bar
where: Physical Properties table (Density row)
- benchmark: density
value: 7.7
unit: g/cc
scope: material
conditions:
temperature: not stated
heat_treatment: not stated on the slide
method: NASA Glenn 2018 comparison table, 440C column, printed as 7.7 g/cc
status: ground
source: nasa-2018-ntrs
where: Technical Properties Comparison table, first table (Density row)
- benchmark: elastic_modulus
value: 200
unit: GPa
scope: material
conditions:
temperature: not stated
heat_treatment: not stated
method: Physical properties table as printed (Modulus of Elasticity 200 GPa)
status: ground
source: aalco-440c-bar
where: Physical Properties table (Modulus of Elasticity row)
- benchmark: elastic_modulus
value: 200
unit: GPa
scope: material
conditions:
temperature: not stated
heat_treatment: not printed on the datasheet
method: UPMET datasheet, Physical Properties table, printed as 200 GPa
status: ground
source: upmet-440c
where: Physical Properties table (Elastic Modulus row)
- benchmark: elastic_modulus
value: 200
unit: GPa
scope: material
conditions:
temperature: not stated
heat_treatment: not stated on the slide
method: NASA Glenn 2018 comparison table, printed as 200 GPa (Young's Modulus row)
status: ground
source: nasa-2018-ntrs
where: Technical Properties Comparison table (Young's Modulus row)
- benchmark: elastic_modulus
value: 30.4
unit: psi x 10^6
scope: material
conditions:
temperature: 70 F
heat_treatment: not stated
basis: dynamic modulus, as printed
method: Physical properties table, Modulus of Elasticity, Dynamic, printed as 30.4 psi x 10^6 at 70 F; dynamic, not the static value
status: ground
source: rolled-440c
where: Physical Properties table (Modulus of Elasticity, Dynamic row)
- benchmark: poissons_ratio
value: 0.3
unit: '-'
scope: material
conditions:
heat_treatment: not stated on the slide
method: NASA Glenn 2018 comparison table, printed as 0.3 for 440C
status: ground
source: nasa-2018-ntrs
where: Technical Properties Comparison table (Poisson's ratio row)
- benchmark: thermal_conductivity
value: 24.2
unit: W/m.K
scope: material
conditions:
temperature: not stated
method: Physical properties table as printed (Thermal Conductivity 24.2 W/m.K)
status: ground
source: aalco-440c-bar
where: Physical Properties table (Thermal Conductivity row)
- benchmark: thermal_conductivity
value: 24
unit: W/m-°K
scope: material
conditions:
temperature: not stated
heat_treatment: not stated on the slide
method: NASA Glenn 2018 comparison table, printed as 24 W/m-°K for 440C
status: ground
source: nasa-2018-ntrs
where: Technical Properties Comparison table (Thermal conductivity row)
- benchmark: thermal_conductivity
value: 13.2
unit: Btu·ft/ft2·hr·°F
scope: material
conditions:
temperature: 70 F
heat_treatment: not stated
method: Physical properties table at 70 F, printed as 13.2 Btu ft/ft2 hr F (unit printed with bullets)
status: ground
source: rolled-440c
where: Physical Properties table (Thermal Conductivity row, temperature column 70)
- benchmark: cte
value: 10.1
unit: 10-6/K
scope: material
conditions:
temperature: not stated
unit_in_source: x10^-6 /K
method: Physical properties table as printed (Thermal Expansion 10.1 x10^-6 /K); same unit written in short form
status: ground
source: aalco-440c-bar
where: Physical Properties table (Thermal Expansion row)
- benchmark: cte
value: 10
unit: 10-6/°C
scope: material
conditions:
temperature: not stated
heat_treatment: not stated on the slide
method: NASA Glenn 2018 comparison table, printed as 10x10^-6/°C for 440C
status: ground
source: nasa-2018-ntrs
where: Technical Properties Comparison table (Thermal expansion row)
- benchmark: cte
value: 5.6
unit: in/in°F x 10^-6
scope: material
conditions:
temperature: 70 F to the indicated temperature (table column at 70 F)
heat_treatment: not stated
method: 'Physical properties table, coefficient marked with footnote: 70 F to indicated temperature; printed in inches per inch per F'
status: ground
source: rolled-440c
where: Physical Properties table (Coefficient of Thermal Expansion row and footnote)
- benchmark: melting_point
value: 2500
value_high: 2700
bound: range
unit: °F
scope: material
conditions:
temperature: melting range as printed
heat_treatment: not stated
method: Physical properties table as printed (Melting Range 2500 - 2700 F)
status: ground
source: rolled-440c
where: Physical Properties table (Melting Range row)
- benchmark: electrical_resistivity
value: 0.6
unit: 10-6 ohm.m
scope: material
conditions:
temperature: not stated
unit_in_source: x10^-6 Ω.m
method: Physical properties table as printed (Electrical Resistivity 0.6 x10^-6 Ω.m)
status: ground
source: aalco-440c-bar
where: Physical Properties table (Electrical Resistivity row)
- benchmark: electrical_resistivity
value: 0.6
unit: 10-6 ohm.m
scope: material
conditions:
temperature: not stated
heat_treatment: not stated on the slide
basis: approximate, printed with a tilde
method: NASA Glenn 2018 comparison table, first table, printed as ~0.60x10^-6 Ω-m for 440C
status: ground
note: The second 440C table on the same slide prints about 36 x10^-6 Ω-cm, which conflicts; the first table is used.
