Rubidium Rb

Rb · CAS 7440-17-7

Rubidium (Rb, CAS 7440-17-7) is a soft, silvery alkali metal with atomic number 37.

9 sources · Updated 2026-11-01 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Recipe, share of the weight

  • Rb 100.0%Rubidium

Best for

Atomic frequency references: rubidium clocks were flown on GPS Block IIR satellites and on the Galileo test satellite GIOVE-A (NASA-hosted paper; Airbus catalogue)

Weakest at

Handling: it reacts violently with water and tarnishes in air, and CAMEO Chemicals says it burns spontaneously in dry oxygen

Risk at a glance

  • People Moderate. Severe burns; reacts violently with water
  • If it fails High. Reaction with water or moist air
  • Corrosion Severe. Water is the severe case: the reaction gives corrosive rubidium hydroxide and flammable hydrogen.

Quick facts: Rb

Key properties of Rb
PropertyValueBasis
Density1.46 to 1.53 g/cm³4 sourced values across conditions
Young's modulus2.4 GPa1 sourced value
Thermal conductivity58 W/(m·K)1 sourced value
Melting point38.9 to 39.5 °C3 sourced values across conditions
Specific heat364 J/(kg·K)1 sourced value

What is the density of Rubidium (Rb)?

Rubidium (Rb) has a density of 1.46 to 1.53 g/cm³. The range covers 4 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the thermal conductivity of Rubidium (Rb)?

Rubidium (Rb) has a thermal conductivity of 58 W/(m·K). The source and test conditions are listed in the properties table on this page.

What is the melting point of Rubidium (Rb)?

Rubidium (Rb) has a melting point of 38.9 to 39.5 °C. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the Young's modulus of Rubidium (Rb)?

Rubidium (Rb) has a Young's modulus of 2.4 GPa. The source and test conditions are listed in the properties table on this page.

What is Rubidium (Rb) used for?

Uses recorded in the sources include Rubidium atomic frequency standard on navigation satellites; GPS Block IIR navigation satellites; Photomultiplier tubes, night-vision devices and photoelectric cells.

Why it exists

Rubidium is a soft, silvery alkali metal, and it is one of the reactive metals in its group. The USGS names its main use as an atomic resonance-frequency reference, the principle behind the rubidium clocks flown on navigation satellites. Specialty glass is the leading market for rubidium compounds according to the same USGS chapter, and the metal also appears in photomultiplier tubes, night-vision devices and catalysts. Rubidium is a byproduct of pollucite and lepidolite mining, not a primary product, so supply depends on those mines and on stockpiles.

Where it's used

Navigation satellite clocks

Airbus lists a Rubidium Atomic Frequency Standard that was first flown on GIOVE-A, the Galileo test satellite, with successful operation since then. A NASA-hosted paper by Riley describes rubidium atomic frequency standards provided for the GPS Block IIR satellites.

Optical sensors

The USGS says rubidium's photoemissive properties make it useful for photomultiplier tubes, night-vision devices, photoelectric cells and spectrometers.

Recipe

Rb

Rubidium is a single element, Rb, with atomic number 37, and it is an alkali metal. Natural rubidium is a mix of two isotopes: rubidium-85 with a mole fraction of 0.7217 and rubidium-87 with 0.2783, per the NIST table. No source opened for this profile describes how the metal is made.

What Rb is made of
IngredientAtoms per unitShare of the weightWhat it does
Rubidium Rb 1 100.0% The whole material. The element's mass is taken from PubChem's computed molecular weight, 85.468 g/mol.

Weight shares are calculated from standard atomic weights.

What it can do

Set a time reference

The USGS describes rubidium as an atomic resonance-frequency reference, the basis of the clocks flown for global positioning.

Respond to light

Rubidium's photoemissive properties are used in photomultiplier tubes and night-vision devices, per the USGS.

Stand in for cesium

The USGS says the two can be used interchangeably in many applications because of their similar physical properties and atomic radii.

How it compares

The USGS says rubidium and cesium can be used interchangeably in many applications, because they have similar physical properties and atomic radii, and that cesium is the more electropositive of the two and is preferred for some uses. Within this profile, the density of 1.532 g/cm3 and the melting point of 38.9 °C in the safety data sheet are the figures to set against other metals in the same table, and the table rows below use this profile's own values.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details.

