Rubidium Rb
Rb · CAS 7440-17-7
Rubidium (Rb, CAS 7440-17-7) is a soft, silvery alkali metal with atomic number 37.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Recipe, share of the weight
- Rb 100.0%Rubidium
Best for
Atomic frequency references: rubidium clocks were flown on GPS Block IIR satellites and on the Galileo test satellite GIOVE-A (NASA-hosted paper; Airbus catalogue)
Weakest at
Handling: it reacts violently with water and tarnishes in air, and CAMEO Chemicals says it burns spontaneously in dry oxygen
Risk at a glance
- People Moderate. Severe burns; reacts violently with water
- If it fails High. Reaction with water or moist air
- Corrosion Severe. Water is the severe case: the reaction gives corrosive rubidium hydroxide and flammable hydrogen.
Quick facts: Rb
| Property | Value | Basis |
|---|---|---|
| Density | 1.46 to 1.53 g/cm³ | 4 sourced values across conditions |
| Young's modulus | 2.4 GPa | 1 sourced value |
| Thermal conductivity | 58 W/(m·K) | 1 sourced value |
| Melting point | 38.9 to 39.5 °C | 3 sourced values across conditions |
| Specific heat | 364 J/(kg·K) | 1 sourced value |
What is the density of Rubidium (Rb)?
Rubidium (Rb) has a density of 1.46 to 1.53 g/cm³. The range covers 4 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the thermal conductivity of Rubidium (Rb)?
Rubidium (Rb) has a thermal conductivity of 58 W/(m·K). The source and test conditions are listed in the properties table on this page.
What is the melting point of Rubidium (Rb)?
Rubidium (Rb) has a melting point of 38.9 to 39.5 °C. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the Young's modulus of Rubidium (Rb)?
Rubidium (Rb) has a Young's modulus of 2.4 GPa. The source and test conditions are listed in the properties table on this page.
What is Rubidium (Rb) used for?
Uses recorded in the sources include Rubidium atomic frequency standard on navigation satellites; GPS Block IIR navigation satellites; Photomultiplier tubes, night-vision devices and photoelectric cells.
Why it exists
Rubidium is a soft, silvery alkali metal, and it is one of the reactive metals in its group. The USGS names its main use as an atomic resonance-frequency reference, the principle behind the rubidium clocks flown on navigation satellites. Specialty glass is the leading market for rubidium compounds according to the same USGS chapter, and the metal also appears in photomultiplier tubes, night-vision devices and catalysts. Rubidium is a byproduct of pollucite and lepidolite mining, not a primary product, so supply depends on those mines and on stockpiles.
Where it's used
Navigation satellite clocks
Airbus lists a Rubidium Atomic Frequency Standard that was first flown on GIOVE-A, the Galileo test satellite, with successful operation since then. A NASA-hosted paper by Riley describes rubidium atomic frequency standards provided for the GPS Block IIR satellites.
Optical sensors
The USGS says rubidium's photoemissive properties make it useful for photomultiplier tubes, night-vision devices, photoelectric cells and spectrometers.
Recipe
Rb
Rubidium is a single element, Rb, with atomic number 37, and it is an alkali metal. Natural rubidium is a mix of two isotopes: rubidium-85 with a mole fraction of 0.7217 and rubidium-87 with 0.2783, per the NIST table. No source opened for this profile describes how the metal is made.
| Ingredient | Atoms per unit | Share of the weight | What it does |
|---|---|---|---|
| Rubidium Rb | 1 | 100.0% | The whole material. The element's mass is taken from PubChem's computed molecular weight, 85.468 g/mol. |
Weight shares are calculated from standard atomic weights.
What it can do
Set a time reference
The USGS describes rubidium as an atomic resonance-frequency reference, the basis of the clocks flown for global positioning.
Respond to light
Rubidium's photoemissive properties are used in photomultiplier tubes and night-vision devices, per the USGS.
Stand in for cesium
The USGS says the two can be used interchangeably in many applications because of their similar physical properties and atomic radii.
How it compares
The USGS says rubidium and cesium can be used interchangeably in many applications, because they have similar physical properties and atomic radii, and that cesium is the more electropositive of the two and is preferred for some uses. Within this profile, the density of 1.532 g/cm3 and the melting point of 38.9 °C in the safety data sheet are the figures to set against other metals in the same table, and the table rows below use this profile's own values.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details.