source: nasa-2018-ntrs
where: Technical Properties Comparison table, first table (Electrical resistivity row)
- benchmark: max_service_temp
value: 400
unit: °C
scope: material
conditions:
basis: maximum use temperature, printed as about 400 C (approximate)
heat_treatment: not stated on the slide
method: NASA Glenn 2018 comparison table, Maximum use temp row, printed as ~400 °C for 440C
status: ground
note: Printed with a tilde (about 400 C); the slide does not give the basis or the temper.
source: nasa-2018-ntrs
where: Technical Properties Comparison table (Maximum use temp row)
- benchmark: fracture_toughness
value: 22
unit: MPa/√m
scope: material
conditions:
heat_treatment: not stated on the slide
method: NASA Glenn 2018 comparison table, printed as 22 MPa/√m for 440C (Fracture toughness row); benchmark name is not in property-canon.yaml
status: ground
source: nasa-2018-ntrs
where: Technical Properties Comparison table (Fracture toughness row)
- benchmark: hardness
label: Rockwell C after a one-hour temper at 300 F
value: 60
unit: HRC
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered one hour at 300 F
specimen: 1 in round
method: Typical Hardness table, Rockwell C row, as printed
status: ground
source: rolled-440c
where: Typical Hardness table (300 F column)
- benchmark: hardness
label: Rockwell C after a one-hour temper at 400 F
value: 59
unit: HRC
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered one hour at 400 F
specimen: 1 in round
method: Typical Hardness table, Rockwell C row, as printed
status: ground
source: rolled-440c
where: Typical Hardness table (400 F column)
- benchmark: hardness
label: Rockwell C after a one-hour temper at 500 F
value: 57
unit: HRC
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered one hour at 500 F
specimen: 1 in round
method: Typical Hardness table, Rockwell C row, as printed
status: ground
source: rolled-440c
where: Typical Hardness table (500 F column)
- benchmark: hardness
label: Rockwell C after a one-hour temper at 600 F
value: 56
unit: HRC
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered one hour at 600 F
specimen: 1 in round
method: Typical Hardness table, Rockwell C row, as printed
status: ground
source: rolled-440c
where: Typical Hardness table (600 F column)
- benchmark: hardness
label: Rockwell C after a one-hour temper at 700 F
value: 56
unit: HRC
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered one hour at 700 F
specimen: 1 in round
method: Typical Hardness table, Rockwell C row, as printed
status: ground
source: rolled-440c
where: Typical Hardness table (700 F column)
- benchmark: hardness
label: Rockwell C after a one-hour temper at 800 F
value: 56
unit: HRC
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered one hour at 800 F
specimen: 1 in round
method: Typical Hardness table, Rockwell C row, as printed
status: ground
source: rolled-440c
where: Typical Hardness table (800 F column)
- benchmark: hardness
label: Annealed hardness (approximate)
value: 223
unit: HB
scope: material
conditions:
heat_treatment: 'annealed: heat to 1550 to 1600 F, slow cool in the furnace'
method: Annealing paragraph, printed as Brinell hardness should be approximately 223
status: ground
note: Approximate value, as printed.
source: rolled-440c
where: Annealing paragraph
- benchmark: hardness
label: Brinell hardness at the 600 F temper
value: 580
unit: HB
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered 600 F
test_temperature: not printed
method: Typical Mechanical Properties table, Brinell Hardness column, as printed
status: ground
source: aircraft-materials-440c
where: Typical Mechanical Properties table (Alloy 440C row, Brinell Hardness)
- benchmark: hardness
label: As heat treated, before any tempering
value: 60
unit: HRC
scope: material
conditions:
heat_treatment: heat treated to HRC 60 per the HPOTP bearing procedure, not tempered in this row
specimen: AISI 440C rods 7.9 mm diameter
method: 'Tempering section, text: as-heat-treated material (HRC 60)'
status: ground
source: nasa-1984-ntrs
where: Tempering Behavior and Hot Hardness section (Specimens; Figure 14 text)
- benchmark: hardness
label: After tempering at 540 C for 10 to 945 s, from HRC 60
value: 57
value_high: 58
bound: range
unit: HRC
scope: material
conditions:
heat_treatment: from HRC 60, tempered at 540 C (1000 F) for 10 to 945 s
temperature: 540 C (1000 F)
time: 10, 105 and 945 s
method: Short-term tempering results, printed as reduced the hardness from the initial value of HRC 60 to HRC 57-58
status: ground
source: nasa-1984-ntrs
where: Short-Term Tempering Behavior, Results
- benchmark: hardness
label: After tempering at 650 C for 105 s, from HRC 60
value: 50.5
unit: HRC
scope: material
conditions:
heat_treatment: from HRC 60, tempered at 650 C (1200 F) for 105 s
temperature: 650 C (1200 F)
time: 105 s
method: Results text, printed as the hardness was reduced to HRC 50.5 at 105 seconds
status: ground
source: nasa-1984-ntrs
where: Short-Term Tempering Behavior, Results (text after Figure 12)
- benchmark: hardness
label: After tempering at 650 C for 420 s, from HRC 60
value: 46.5
unit: HRC
scope: material
conditions:
heat_treatment: from HRC 60, tempered at 650 C (1200 F) for 420 s
temperature: 650 C (1200 F)
time: 420 s
method: Results text, printed as the hardness was reduced to HRC 46.5 at 420 seconds
status: ground
source: nasa-1984-ntrs
where: Short-Term Tempering Behavior, Results (text after Figure 12)
- benchmark: hardness
label: After tempering at 760 C for 10 s, from HRC 60
value: 44
unit: HRC
scope: material
conditions:
heat_treatment: from HRC 60, tempered at 760 C (1400 F) for 10 s
temperature: 760 C (1400 F)
time: 10 s
method: Results text, printed as the hardness was reduced to HRC 44 in 10 seconds at 760 C
status: ground
source: nasa-1984-ntrs
where: Short-Term Tempering Behavior, Results (text after Figure 12)
- benchmark: hardness
label: After tempering at 760 C for 105 s, from HRC 60
value: 40
unit: HRC
scope: material
conditions:
heat_treatment: from HRC 60, tempered at 760 C (1400 F) for 105 s
temperature: 760 C (1400 F)
time: 105 s
method: Results text, printed as HRC 40 in 105 seconds at 760 C
status: ground
note: The Figure 14 caption prints HRC 58 for 760 C at 105 s; the text value of HRC 40 is used.
