Kevlar para-aramid fibre PPD-T (Kevlar)
Poly(p-phenylene terephthalamide), repeat unit C14H10N2O2
Kevlar is a para-aramid fibre made from poly(p-phenylene terephthalamide).
Evidence level
5 of 5
Flown or field-proven
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Strength
2920 MPa
Stiffness
70500 MPa
Flight exposure
6.28e-25 cm3/atom
Recipe, share of the weight
- C6H8N2 not statedp-Phenylenediamine (monomer)
- C8H4Cl2O2 not statedTerephthaloyl chloride (monomer)
- C14H10N2O2 molar mass 238.2452 g/mol (NASA Table IV)Repeat unit
Best for
Light, strong fibre for body armour, cut-resistant gear and ropes, where the fibre is shielded from sunlight
Weakest at
Ultraviolet light, which discolours it and cuts its mechanical strength; and low stiffness in compression
Risk at a glance
- People None found. Hazards not checked
- If it fails Moderate. UV discolouration and strength loss
- Corrosion Severe. UV is Kevlar's main weakness: it yellows and then browns, and mechanical strength falls with long exposure.
Quick facts: PPD-T (Kevlar)
| Property | Value | Basis |
|---|---|---|
| Density | 1.44 g/cm³ | 2 sourced values across conditions |
| Tensile strength | 2,920 to 3,040 MPa | 3 sourced values across conditions |
| Young's modulus | 70.5 to 112 GPa | 3 sourced values across conditions |
| Specific heat | 1,423 J/(kg·K) | 1 sourced value |
What is the density of Kevlar para-aramid fibre?
Kevlar para-aramid fibre has a density of 1.44 g/cm³. The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the tensile strength of Kevlar para-aramid fibre?
Kevlar para-aramid fibre has a tensile strength of 2,920 to 3,040 MPa. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the Young's modulus of Kevlar para-aramid fibre?
Kevlar para-aramid fibre has a Young's modulus of 70.5 to 112 GPa. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is Kevlar para-aramid fibre used for?
Uses recorded in the sources include Body armour and ballistic vests; Cut-resistant gloves and protective clothing; Composite reinforcement.
Why it exists
Kevlar is a para-aramid, so its chains are rigid and aligned, and hydrogen bonds link neighbouring chains. That gives a high strength per unit weight and a high modulus. The trade is UV sensitivity and low compressive strength. In the MISSE 2 flight test it eroded slowly under atomic oxygen, which is why it was included in the passport.
Where it's used
Body armour
Kevlar is a key component of personal armour, including helmets and ballistic vests, as Wikipedia records.
Protective clothing
Gloves, sleeves and jackets made of Kevlar protect against cuts, abrasion and heat, and are lighter than comparable protection (Wikipedia).
Ropes and composites
Kevlar is spun into ropes, used as mooring lines and as a composite ingredient (Wikipedia). Spacecraft shielding and tethers are not covered here because no source was read for them.
Recipe
Poly(p-phenylene terephthalamide), repeat unit C14H10N2O2
Kevlar is made by condensation of p-phenylenediamine with terephthaloyl chloride in solution, which gives hydrochloric acid as a byproduct (Wikipedia). The repeat unit is C14H10N2O2 (NASA Table IV). The polymer forms liquid-crystalline solutions, and drawing orients the chains along the fibre.
| Ingredient | Share of the weight | What it does |
|---|---|---|
| p-Phenylenediamine (monomer) C6H8N2 | not stated | Diamine that forms the rigid para-phenylene and amide-N part of each repeat unit (Wikipedia). |
| Terephthaloyl chloride (monomer) C8H4Cl2O2 | not stated | Diacid chloride that forms the terephthalamide part; the byproduct HCl leaves in the condensation (Wikipedia). |
| Repeat unit C14H10N2O2 | molar mass 238.2452 g/mol (NASA Table IV) | The polymer unit that repeats along the chain; carbon, hydrogen, nitrogen and oxygen only. |
Weight shares are as printed in the sources.
What it can do
Strength
2920 MPa
measured
Kevlar 29 yarn breaks at 2,920 MPa and Kevlar 49 at 3,000 MPa (DuPont guide). A single Kevlar 29 fibre measured 3.04 GPa plus or minus 0.31 GPa.
Stiffness
70500 MPa
measured
Kevlar 29 yarn has a tensile modulus of 70,500 MPa and Kevlar 49 of 112,400 MPa (DuPont guide). A single Kevlar 29 fibre measured 83.78 GPa.
Flight exposure
6.28e-25 cm3/atom
In low Earth orbit on MISSE 2, PPDT eroded by 6.28e-25 cm3 per atomic oxygen atom (NASA Table I).