Benchmarks
MeasurementRb
Capacity and energy
First ionization energyValue printed on a reference data page403 kJ/mol
Thermal behavior and safety
Melting point, Alfa Aesar safety data sheetValue printed in a supplier safety data sheet38.9 °C4
Melting point, Wolfram ElementData39.31 °C5
Melting point, PAC Chemical Database (via PubChem)39.5 °C6
Specific heat capacity, solid phase364 J/(kg K)8
Thermal conductivityValue printed on a reference data page58 W/(m K)9
Physical and electrical
Density at 20 °C, Alfa Aesar safety data sheetValue printed in a supplier safety data sheet1.532 g/cm³1
Density, element (Wolfram ElementData)1.532 g/cm³2
Density of solid (WebElements)Value printed on a reference data page1532 kg/m33
Density of liquid rubidium (Wolfram ElementData)Value printed on a reference data page1.46 g/cm³
Other measurements
Boiling point, Wolfram ElementData688 °C7
Young's modulusValue printed on a reference data page2.4 GPa10
Bulk modulusValue printed on a reference data page2.5 GPa
Molecular weight of the element (PubChem computed)85.47 g/mol11
Mole fraction of rubidium-85 in natural rubidium0.7217 -12
Mole fraction of rubidium-87 in natural rubidium0.2783 -13
Atomic numberValue printed on a reference data page37 -
ElectronegativityValue printed on a reference data page0.82 -
Atomic radiusValue printed on a reference data page265 pm
Lattice constant of the rubidium cell as printedValue printed on a reference data page558.5 pm14
Abundance in Earth's crust as printedValue printed on a reference data page0.006 %
World recoverable reserves of rubidium materials (USGS estimate)< 2×10^5 tons15

Why choose it, and why not

Good for

  • Timing: rubidium frequency standards were flown on navigation satellites, as the Airbus catalogue and the NASA-hosted paper describe.
  • Specialty glass and optical devices: the USGS names specialty glass as the leading market, with photomultiplier tubes and night-vision devices.

Watch out for

  • Reacts violently with water, forming flammable hydrogen and corrosive rubidium hydroxide.
  • Tarnishes in air. No corrosion rate was found, so storage under inert gas is the only guidance in the sources.
  • Supply: the USGS reports no official rubidium production data for 2025, and rubidium comes mainly from byproducts.

Rubidium is a reactive alkali metal whose main documented use is as a frequency reference in navigation satellites. Its handling risk is high, and the sources in this profile give no space-environment data for the metal itself.

Used in space products

Space hardware whose maker names Rb, with the part it is used for.

Space products that use Rb
ProductWhere it is used
GPS III satelliteLockheed Martin Digital Rubidium Atomic Frequency Standard (demonstration, SV10)

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Density at 20 °C, Alfa Aesar safety data sheet—form solid metal, product 10315 (rubidium metal, 7440-17-7)temperature 20 °Cunit in source g/cm³—
2Density, element (Wolfram ElementData)Value printed on a reference data page that cites Mathematica ElementDataform solid metaltemperature not stated on the pageAgrees with the safety data sheet value above.
3Density of solid (WebElements)—form solid metaltemperature not stated on the pageunit in source kg m‑3The same figure as 1.532 g/cm3 in other sources, in SI units.
4Melting point, Alfa Aesar safety data sheet—form rubidium metalunit in source 38.9 °C (102 °F)pressure not statedThree sources give 38.9 °C, 39.31 °C and 39.5 °C. This profile keeps all three rather than choosing one.
5Melting point, Wolfram ElementDataValue printed on a reference data page that cites Mathematica ElementDataform rubidium metalpressure not statedSee the safety data sheet value of 38.9 °C; the sources disagree by about one kelvin.
6Melting point, PAC Chemical Database (via PubChem)Value listed in the PubChem record, attributed to the U.S. DOE PAC Chemical Databaseform rubidiumpressure not stated—
7Boiling point, Wolfram ElementDataValue printed on a reference data page that cites Mathematica ElementDatapressure not stated on the page—
8Specific heat capacity, solid phaseValue printed on a reference data page; the page notes it is given for the solid phasephase solidtemperature not stated on the page—
9Thermal conductivity—temperature not stated on the pageWebElements prints the same 58 W m-1 K-1.
10Young's modulus—temperature not stated on the pageWolfram ElementData prints the same 2.4 GPa.
11Molecular weight of the element (PubChem computed)Computed value printed by PubChem 2.2 (release 2025.05.06)form Rb, element, computed from the isotope mix—
12Mole fraction of rubidium-85 in natural rubidiumValue printed on the NIST atomic weights and isotopic compositions pageisotope 85Rbbasis standard isotopic composition, mole fraction; uncertainty printed as (2)—
13Mole fraction of rubidium-87 in natural rubidiumValue printed on the NIST atomic weights and isotopic compositions pageisotope 87Rbbasis standard isotopic composition, mole fraction; uncertainty printed as (2)—
14Lattice constant of the rubidium cell as printed—structure three equal constants with right angles printed; space group number 229 printed on the same pagetemperature not stated on the pagePubChem lists a different cell for rubidium (from an older paper); the two are not reconciled here.
15World recoverable reserves of rubidium materials (USGS estimate)Estimate printed in the USGS Mineral Commodity Summaries chapterbasis recoverable rubidium materials; USGS names Australia, Canada, China and Namibia as the countries estimated to hold themnote printed as less than the figure—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Air at room temperature not rated Rubidium tarnishes rapidly in air; no corrosion rate was found in any source opened.1
Liquid water and moist air severe Water is the severe case: the reaction gives corrosive rubidium hydroxide and flammable hydrogen.2
Corrosion details
#EnvironmentDetailsTest conditions
1 Air at room temperature CAMEO Chemicals says rubidium tarnishes rapidly upon exposure to air, and PubChem's summary of the same source says it tarnishes in air. Neither gives a rate, a film thickness or a time scale, so none is recorded. The supplier safety data sheet asks for storage under dry inert gas and away from air. exposure room-temperature air; humidity, time and temperature not stated
2 Liquid water and moist air CAMEO Chemicals says rubidium reacts violently with water to form corrosive rubidium hydroxide and hydrogen, a flammable gas, and that the heat of the reaction usually ignites the hydrogen. The safety data sheet also lists a severe skin burn and eye damage hazard (H314). exposure contact with liquid water or moisture