source: nasa-1984-ntrs
where: Short-Term Tempering Behavior, Results (text after Figure 12)
- benchmark: hardness
label: Hot hardness at 540 C, used HPOTP race
value: 30
bound: upper
unit: HRC
scope: material
conditions:
temperature: 540 C (1000 F)
specimen: cut from a used HPOTP bearing race that measured HRC 50 at room temperature
test: hot-hardness apparatus; diamond pyramid hardness numbers converted in the text
method: Hot-Hardness Measurements section, printed as less than DPHN 300 (HRC 30) at 540 C (1000 F)
status: ground
source: nasa-1984-ntrs
where: Hot-Hardness Measurements section (Figure 15 discussion)
- benchmark: hardness
label: Hardness range as compared by NASA Glenn
value: 58
value_high: 62
bound: range
unit: HRC
scope: material
conditions:
heat_treatment: not stated on the slide
method: NASA Glenn 2018 comparison table, Hardness row, printed as 58 to 62 HRC for 440C
status: ground
source: nasa-2018-ntrs
where: Technical Properties Comparison table (Hardness row, 440C column)
- benchmark: ultimate_tensile_strength
value: 1965
unit: MPa
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered 600 F
test_temperature: not printed
method: Typical Mechanical Properties table, Ultimate Tensile Strength column (MPa), as printed
status: ground
source: aircraft-materials-440c
where: Typical Mechanical Properties table (Alloy 440C row, Ultimate Tensile Strength column)
- benchmark: ultimate_tensile_strength
value: 285
unit: ksi
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered 600 F
temperature: 70 F
method: Representative Tensile Properties table, Ultimate Tensile Strength row, printed as 285 ksi
status: ground
source: rolled-440c
where: Mechanical Properties table (Representative Tensile Properties, Ultimate Tensile Strength row)
- benchmark: yield_strength
value: 1896
unit: MPa
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered 600 F
test_temperature: not printed
basis: 0.2 percent offset yield, as printed
method: Typical Mechanical Properties table, Yield Strength 0.2% (MPa) column, as printed
status: ground
source: aircraft-materials-440c
where: Typical Mechanical Properties table (Yield Strength column)
- benchmark: yield_strength
value: 275
unit: ksi
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered 600 F
temperature: 70 F
basis: 0.2 percent offset yield, as printed
method: Representative Tensile Properties table, 0.2% Yield Strength row, printed as 275 ksi
status: ground
source: rolled-440c
where: Mechanical Properties table (0.2% Yield Strength row)
- benchmark: elongation
value: 2
unit: '%'
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered 600 F
gauge: 2 in, as printed in the Elongation column
method: Typical Mechanical Properties table, Elongation column, as printed
status: ground
source: aircraft-materials-440c
where: Typical Mechanical Properties table (Elongation column)
- benchmark: elongation
value: 2
unit: '%'
scope: material
conditions:
heat_treatment: hardened 1900 F, oil quench, tempered 600 F
temperature: 70 F
method: Representative Tensile Properties table, Elongation row, printed as 2 %
status: ground
source: rolled-440c
where: Mechanical Properties table (Elongation row)
corrosion:
- environment: Atmosphere, fresh water, foods, alkalies and mild acids
headline: Good general resistance, best when hardened, tempered and passivated.
effect: 'Aalco: good resistance to the atmosphere, fresh water, foods, alkalies and mild acids, with the best resistance in the hardened, tempered and passivated condition. A smooth polished surface also helps.'
rating: low
conditions:
best_case: hardened, tempered and passivated, polished
source: aalco-440c-bar
where: Corrosion Resistance section
- environment: Compared with the common austenitic grades
headline: Lower corrosion resistance than the common austenitic grades.
effect: 'Aalco: corrosion resistance is lower than the common austenitic grades, and the useful temperature range is limited by loss of ductility below zero and loss of strength by over-tempering at elevated temperatures.'
rating: moderate
source: aalco-440c-bar
where: Martensitic stainless steels paragraph
- environment: Many environments, compared with 304
headline: About the same as 304 in many environments.
effect: 'Aalco: the corrosion resistance of 440C approximates that of 304 in many environments.'
rating: low
source: aalco-440c-bar
where: Corrosion Resistance section
- environment: Annealed condition, or hardened and tempered above about 800 F (427 C)
headline: Corrosion resistance is reduced when annealed or tempered above 800 F.
effect: 'Carpenter: 440C is not usually recommended for elevated temperature applications, since corrosion resistance is reduced when used in the annealed condition or hardened and tempered above about 800 F (427 C).'
rating: moderate
conditions:
temperature: above about 800 F (427 C) temper, or annealed
source: carpenter-440c
where: Product description paragraph
- environment: Tempering between 425 and 565 C
headline: Avoid this tempering range.
effect: 'Aalco: tempering in the range 425 to 565 C is to be avoided because of reduced impact resistance and corrosion resistance.'
