Materials/Semiconductors/Collections

Semiconductor materials

semiconductor-materials

About semiconductor materials

Semiconductor materials (silicon, germanium, silicon-germanium, gallium arsenide, gallium nitride, selenium, tellurium, bismuth telluride): band gap, thermal and electrical data with sources.

Semiconductors are the base of chips, solar cells, detectors and thermoelectric generators. Their electrical behaviour depends strongly on purity, doping and temperature, so each value names its condition.

At a glance

  • Highest density: Bismuth telluride reaches 7.64 g/cm³. Lowest: Silicon starts at 2.33 g/cm³. (10 of 10 grades have a sourced value.)
  • Highest melting point: Gallium nitride (GaN) reaches 2,500 °C. Lowest: Selenium starts at 221 °C. (9 of 10 grades have a sourced value.)

Ranges run across the conditions each source reports (temper, heat treatment, form), measured at room temperature where the source says so.

How they compare

The same measurements for every material in the collection. A range means the grade has values under several conditions; "at least" means the source gives a specified minimum. "no data" means no sourced value yet. For ranked tables, open a benchmark.

Semiconductor materials: how the grades compare
MaterialDensityMelting pointElectrical resistivityThermal conductivityYoung's modulusThermal expansion
Siliconsemiconductor 2.33 g/cm³1,415 °Cno data150 W/(m·K)no datano data
Germaniumsemiconductor 5.33 g/cm³936 to 937 °Cno data58.6 W/(m·K)103 GPa5.8 to 6.1 ppm/K
Silicon-germanium alloy (SiGe)semiconductor 4.31 g/cm³no datano datano datano datano data
Gallium arsenide (GaAs)semiconductor 5.32 g/cm³1,238 to 1,240 °C3,300,000 Ω·m46 to 55 W/(m·K)no data5.73 to 6.86 ppm/K
Gallium nitride (GaN)wide-bandgap semiconductor 6.15 g/cm³2,500 °Cno data130 W/(m·K)no data5.59 ppm/K
Arsenic (As)Metalloid: feedstock for gallium arsenide semiconductors and a dopant 5.73 g/cm³817 °Cno data50 W/(m·K)8 GPano data
Boronneutron absorber, hard amorphous powder and reinforcing fibre 2.35 to 2.61 g/cm³2,075 °Cno data27 W/(m·K)428 GPa4.5 to 6 ppm/K
Seleniumchalcogen element; photoconductor and CIGS solar-cell component 4.81 g/cm³221 °Cno data0.52 W/(m·K)10 GPano data
Telluriummetalloid, semiconductor compound element and alloy additive 6 to 6.25 g/cm³450 °Cno data3 W/(m·K)43 GPano data
Bismuth telluridethermoelectric alloy base and layered topological insulator 6.5 to 7.64 g/cm³573 to 629 °Cno data1.29 to 1.48 W/(m·K)no datano data

What these materials are made of

Composition by weight, as printed in the sources for each grade (the first constituents listed).

Composition of each grade
MaterialMain constituents
SiliconSi 100%
GermaniumGe 100%
Silicon-germanium alloy (SiGe)Si 80% · Ge 20%
Gallium arsenide (GaAs)Ga 48.2% · As 51.8%
Arsenic (As)As 100.0%
Boron10B 20% · 11B 80%
SeleniumSe 100%
TelluriumTe 100.0%
Bismuth tellurideBi 40% · Te 60%

Where they are used

Uses
UseGrades
Single-crystal silicon wafer substrateSilicon
Semiconductor chipsSilicon
Silicon solar cellSilicon
Infrared lenses and windows for thermal imagingGermanium
ATR prisms for infrared spectroscopyGermanium
Optical fibre glassGermanium
SiGe heterojunction bipolar transistors (HBTs) in RF and mixed-signal chipsSilicon-germanium alloy (SiGe)
SiGe strain layer in CMOS transistorsSilicon-germanium alloy (SiGe)
Radioisotope thermoelectric generators (MHW-RTG and GPHS-RTG; a power source, not a battery)Silicon-germanium alloy (SiGe)
Triple-junction space solar cell (GaInP/GaAs/Ge)Gallium arsenide (GaAs)
Power amplifier in cellular handsetsGallium arsenide (GaAs)
Laser diodes, LEDs and photodetectorsGallium arsenide (GaAs)
GaN power transistor (EPC2045, 100 V)Gallium nitride (GaN)
GaN integrated circuits and optoelectronic devicesGallium nitride (GaN)
EPC1001 enhancement-mode GaN transistor (ground test)Gallium nitride (GaN)
Gallium arsenide and indium gallium arsenide semiconductorsArsenic (As)

When each grade fits

Best use and weak spots of each grade
MaterialBest forWeakest at
SiliconSemiconductor wafers: a 1.12 eV band gap at 300 K and a well-documented resistivity range from dopingLight emission and heat flow: an indirect band gap (not stated in the sources read) and thermal conductivity of 150 W/(m·K), well below metals
GermaniumInfrared optics from 1.8 to 23 µm (thermal-imaging lenses, ATR prisms) and substrates for triple-junction space solar cellsTemperature limit and supply: Crystran says germanium becomes opaque at all wavelengths a little above 350 K, and the USGS says supply runs through a few producers, China the leading one
Silicon-germanium alloy (SiGe)High-temperature thermoelectric legs for radioisotope generators, and SiGe transistors for fast RF chipsThermoelectric efficiency: NASA says the figure of merit of Si-Ge is much lower than that of lead telluride
Gallium arsenide (GaAs)Light emission, RF power and multijunction space solar cells, where the band gap and electron mobility of GaAs beat silicon (1.424 eV and up to 8500 cm2/(V·s))Cost and toxicity: the arsenic content is classed as carcinogenic in GHS, and the gallium supply is concentrated in China (99% of primary low-purity gallium)
Gallium nitride (GaN)High-voltage and high-frequency power switching, and radiation-tolerant electronics where a wide band gap and high breakdown field matter (NASA ground tests of GaN transistors)Modest electron mobility compared with the best III-V materials, and the cost and limited supply of gallium
Arsenic (As)Source of high-purity arsenic metal for GaAs and InGaAs semiconductors and for specialty infrared optics (USGS)Toxicity: PubChem reports H301 and H331 for most reporting companies, and ATSDR classes inorganic arsenic as a known human carcinogen
BoronThermal-neutron absorption where boron-10 content matters (NIST cross sections; NASA 1995 shielding report) and boron fibre for stiff composite plies (Specialty Materials datasheet)Oxidation and reactivity: amorphous boron powder can ignite spontaneously as dust and reacts violently with steam at red heat (Materion; PubChem, citing Bretherick)
SeleniumThin-film photovoltaics and photoconductive devices where a selenium compound is the active absorber or photoconductorToxicity and reactivity: the supplier SDS classes it as toxic if swallowed or inhaled, it burns in air when heated, and it releases toxic hydrogen selenide if heated above 50 degC in water
TelluriumCdTe thin-film solar cells and bismuth telluride thermoelectric devices, the two largest uses (USGS)Supply and toxicity: most of it is a copper by-product, China leads refined output, and the element is toxic if swallowed
Bismuth tellurideRoom-temperature thermoelectric coolers and generators, where the p-type alloy reached zT 1.24 before storageHumid, hot storage: 600 h at 85 degC and 85% RH oxidised the surface and cut zT by 19 and 22 percent (authors)