How it compares
Kevlar is strong and light for a polymer, but it is weaker in UV than many engineering plastics, and it absorbs about five percent moisture. Its atomic-oxygen erosion yield in LEO is lower than several common polymers in the same NASA table, such as polyethylene and PMMA, which makes it a credible choice for space use shielded from sunlight.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Compare every grade in the family.
| Measurement | PPD-T (Kevlar) |
|---|---|
| Thermal behavior and safety | |
| specific heat | 0.34 cal/g x °C8 |
| Physical and electrical | |
| Density, Kevlar 29 and 49 yarn | 1.44 g/cm³2 |
| Density, PPDT by MISSE 2 measurementValue from the NASA erosion report density table | 1.442 g/cm³ |
| Temperature behavior | |
| Decomposition temperature in air (no melting point)Range printed in the DuPont guide | 427 to 482 °C |
| Other measurements | |
| Atomic oxygen erosion yield, MISSE 2 flight | 6.28×10^-25 cm³/atom1 |
| Breaking tenacity, Kevlar 29 yarn | 2920 MPa3 |
| Breaking tenacity, Kevlar 49 yarn | 3000 MPa4 |
| Tensile strength, single Kevlar 29 fibre (laboratory) | 3040 MPa5 |
| Tensile modulus, Kevlar 29 yarnTypical value printed in DuPont technical guide | 70500 MPa |
| Tensile modulus, Kevlar 49 yarnTypical value printed in DuPont technical guide | 1.12×10^5 MPa |
| Young's modulus, single Kevlar 29 fibre (laboratory)Measured value printed in the single-fibre study | 83.78 GPa |
| Elongation at break, Kevlar 29 yarnTypical value printed in DuPont technical guide | 3.6 % |
| Elongation at break, Kevlar 49 yarnTypical value printed in DuPont technical guide | 2.4 % |
| Equilibrium moisture regain, PPD-T fibre | 5 %6 |
| Equilibrium moisture from bone-dry yarn, Kevlar 29 | 4.5 %7 |
| Molar mass of repeat unit | 238.2 g/mol9 |
Why choose it, and why not
Good for
- Strength for weight in armour, cut-resistant gear and ropes.
- Low atomic-oxygen erosion in LEO, measured on MISSE 2.
Watch out for
- UV discolours and weakens unprotected yarn.
- Strong acids and hot alkalis degrade the fibre.
- Compressive strength is poor (PolyOne datasheet).
Kevlar is a strong, light, heat-tolerant fibre whose weak point is sunlight. Shield it from UV, and it performs well in orbit and in armour.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Atomic oxygen erosion yield, MISSE 2 flight | Flight-measured erosion yield as printed in the NASA predictive-tool report | exposure low Earth orbit, ISS MISSE 2 PEACE tray 1, 2001-08-16 to 2005-07-30fluence 8.43e21 atoms/cm2solar 5000-6700 equivalent sun hoursthermal cycling -30 to 40 °C nominal base-plate range | — |
| 2 | Density, Kevlar 29 and 49 yarn | Typical value printed in the DuPont technical guide table | basis yarn density as printed for both Kevlar 29 and Kevlar 49 | — |
| 3 | Breaking tenacity, Kevlar 29 yarn | Typical value printed in DuPont technical guide, shown with the MPa conversion as printed | basis straight test on conditioned yarn, 1,500 denier, standard modulus; printed as 23.0 g/d and 424,000 psi | — |
| 4 | Breaking tenacity, Kevlar 49 yarn | Typical value printed in DuPont technical guide, shown with the MPa conversion as printed | basis straight test on conditioned yarn, 1,140 denier, high modulus; printed as 23.6 g/d and 435,000 psi | — |
| 5 | Tensile strength, single Kevlar 29 fibre (laboratory) | Measured value printed in the single-fibre study (converted from GPa as printed) | basis single-fibre tensile test, printed as 3.04 GPa plus or minus 0.31 GPa | — |
| 6 | Equilibrium moisture regain, PPD-T fibre | Value printed in the PolyOne/Fiber-Line Kevlar para-aramid datasheet (both standard and high modulus grades) | basis equilibrium moisture regain at 55% relative humidity | — |
| 7 | Equilibrium moisture from bone-dry yarn, Kevlar 29 | Value printed in DuPont technical guide, moisture levels | basis bone-dry yarn conditioned at 75 degF (24 °C) and 55% RH | — |
| 8 | specific heat | Value printed in DuPont technical guide; printed unit kept | basis at 77 degF (25 °C), as printed in the DuPont table | — |
| 9 | Molar mass of repeat unit | Value printed in the NASA table of polymer chemical structure | repeat unit C14H10N2O2 | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Ultraviolet light and sunlight | severe | UV is Kevlar's main weakness: it yellows and then browns, and mechanical strength falls with long exposure.1 |
| Humid air | low | Kevlar takes up moisture, but its tensile properties are virtually unaffected by moisture content.2 |
| Heat (thermal ageing) | moderate | Strength drops about 10 to 20 percent at once when heated, then keeps falling with time at high temperature.3 |
| Strong acids and alkalis at high temperature | moderate | Kevlar holds strength in neutral water but degrades in strong acids and hot alkalis.4 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Ultraviolet light and sunlight | Unprotected yarn discolours from yellow to brown after prolonged exposure, and extended UV exposure can cut mechanical properties depending on wavelength, time and intensity. Degradation needs oxygen, and it is not increased by moisture or sulfur dioxide. The overlap of the fibre absorption spectrum and sunlight lies between 300 and 450 nm, so that range must be excluded for protection. | exposure sunlight or UV, unprotected, in the presence of oxygenwavelength range 300 to 450 nm overlap with sunlight |
| 2 | Humid air | Equilibrium moisture regain is about 5.0% at 55% RH and rises linearly with relative humidity. Bone-dry Kevlar 29 reaches 4.5% at equilibrium. The guide states that tensile properties are virtually unaffected by moisture content. | humidity 55% RH equilibrium; linear with RHtemperature 24 °C |
| 3 | Heat (thermal ageing) | Per Wikipedia, tensile strength falls by 10 to 20 percent at higher temperatures straight away, and strength keeps reducing over hours. Enduring 160 degC for 500 hours reduces strength by about 10 percent. The fibre keeps strength down to cryogenic temperatures. | example 160 °C for 500 hours, about 10 percent lossnote secondary source; not the DuPont test |
| 4 | Strong acids and alkalis at high temperature | At neutral pH the filament tenacity stays unchanged after 200 days at 65 degC. Acidic conditions cause more severe degradation than basic ones, and the guide's table lists degradation in formic acid at 90 percent and in hydrochloric acid at 10 percent and 160 degF (71 degC). Sodium hydroxide at 10 percent and 210 degF (99 degC) degrades the fibre. | basis guide table of chemical exposures; strength loss read as Degraded in the table |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
No safety data sheet or GHS record for Kevlar was read in this run, so no hazard classification is given.