| Measurement | Rb |
|---|---|
| Capacity and energy | |
| First ionization energyValue printed on a reference data page | 403 kJ/mol |
| Thermal behavior and safety | |
| Melting point, Alfa Aesar safety data sheetValue printed in a supplier safety data sheet | 38.9 °C4 |
| Melting point, Wolfram ElementData | 39.31 °C5 |
| Melting point, PAC Chemical Database (via PubChem) | 39.5 °C6 |
| Specific heat capacity, solid phase | 364 J/(kg K)8 |
| Thermal conductivityValue printed on a reference data page | 58 W/(m K)9 |
| Physical and electrical | |
| Density at 20 °C, Alfa Aesar safety data sheetValue printed in a supplier safety data sheet | 1.532 g/cm³1 |
| Density, element (Wolfram ElementData) | 1.532 g/cm³2 |
| Density of solid (WebElements)Value printed on a reference data page | 1532 kg/m33 |
| Density of liquid rubidium (Wolfram ElementData)Value printed on a reference data page | 1.46 g/cm³ |
| Other measurements | |
| Boiling point, Wolfram ElementData | 688 °C7 |
| Young's modulusValue printed on a reference data page | 2.4 GPa10 |
| Bulk modulusValue printed on a reference data page | 2.5 GPa |
| Molecular weight of the element (PubChem computed) | 85.47 g/mol11 |
| Mole fraction of rubidium-85 in natural rubidium | 0.7217 -12 |
| Mole fraction of rubidium-87 in natural rubidium | 0.2783 -13 |
| Atomic numberValue printed on a reference data page | 37 - |
| ElectronegativityValue printed on a reference data page | 0.82 - |
| Atomic radiusValue printed on a reference data page | 265 pm |
| Lattice constant of the rubidium cell as printedValue printed on a reference data page | 558.5 pm14 |
| Abundance in Earth's crust as printedValue printed on a reference data page | 0.006 % |
| World recoverable reserves of rubidium materials (USGS estimate) | < 2×10^5 tons15 |
Why choose it, and why not
Good for
- Timing: rubidium frequency standards were flown on navigation satellites, as the Airbus catalogue and the NASA-hosted paper describe.
- Specialty glass and optical devices: the USGS names specialty glass as the leading market, with photomultiplier tubes and night-vision devices.
Watch out for
- Reacts violently with water, forming flammable hydrogen and corrosive rubidium hydroxide.
- Tarnishes in air. No corrosion rate was found, so storage under inert gas is the only guidance in the sources.
- Supply: the USGS reports no official rubidium production data for 2025, and rubidium comes mainly from byproducts.
Rubidium is a reactive alkali metal whose main documented use is as a frequency reference in navigation satellites. Its handling risk is high, and the sources in this profile give no space-environment data for the metal itself.
Used in space products
Space hardware whose maker names Rb, with the part it is used for.
| Product | Where it is used |
|---|---|
| GPS III satelliteLockheed Martin | Digital Rubidium Atomic Frequency Standard (demonstration, SV10) |
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Density at 20 °C, Alfa Aesar safety data sheet | — | form solid metal, product 10315 (rubidium metal, 7440-17-7)temperature 20 °Cunit in source g/cm³ | — |
| 2 | Density, element (Wolfram ElementData) | Value printed on a reference data page that cites Mathematica ElementData | form solid metaltemperature not stated on the page | Agrees with the safety data sheet value above. |
| 3 | Density of solid (WebElements) | — | form solid metaltemperature not stated on the pageunit in source kg m‑3 | The same figure as 1.532 g/cm3 in other sources, in SI units. |
| 4 | Melting point, Alfa Aesar safety data sheet | — | form rubidium metalunit in source 38.9 °C (102 °F)pressure not stated | Three sources give 38.9 °C, 39.31 °C and 39.5 °C. This profile keeps all three rather than choosing one. |
| 5 | Melting point, Wolfram ElementData | Value printed on a reference data page that cites Mathematica ElementData | form rubidium metalpressure not stated | See the safety data sheet value of 38.9 °C; the sources disagree by about one kelvin. |
| 6 | Melting point, PAC Chemical Database (via PubChem) | Value listed in the PubChem record, attributed to the U.S. DOE PAC Chemical Database | form rubidiumpressure not stated | — |
| 7 | Boiling point, Wolfram ElementData | Value printed on a reference data page that cites Mathematica ElementData | pressure not stated on the page | — |
| 8 | Specific heat capacity, solid phase | Value printed on a reference data page; the page notes it is given for the solid phase | phase solidtemperature not stated on the page | — |
| 9 | Thermal conductivity | — | temperature not stated on the page | WebElements prints the same 58 W m-1 K-1. |
| 10 | Young's modulus | — | temperature not stated on the page | Wolfram ElementData prints the same 2.4 GPa. |
| 11 | Molecular weight of the element (PubChem computed) | Computed value printed by PubChem 2.2 (release 2025.05.06) | form Rb, element, computed from the isotope mix | — |
| 12 | Mole fraction of rubidium-85 in natural rubidium | Value printed on the NIST atomic weights and isotopic compositions page | isotope 85Rbbasis standard isotopic composition, mole fraction; uncertainty printed as (2) | — |
| 13 | Mole fraction of rubidium-87 in natural rubidium | Value printed on the NIST atomic weights and isotopic compositions page | isotope 87Rbbasis standard isotopic composition, mole fraction; uncertainty printed as (2) | — |
| 14 | Lattice constant of the rubidium cell as printed | — | structure three equal constants with right angles printed; space group number 229 printed on the same pagetemperature not stated on the page | PubChem lists a different cell for rubidium (from an older paper); the two are not reconciled here. |
| 15 | World recoverable reserves of rubidium materials (USGS estimate) | Estimate printed in the USGS Mineral Commodity Summaries chapter | basis recoverable rubidium materials; USGS names Australia, Canada, China and Namibia as the countries estimated to hold themnote printed as less than the figure | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Air at room temperature | not rated | Rubidium tarnishes rapidly in air; no corrosion rate was found in any source opened.1 |
| Liquid water and moist air | severe | Water is the severe case: the reaction gives corrosive rubidium hydroxide and flammable hydrogen.2 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Air at room temperature | CAMEO Chemicals says rubidium tarnishes rapidly upon exposure to air, and PubChem's summary of the same source says it tarnishes in air. Neither gives a rate, a film thickness or a time scale, so none is recorded. The supplier safety data sheet asks for storage under dry inert gas and away from air. | exposure room-temperature air; humidity, time and temperature not stated |
| 2 | Liquid water and moist air | CAMEO Chemicals says rubidium reacts violently with water to form corrosive rubidium hydroxide and hydrogen, a flammable gas, and that the heat of the reaction usually ignites the hydrogen. The safety data sheet also lists a severe skin burn and eye damage hazard (H314). | exposure contact with liquid water or moisture |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
Rubidium is classed as a skin corrosive and as a water-reactive substance, so it is handled as a hazardous material.
