Calcium Ca
Ca · CAS 7440-70-2
Calcium is a silvery alkaline-earth metal, the fifth most abundant element in the Earth's crust, and it is never found as the free metal in nature.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Capacity
1338 mAh/g
Melting
842 degC
Stiffness
20 GPa
Heat and electricity
200 W/(m K)
Recipe, share of the weight
- Ca 100.0%Calcium
Best for
Deoxidising steel and as a reactive getter for residual gases; research anodes for calcium batteries, where its theoretical volumetric capacity is 2073 mAh/cm3
Weakest at
Any contact with water or moist air, which releases flammable hydrogen (H261), and self-ignition at about 730 to 750 degC in air
Risk at a glance
- People Severe. Water-reactive and flammable on contact with water
- If it fails High. Hydrogen release on contact with water
- Corrosion Severe. Calcium reacts with water to form calcium hydroxide and hydrogen. The supplier safety data sheet calls the reaction violent.
Quick facts: Ca
| Property | Value | Basis |
|---|---|---|
| Density | 1.54 to 1.57 g/cm³ | 3 sourced values across conditions |
| Young's modulus | 20 GPa | 1 sourced value |
| Thermal conductivity | 200 W/(m·K) | 1 sourced value |
| Thermal expansion (CTE) | 22.3 ppm/K | 1 sourced value |
| Melting point | 842 °C | 1 sourced value |
| Electrical resistivity | 3.4e-8 Ω·m | 1 sourced value |
What is the density of Calcium?
Calcium has a density of 1.54 to 1.57 g/cm³. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What is the thermal conductivity of Calcium?
Calcium has a thermal conductivity of 200 W/(m·K). The source and test conditions are listed in the properties table on this page.
What is the coefficient of thermal expansion of Calcium?
Calcium has a coefficient of thermal expansion of 22.3 ppm/K. The source and test conditions are listed in the properties table on this page.
What is the melting point of Calcium?
Calcium has a melting point of 842 °C. The source and test conditions are listed in the properties table on this page.
What is the Young's modulus of Calcium?
Calcium has a Young's modulus of 20 GPa. The source and test conditions are listed in the properties table on this page.
What is Calcium used for?
Uses recorded in the sources include Rechargeable calcium-metal battery (research stage); Vacuum tubes (calcium as a getter); Steel and alloys (deoxidiser and desulphuriser).
Why it exists
Calcium is the fifth most abundant element in the Earth's crust but is never found as the free metal. As a metal it is a strong reducing agent. Industry uses it to remove oxygen and sulphur from steel, and it has been used as a getter for residual gases in vacuum tubes. It is studied as a battery anode because its volumetric capacity is high. Its reactivity with water and air is the main problem for handling and for any cell that uses it.
Where it's used
Steelmaking
WebElements lists calcium as a deoxidiser, desulphuriser and decarbonizer for various alloys, and as a reducing agent for preparing other metals such as thorium, uranium and zirconium.
Vacuum tubes
Calcium is used as a getter for residual gases in vacuum tubes, according to WebElements. The sources read give no pumping numbers.
Rechargeable batteries, still under research
A thesis abstract gives calcium metal a theoretical volumetric capacity of 2073 mAh/cm3, against 850 for graphite. It also says only a handful of reversible electrolytes have been reported since 2015, so calcium metal anodes are not yet in use.
Recipe
Ca
Calcium metal is the pure element, Ca, with one atom per formula unit. It is not an alloy in this profile.
| Ingredient | Atoms per unit | Share of the weight | What it does |
|---|---|---|---|
| Calcium Ca | 1 | 100.0% | The only element in the metal. The NIST standard atomic weight is 40.078, as printed. |
Weight shares are calculated from standard atomic weights.
What it can do
Capacity
1338 mAh/g
A 2019 review gives 1338 mAh/g for calcium metal as an anode, with each calcium atom giving two electrons. Its volumetric capacity is 2073 mAh/cm3 in the thesis abstract.
Melting
842 degC
Calcium melts at 842 degC and boils at 1484 degC. Its heat of fusion is 8.54 kJ/mol.
Stiffness
20 GPa
Young's modulus is 20 GPa, bulk modulus 17 GPa and Poisson's ratio 0.31, as printed by WebElements.
Heat and electricity
200 W/(m K)
Thermal conductivity is 200 W/(m K), and electrical resistivity is 3.4 microohm cm at a temperature the source does not state.