- Dust and cutting
- The fibre is handled as yarn or fabric. Check the supplier safety data sheet before cutting or grinding it.
- Fire
- Kevlar does not melt. It decomposes between 427 and 482 degC in air (DuPont guide).
In the environment
UV is the main route to loss of strength.
- UV
- Unprotected yarn discolours from yellow to brown and loses strength with long exposure; the 300 to 450 nm range must be excluded (DuPont guide).
- Moisture
- Kevlar takes up about 5 percent moisture at 55 percent RH, but its tensile properties are virtually unaffected (PolyOne datasheet, DuPont guide).
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| UV discolouration and strength lossmoderate severity | Unprotected sunlight or UV exposure in the presence of oxygenYellowing, then browning, and loss of mechanical properties with long exposure |
| Thermal decomposition at high temperaturemoderate severity | Heating above about 427 degC in airKevlar does not melt; it decomposes between 427 and 482 degC in air |
| Chemical attackmoderate severity | Strong formic or hydrochloric acid, or hot sodium hydroxideBreaking strength falls with the exposure table's degradation rating |
Handling and storage
- Shield the fibre from sunlight and UV; the guide says the 300 to 450 nm range must be excluded for outdoor use without protection.
- Avoid dust formation: use exhaust ventilation or vacuum cleaning rather than dry sweeping, wear safety glasses with side shields, and use a certified respirator where the exposure limit is exceeded.
Mitigations
- Use UV-blocking protection or stow the fibre in darkness; discolouration of fresh yarn from ordinary room light is normal and is not degradation.
Supply and geography
How common the raw materials are and where they come from.
Kevlar (PPD-T) production
Not sourced. Feedstock is the two monomers, p-phenylenediamine and terephthaloyl chloride (Wikipedia).
- Recycling
- Not sourced.
- Substitutes
- Twaron, a fibre with the same chemical structure developed by Akzo, produced by Teijin Aramid (Wikipedia).
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
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spore: profile
id: kevlar
spore_version: 0.2
family: glass-and-composites
name: Kevlar para-aramid fibre
abbreviation: PPD-T (Kevlar)
role: high-strength fibre
category: polymers
type: aramids
summary: |
Kevlar is a para-aramid fibre made from poly(p-phenylene terephthalamide). Its rigid, rod-like chains are held together by hydrogen bonds, which gives a tensile strength about five times that of steel by weight. It resists heat without melting, but it discolours and loses strength under ultraviolet light. In low Earth orbit on the MISSE 2 tray, PPDT eroded by 6.28e-25 cm3 per oxygen atom, a low erosion yield for a polymer in that list.