- Skin and eyes
- The safety data sheet and PubChem's GHS summary both give H314, causes severe skin burns and eye damage.
- Water
- H260 means contact with water releases flammable gases which may ignite spontaneously. CAMEO Chemicals says the heat of the reaction usually ignites the hydrogen.
- First aid
- The first-aid text quoted from the Emergency Response Guidebook says to wipe the metal off the skin at once and flush with running water.
If it reacts
These are reactions the sources describe; no incident record was opened.
- Fire
- Do not use water or foam on a rubidium fire. Use dry chemical, dry sand or class D extinguishers, as the Emergency Response Guidebook guide quoted by CAMEO Chemicals says.
- Burning
- PubChem's reactivity profile, reproduced from CAMEO Chemicals, says the metal burns spontaneously in dry oxygen and catches fire in air when molten.
Handling and storage
The supplier safety data sheet sets the storage rules.
- Storage
- Handle under dry protective gas and keep the container tightly sealed. Store under dry inert gas, away from water, moisture, air and oxidizing agents.
- Spills
- Cover a spill with dry earth, dry sand or another non-combustible material, and do not apply water.
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Reaction with water or moist airhigh severity | Water or humid air reaching the metalFlammable hydrogen gas, usually ignited by the heat of the reaction, plus corrosive rubidium hydroxide (CAMEO Chemicals). |
| Spontaneous burning in dry oxygenhigh severity | Exposure to dry oxygen; readily catches fire in air when moltenThe metal burns spontaneously in dry oxygen, according to the CAMEO Chemicals reactivity profile reproduced in PubChem. |
| Tarnish in airlow severity | Exposure to airA tarnish film forms on the metal; no thickness or rate is recorded in the sources opened. |
Side effects on surrounding parts
| Affects | Effect |
|---|---|
| Storage area and the people handling the metal | Hydrogen and corrosive rubidium hydroxide are released when the metal reacts with water, and the hydrogen is flammable. |
Handling and storage
- Handle under dry protective gas, keep the container tightly sealed, and store under dry inert gas, away from water, moisture, air and oxidizing agents, according to the Alfa Aesar safety data sheet.
- For a spill, cover with dry earth, dry sand or another non-combustible material and do not apply water, per the Emergency Response Guidebook guide quoted by CAMEO Chemicals.
Mitigations
- Use dry chemical, dry sand, sodium chloride powder, graphite powder or class D extinguishers on metal fires (Emergency Response Guidebook guide quoted by CAMEO Chemicals).
Supply and geography
How common the raw materials are and where they come from.
Rubidium
Rubidium is not a major constituent of any mineral; the crustal abundance printed on the reference data page is in the properties list.
- Recycling
- USGS: Recycling: None.
- Substitutes
- USGS: rubidium and cesium can be used interchangeably in many applications because they have similar physical properties and atomic radii; cesium is more electropositive and is preferred for some applications.
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
Show the full YAML
spore: profile
id: rubidium
spore_version: 0.2
family: alkali-metals
name: Rubidium
abbreviation: Rb
role: atomic clock reference metal
category: metals
type: heavy-metals
summary: Rubidium (Rb, CAS 7440-17-7) is a soft, silvery alkali metal with atomic number 37. An Alfa Aesar safety data sheet gives its density as 1.532 g/cm3 at 20 °C, and sources in this profile give its melting point as 38.9 °C, 39.31 °C and 39.5 °C. It reacts violently with water and tarnishes in air, so it is stored under dry inert gas. The USGS found no reported rubidium mine production worldwide in 2025, and its main use named in the source is as an atomic resonance-frequency reference, which is the basis of rubidium clocks flown on navigation satellites.
best_for: 'Atomic frequency references: rubidium clocks were flown on GPS Block IIR satellites and on the Galileo test satellite GIOVE-A (NASA-hosted paper; Airbus catalogue)'
weakest_at: 'Handling: it reacts violently with water and tarnishes in air, and CAMEO Chemicals says it burns spontaneously in dry oxygen'
identity:
formula: Rb
cas: 7440-17-7
source: pubchem-rb
where: PubChem compound record CID 5357696, section 2.3.1 (CAS)
tags:
environments: []
stresses: []
applications:
- electronics-and-chips
- optics-and-cameras
properties:
- benchmark: density
label: Density at 20 °C, Alfa Aesar safety data sheet
value: 1.532
unit: g/cm3
scope: material
conditions:
form: solid metal, product 10315 (rubidium metal, 7440-17-7)
temperature: 20 °C
unit_in_source: g/cm³
method: Value printed in a supplier safety data sheet
status: ground
source: purdue-rb-sds
where: Section 9, Density at 20 °C (68 °F)
- benchmark: density
label: Density, element (Wolfram ElementData)
value: 1.532
unit: g/cm3
scope: material
conditions:
form: solid metal
temperature: not stated on the page
method: Value printed on a reference data page that cites Mathematica ElementData
status: ground
note: Agrees with the safety data sheet value above.
