Kevlar para-aramid fibre PPD-T (Kevlar)

Poly(p-phenylene terephthalamide), repeat unit C14H10N2O2

Kevlar is a para-aramid fibre made from poly(p-phenylene terephthalamide).

8 sources · Updated 2026-10-19 · CC BY 4.0

Evidence level

5 of 5

Flown or field-proven

Strength

2920 MPa

Stiffness

70500 MPa

Flight exposure

6.28e-25 cm3/atom

Recipe, share of the weight

  • C6H8N2 not statedp-Phenylenediamine (monomer)
  • C8H4Cl2O2 not statedTerephthaloyl chloride (monomer)
  • C14H10N2O2 molar mass 238.2452 g/mol (NASA Table IV)Repeat unit

Best for

Light, strong fibre for body armour, cut-resistant gear and ropes, where the fibre is shielded from sunlight

Weakest at

Ultraviolet light, which discolours it and cuts its mechanical strength; and low stiffness in compression

Risk at a glance

  • People None found. Hazards not checked
  • If it fails Moderate. UV discolouration and strength loss
  • Corrosion Severe. UV is Kevlar's main weakness: it yellows and then browns, and mechanical strength falls with long exposure.

Quick facts: PPD-T (Kevlar)

Key properties of PPD-T (Kevlar)
PropertyValueBasis
Density1.44 g/cm³2 sourced values across conditions
Tensile strength2,920 to 3,040 MPa3 sourced values across conditions
Young's modulus70.5 to 112 GPa3 sourced values across conditions
Specific heat1,423 J/(kg·K)1 sourced value

What is the density of Kevlar para-aramid fibre?

Kevlar para-aramid fibre has a density of 1.44 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the tensile strength of Kevlar para-aramid fibre?

Kevlar para-aramid fibre has a tensile strength of 2,920 to 3,040 MPa. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the Young's modulus of Kevlar para-aramid fibre?

Kevlar para-aramid fibre has a Young's modulus of 70.5 to 112 GPa. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is Kevlar para-aramid fibre used for?

Uses recorded in the sources include Body armour and ballistic vests; Cut-resistant gloves and protective clothing; Composite reinforcement.

Why it exists

Kevlar is a para-aramid, so its chains are rigid and aligned, and hydrogen bonds link neighbouring chains. That gives a high strength per unit weight and a high modulus. The trade is UV sensitivity and low compressive strength. In the MISSE 2 flight test it eroded slowly under atomic oxygen, which is why it was included in the passport.

Where it's used

Body armour

Kevlar is a key component of personal armour, including helmets and ballistic vests, as Wikipedia records.

Protective clothing

Gloves, sleeves and jackets made of Kevlar protect against cuts, abrasion and heat, and are lighter than comparable protection (Wikipedia).

Ropes and composites

Kevlar is spun into ropes, used as mooring lines and as a composite ingredient (Wikipedia). Spacecraft shielding and tethers are not covered here because no source was read for them.

Recipe

Poly(p-phenylene terephthalamide), repeat unit C14H10N2O2

Kevlar is made by condensation of p-phenylenediamine with terephthaloyl chloride in solution, which gives hydrochloric acid as a byproduct (Wikipedia). The repeat unit is C14H10N2O2 (NASA Table IV). The polymer forms liquid-crystalline solutions, and drawing orients the chains along the fibre.

What PPD-T (Kevlar) is made of
IngredientShare of the weightWhat it does
p-Phenylenediamine (monomer) C6H8N2 not stated Diamine that forms the rigid para-phenylene and amide-N part of each repeat unit (Wikipedia).
Terephthaloyl chloride (monomer) C8H4Cl2O2 not stated Diacid chloride that forms the terephthalamide part; the byproduct HCl leaves in the condensation (Wikipedia).
Repeat unit C14H10N2O2 molar mass 238.2452 g/mol (NASA Table IV) The polymer unit that repeats along the chain; carbon, hydrogen, nitrogen and oxygen only.

Weight shares are as printed in the sources.

What it can do

Strength

2920 MPa

measured

Kevlar 29 yarn breaks at 2,920 MPa and Kevlar 49 at 3,000 MPa (DuPont guide). A single Kevlar 29 fibre measured 3.04 GPa plus or minus 0.31 GPa.

Stiffness

70500 MPa

measured

Kevlar 29 yarn has a tensile modulus of 70,500 MPa and Kevlar 49 of 112,400 MPa (DuPont guide). A single Kevlar 29 fibre measured 83.78 GPa.