rating: moderate
conditions:
temperature: 425 to 565 C tempering
source: aalco-440c-bar
where: Heat Treatment section
- environment: General corrosion, rated Marginal by NASA
headline: NASA rates 440C corrosion resistance Marginal, and hard steels rust.
effect: NASA Glenn's 2018 comparison rates the corrosion resistance of 440C as Marginal, against Excellent for 60NiTi in aqueous and acidic service, and says hard steels are prone to rusting, even stainless steels like 440C.
rating: moderate
source: nasa-2018-ntrs
where: Technical Properties Comparison table (Corrosion resistance row); Materials Requirements slide
- environment: Overheating during grinding
headline: Grinding heat lowers hardness and corrosion resistance.
effect: 'Rolled Alloys: do not overheat while grinding, since both the hardness and corrosion resistance may be lowered.'
rating: moderate
source: rolled-440c
where: Grinding and Polishing section
- environment: Above the tempering temperature
headline: Not recommended above the tempering temperature, because of over-tempering.
effect: 'Aalco: not recommended for use in temperatures above the relevant tempering temperature, because mechanical properties are reduced by over-tempering.'
rating: unknown
source: aalco-440c-bar
where: Heat Resistance section
risks:
hazards:
- text: In a NIOSH-authored study of stainless steel welding fume, the hexavalent chromium fraction ranged from 2800 to 34,000 ppm across eight welding process and shielding-gas combinations, and generation rates ranged from 69 to 7800 ug/min.
ghs: []
source: pmc-cr6-welding
where: Abstract (Cr6+ fraction and generation rate results)
failure_risks:
- mode: Ball wear in unlubricated sliding contact
trigger: 440C in self-mated sliding contact without lubrication (liquid-nitrogen test rig)
consequence: Wear rates were high enough to explain the ball wear sometimes seen in HPOTP bearings.
severity: high
source: nasa-1984-ntrs
where: Summary
- mode: Softening from heat
trigger: Bulk bearing temperatures of 480 C (900 F) or more, or extended time at 540 C (1000 F)
consequence: 'NASA 1984: hot hardness falls rapidly at 540 C (1000 F) and above, and at 760 C (1400 F) hardness fell from HRC 60 to HRC 44 in 10 s and HRC 40 in 105 s.'
severity: high
source: nasa-1984-ntrs
where: Summary; Hot-Hardness Measurements section; Results text
- mode: Over-tempering
trigger: Service or tempering above the tempering temperature
consequence: 'Aalco: mechanical properties are reduced by over-tempering at elevated temperatures, so use above the tempering temperature is not recommended.'
severity: moderate
source: aalco-440c-bar
where: Martensitic stainless steels paragraph; Heat Resistance section
- mode: Rusting in moist or wet service
trigger: Moisture or wet service
consequence: NASA Glenn says hard steels are prone to rusting, even stainless steels such as 440C.
severity: moderate
source: nasa-2018-ntrs
where: Materials Requirements slide (Technical Challenge list)
- mode: Soft or hard welds from the wrong filler
trigger: Choice of welding filler (Aalco lists 420, 309 and 310 fillers)
consequence: 'Aalco: a grade 420 filler gives a high-hardness weld, while 309 or 310 gives soft welds with higher ductility.'
severity: moderate
source: aalco-440c-bar
where: Weldability section
side_effects: []
handling:
- text: Machine in the annealed condition; once hardened, machining becomes much harder and probably impossible (Aalco). Chips are tough and stringy, so chip breakers matter (Aalco, Rolled Alloys).
source: aalco-440c-bar
where: Machinability section
- text: Do not overheat when grinding, since hardness and corrosion resistance can be lowered (Rolled Alloys).
source: rolled-440c
where: Grinding and Polishing section
- text: 'Hardening: heat to 1010 to 1065 C, then quench in warm oil or air, with oil for heavy sections (Aalco).'
source: aalco-440c-bar
where: Heat Treatment section (Hardening)
- text: 'Hardening: heat to 1850 to 1950 F, quench in warm oil or air, and temper immediately between 300 and 800 F, depending on the hardness wanted (Rolled Alloys).'
source: rolled-440c
where: Hardening section
- text: 'Weldability: if welding is needed, preheat to about 250 C and follow with a full anneal (Aalco).'
source: aalco-440c-bar
where: Weldability section
- text: 'Weldability: Rolled Alloys preheats to about 500 F, welds, then anneals at 1350 to 1400 F for 6 to 8 hours, cooling slowly in the furnace.'
source: rolled-440c
where: Weldability section
mitigations:
- text: Keep the temper at or below about 800 F (427 C) where corrosion resistance matters (Carpenter).
source: carpenter-440c
where: Product description paragraph
- text: Avoid tempering between 425 and 565 C, the range that lowers impact and corrosion resistance; 590 to 675 C gives lower hardness and high impact resistance (Aalco).
source: aalco-440c-bar
where: Heat Treatment section
- text: 'Short overheats are tolerable: tempering times of 10 seconds or less can be taken up to 650 C (1200 F) without significant hardness loss (NASA 1984).'
source: nasa-1984-ntrs
where: Summary
- text: Weld with 309 or 310 filler when soft, ductile welds are wanted, since 420 gives a high-hardness weld (Aalco).
source: aalco-440c-bar
where: Weldability section
uses:
- application: mechanisms
device: Rolling-element bearings (ball and roller)
example: Carpenter says 440C has been used primarily as a bearing steel, in the hardened plus tempered condition.