source: periodictable-rb
where: Overview and Bulk physical properties, Density
- benchmark: density
label: Density of solid (WebElements)
value: 1532
unit: kg/m3
scope: material
conditions:
form: solid metal
temperature: not stated on the page
unit_in_source: kg m‑3
method: Value printed on a reference data page
status: ground
note: The same figure as 1.532 g/cm3 in other sources, in SI units.
source: webelements-rb
where: Density properties, Density of solid
- benchmark: density
label: Density of liquid rubidium (Wolfram ElementData)
value: 1.46
unit: g/cm3
scope: material
conditions:
form: liquid metal
temperature: not stated on the page
method: Value printed on a reference data page
status: ground
source: periodictable-rb
where: Bulk physical properties, Density (Liquid)
- benchmark: melting_point
label: Melting point, Alfa Aesar safety data sheet
value: 38.9
unit: °C
scope: material
conditions:
form: rubidium metal
unit_in_source: 38.9 °C (102 °F)
pressure: not stated
method: Value printed in a supplier safety data sheet
status: ground
note: Three sources give 38.9 °C, 39.31 °C and 39.5 °C. This profile keeps all three rather than choosing one.
source: purdue-rb-sds
where: Section 9, Melting point/Melting range
- benchmark: melting_point
label: Melting point, Wolfram ElementData
value: 39.31
unit: °C
scope: material
conditions:
form: rubidium metal
pressure: not stated
method: Value printed on a reference data page that cites Mathematica ElementData
status: ground
note: See the safety data sheet value of 38.9 °C; the sources disagree by about one kelvin.
source: periodictable-rb
where: Overview and Thermal properties, Melting Point
- benchmark: melting_point
label: Melting point, PAC Chemical Database (via PubChem)
value: 39.5
unit: °C
scope: material
conditions:
form: rubidium
pressure: not stated
method: Value listed in the PubChem record, attributed to the U.S. DOE PAC Chemical Database
status: ground
source: pubchem-rb
where: Section 3.2.3 Melting Point
- benchmark: boiling_point
label: Boiling point, Wolfram ElementData
value: 688
unit: °C
scope: material
conditions:
pressure: not stated on the page
method: Value printed on a reference data page that cites Mathematica ElementData
status: ground
source: periodictable-rb
where: Overview and Thermal properties, Boiling Point
- benchmark: specific_heat
label: Specific heat capacity, solid phase
value: 364
unit: J/(kg K)
scope: material
conditions:
phase: solid
temperature: not stated on the page
method: Value printed on a reference data page; the page notes it is given for the solid phase
status: ground
source: periodictable-rb
where: Thermal properties, Specific Heat
- benchmark: thermal_conductivity
label: Thermal conductivity
value: 58
unit: W/(m K)
scope: material
conditions:
temperature: not stated on the page
method: Value printed on a reference data page
status: ground
note: WebElements prints the same 58 W m-1 K-1.
source: periodictable-rb
where: Thermal properties, Thermal Conductivity
- benchmark: elastic_modulus
label: Young's modulus
value: 2.4
unit: GPa
scope: material
conditions:
temperature: not stated on the page
method: Value printed on a reference data page
status: ground
note: Wolfram ElementData prints the same 2.4 GPa.
source: webelements-rb
where: Elastic properties, Young's modulus
- benchmark: bulk_modulus
label: Bulk modulus
value: 2.5
unit: GPa
scope: material
conditions:
temperature: not stated on the page
method: Value printed on a reference data page
status: ground
source: periodictable-rb
where: Bulk physical properties, Bulk Modulus
- benchmark: molar_mass
label: Molecular weight of the element (PubChem computed)
value: 85.468
unit: g/mol
scope: material
conditions:
form: Rb, element, computed from the isotope mix
method: Computed value printed by PubChem 2.2 (release 2025.05.06)
status: calculated
source: pubchem-rb
where: Section 3.1 Computed Properties, Molecular Weight
- benchmark: isotopic_abundance
label: Mole fraction of rubidium-85 in natural rubidium
value: 0.7217
unit: '-'
scope: material
conditions:
isotope: 85Rb
basis: standard isotopic composition, mole fraction; uncertainty printed as (2)
method: Value printed on the NIST atomic weights and isotopic compositions page
status: ground
source: nist-rb
where: Table of isotopes, row 85, Isotopic composition (mole fraction)
- benchmark: isotopic_abundance
label: Mole fraction of rubidium-87 in natural rubidium
value: 0.2783
unit: '-'
scope: material
conditions:
isotope: 87Rb
basis: standard isotopic composition, mole fraction; uncertainty printed as (2)
method: Value printed on the NIST atomic weights and isotopic compositions page
status: ground
source: nist-rb
where: Table of isotopes, row 87, Isotopic composition (mole fraction)
- benchmark: atomic_number
label: Atomic number
value: 37
unit: '-'
scope: material
conditions:
element: rubidium, Rb
method: Value printed on a reference data page
status: ground
source: periodictable-rb
where: Overview, Atomic Number
- benchmark: first_ionization_energy
label: First ionization energy
value: 403
unit: kJ/mol
scope: material
conditions:
basis: first value of the ionization energy list printed on the page
method: Value printed on a reference data page
status: ground
source: periodictable-rb
where: Reactivity, Ionization Energies (first entry of the list)
- benchmark: electronegativity
label: Electronegativity
value: 0.82
unit: '-'
scope: material
conditions:
scale: scale not named on the page
method: Value printed on a reference data page
status: ground
source: periodictable-rb
where: Reactivity, Electronegativity
- benchmark: atomic_radius
label: Atomic radius
value: 265
unit: pm
scope: material
conditions:
basis: as printed on the page; definition not stated
method: Value printed on a reference data page
status: ground
source: periodictable-rb
where: Atomic dimensions and structure, Atomic Radius
- benchmark: lattice_constant
label: Lattice constant of the rubidium cell as printed
value: 558.5
unit: pm
scope: material
conditions:
structure: three equal constants with right angles printed; space group number 229 printed on the same page
temperature: not stated on the page
method: Value printed on a reference data page
status: ground
note: PubChem lists a different cell for rubidium (from an older paper); the two are not reconciled here.