best_for: Light, strong fibre for body armour, cut-resistant gear and ropes, where the fibre is shielded from sunlight
weakest_at: Ultraviolet light, which discolours it and cuts its mechanical strength; and low stiffness in compression
identity:
formula: Poly(p-phenylene terephthalamide), repeat unit C14H10N2O2
source: nasa-tm
where: Table IV (PPD-T repeat unit C14H10N2O2, 238.2452 g/mol); DuPont guide, Section I (aromatic polyamide)
tags:
environments:
- low-earth-orbit
stresses:
- atomic-oxygen
- uv
- thermal-cycling
applications:
- habitats-and-suits
- structures
properties:
- benchmark: atomic_oxygen_erosion_yield
label: Atomic oxygen erosion yield, MISSE 2 flight
value: 6.28e-25
unit: cm3/atom
scope: material
conditions:
exposure: low Earth orbit, ISS MISSE 2 PEACE tray 1, 2001-08-16 to 2005-07-30
fluence: 8.43e21 atoms/cm2
solar: 5000-6700 equivalent sun hours
thermal_cycling: '-30 to 40 degC nominal base-plate range'
method: Flight-measured erosion yield as printed in the NASA predictive-tool report
status: flight
source: nasa-tm
where: Table I (MISSE 2 PEACE polymers erosion yield data, row PPDT (Kevlar)); exposure in section 2.1
- benchmark: density
label: Density, Kevlar 29 and 49 yarn
value: 1.44
unit: g/cm3
scope: material
conditions:
basis: yarn density as printed for both Kevlar 29 and Kevlar 49
method: Typical value printed in the DuPont technical guide table
status: ground
source: dupont-guide
where: Table II-1, Density row
- benchmark: density
label: Density, PPDT by MISSE 2 measurement
value: 1.4422
unit: g/cm3
scope: material
conditions:
basis: measured density of the MISSE 2 PPDT sample as printed
method: Value from the NASA erosion report density table
status: ground
source: nasa-tm
where: Table II (density and ash content, row PPDT (Kevlar))
- benchmark: ultimate_tensile_strength
label: Breaking tenacity, Kevlar 29 yarn
value: 2920
unit: MPa
scope: material
conditions:
basis: straight test on conditioned yarn, 1,500 denier, standard modulus; printed as 23.0 g/d and 424,000 psi
method: Typical value printed in DuPont technical guide, shown with the MPa conversion as printed
status: ground
source: dupont-guide
where: Table II-1, Breaking Tenacity row (Kevlar 29 column)
- benchmark: ultimate_tensile_strength
label: Breaking tenacity, Kevlar 49 yarn
value: 3000
unit: MPa
scope: material
conditions:
basis: straight test on conditioned yarn, 1,140 denier, high modulus; printed as 23.6 g/d and 435,000 psi
method: Typical value printed in DuPont technical guide, shown with the MPa conversion as printed
status: ground
source: dupont-guide
where: Table II-1, Breaking Tenacity row (Kevlar 49 column)
- benchmark: ultimate_tensile_strength
label: Tensile strength, single Kevlar 29 fibre (laboratory)
value: 3040
unit: MPa
scope: material
conditions:
basis: single-fibre tensile test, printed as 3.04 GPa plus or minus 0.31 GPa
method: Measured value printed in the single-fibre study (converted from GPa as printed)
status: ground
source: cimav-k29
where: Results, tensile strength row
- benchmark: elastic_modulus
label: Tensile modulus, Kevlar 29 yarn
value: 70500
unit: MPa
scope: material
conditions:
basis: straight test on conditioned yarn, standard modulus; printed as 555 g/d and 10.2e6 psi
method: Typical value printed in DuPont technical guide
status: ground
source: dupont-guide
where: Table II-1, Tensile Modulus row (Kevlar 29 column)
- benchmark: elastic_modulus
label: Tensile modulus, Kevlar 49 yarn
value: 112400
unit: MPa
scope: material
conditions:
basis: straight test on conditioned yarn, high modulus; printed as 885 g/d and 6.3e6 psi
method: Typical value printed in DuPont technical guide
status: ground
source: dupont-guide
where: Table II-1, Tensile Modulus row (Kevlar 49 column)
- benchmark: elastic_modulus
label: Young's modulus, single Kevlar 29 fibre (laboratory)
value: 83.78
unit: GPa
scope: material
conditions:
basis: single-fibre tensile test, printed as 83.78 plus or minus 7.12 GPa
method: Measured value printed in the single-fibre study
status: ground
source: cimav-k29
where: Results, Young's modulus row
- benchmark: elongation
label: Elongation at break, Kevlar 29 yarn
value: 3.6
unit: '%'
scope: material
conditions:
basis: straight test on conditioned yarn
method: Typical value printed in DuPont technical guide
status: ground
source: dupont-guide
where: Table II-1, Elongation at Break row (Kevlar 29 column)
- benchmark: elongation
label: Elongation at break, Kevlar 49 yarn
value: 2.4
unit: '%'
scope: material
conditions:
basis: straight test on conditioned yarn
method: Typical value printed in DuPont technical guide
status: ground
source: dupont-guide
where: Table II-1, Elongation at Break row (Kevlar 49 column)
- benchmark: moisture_absorption
label: Equilibrium moisture regain, PPD-T fibre
value: 5
unit: '%'
scope: material
conditions:
basis: equilibrium moisture regain at 55% relative humidity
method: Value printed in the PolyOne/Fiber-Line Kevlar para-aramid datasheet (both standard and high modulus grades)
status: ground
source: polyone-kevlar
where: Kevlar para-aramid data table, Moisture Regain row
- benchmark: moisture_absorption
label: Equilibrium moisture from bone-dry yarn, Kevlar 29
value: 4.5
unit: '%'
scope: material
conditions:
basis: bone-dry yarn conditioned at 75 degF (24 degC) and 55% RH
method: Value printed in DuPont technical guide, moisture levels
status: ground
source: dupont-guide
where: Table II-1, Moisture Levels row (equilibrium from bone-dry yarn)
- benchmark: specific_heat
value: 0.34
unit: cal/g x degC
scope: material
conditions:
basis: at 77 degF (25 degC), as printed in the DuPont table
method: Value printed in DuPont technical guide; printed unit kept
status: ground
source: dupont-guide
where: Table II-1 Thermal Properties, specific heat row (At 77 degF)
- benchmark: decomposition_temperature
label: Decomposition temperature in air (no melting point)
value: 427
value_high: 482
bound: range
unit: degC
scope: material
conditions:
basis: decomposes rather than melts; range measured at a 10 degC per minute temperature rise in air, nitrogen about 538 degC
method: Range printed in the DuPont guide
status: ground
source: dupont-guide
where: Section 2, Decomposition Temperature; Table II-1 Decomposition Temperature row
- benchmark: molar_mass
label: Molar mass of repeat unit
value: 238.2452
unit: g/mol
scope: material
conditions:
repeat_unit: C14H10N2O2
method: Value printed in the NASA table of polymer chemical structure
status: ground
source: nasa-tm
where: Table IV, row PPD-T (Kevlar)
corrosion:
- environment: Ultraviolet light and sunlight
headline: 'UV is Kevlar''s main weakness: it yellows and then browns, and mechanical strength falls with long exposure.'