source: carpenter-440c
where: Product description paragraph
- application: mechanisms
device: Valve seats and valve parts
example: Aalco lists valve seats and says 440C is particularly suited to ball bearings and valve parts; UPMET lists ball bearings and valves.
source: aalco-440c-bar
where: Applications list (Valve seats)
- application: propulsion-and-tanks
device: High-pressure oxygen turbopump bearings of the Space Shuttle main engine (HPOTP)
example: NASA's 1984 Battelle report measured 440C wear and tempering for these bearings and found that unlubricated 440C wear could explain the ball wear seen in service.
source: nasa-1984-ntrs
where: Introduction and Summary
- application: mechanisms
device: Bearing races in spacecraft reaction-wheel assemblies (NASA comparison)
example: NASA Glenn's 2018 slides compare 440C with 60NiTi and credit 60NiTi bearing races with 2x (against Rex 20) to 5x (against 440C) improvement in a reaction-wheel bearing.
source: nasa-2018-ntrs
where: Space Bearing Application slide (Typical Reaction Wheel Assembly)
supply:
- subject: Chromium
abundance: World mine production about 51,000 thousand metric tons, gross weight, in 2025 (estimated). World resources are greater than 12 billion tons of shipping-grade chromite, 95 percent in Kazakhstan and southern Africa (USGS 2026).
producers:
- country: South Africa
share_percent: 45.1
year: 2025
- country: Turkey
share_percent: 17.6
year: 2025
- country: Kazakhstan
share_percent: 13.7
year: 2025
- country: India
share_percent: 5.9
year: 2025
- country: Brazil
share_percent: 3.9
year: 2025
- country: Zimbabwe
share_percent: 3.9
year: 2025
- country: Finland
share_percent: 3.7
year: 2025
critical_lists: []
recycling: Recycled chromium in reported stainless-steel scrap receipts was 21 percent of US apparent consumption in 2025 (USGS 2026).
substitutes:
- Chromium has no substitute in stainless steel, the leading end use, or in superalloys (USGS 2026)
source: usgs-chromium-2026
where: World Mine Production and Reserves table (2025e, gross weight; shares computed from the printed tonnage); World Resources; Substitutes; Recycling
- subject: Chromium import reliance (United States)
abundance: US net import reliance was 79 percent of apparent consumption in 2025 (estimated). Chromite imports for 2021 to 2024 came from South Africa (96 percent) and Turkey (3 percent).
producers: []
critical_lists: []
recycling: Recycled chromium was 21 percent of US apparent consumption in 2025.
substitutes: []
source: usgs-chromium-2026
where: Salient Statistics (Net import reliance row); Import Sources (2021-24)
- subject: Molybdenum
abundance: World mine production 260,000 t of molybdenum content in 2025 (estimated). Identified resources are about 5.4 million tons in the United States and about 20 million tons in the rest of the world (USGS 2026).
producers:
- country: China
share_percent: 37.3
year: 2025
- country: Chile
share_percent: 16.2
year: 2025
- country: United States
share_percent: 15.4
year: 2025
- country: Peru
share_percent: 15
year: 2025
- country: Mexico
share_percent: 6.5
year: 2025
critical_lists: []
recycling: Molybdenum recycled from steel, superalloy and catalyst scrap may be as much as 30 percent of apparent supply (USGS 2026).
substitutes:
- Little substitution in its main use in steels and cast irons; potential substitutes in alloy steels include boron, chromium, niobium and vanadium (USGS 2026)
source: usgs-molybdenum-2026
where: World Mine Production and Reserves table (2025e, molybdenum content; shares computed from the printed tonnage); Substitutes; Recycling
- subject: Molybdenum trade and policy
abundance: The United States is a net exporter of molybdenum (USGS 2026), with 40,000 t of molybdenum content mine production in 2025 (estimated). China imposed export controls on molybdenum powders in February 2025.
producers: []
critical_lists: []
recycling: ''
substitutes: []
source: usgs-molybdenum-2026
where: Salient Statistics (Net import reliance row, E = net exporter); Events, Trends, and Issues
media: []
documents:
- title: 'Rolled Alloys: Stainless 440C data sheet (Bulletin No. 1142)'
type: datasheet
url: https://www.rolledalloys.ca/wp-content/uploads/440C_stainless-steel-data-sheet.pdf
year: 2015
- title: 'AircraftMaterials UK: Stainless Steel 440C technical data sheet'
type: datasheet
url: https://www.aircraftmaterials.com/data/alstst/440c.html
- title: 'Aalco: Stainless Steel - Martensitic - 1.4125 (440C) Bar datasheet (EN 10088-3:2005)'
type: datasheet
url: https://www.aalco.co.uk/datasheets/Stainless-Steel-14125-440C-Bar_312.ashx
- title: 'United Performance Metals: Alloy 440C datasheet'
type: datasheet
url: https://www.upmet.com/sites/default/files/datasheets/440c.pdf
- title: 'Carpenter Technology: 440C alloy page'
type: datasheet
url: https://www.carpentertechnology.com/alloy-finder/440c
- title: 'NASA Glenn (DellaCorte, 2018): Ni-Ti Next Generation Bearings for Space Applications'
type: report
url: https://ntrs.nasa.gov/api/citations/20180002168/downloads/20180002168.pdf
year: 2018
- title: 'Battelle for NASA (Dufrane et al., 1984): Measurements of elastohydrodynamic film thicknesses, wear, and tempering behavior of high pressure oxygen turbopump bearings'
type: report
url: https://ntrs.nasa.gov/api/citations/19840014892/downloads/19840014892.pdf
year: 1984
- title: Effects of Heat Treatment on the Properties of SS440C for Blades Applications (Springer Proceedings in Physics 289; UniMAP repository copy)
type: paper
url: https://ris.unimap.edu.my/entities/publication/1eddb8c2-050b-427f-8b49-0de618f67a03
- title: 'USGS Mineral Commodity Summaries 2026: Chromium'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-chromium.pdf
year: 2026
- title: 'USGS Mineral Commodity Summaries 2026: Molybdenum'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-molybdenum.pdf
year: 2026
- title: 'Keane et al. (NIOSH): Selecting Processes to Minimize Hexavalent Chromium from Stainless Steel Welding'
type: paper
url: https://pmc.ncbi.nlm.nih.gov/articles/PMC4681305
- title: Google Patents JP6207408B2 (background text naming SUS440C and JIS G4303)
type: paper
url: https://patents.google.com/patent/JP6207408B2/en
gaps:
- ASTM A582 is not printed by any fetched 440C source (Rolled Alloys, Carpenter, Aalco, Aircraft Materials, UPMET, NASA 2018), so it is not in designations. Aalco names 440F (UNS S44020) as a free-machining variant, which is a different grade.