Flight exposure

6.28e-25 cm3/atom

In low Earth orbit on MISSE 2, PPDT eroded by 6.28e-25 cm3 per atomic oxygen atom (NASA Table I).

How it compares

Kevlar is strong and light for a polymer, but it is weaker in UV than many engineering plastics, and it absorbs about five percent moisture. Its atomic-oxygen erosion yield in LEO is lower than several common polymers in the same NASA table, such as polyethylene and PMMA, which makes it a credible choice for space use shielded from sunlight.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Compare every grade in the family.

Benchmarks
MeasurementPPD-T (Kevlar)
Thermal behavior and safety
specific heat0.34 cal/g x °C8
Physical and electrical
Density, Kevlar 29 and 49 yarn1.44 g/cm³2
Density, PPDT by MISSE 2 measurementValue from the NASA erosion report density table1.442 g/cm³
Temperature behavior
Decomposition temperature in air (no melting point)Range printed in the DuPont guide427 to 482 °C
Other measurements
Atomic oxygen erosion yield, MISSE 2 flight6.28×10^-25 cm³/atom1
Breaking tenacity, Kevlar 29 yarn2920 MPa3
Breaking tenacity, Kevlar 49 yarn3000 MPa4
Tensile strength, single Kevlar 29 fibre (laboratory)3040 MPa5
Tensile modulus, Kevlar 29 yarnTypical value printed in DuPont technical guide70500 MPa
Tensile modulus, Kevlar 49 yarnTypical value printed in DuPont technical guide1.12×10^5 MPa
Young's modulus, single Kevlar 29 fibre (laboratory)Measured value printed in the single-fibre study83.78 GPa
Elongation at break, Kevlar 29 yarnTypical value printed in DuPont technical guide3.6 %
Elongation at break, Kevlar 49 yarnTypical value printed in DuPont technical guide2.4 %
Equilibrium moisture regain, PPD-T fibre5 %6
Equilibrium moisture from bone-dry yarn, Kevlar 294.5 %7
Molar mass of repeat unit238.2 g/mol9

Why choose it, and why not

Good for

  • Strength for weight in armour, cut-resistant gear and ropes.
  • Low atomic-oxygen erosion in LEO, measured on MISSE 2.

Watch out for

  • UV discolours and weakens unprotected yarn.
  • Strong acids and hot alkalis degrade the fibre.
  • Compressive strength is poor (PolyOne datasheet).