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

Rubidium is classed as a skin corrosive and as a water-reactive substance, so it is handled as a hazardous material.

Skin and eyes
The safety data sheet and PubChem's GHS summary both give H314, causes severe skin burns and eye damage.
Water
H260 means contact with water releases flammable gases which may ignite spontaneously. CAMEO Chemicals says the heat of the reaction usually ignites the hydrogen.
First aid
The first-aid text quoted from the Emergency Response Guidebook says to wipe the metal off the skin at once and flush with running water.

If it reacts

These are reactions the sources describe; no incident record was opened.

Fire
Do not use water or foam on a rubidium fire. Use dry chemical, dry sand or class D extinguishers, as the Emergency Response Guidebook guide quoted by CAMEO Chemicals says.
Burning
PubChem's reactivity profile, reproduced from CAMEO Chemicals, says the metal burns spontaneously in dry oxygen and catches fire in air when molten.

Handling and storage

The supplier safety data sheet sets the storage rules.

Storage
Handle under dry protective gas and keep the container tightly sealed. Store under dry inert gas, away from water, moisture, air and oxidizing agents.
Spills
Cover a spill with dry earth, dry sand or another non-combustible material, and do not apply water.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Reaction with water or moist airhigh severityWater or humid air reaching the metalFlammable hydrogen gas, usually ignited by the heat of the reaction, plus corrosive rubidium hydroxide (CAMEO Chemicals).
Spontaneous burning in dry oxygenhigh severityExposure to dry oxygen; readily catches fire in air when moltenThe metal burns spontaneously in dry oxygen, according to the CAMEO Chemicals reactivity profile reproduced in PubChem.
Tarnish in airlow severityExposure to airA tarnish film forms on the metal; no thickness or rate is recorded in the sources opened.

Side effects on surrounding parts

Side effects on surrounding parts
AffectsEffect
Storage area and the people handling the metalHydrogen and corrosive rubidium hydroxide are released when the metal reacts with water, and the hydrogen is flammable.

Handling and storage

  • Handle under dry protective gas, keep the container tightly sealed, and store under dry inert gas, away from water, moisture, air and oxidizing agents, according to the Alfa Aesar safety data sheet.
  • For a spill, cover with dry earth, dry sand or another non-combustible material and do not apply water, per the Emergency Response Guidebook guide quoted by CAMEO Chemicals.

Mitigations

  • Use dry chemical, dry sand, sodium chloride powder, graphite powder or class D extinguishers on metal fires (Emergency Response Guidebook guide quoted by CAMEO Chemicals).

Supply and geography

How common the raw materials are and where they come from.

Rubidium

Rubidium is not a major constituent of any mineral; the crustal abundance printed on the reference data page is in the properties list.

Recycling
USGS: Recycling: None.
Substitutes
USGS: rubidium and cesium can be used interchangeably in many applications because they have similar physical properties and atomic radii; cesium is more electropositive and is preferred for some applications.

Updated