- The JIS standard itself was not reached. SUS440C and JIS G4303 come from the background text of Japanese patent JP6207408B2. The Nachi-Fujikoshi SUS440C table returned a 404 error.
- No tensile, yield or elongation value for annealed 440C was taken from a fetched source. Wikipedia's annealed row was not used, because the brief limits Wikipedia to composition and history.
- No tensile or yield values across the 300 to 800 F temper range were found. The only 600 F strength values are representative values from two datasheets (Rolled Alloys and Aircraft Materials), and no strength temper curve was read.
- Aalco's EN 10088-3 ranges (proof stress 448 to 1900 MPa, tensile 758 to 2030 MPa, elongation 4 to 14 %) span several tempers, so they are not used as single values.
- UPMET's 440C datasheet prints yield 448 MPa, tensile 75 MPa (probably a typo), elongation 14 % and hardness 269 HB max with no heat-treatment condition, so none are used. Its density (7650 kg/cm3) has a unit slip, and its thermal conductivity (24.2 at 212 F) and electrical resistivity (600) have no unit.
- The Carpenter 440C page gives composition, specifications and uses only, with no property values.
- 'The UniMAP copy of the Springer paper prints an as-received annealed hardness of 11.4 HRC, which does not fit the other annealed data (Rolled Alloys: about 223 HB), so it is not used. Its tensile results are not given as numbers in the abstract.'
- The NASA 2018 slides give 440C electrical resistivity as about 0.60 x10^-6 ohm.m in one table and about 36 x10^-6 ohm.cm in the other; only the first is used. Its 1900 MPa tensile value has no temper, so it is not used.
- No specific heat value was read from any fetched 440C source.
- No 440C safety data sheet was reached. The PubChem chromium and molybdenum records fetched in this run carry no hazard codes in their text, so they are not cited. OSHA (403), DOL (blocked) and CDC stacks (access denied) could not be read. The hazard source is a NIOSH-authored study of stainless steel welding fume, not a 440C study.
- No source for dust or fume from grinding or machining 440C was read.
- USGS critical-mineral list status for chromium and molybdenum was not checked (the MCS chapters do not print the lists), so critical_lists is empty.
- Supply shares are computed by hand from printed tonnage (basis given per producer); they are not printed percentages.
- 'No ESA or ECSS source for 440C was found. The space links come from two NASA reports only: a Space Shuttle main engine turbopump bearing study (1984) and a 2018 reaction-wheel bearing comparison.'
- hardness and fracture_toughness are not in property-canon.yaml, so short names are used for them.
- 'Not usable in this run: Starrapid 440C PDF (download failed), ASM Alloy Digest SS-101 (no text), Hudson Tool Steel 440C page (no text), AZoM 440C bar page (supplier list, no property values), SB Specialty Metals 440C data sheet (no values in text).'
- No cryogenic tensile data and no high-temperature tensile data for 440C were found beyond the 1984 hardness tests.