source: periodictable-rb
where: Atomic dimensions and structure, Lattice Constants
- benchmark: crustal_abundance
label: Abundance in Earth's crust as printed
value: 0.006
unit: '%'
scope: material
conditions:
basis: percent in Earth's crust, as printed on the page
method: Value printed on a reference data page
status: ground
source: periodictable-rb
where: Abundances, % in Earth's Crust
- benchmark: recoverable_reserves
label: World recoverable reserves of rubidium materials (USGS estimate)
value: 200000
bound: upper
unit: tons
scope: material
conditions:
basis: recoverable rubidium materials; USGS names Australia, Canada, China and Namibia as the countries estimated to hold them
note: printed as less than the figure
method: Estimate printed in the USGS Mineral Commodity Summaries chapter
status: ground
source: usgs-mcs2026-rubidium
where: World Mine Production and Reserves
corrosion:
- environment: Air at room temperature
headline: Rubidium tarnishes rapidly in air; no corrosion rate was found in any source opened.
effect: CAMEO Chemicals says rubidium tarnishes rapidly upon exposure to air, and PubChem's summary of the same source says it tarnishes in air. Neither gives a rate, a film thickness or a time scale, so none is recorded. The supplier safety data sheet asks for storage under dry inert gas and away from air.
rating: unknown
conditions:
exposure: room-temperature air; humidity, time and temperature not stated
source: cameo-rb
where: Air and Water Reactions (section 9.7.1)
- environment: Liquid water and moist air
headline: 'Water is the severe case: the reaction gives corrosive rubidium hydroxide and flammable hydrogen.'
effect: CAMEO Chemicals says rubidium reacts violently with water to form corrosive rubidium hydroxide and hydrogen, a flammable gas, and that the heat of the reaction usually ignites the hydrogen. The safety data sheet also lists a severe skin burn and eye damage hazard (H314).
rating: severe
conditions:
exposure: contact with liquid water or moisture
source: cameo-rb
where: Air and Water Reactions (section 9.7.1); Reactivity Alerts (section 9.7.3)
risks:
hazards:
- text: PubChem's GHS summary for rubidium lists H260 (in contact with water releases flammable gases which may ignite spontaneously) and H314 (causes severe skin burns and eye damage), with signal word Danger.
ghs:
- H260
- H314
source: pubchem-rb
where: Section 9.1.1 GHS Classification
- text: The Alfa Aesar safety data sheet (copy hosted by Purdue) gives the same two hazard statements, Danger, and the precautionary statement P231+P232, which reads 'Handle under inert gas. Protect from moisture.'
ghs:
- H260
- H314
source: purdue-rb-sds
where: Section 2, GHS label elements
- text: For fires involving rubidium, the Emergency Response Guidebook guide quoted by CAMEO Chemicals says do not use water or foam, and suggests dry chemical, dry sand or class D extinguishers for metal fires.
ghs: []
source: cameo-rb
where: Fire Fighting and Emergency Response Planning (ERG Guide 138)
- text: The Emergency Response Guidebook first-aid text says to wipe the metal off the skin at once and flush skin or eyes with running water.
ghs: []
source: cameo-rb
where: First Aid, Specific First Aid (ERG Guide 138)
failure_risks:
- mode: Reaction with water or moist air
trigger: Water or humid air reaching the metal
consequence: Flammable hydrogen gas, usually ignited by the heat of the reaction, plus corrosive rubidium hydroxide (CAMEO Chemicals).
severity: high
source: cameo-rb
where: Air and Water Reactions (section 9.7.1)
- mode: Spontaneous burning in dry oxygen
trigger: Exposure to dry oxygen; readily catches fire in air when molten
consequence: The metal burns spontaneously in dry oxygen, according to the CAMEO Chemicals reactivity profile reproduced in PubChem.