How it compares
Calcium sits directly below magnesium in the periodic table, the closest metal type in this collection. WebElements describes calcium as more reactive with air and water than magnesium, which is virtually unreactive with cold water. For a battery anode, the thesis abstract gives calcium metal 2073 mAh/cm3 by volume, against 850 mAh/cm3 for graphite.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.
| Measurement | Ca | Na |
|---|---|---|
| Capacity and energy | ||
| Theoretical specific capacity | 1338 mAh/g13 | 1166 mAh/g |
| Theoretical volumetric capacity | 2073 mAh/cm³14 | no data |
| Thermal behavior and safety | ||
| melting point | 842 °C4 | 97.82 °C |
| enthalpy of fusion | 8.54 kJ/mol6 | no data |
| Thermal conductivity | 200 W/(m K)11 | 87.22 W/m K |
| Physical and electrical | ||
| Density | 1550 kg/m31 | 0.968 g/cm³ |
| Density | 1.54 g/cm³2 | 0.968 g/cm³ |
| Density used for calcium metal in an electrode model | 1.57 g/cm³3 | 0.968 g/cm³ |
| electrical resistivity | 3.4 µΩ·cm10 | 4.77 µΩ·cm |
| Temperature behavior | ||
| Relative self-ignition temperature of solid calciumValue printed in a supplier safety data sheet | 730 to 750 °C | no data |
| Other measurements | ||
| boiling point | 1484 °C5 | 881.4 °C |
| Young's modulus | 20 GPa7 | no data |
| bulk modulus | 17 GPa8 | no data |
| poissons ratio | 0.31 -9 | no data |
| Thermal expansion (CTE) | 22.3 10^-6/K12 | no data |
Why choose it, and why not
Good for
- Deoxidising steel, where it removes oxygen and sulphur.
- Research anodes for calcium batteries, where its volumetric capacity is high.
Watch out for
- Water and moist air. Calcium releases hydrogen on contact with water, and its surface reacts with air.
- Heat. Solid calcium self-ignites at about 730 to 750 degC in air.
- Rechargeable cells. Electrolytes that plate and strip calcium reversibly are few, and a passivating layer forms on the metal.
Calcium is a useful reactive metal for steel and getters, and a promising but unproven anode for rechargeable batteries. Handling needs inert, dry conditions.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Density | Value printed in a database element page (WebElements) | basis density of solid as printed by the sourcetemperature not stated by the source | — |
| 2 | Density | Value printed in a supplier safety data sheet under REACH | temperature 20 °C | — |
| 3 | Density used for calcium metal in an electrode model | Table value in an open-access review of multivalent batteries | basis density the review uses for calcium metal in its electrode model, not a measured valuetemperature not stated by the source | — |
| 4 | melting point | Value printed in a database element page (WebElements) and in a supplier safety data sheet | basis melting point as printed (the page also gives 1115 K) | — |
| 5 | boiling point | Value printed in a database element page (WebElements) and in a supplier safety data sheet | pressure 1 atm | — |
| 6 | enthalpy of fusion | Value printed in a database element page (WebElements) | temperature at the melting point | — |
| 7 | Young's modulus | Value printed in a database element page (WebElements) | basis polycrystalline metal as printed; temperature not stated | — |
| 8 | bulk modulus | Value printed in a database element page (WebElements) | basis as printed; temperature not stated | — |
| 9 | poissons ratio | Value printed in a database element page (WebElements) | basis as printed (no units) | — |
| 10 | electrical resistivity | Converted by Space Mushroom from ohm m to microohm cm (1 ohm m is 100 million microohm cm); the source prints the value in ohm m | unit in source 3.4 x 10^-8 ohm m, printed as 3.4 x 10-8 ohm m with the alternative unit mohm cmtemperature not stated by the source | — |
| 11 | Thermal conductivity | Value printed in a database element page (WebElements) | basis as printed; temperature not stated | — |
| 12 | Thermal expansion (CTE) | Value printed in a database element page (WebElements) | basis linear coefficient as printed (22.3 x 10-6 per K); temperature not stated | — |
| 13 | Theoretical specific capacity | Value stated in an open-access review of multivalent batteries; no working is shown | reaction Ca to Ca2+, two electrons per calcium atomelectrode calcium metal anode (conf. 1 and conf. 2 in the source both list 1338) | — |
| 14 | Theoretical volumetric capacity | Value stated in a doctoral thesis abstract; no working is shown | electrode calcium metal anodecomparison graphite 850 mAh/cm3 and lithium metal 2062 mAh/cm3 as quoted in the same abstract | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Liquid water | severe | Calcium reacts with water to form calcium hydroxide and hydrogen. The supplier safety data sheet calls the reaction violent.1 |
| Room air at room temperature | moderate | A thin oxide layer protects calcium in air, though less well than the layer on magnesium.2 |
| Air or oxygen when heated | severe | Calcium self-ignites at about 730 to 750 degC in air.3 |