sources:
rolled-440c:
title: 'Rolled Alloys: Stainless 440C data sheet (Bulletin No. 1142, 08/15)'
id: Bulletin No. 1142
url: https://www.rolledalloys.ca/wp-content/uploads/440C_stainless-steel-data-sheet.pdf
kind: datasheet
year: 2015
license: cited, not reproduced
aircraft-materials-440c:
title: 'AircraftMaterials UK: Stainless Steel 440C technical data sheet (Alloy 440C, AISI 440C, AMS 5630)'
id: Alloy 440C page
url: https://www.aircraftmaterials.com/data/alstst/440c.html
kind: datasheet
license: cited, not reproduced
aalco-440c-bar:
title: 'Aalco: Stainless Steel - Martensitic - 1.4125 (440C) Bar, EN 10088-3:2005 datasheet'
id: EN 10088-3:2005 bar
url: https://www.aalco.co.uk/datasheets/Stainless-Steel-14125-440C-Bar_312.ashx
kind: datasheet
license: cited, not reproduced
upmet-440c:
title: 'United Performance Metals: Alloy 440C datasheet (AMS 5630 chemistry)'
id: ALLOY 440C
url: https://www.upmet.com/sites/default/files/datasheets/440c.pdf
kind: datasheet
license: cited, not reproduced
carpenter-440c:
title: 'Carpenter Technology: 440C alloy page (type analysis, applicable specifications, uses)'
id: UNS S44004
url: https://www.carpentertechnology.com/alloy-finder/440c
kind: datasheet
license: cited, not reproduced
nasa-2018-ntrs:
title: 'NASA Glenn: DellaCorte, Ni-Ti Next Generation Bearings for Space Applications (Schaeffler International Bearing Conference, 24 January 2018)'
id: NTRS 20180002168
url: https://ntrs.nasa.gov/api/citations/20180002168/downloads/20180002168.pdf
kind: report
year: 2018
license: public domain (NASA)
nasa-1984-ntrs:
title: 'Dufrane et al., Battelle for NASA: Measurements of elastohydrodynamic film thicknesses, wear, and tempering behavior of high pressure oxygen turbopump bearings (AISI 440C)'
id: NTRS 19840014892 (report dated 2 April 1984)
url: https://ntrs.nasa.gov/api/citations/19840014892/downloads/19840014892.pdf
kind: report
year: 1984
license: public domain (NASA)
springer-unimap-440c:
title: Effects of Heat Treatment on the Properties of SS440C for Blades Applications (Springer Proceedings in Physics 289, pp. 145-152; UniMAP repository copy)
id: Springer Proc. Phys. 289, 145-152
url: https://ris.unimap.edu.my/entities/publication/1eddb8c2-050b-427f-8b49-0de618f67a03
kind: paper
license: cited, not reproduced
usgs-chromium-2026:
title: 'USGS Mineral Commodity Summaries 2026: Chromium'
id: mcs2026-chromium
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-chromium.pdf
kind: report
year: 2026
license: public domain (USGS)
usgs-molybdenum-2026:
title: 'USGS Mineral Commodity Summaries 2026: Molybdenum'
id: mcs2026-molybdenum
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-molybdenum.pdf
kind: report
year: 2026
license: public domain (USGS)
pmc-cr6-welding:
title: 'Keane M, Siert A, Stone S, Chen B, et al. (NIOSH): Selecting Processes to Minimize Hexavalent Chromium from Stainless Steel Welding (Welding Journal)'
id: PMC4681305
url: https://pmc.ncbi.nlm.nih.gov/articles/PMC4681305
kind: paper
license: open access (PMC)
patent-jp6207408:
title: 'Google Patents JP6207408B2: background text naming SUS440C and JIS G4303'
id: JP6207408B2
url: https://patents.google.com/patent/JP6207408B2/en
kind: web
license: public patent text
wiki-440c:
title: 'Wikipedia: 440C (composition cross-check only)'
id: 440C
url: https://en.wikipedia.org/wiki/440C
kind: web
license: CC BY-SA 4.0 (cited, not reproduced)
license: CC-BY-4.0
updated: '2026-10-24'
review:
status: draft
method: assistant
checked_values: 44
unreachable: 0
caveats: 6
note: 'Read by an AI assistant on 2026-10-24 from pages fetched in this run: Rolled Alloys bulletin 1142, AircraftMaterials 440C sheet, Aalco EN 10088-3 bar datasheet, UPMET 440C datasheet, Carpenter 440C page, NASA Glenn 2018 slides, NASA/Battelle 1984 turbopump bearing report, UniMAP copy of the Springer SS440C paper, USGS MCS 2026 chromium and molybdenum, the NIOSH-authored welding fume study (PMC), Google Patents JP6207408B2 (JIS name only) and Wikipedia (composition only).'
story:
recipe:
line: 440C is an iron-based martensitic stainless steel. Carbon (0.95 to 1.20 percent) is the highest of the 400 series, and chromium (16 to 18 percent) gives the stainless film. Rolled Alloys, Carpenter and Aalco print the same carbon and chromium limits, and Wikipedia gives the same ranges. Molybdenum is 0.75 percent maximum in Rolled Alloys and Carpenter, while EN 10088-3 (Aalco) allows 0.40 to 0.80 percent. The record gives limits, not a single analysis.
parts:
- name: Iron
symbol: Fe
share_note: balance (the rest)
role: The matrix. As a martensitic stainless steel it can be hardened by heat treatment (Rolled Alloys).
source: rolled-440c
where: Chemical composition table (Fe balance)
- name: Carbon
symbol: C
share_percent: 0.95
share_high: 1.2
role: Gives the high hardness; Rolled Alloys calls 440C the highest carbon content of the 400 series stainless steels.
source: rolled-440c
where: Chemical composition table (C, min 0.95, max 1.2); Features list
- name: Chromium
symbol: Cr
share_percent: 16
share_high: 18
role: Keeps the stainless characteristics despite the high carbon (Rolled Alloys).
source: rolled-440c
where: Chemical composition table (Cr, min 16.0, max 18.0)
- name: Molybdenum
symbol: Mo
share_percent: 0
share_high: 0.75
role: Maximum 0.75 (Rolled Alloys and Carpenter); EN 10088-3 allows 0.40 to 0.80 (Aalco).
source: rolled-440c
where: Chemical composition table (Mo, max 0.75)
- name: Manganese
symbol: Mn
share_percent: 0
share_high: 1
role: Residual element, held to a maximum.
source: rolled-440c
where: Chemical composition table (Mn, max 1.00)
- name: Silicon
symbol: Si
share_percent: 0
share_high: 1
role: Residual element, held to a maximum.
source: rolled-440c
where: Chemical composition table (Si, max 1.00)
- name: Phosphorus
symbol: P
share_percent: 0
share_high: 0.04
role: Impurity held to a maximum.
source: rolled-440c
where: Chemical composition table (P, max 0.04)
- name: Sulfur
symbol: S
share_percent: 0
share_high: 0.03
role: Impurity held to a maximum.
source: rolled-440c
where: Chemical composition table (S, max 0.03)
risk_groups:
- title: For people
level: 1
verdict: Welding fume is the main human-health watch point
lead: No safety data sheet for 440C was reached. The hazard source found is a NIOSH-authored study of stainless steel welding fume.
points:
- label: Welding fume
line: In the NIOSH-authored study, the hexavalent chromium fraction of stainless steel welding fume ranged from 2800 to 34,000 ppm across eight process and shielding-gas combinations.