severity: high
source: pubchem-rb
where: Section 9.7.4, Reactivity Profile
- mode: Tarnish in air
trigger: Exposure to air
consequence: A tarnish film forms on the metal; no thickness or rate is recorded in the sources opened.
severity: low
source: cameo-rb
where: Air and Water Reactions (section 9.7.1)
side_effects:
- text: Hydrogen and corrosive rubidium hydroxide are released when the metal reacts with water, and the hydrogen is flammable.
affects: Storage area and the people handling the metal
source: cameo-rb
where: Air and Water Reactions (section 9.7.1)
handling:
- text: Handle under dry protective gas, keep the container tightly sealed, and store under dry inert gas, away from water, moisture, air and oxidizing agents, according to the Alfa Aesar safety data sheet.
source: purdue-rb-sds
where: Section 7, Handling and storage
- text: For a spill, cover with dry earth, dry sand or another non-combustible material and do not apply water, per the Emergency Response Guidebook guide quoted by CAMEO Chemicals.
source: cameo-rb
where: Nonfire Spill Response (section 9.5.1)
mitigations:
- text: Use dry chemical, dry sand, sodium chloride powder, graphite powder or class D extinguishers on metal fires (Emergency Response Guidebook guide quoted by CAMEO Chemicals).
source: cameo-rb
where: Emergency Response Planning, Fire Involving Metals or Powders
uses:
- application: electronics-and-chips
device: Rubidium atomic frequency standard on navigation satellites
example: Airbus's catalogue entry says the Rubidium Atomic Frequency Standard was first flown on GIOVE-A, the Galileo test satellite, and has operated successfully since.
source: satcatalog-rafs
where: Overview of the component page
- application: electronics-and-chips
device: GPS Block IIR navigation satellites
example: A NASA-hosted paper by Riley describes rubidium atomic frequency standards provided for the GPS Block IIR NAVSTAR satellites, which were to replenish and upgrade the space segment of the Global Positioning System.
source: ntrs-riley-1990
where: Abstract
- application: optics-and-cameras
device: Photomultiplier tubes, night-vision devices and photoelectric cells
example: The USGS says rubidium's photoemissive properties make it useful for photomultiplier tubes, night-vision devices, photoelectric cells and spectrometers.
source: usgs-mcs2026-rubidium
where: Domestic Production and Use
supply:
- subject: Rubidium
abundance: Rubidium is not a major constituent of any mineral; the crustal abundance printed on the reference data page is in the properties list.
producers: []
critical_lists: []
recycling: 'USGS: Recycling: None.'
substitutes:
- 'USGS: rubidium and cesium can be used interchangeably in many applications because they have similar physical properties and atomic radii; cesium is more electropositive and is preferred for some applications.'
source: usgs-mcs2026-rubidium
where: Domestic Production and Use; World Mine Production and Reserves (the USGS prints that there were no official sources for rubidium production data in 2025, so no country shares are recorded); Recycling; Substitutes (Mineral Commodity Summaries, February 2026). Rubidium is a byproduct of pollucite (cesium) and lepidolite (lithium) mining, per the same chapter.
documents:
- title: Alfa Aesar safety data sheet, rubidium metal, product 10315 (copy hosted by Purdue University; last revision 2015)
type: sds
url: https://www.physics.purdue.edu/primelab/safety/MSDS/SDS/rubidium%20metal%20%20-%20Alfa%2010315.pdf
year: 2015
- title: 'PubChem: Rubidium, CID 5357696, GHS and computed properties'
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/Rubidium
year: 2026
- title: 'CAMEO Chemicals: Rubidium (NOAA chemical 1439)'
type: database
url: https://cameochemicals.noaa.gov/chemical/1439
year: 2026
- title: 'USGS Mineral Commodity Summaries 2026: Rubidium'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-rubidium.pdf
year: 2026
- title: 'NIST: Atomic weights and isotopic compositions for rubidium'
type: database
url: https://physics.nist.gov/cgi-bin/Compositions/stand_alone.pl?ele=Rb&all=all&ascii=html
year: 2026
- title: 'WebElements: Rubidium physical properties'
type: database
url: https://www.webelements.com/rubidium/physics.html
year: 2026
- title: 'Wolfram ElementData: Rubidium (periodictable.com)'
type: database
url: https://periodictable.com/Elements/037/data.html
year: 2026
- title: Airbus Rubidium Atomic Frequency Standard component entry (satcatalog.com)
type: database
url: https://www.satcatalog.com/component/rubidium-atomic-frequency-standard/
year: 2026
- title: Rubidium atomic frequency standards for GPS Block IIR (NASA NTRS 19910016457)
type: report
url: https://ntrs.nasa.gov/citations/19910016457
year: 1990
gaps:
- No flight, radiation, vacuum, outgassing or thermal-cycling result for rubidium metal was found in any source opened. The satellite-clock sources describe units, not the metal.
- Melting point is recorded from three sources that disagree (38.9, 39.31 and 39.5 °C); none is chosen as the reference value.
- Electrical resistivity and conductivity are printed with exponents on both data pages and were not recorded (exponent-form values).
- Mechanical strength of pure rubidium (yield, tensile, hardness in engineering units) was not found; the Mohs and Brinell figures on the reference page are not recorded because no canonical property name fits.
- PubChem lists a different crystal cell for rubidium from an older paper; the cubic cell in the properties is from Wolfram ElementData only, and the conflict is not resolved.