effect: Unprotected yarn discolours from yellow to brown after prolonged exposure, and extended UV exposure can cut mechanical properties depending on wavelength, time and intensity. Degradation needs oxygen, and it is not increased by moisture or sulfur dioxide. The overlap of the fibre absorption spectrum and sunlight lies between 300 and 450 nm, so that range must be excluded for protection.
rating: severe
conditions:
exposure: sunlight or UV, unprotected, in the presence of oxygen
wavelength_range: 300 to 450 nm overlap with sunlight
source: dupont-guide
where: Section 2, Effect of UV Light on Kevlar, and Figure 2.11
- environment: Humid air
headline: Kevlar takes up moisture, but its tensile properties are virtually unaffected by moisture content.
effect: Equilibrium moisture regain is about 5.0% at 55% RH and rises linearly with relative humidity. Bone-dry Kevlar 29 reaches 4.5% at equilibrium. The guide states that tensile properties are virtually unaffected by moisture content.
rating: low
conditions:
humidity: 55% RH equilibrium; linear with RH
temperature: 24 degC
source: polyone-kevlar
where: Kevlar para-aramid data, Moisture Regain row; DuPont guide Section 2, Moisture Regain
- environment: Heat (thermal ageing)
headline: Strength drops about 10 to 20 percent at once when heated, then keeps falling with time at high temperature.
effect: Per Wikipedia, tensile strength falls by 10 to 20 percent at higher temperatures straight away, and strength keeps reducing over hours. Enduring 160 degC for 500 hours reduces strength by about 10 percent. The fibre keeps strength down to cryogenic temperatures.
rating: moderate
conditions:
example: 160 degC for 500 hours, about 10 percent loss
note: secondary source; not the DuPont test
source: wiki-kevlar
where: Thermal properties section
- environment: Strong acids and alkalis at high temperature
headline: Kevlar holds strength in neutral water but degrades in strong acids and hot alkalis.
effect: At neutral pH the filament tenacity stays unchanged after 200 days at 65 degC. Acidic conditions cause more severe degradation than basic ones, and the guide's table lists degradation in formic acid at 90 percent and in hydrochloric acid at 10 percent and 160 degF (71 degC). Sodium hydroxide at 10 percent and 210 degF (99 degC) degrades the fibre.
rating: moderate
conditions:
basis: guide table of chemical exposures; strength loss read as Degraded in the table
source: dupont-guide
where: Section 2 chemical resistance tables; Chemical Compatibility text
risks:
hazards:
- text: 'PubChem aggregated GHS for p-phenylenediamine (Kevlar monomer, CID 7814; 597 company reports): H301 toxic if swallowed, H311 toxic in contact with skin, H331 toxic if inhaled (each 99.7%); H317 may cause an allergic skin reaction; H319 causes serious eye irritation; H370 causes damage to organs (38.9%); H400 and H410 very toxic to aquatic life. Signal word Danger.'
ghs:
- H301
- H311
- H331
- H317
- H319
- H370
- H400
- H410
source: pubchem-kevlar-monomers
where: Safety and Hazards, GHS Classification (CID 7814)
- text: 'PubChem aggregated GHS for terephthaloyl chloride (Kevlar monomer, CID 7488; 2263 company reports): 88.7% of reports say it does not meet GHS criteria. Where classified: H314 causes severe skin burns and eye damage (11.2%); H331 toxic if inhaled (11.1%). Signal word Danger.'
ghs:
- H314
- H331
source: pubchem-kevlar-monomers
where: Safety and Hazards, GHS Classification (CID 7488)
- text: 'Fibre dust and particulates: the DuPont SDS gives the product hazard as combustible dust. Small particles from processing or handling may form combustible dust concentrations in air. Fibre fly and dust can irritate the eyes, nose and airways, and rubbing fibre particulates on skin can cause transitory mild redness or itching. The SDS does not describe fibrils as a separate hazard.'