- label: Scope
line: The study covers welding fume in general, not 440C alone, so treat it as a guide until a 440C safety data sheet is checked.
- title: In service
level: 2
verdict: Heat and poor lubrication are the failure routes
lead: NASA's 1984 study of turbopump bearings found that 440C softens with heat and wears fast when unlubricated.
points:
- label: Heat
line: Bulk bearing temperatures of 480 C (900 F) or more could not be tolerated, and hot hardness falls rapidly from 540 C (1000 F).
- label: Wear
line: Unlubricated 440C wear rates were high enough to explain the ball wear seen in service.
- title: Corrosion and temper
level: 1
verdict: Temper choice sets corrosion resistance
lead: Corrosion resistance is best in the hardened, tempered and passivated condition (Aalco).
points:
- label: Avoid
line: Tempering between 425 and 565 C reduces impact and corrosion resistance (Aalco).
- label: Above 800 F
line: Hardened and tempered above about 800 F (427 C), or annealed, the corrosion resistance is reduced (Carpenter).
why: '440C is a high-carbon martensitic stainless steel built for hardness. It is hardened by heat treatment, and Carpenter says it is used in the hardened plus tempered condition. Its main use is bearings and valve parts, and NASA studied 440C bearings in the Space Shuttle main engine''s high-pressure oxygen turbopump. The trade-off is corrosion resistance: Carpenter says it falls in the annealed state and after tempering above about 800 F (427 C), and NASA''s 2018 comparison rates it marginal.'
uses:
- where: Bearings and valve parts
line: 'Rolled Alloys, Aalco and UPMET all list bearings and valve parts (UPMET: ball bearings and valves). Aalco also lists high-quality knife blades, surgical instruments and chisels.'
- where: Space Shuttle main engine turbopump bearings
line: A 1984 NASA report on the high-pressure oxygen turbopump bearings measured 440C wear and tempering. It found that wear in unlubricated contact could explain the ball wear seen in service.
- where: Space reaction-wheel bearing comparison (2018)
line: NASA Glenn's 2018 slides compare 440C with 60NiTi for space bearings. They credit 60NiTi bearing races with 2x (against Rex 20) to 5x (against 440C) improvement in a reaction-wheel bearing.
can_do:
- label: Hardness
line: 'Hardened and tempered, 440C reaches about HRC 60, the highest hardness of any stainless steel (Carpenter, Rolled Alloys). The temper sets it: 60 HRC after a one-hour temper at 300 F, and 56 HRC after tempering at 600 to 800 F (Rolled Alloys).'
- label: Strength
line: At the 600 F temper, Aircraft Materials gives 1965 MPa tensile and 1896 MPa yield, and Rolled Alloys gives 285 ksi and 275 ksi for the same heat treatment, with 2 percent elongation.
- label: Stiffness
line: Young's modulus is 200 GPa in the Aalco, UPMET and NASA 2018 records.
- label: Heat tolerance
line: In NASA's 1984 tests, tempering at 540 C (1000 F) for 10 to 945 s dropped hardness from HRC 60 only to HRC 57 to 58. Bulk bearing temperatures of 480 C (900 F) or more could not be tolerated in the turbopump bearings.
- label: Service temperature
line: NASA Glenn gives about 400 C as the maximum use temperature of 440C in its 2018 comparison.
compare: Against common stainless steels, 440C trades corrosion resistance for hardness. Aalco says its corrosion resistance approximates that of 304 in many environments, and that martensitic grades resist corrosion less than the common austenitic grades. NASA's 2018 comparison rates 440C corrosion resistance as marginal and calls the austenitic 304 soft, while it lists 60NiTi, a superelastic bearing alloy, as excellent in aqueous and acidic service.
compare_rows:
- label: Tensile strength at the 600 F temper
benchmark: ultimate_tensile_strength
- label: Density
benchmark: density
- label: Melting range
benchmark: melting_point
handling:
- Machine in the annealed condition. Once hardened, machining becomes much harder and probably impossible (Aalco).
- Do not overheat when grinding, since hardness and corrosion resistance can fall (Rolled Alloys).
- Temper straight after quenching, at the temperature that gives the hardness you need (Rolled Alloys, Aalco).
- Welding is seldom needed. If it is, preheat (about 250 C, or 500 F) and anneal afterwards (Aalco, Rolled Alloys).
good_for:
- Bearings, where hardness and wear resistance matter (Carpenter, Aalco, Rolled Alloys).
- Valve seats and valve parts (Aalco, Rolled Alloys, UPMET).
- Knife blades, surgical instruments and chisels (Aalco, UPMET).
watch_out:
- Corrosion. NASA rates it marginal, and Aalco says it is less corrosion resistant than the common austenitic grades.
- Tempering between 425 and 565 C, which reduces impact and corrosion resistance (Aalco).
- Long holds at 540 C (1000 F), or bulk temperatures of 480 C (900 F) and above, which take bearing hardness to unusable levels (NASA 1984).
- Welding, which is seldom done. Filler choice changes the weld hardness (Aalco, Rolled Alloys).
verdict: Of the stainless steels in these sources, 440C is the hardest when heat-treated, so it is the bearing and valve choice when hardness matters most. Accept its marginal corrosion resistance, keep the temper at or below about 800 F (427 C), and keep service below about 400 C.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.