- The manufacturing process for rubidium metal was not described in any source opened, so the recipe gives composition only.
- No corrosion rate, film thickness or ageing time for rubidium in air or under inert gas was found; the corrosion rating for air is unknown.
- 'No country shares of production are recorded: the USGS states that there were no official sources for rubidium production data in 2025.'
- The USGS chapter text read does not state whether rubidium is on a critical-minerals list, so critical_lists is empty.
- DTIC clock papers on the space rubidium clock for Galileo and on GPS rubidium clock life tests could not be opened (the pages returned a maintenance notice), so their design figures are not recorded.
- 'Several property names are not in spores/property-canon.yaml and were used as snake_case names: molar_mass, isotopic_abundance, atomic_number, first_ionization_energy, electronegativity, atomic_radius, lattice_constant, crustal_abundance and recoverable_reserves.'
- No designations (UNS, EN, DIN, JIS) apply to the element; the CAS number is the identifier used.
sources:
purdue-rb-sds:
title: 'Safety data sheet: Rubidium metal, Alfa Aesar product 10315 (copy hosted by Purdue University)'
id: Alfa Aesar product 10315, CAS 7440-17-7
url: https://www.physics.purdue.edu/primelab/safety/MSDS/SDS/rubidium%20metal%20%20-%20Alfa%2010315.pdf
year: 2015
kind: datasheet
license: Supplier safety data sheet (cited, not reproduced)
pubchem-rb:
title: 'PubChem compound record: Rubidium (CID 5357696)'
id: PubChem CID 5357696; CAS 7440-17-7
url: https://pubchem.ncbi.nlm.nih.gov/compound/Rubidium
year: 2026
kind: database
license: Public database record (cited)
cameo-rb:
title: 'CAMEO Chemicals: Rubidium (NOAA chemical 1439), with Emergency Response Guidebook guide 138'
id: UN 1423 (as printed on the record)
url: https://cameochemicals.noaa.gov/chemical/1439
year: 2026
kind: database
license: NOAA public record (cited)
usgs-mcs2026-rubidium:
title: 'Mineral Commodity Summaries 2026: Rubidium (U.S. Geological Survey, February 2026)'
id: USGS Mineral Commodity Summaries, February 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-rubidium.pdf
year: 2026
kind: report
license: U.S. government work (cited)
nist-rb:
title: 'NIST: Atomic weights and isotopic compositions, rubidium (Rb, atomic number 37)'
id: NIST Physical Measurement Laboratory
url: https://physics.nist.gov/cgi-bin/Compositions/stand_alone.pl?ele=Rb&all=all&ascii=html
year: 2026
kind: database
license: U.S. government work (cited)
webelements-rb:
title: 'WebElements: Rubidium, physical properties'
id: WebElements periodic table, element 37
url: https://www.webelements.com/rubidium/physics.html
year: 2026
kind: database
license: Cited, not reproduced
periodictable-rb:
title: 'Wolfram ElementData: Technical data for Rubidium (periodictable.com)'
id: Mathematica ElementData, Wolfram Research
url: https://periodictable.com/Elements/037/data.html
year: 2026
kind: database
license: Cited, not reproduced
satcatalog-rafs:
title: Rubidium Atomic Frequency Standard (Airbus), component entry, satcatalog.com
id: Airbus Rubidium Atomic Frequency Standard
url: https://www.satcatalog.com/component/rubidium-atomic-frequency-standard/
year: 2026
kind: database
license: Cited, not reproduced
ntrs-riley-1990:
title: Rubidium atomic frequency standards for GPS Block IIR (Riley, Edgerton, Germeshausen and Grier)
id: NASA NTRS citation 19910016457
url: https://ntrs.nasa.gov/citations/19910016457
year: 1990
kind: paper
license: NASA public record (cited)
license: CC-BY-4.0
updated: '2026-11-01'
review:
status: draft
method: assistant
checked_values: 22
unreachable: 2
caveats: 3
note: 'Read by an AI assistant on 2026-11-01 from the pages and PDFs named in each entry. verify-values found all 20 other values printed in their sources. Two PubChem values (melting point 39.5 °C and molar mass 85.468 g/mol) could not be re-checked by script because the PubChem page returns a browser-check shell to curl; they were read in a browser in this run. Caveats: the melting point disagrees across three sources and all three are kept; the PubChem page is JavaScript-rendered; the corrosion rating for air is unknown because no rate was found.'
story:
recipe:
line: 'Rubidium is a single element, Rb, with atomic number 37, and it is an alkali metal. Natural rubidium is a mix of two isotopes: rubidium-85 with a mole fraction of 0.7217 and rubidium-87 with 0.2783, per the NIST table. No source opened for this profile describes how the metal is made.'
parts:
- name: Rubidium
symbol: Rb
atoms: 1
atomic_weight: 85.468
role: The whole material. The element's mass is taken from PubChem's computed molecular weight, 85.468 g/mol.
risk_groups:
- title: For people
level: 2
verdict: Severe burns; reacts violently with water
lead: Rubidium is classed as a skin corrosive and as a water-reactive substance, so it is handled as a hazardous material.
points:
- label: Skin and eyes
line: The safety data sheet and PubChem's GHS summary both give H314, causes severe skin burns and eye damage.