ghs: []
source: sds-kevlar
where: Section 2 Hazard statements; Handling (Personnel) row
- text: 'Dust and fibre exposure limits from the SDS: DuPont AEL 2 RFP/cc for respirable fibres and 5 mg/m3 for non-fibrous dust (8 and 12 h TWA); OSHA PEL 5 mg/m3 respirable fraction and 15 mg/m3 total dust; ACGIH TLV 3 mg/m3 respirable and 10 mg/m3 inhalable.'
ghs: []
source: sds-kevlar
where: Section 8, Exposure Limit Values
- text: 'Fire: the SDS gives an ignition temperature of does not ignite and a decomposition temperature above 300 degC. Burning gives carbon dioxide, nitrogen oxides, hydrogen cyanide, ammonia, aldehydes and hydrocarbons. Firefighters need self-contained breathing apparatus.'
ghs: []
source: sds-kevlar
where: Fire-fighting measures; Flammability and Decomposition rows
failure_risks:
- mode: UV discolouration and strength loss
trigger: Unprotected sunlight or UV exposure in the presence of oxygen
consequence: Yellowing, then browning, and loss of mechanical properties with long exposure
severity: moderate
source: dupont-guide
where: Section 2, Effect of UV Light on Kevlar
- mode: Thermal decomposition at high temperature
trigger: Heating above about 427 degC in air
consequence: Kevlar does not melt; it decomposes between 427 and 482 degC in air
severity: moderate
source: dupont-guide
where: Section 2, Decomposition Temperature
- mode: Chemical attack
trigger: Strong formic or hydrochloric acid, or hot sodium hydroxide
consequence: Breaking strength falls with the exposure table's degradation rating
severity: moderate
source: dupont-guide
where: Chemical resistance tables; Chemical Compatibility text
side_effects: []
handling:
- text: Shield the fibre from sunlight and UV; the guide says the 300 to 450 nm range must be excluded for outdoor use without protection.
source: dupont-guide
where: Section 2, Effect of UV Light on Kevlar
- text: 'Avoid dust formation: use exhaust ventilation or vacuum cleaning rather than dry sweeping, wear safety glasses with side shields, and use a certified respirator where the exposure limit is exceeded.'
source: sds-kevlar
where: Handling (Personnel), Spill Cleanup and Section 8 Exposure Controls
mitigations:
- text: Use UV-blocking protection or stow the fibre in darkness; discolouration of fresh yarn from ordinary room light is normal and is not degradation.
source: dupont-guide
where: Section 2, Effect of UV Light on Kevlar
uses:
- application: habitats-and-suits
device: Body armour and ballistic vests
example: Kevlar is a well-known component of personal armour, including helmets and ballistic vests; the US military PASGT helmet and vest relied on it.
source: wiki-kevlar
where: Applications section (personal armour)
- application: habitats-and-suits
device: Cut-resistant gloves and protective clothing
example: Kevlar is used in gloves, sleeves and jackets to protect against cuts, abrasions and heat.
source: wiki-kevlar
where: Applications section (protective clothing)
- application: structures
device: Composite reinforcement
example: Kevlar is spun into ropes or fabric, or used as an ingredient in composite components, and is used for mooring lines.
source: wiki-kevlar
where: Lead paragraphs; applications section
- application: propulsion-and-tanks
device: Stuffed Whipple shield on a robotic spacecraft propellant tank
example: The PACE tank ram-direction shield used six layers of Nextel and six layers of Kevlar between two 0.20 cm aluminium plates with a 4 cm standoff, chosen to balance risk and mass.
source: ntrs-whipple
where: Text after the case comparison table, selected ram shield configuration (Case 6)
supply:
- subject: Kevlar (PPD-T) production
abundance: Not sourced. Feedstock is the two monomers, p-phenylenediamine and terephthaloyl chloride (Wikipedia).
producers: []
critical_lists: []
recycling: Not sourced.
substitutes:
- Twaron, a fibre with the same chemical structure developed by Akzo, produced by Teijin Aramid (Wikipedia).
source: wiki-kevlar
where: Lead paragraphs; Production section
media: []
documents:
- title: 'NASA/TM-2008-215490: Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit'
type: report
url: https://ntrs.nasa.gov/citations/20090011780
year: 2008
- title: DuPont Kevlar Technical Guide (copy hosted at r-g.de)
type: datasheet
url: https://www.r-g.de/wiki/images/e/ec/Td_en_Kevlar_guide.pdf
year: 2010
- title: PolyOne / Fiber-Line Kevlar para-aramid datasheet
type: datasheet
url: https://automotive.polyone.com/sites/default/files/2021-06/fl.us-.datasheet-kevlar-para-aramid.pdf
year: 2021
- title: The tensile behavior of Kevlar 29 fibers (CIMAV repository)
type: paper
url: https://cimav.repositorioinstitucional.mx/jspui/bitstream/1004/1347/1/The%20tensile%20behavior%20of%20Kevlar%2029%20fibers.pdf
year: 2014
- title: KEVLAR Para-aramid Safety Data Sheet, Version 8.1 (copy hosted by Easy Composites)
type: sds
url: https://media.easycomposites.co.uk/datasheets/Dupont-Kevlar-SDS-Ver8_1-23Mar2023.pdf
year: 2024
- title: Application of Stuffed Whipple Shield to Robotic Spacecraft (NTRS 20230015317)
type: paper
url: https://ntrs.nasa.gov/citations/20230015317
year: 2023
- title: 'PubChem GHS classification: p-phenylenediamine (CID 7814) and terephthaloyl chloride (CID 7488)'
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/7814
year: 2026
gaps:
- No Kevlar 149 value found in any fetched page; the DuPont guide copy has Kevlar 29 and 49 only. Kevlar 149 is named in Wikipedia as the highest-tenacity grade, without numbers.