Kevlar is a strong, light, heat-tolerant fibre whose weak point is sunlight. Shield it from UV, and it performs well in orbit and in armour.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Atomic oxygen erosion yield, MISSE 2 flightFlight-measured erosion yield as printed in the NASA predictive-tool reportexposure low Earth orbit, ISS MISSE 2 PEACE tray 1, 2001-08-16 to 2005-07-30fluence 8.43e21 atoms/cm2solar 5000-6700 equivalent sun hoursthermal cycling -30 to 40 °C nominal base-plate range—
2Density, Kevlar 29 and 49 yarnTypical value printed in the DuPont technical guide tablebasis yarn density as printed for both Kevlar 29 and Kevlar 49—
3Breaking tenacity, Kevlar 29 yarnTypical value printed in DuPont technical guide, shown with the MPa conversion as printedbasis straight test on conditioned yarn, 1,500 denier, standard modulus; printed as 23.0 g/d and 424,000 psi—
4Breaking tenacity, Kevlar 49 yarnTypical value printed in DuPont technical guide, shown with the MPa conversion as printedbasis straight test on conditioned yarn, 1,140 denier, high modulus; printed as 23.6 g/d and 435,000 psi—
5Tensile strength, single Kevlar 29 fibre (laboratory)Measured value printed in the single-fibre study (converted from GPa as printed)basis single-fibre tensile test, printed as 3.04 GPa plus or minus 0.31 GPa—
6Equilibrium moisture regain, PPD-T fibreValue printed in the PolyOne/Fiber-Line Kevlar para-aramid datasheet (both standard and high modulus grades)basis equilibrium moisture regain at 55% relative humidity—
7Equilibrium moisture from bone-dry yarn, Kevlar 29Value printed in DuPont technical guide, moisture levelsbasis bone-dry yarn conditioned at 75 degF (24 °C) and 55% RH—
8specific heatValue printed in DuPont technical guide; printed unit keptbasis at 77 degF (25 °C), as printed in the DuPont table—
9Molar mass of repeat unitValue printed in the NASA table of polymer chemical structurerepeat unit C14H10N2O2—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Ultraviolet light and sunlight severe UV is Kevlar's main weakness: it yellows and then browns, and mechanical strength falls with long exposure.1
Humid air low Kevlar takes up moisture, but its tensile properties are virtually unaffected by moisture content.2
Heat (thermal ageing) moderate Strength drops about 10 to 20 percent at once when heated, then keeps falling with time at high temperature.3
Strong acids and alkalis at high temperature moderate Kevlar holds strength in neutral water but degrades in strong acids and hot alkalis.4
Corrosion details
#EnvironmentDetailsTest conditions
1 Ultraviolet light and sunlight Unprotected yarn discolours from yellow to brown after prolonged exposure, and extended UV exposure can cut mechanical properties depending on wavelength, time and intensity. Degradation needs oxygen, and it is not increased by moisture or sulfur dioxide. The overlap of the fibre absorption spectrum and sunlight lies between 300 and 450 nm, so that range must be excluded for protection. exposure sunlight or UV, unprotected, in the presence of oxygenwavelength range 300 to 450 nm overlap with sunlight
2 Humid air Equilibrium moisture regain is about 5.0% at 55% RH and rises linearly with relative humidity. Bone-dry Kevlar 29 reaches 4.5% at equilibrium. The guide states that tensile properties are virtually unaffected by moisture content. humidity 55% RH equilibrium; linear with RHtemperature 24 °C
3 Heat (thermal ageing) Per Wikipedia, tensile strength falls by 10 to 20 percent at higher temperatures straight away, and strength keeps reducing over hours. Enduring 160 degC for 500 hours reduces strength by about 10 percent. The fibre keeps strength down to cryogenic temperatures. example 160 °C for 500 hours, about 10 percent lossnote secondary source; not the DuPont test
4 Strong acids and alkalis at high temperature At neutral pH the filament tenacity stays unchanged after 200 days at 65 degC. Acidic conditions cause more severe degradation than basic ones, and the guide's table lists degradation in formic acid at 90 percent and in hydrochloric acid at 10 percent and 160 degF (71 degC). Sodium hydroxide at 10 percent and 210 degF (99 degC) degrades the fibre. basis guide table of chemical exposures; strength loss read as Degraded in the table

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

No safety data sheet or GHS record for Kevlar was read in this run, so no hazard classification is given.

Dust and cutting
The fibre is handled as yarn or fabric. Check the supplier safety data sheet before cutting or grinding it.
Fire
Kevlar does not melt. It decomposes between 427 and 482 degC in air (DuPont guide).

In the environment

UV is the main route to loss of strength.

UV
Unprotected yarn discolours from yellow to brown and loses strength with long exposure; the 300 to 450 nm range must be excluded (DuPont guide).
Moisture
Kevlar takes up about 5 percent moisture at 55 percent RH, but its tensile properties are virtually unaffected (PolyOne datasheet, DuPont guide).

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
UV discolouration and strength lossmoderate severityUnprotected sunlight or UV exposure in the presence of oxygenYellowing, then browning, and loss of mechanical properties with long exposure
Thermal decomposition at high temperaturemoderate severityHeating above about 427 degC in airKevlar does not melt; it decomposes between 427 and 482 degC in air
Chemical attackmoderate severityStrong formic or hydrochloric acid, or hot sodium hydroxideBreaking strength falls with the exposure table's degradation rating

Handling and storage

  • Shield the fibre from sunlight and UV; the guide says the 300 to 450 nm range must be excluded for outdoor use without protection.
  • Avoid dust formation: use exhaust ventilation or vacuum cleaning rather than dry sweeping, wear safety glasses with side shields, and use a certified respirator where the exposure limit is exceeded.

Mitigations

  • Use UV-blocking protection or stow the fibre in darkness; discolouration of fresh yarn from ordinary room light is normal and is not degradation.

Supply and geography

How common the raw materials are and where they come from.

Kevlar (PPD-T) production

Not sourced. Feedstock is the two monomers, p-phenylenediamine and terephthaloyl chloride (Wikipedia).

Recycling
Not sourced.
Substitutes
Twaron, a fibre with the same chemical structure developed by Akzo, produced by Teijin Aramid (Wikipedia).