Materials/Metals and alloys/Collections

Alkali and alkaline earth metals

alkali-and-alkaline-earth-metals

About alkali and alkaline earth metals

Sodium, potassium, caesium, calcium and barium metals: density, melting point and reactivity data with sources.

The alkali and alkaline earth metals are soft, light and highly reactive. They are used as coolants, getters, reducing agents and in batteries, and they need careful storage because they react with air and water.

At a glance

  • Highest density: Barium metal reaches 3.62 g/cm³. Lowest: K starts at 0.86 g/cm³. (4 of 5 grades have a sourced value.)
  • Highest melting point: Calcium reaches 842 °C. Lowest: K starts at -12.6 °C. (5 of 5 grades have a sourced value.)
  • Highest electrical resistivity: Barium metal reaches 3.4e-7 Ω·m. Lowest: Calcium starts at 3.4e-8 Ω·m. (3 of 5 grades have a sourced value.)

Ranges run across the conditions each source reports (temper, heat treatment, form), measured at room temperature where the source says so.

How they compare

The same measurements for every material in the collection. A range means the grade has values under several conditions; "at least" means the source gives a specified minimum. "no data" means no sourced value yet. For ranked tables, open a benchmark.

Alkali and alkaline earth metals: how the grades compare
MaterialDensityMelting pointElectrical resistivityThermal conductivityYoung's modulusThermal expansion
Sodium (Na)coolant 0.97 g/cm³97.8 °C4.8e-8 Ω·m132 W/(m·K)no datano data
Kliquid-metal coolant 0.86 g/cm³-12.6 to 64 °Cno data0.23 cal/(sec degC cm)no datano data
Caesium (Cs)atomic-clock and ion-thruster element 1,827 to 1,892 kg/cu m28.4 to 28.6 °Cno datano datano datano data
Calciumdeoxidiser, vacuum getter and research battery anode 1.54 to 1.57 g/cm³842 °C3.4e-8 Ω·m200 W/(m·K)20 GPa22.3 ppm/K
Barium metalgetter 3.51 to 3.62 g/cm³725 to 727 °C3.4e-7 Ω·m18.4 W/(m·K)13 GPa20.6 ppm/K

What these materials are made of

Composition by weight, as printed in the sources for each grade (the first constituents listed).

Composition of each grade
MaterialMain constituents
Sodium (Na)Na 100.0%
KK 100.0%
Caesium (Cs)Cs 100.0%
CalciumCa 100.0%
Barium metalBa 100.0%

Where they are used

Uses
UseGrades
Stainless steel and sodium heat pipe, a radiator element for a nuclear electric propulsion spacecraft (test article)Sodium (Na)
High-temperature sodium-sulfur batterySodium (Na)
Liquid sodium coolant of a sodium-cooled fast reactorSodium (Na)
Liquid-metal reactor coolant loop for a space fission power systemK
Primary test circuit for fission surface power (ground test)K
Caesium contact-ionization ion thrusterCaesium (Cs)
Caesium fountain primary frequency standard (NIST-F2)Caesium (Cs)
Atomic clocks for global positioning systemsCaesium (Cs)
Rechargeable calcium-metal battery (research stage)Calcium
Vacuum tubes (calcium as a getter)Calcium
Steel and alloys (deoxidiser and desulphuriser)Calcium
Getter alloy in an electronic vacuum tubeBarium metal
Barium-impregnated hollow cathode in ion and Hall thrustersBarium metal
Miniature reservoir dispenser cathodeBarium metal

When each grade fits

Best use and weak spots of each grade
MaterialBest forWeakest at
Sodium (Na)Heat transfer in a liquid metal at high temperature and low pressure, as in fast-reactor coolant loopsAny contact with water, moist air or oxygen. It reacts violently, may ignite and must be kept dry and under inert cover
KLiquid-metal heat transport in space fission reactor loops, where NaK stays liquid at room temperatureAny contact with water or oxygen: it reacts violently with water and forms a surface crust in air
Caesium (Cs)Frequency standards and atomic clocks, where the caesium-133 hyperfine transition defines the SI secondHandling: it ignites spontaneously in air and reacts violently with water, and it melts at 28 C, so it stays liquid in a warm room
CalciumDeoxidising steel and as a reactive getter for residual gases; research anodes for calcium batteries, where its theoretical volumetric capacity is 2073 mAh/cm3Any contact with water or moist air, which releases flammable hydrogen (H261), and self-ignition at about 730 to 750 degC in air
Barium metalGetter alloys and barium-impregnated electron emitters inside a sealed vacuum, where the metal is never exposed to water or airAny contact with water or moist air: it reacts at once and releases hydrogen, and powdered barium reacts violently with air