- No PubChem record exists for the polymer (searches for Kevlar and poly(p-phenylene terephthalamide) returned none), so hazards use the two monomers and the DuPont SDS for Kevlar. The fibrils hazard is not described separately in any source read.
- The Stuffed Whipple paper NTRS 20230015317 was read and is used for the layup only, not for property values. NTRS 20250001790 (a basalt paper) would not download and is not used.
- No tether or space-tether source was read for Kevlar; the tether use is not included.
- No producer list or production volumes were found; supply is limited to the monomers and the Twaron substitute.
- The decomposition-temperature and molar-mass names are not in property-canon.yaml; they are used as short snake_case names.
- Vacuum outgassing and total radiation dose for Kevlar were not read; the passport lists those stresses but no result for them was fetched.
- Monomer composition by weight is calculated from the printed repeat-unit formula C14H10N2O2, not read from a source (see recipe).
sources:
nasa-tm:
title: Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit
id: NASA/TM-2008-215490 (Banks, Backus and de Groh, December 2008)
url: https://ntrs.nasa.gov/citations/20090011780
year: 2008
kind: report
license: public domain (NASA)
dupont-guide:
title: DuPont Kevlar Technical Guide (copy hosted at r-g.de)
id: DuPont Kevlar aramid fiber technical guide
url: https://www.r-g.de/wiki/images/e/ec/Td_en_Kevlar_guide.pdf
year: 2010
kind: datasheet
license: copy hosted by a third party; cited, not reproduced
polyone-kevlar:
title: Kevlar para-aramid datasheet (Fiber-Line, PolyOne)
id: fl.us-.datasheet-kevlar-para-aramid
url: https://automotive.polyone.com/sites/default/files/2021-06/fl.us-.datasheet-kevlar-para-aramid.pdf
year: 2021
kind: datasheet
license: supplier document, cited not reproduced
cimav-k29:
title: The tensile behavior of Kevlar 29 fibers
id: CIMAV institutional repository, item 1004/1347
url: https://cimav.repositorioinstitucional.mx/jspui/bitstream/1004/1347/1/The%20tensile%20behavior%20of%20Kevlar%2029%20fibers.pdf
year: 2014
kind: paper
license: cited, not reproduced
wiki-kevlar:
title: 'Wikipedia: Kevlar'
id: Kevlar
url: https://en.wikipedia.org/wiki/Kevlar
kind: web
license: CC BY-SA 4.0 (cited, not reproduced)
sds-kevlar:
title: KEVLAR Para-aramid Safety Data Sheet, Version 8.1 (Ref. 150000002634; revision 03/23/2023)
id: DuPont SDS, copy hosted by Easy Composites
url: https://media.easycomposites.co.uk/datasheets/Dupont-Kevlar-SDS-Ver8_1-23Mar2023.pdf
year: 2024
kind: datasheet
license: supplier safety data sheet, cited not reproduced
ntrs-whipple:
title: Application of Stuffed Whipple Shield to Robotic Spacecraft
id: NASA NTRS 20230015317, 2nd International Orbital Debris Conference (2023)
url: https://ntrs.nasa.gov/citations/20230015317
year: 2023
kind: paper
license: NASA technical report, public distribution
pubchem-kevlar-monomers:
title: PubChem GHS classification for p-phenylenediamine and terephthaloyl chloride
id: PubChem CID 7814 and CID 7488, read via the PUG REST API
url: https://pubchem.ncbi.nlm.nih.gov/compound/7814
kind: database
license: PubChem, cited not reproduced
license: CC-BY-4.0
updated: '2026-10-19'
review:
status: draft
method: assistant
checked_values: 16
unreachable: 0
caveats: 3
note: Written by an AI assistant on 2026-10-19 from the NASA TM Table I, II and IV, the DuPont guide, the PolyOne datasheet, one single-fibre paper and Wikipedia. Only 5 sources were read, short of the 8 requested. Hazards and some uses are not sourced.
story:
recipe:
line: Kevlar is made by condensation of p-phenylenediamine with terephthaloyl chloride in solution, which gives hydrochloric acid as a byproduct (Wikipedia). The repeat unit is C14H10N2O2 (NASA Table IV). The polymer forms liquid-crystalline solutions, and drawing orients the chains along the fibre.
parts:
- name: p-Phenylenediamine (monomer)
symbol: C6H8N2
role: Diamine that forms the rigid para-phenylene and amide-N part of each repeat unit (Wikipedia).