- label: Water
line: H260 means contact with water releases flammable gases which may ignite spontaneously. CAMEO Chemicals says the heat of the reaction usually ignites the hydrogen.
- label: First aid
line: The first-aid text quoted from the Emergency Response Guidebook says to wipe the metal off the skin at once and flush with running water.
- title: If it reacts
level: 1
verdict: Fire needs a dry agent, not water
lead: These are reactions the sources describe; no incident record was opened.
points:
- label: Fire
line: Do not use water or foam on a rubidium fire. Use dry chemical, dry sand or class D extinguishers, as the Emergency Response Guidebook guide quoted by CAMEO Chemicals says.
- label: Burning
line: PubChem's reactivity profile, reproduced from CAMEO Chemicals, says the metal burns spontaneously in dry oxygen and catches fire in air when molten.
- title: Handling and storage
level: 0
verdict: Dry inert gas, sealed container
lead: The supplier safety data sheet sets the storage rules.
points:
- label: Storage
line: Handle under dry protective gas and keep the container tightly sealed. Store under dry inert gas, away from water, moisture, air and oxidizing agents.
- label: Spills
line: Cover a spill with dry earth, dry sand or another non-combustible material, and do not apply water.
why: Rubidium is a soft, silvery alkali metal, and it is one of the reactive metals in its group. The USGS names its main use as an atomic resonance-frequency reference, the principle behind the rubidium clocks flown on navigation satellites. Specialty glass is the leading market for rubidium compounds according to the same USGS chapter, and the metal also appears in photomultiplier tubes, night-vision devices and catalysts. Rubidium is a byproduct of pollucite and lepidolite mining, not a primary product, so supply depends on those mines and on stockpiles.
uses:
- where: Navigation satellite clocks
line: Airbus lists a Rubidium Atomic Frequency Standard that was first flown on GIOVE-A, the Galileo test satellite, with successful operation since then. A NASA-hosted paper by Riley describes rubidium atomic frequency standards provided for the GPS Block IIR satellites.
- where: Optical sensors
line: The USGS says rubidium's photoemissive properties make it useful for photomultiplier tubes, night-vision devices, photoelectric cells and spectrometers.
can_do:
- label: Set a time reference
line: The USGS describes rubidium as an atomic resonance-frequency reference, the basis of the clocks flown for global positioning.
- label: Respond to light
line: Rubidium's photoemissive properties are used in photomultiplier tubes and night-vision devices, per the USGS.
- label: Stand in for cesium
line: The USGS says the two can be used interchangeably in many applications because of their similar physical properties and atomic radii.
compare: The USGS says rubidium and cesium can be used interchangeably in many applications, because they have similar physical properties and atomic radii, and that cesium is the more electropositive of the two and is preferred for some uses. Within this profile, the density of 1.532 g/cm3 and the melting point of 38.9 °C in the safety data sheet are the figures to set against other metals in the same table, and the table rows below use this profile's own values.
compare_rows:
- label: Density
benchmark: density
- label: Melting point
benchmark: melting_point
- label: Thermal conductivity
benchmark: thermal_conductivity
handling:
- Store under dry inert gas in a tightly sealed container, away from water and oxidizing agents.
- Never use water on a rubidium fire or spill; cover spills with dry earth or dry sand.
- 'Wear protection against severe skin burns: the GHS statement H314 applies.'
good_for:
- 'Timing: rubidium frequency standards were flown on navigation satellites, as the Airbus catalogue and the NASA-hosted paper describe.'
- 'Specialty glass and optical devices: the USGS names specialty glass as the leading market, with photomultiplier tubes and night-vision devices.'
watch_out:
- Reacts violently with water, forming flammable hydrogen and corrosive rubidium hydroxide.
- Tarnishes in air. No corrosion rate was found, so storage under inert gas is the only guidance in the sources.
- 'Supply: the USGS reports no official rubidium production data for 2025, and rubidium comes mainly from byproducts.'
verdict: Rubidium is a reactive alkali metal whose main documented use is as a frequency reference in navigation satellites. Its handling risk is high, and the sources in this profile give no space-environment data for the metal itself.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
| # | Source | Type | Year | Used for |
|---|---|---|---|---|
| Safety data sheet: Rubidium metal, Alfa Aesar product 10315 (copy hosted by Purdue University) | datasheet | 2015 | 4 values | |
| PubChem compound record: Rubidium (CID 5357696) | database | 2026 | 5 values | |
| CAMEO Chemicals: Rubidium (NOAA chemical 1439), with Emergency Response Guidebook guide 138 | database | 2026 | 9 values | |
| Mineral Commodity Summaries 2026: Rubidium (U.S. Geological Survey, February 2026) | report | 2026 | 3 values | |
| NIST: Atomic weights and isotopic compositions, rubidium (Rb, atomic number 37) | database | 2026 | 2 values | |
| WebElements: Rubidium, physical properties | database | 2026 | 2 values | |
| Wolfram ElementData: Technical data for Rubidium (periodictable.com) | database | 2026 | 13 values | |
| Rubidium Atomic Frequency Standard (Airbus), component entry, satcatalog.com | database | 2026 | 1 value | |
| Rubidium atomic frequency standards for GPS Block IIR (Riley, Edgerton, Germeshausen and Grier) | paper | 1990 | 1 value |
Updated