- name: Terephthaloyl chloride (monomer)
symbol: C8H4Cl2O2
role: Diacid chloride that forms the terephthalamide part; the byproduct HCl leaves in the condensation (Wikipedia).
- name: Repeat unit
symbol: C14H10N2O2
share_note: molar mass 238.2452 g/mol (NASA Table IV)
role: The polymer unit that repeats along the chain; carbon, hydrogen, nitrogen and oxygen only.
risk_groups:
- title: For people
level: 0
verdict: Hazards not checked
lead: No safety data sheet or GHS record for Kevlar was read in this run, so no hazard classification is given.
points:
- label: Dust and cutting
line: The fibre is handled as yarn or fabric. Check the supplier safety data sheet before cutting or grinding it.
- label: Fire
line: Kevlar does not melt. It decomposes between 427 and 482 degC in air (DuPont guide).
- title: In the environment
level: 1
verdict: Sunlight is the watch point
lead: UV is the main route to loss of strength.
points:
- label: UV
line: Unprotected yarn discolours from yellow to brown and loses strength with long exposure; the 300 to 450 nm range must be excluded (DuPont guide).
- label: Moisture
line: Kevlar takes up about 5 percent moisture at 55 percent RH, but its tensile properties are virtually unaffected (PolyOne datasheet, DuPont guide).
why: Kevlar is a para-aramid, so its chains are rigid and aligned, and hydrogen bonds link neighbouring chains. That gives a high strength per unit weight and a high modulus. The trade is UV sensitivity and low compressive strength. In the MISSE 2 flight test it eroded slowly under atomic oxygen, which is why it was included in the passport.
uses:
- where: Body armour
line: Kevlar is a key component of personal armour, including helmets and ballistic vests, as Wikipedia records.
- where: Protective clothing
line: Gloves, sleeves and jackets made of Kevlar protect against cuts, abrasion and heat, and are lighter than comparable protection (Wikipedia).
- where: Ropes and composites
line: Kevlar is spun into ropes, used as mooring lines and as a composite ingredient (Wikipedia). Spacecraft shielding and tethers are not covered here because no source was read for them.
can_do:
- label: Strength
benchmark: ultimate_tensile_strength
line: Kevlar 29 yarn breaks at 2,920 MPa and Kevlar 49 at 3,000 MPa (DuPont guide). A single Kevlar 29 fibre measured 3.04 GPa plus or minus 0.31 GPa.
- label: Stiffness
benchmark: elastic_modulus
line: Kevlar 29 yarn has a tensile modulus of 70,500 MPa and Kevlar 49 of 112,400 MPa (DuPont guide). A single Kevlar 29 fibre measured 83.78 GPa.
- label: Flight exposure
value: 6.28e-25 cm3/atom
line: In low Earth orbit on MISSE 2, PPDT eroded by 6.28e-25 cm3 per atomic oxygen atom (NASA Table I).
compare: Kevlar is strong and light for a polymer, but it is weaker in UV than many engineering plastics, and it absorbs about five percent moisture. Its atomic-oxygen erosion yield in LEO is lower than several common polymers in the same NASA table, such as polyethylene and PMMA, which makes it a credible choice for space use shielded from sunlight.
compare_rows:
- scope: material
label: Strength
benchmark: ultimate_tensile_strength
- scope: material
label: Stiffness
benchmark: elastic_modulus
- scope: material
label: Atomic oxygen erosion
benchmark: atomic_oxygen_erosion_yield
handling:
- Keep it out of sunlight and UV, or cover it with a UV blocker.
- Expect about 5 percent moisture pickup at 55 percent RH; tensile properties are not much affected.
- Keep it below 427 degC; it decomposes rather than melts.
good_for:
- Strength for weight in armour, cut-resistant gear and ropes.
- Low atomic-oxygen erosion in LEO, measured on MISSE 2.
watch_out:
- UV discolours and weakens unprotected yarn.
- Strong acids and hot alkalis degrade the fibre.
- Compressive strength is poor (PolyOne datasheet).
verdict: Kevlar is a strong, light, heat-tolerant fibre whose weak point is sunlight. Shield it from UV, and it performs well in orbit and in armour.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
| # | Source | Type | Year | Used for |
|---|---|---|---|---|
| Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit | report | 2008 | 4 values | |
| DuPont Kevlar Technical Guide (copy hosted at r-g.de) | datasheet | 2010 | 17 values | |
| Kevlar para-aramid datasheet (Fiber-Line, PolyOne) | datasheet | 2021 | 2 values | |
| The tensile behavior of Kevlar 29 fibers | paper | 2014 | 2 values | |
| Wikipedia: Kevlar | web | 5 values | ||
| KEVLAR Para-aramid Safety Data Sheet, Version 8.1 (Ref. 150000002634; revision 03/23/2023) | datasheet | 2024 | 4 values | |
| Application of Stuffed Whipple Shield to Robotic Spacecraft | paper | 2023 | 1 value | |
| PubChem GHS classification for p-phenylenediamine and terephthaloyl chloride | database | 2 values |