| Halogen gases (fluorine, chlorine, bromine, iodine) | severe | Calcium burns in fluorine and chlorine and reacts with bromine and iodine when heated.4 |
| Dilute or concentrated hydrochloric acid | severe | Calcium dissolves readily in hydrochloric acid and releases hydrogen.5 |
| Electrolyte in a calcium battery cell (research) | moderate | In battery electrolytes a passivating interphase forms on calcium and blocks calcium-ion transport.6 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Liquid water | The metal sinks in water and after about an hour hydrogen bubbles stick to its surface (WebElements, which calls the reaction slow). The Chemos safety data sheet classifies calcium as water-reactive, category 2, with H261 (in contact with water releases flammable gases) and EUH014 (reacts violently with water). | form calcium metal in water, form not stated by the sourcenote the two sources disagree on speed: slow in WebElements, violent in the safety data sheet |
| 2 | Room air at room temperature | The surface of calcium metal is covered with a thin oxide layer that protects it from air, but less well than the layer on magnesium. Once ignited it burns to calcium oxide and calcium nitride. No corrosion rate is given in the source. | atmosphere air at room temperaturerate not measured in the source |
| 3 | Air or oxygen when heated | The supplier safety data sheet gives a relative self-ignition temperature for solid calcium of more than 730 and less than 750 degC (ECHA). Burning calcium forms calcium oxide and calcium nitride (WebElements). | state solidbasis relative self-ignition temperature, not a single ignition point |
| 4 | Halogen gases (fluorine, chlorine, bromine, iodine) | Calcium is very reactive towards the halogens and forms calcium fluoride, chloride, bromide and iodide. The reactions with bromine and iodine need heat to start. | state gas phase, temperature not stated by the source |
| 5 | Dilute or concentrated hydrochloric acid | Calcium metal dissolves readily in dilute or concentrated hydrochloric acid, forming calcium ions in solution and hydrogen gas (Ca + 2HCl gives Ca2+ + 2Cl- + H2). | acid hydrochloric acid, dilute or concentrated |
| 6 | Electrolyte in a calcium battery cell (research) | The thesis names two key problems for calcium metal anodes: a passivating solid electrolyte interphase between calcium and the electrolyte, which inhibits Ca2+ transport to the anode, and strong Ca2+-anion interactions that suppress ionic conductivity. Only a handful of reversible electrolytes have been reported since the first plating and stripping demonstration in 2015. | setting laboratory calcium-metal cells; electrolyte types not listed in the abstract |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
Calcium metal is classified under CLP as water-reactive, category 2. It releases flammable hydrogen on contact with water and self-ignites at about 730 to 750 degC in air.
- Classification
- The Chemos safety data sheet uses the signal word Danger and the GHS02 flame pictogram, with H261 (in contact with water releases flammable gases) and EUH014 (reacts violently with water).
- Fire
- Fire extinguishing advice differs between the two safety data sheets, so use the sheet for the product you hold. Avoid water jets; one sheet names sand, dry powder and foam, the other powder and CO2.
- Skin
- Brush off loose particles and immerse the skin in cool water, following the precautionary statement P302+P335+P334.
If the metal meets water or heat
These are hazard properties from the safety data sheets and reference pages, not field incidents.
- Water
- Water releases flammable hydrogen, which may ignite. Storage at higher temperature speeds the release.
- Heat in air
- Solid calcium self-ignites at about 730 to 750 degC and burns to calcium oxide and calcium nitride.
- Halogens and acids
- Calcium burns in fluorine and chlorine, reacts with bromine and iodine when heated, and dissolves readily in hydrochloric acid with release of hydrogen.
Handling and storage
- Storage
- Store in an inert gas, in a dry place, in a closed container, and keep away from water (P223, P231+P232, P402+P404).
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Hydrogen release on contact with waterhigh severity | Water, moisture or a wet surface contacts the metalFlammable hydrogen is released and may ignite spontaneously, according to the safety data sheet. Storage at higher temperature speeds the release. |
| Self-ignition when heated in airhigh severity | Heating solid calcium in air to its self-ignition rangeCalcium self-ignites at about 730 to 750 degC and burns to calcium oxide and calcium nitride (ECHA value in the safety data sheet; WebElements for the products). |
| Passivating interphase in calcium battery cells (research)moderate severity | Calcium metal in contact with the electrolyte during plating and strippingA passivating interphase and poor ionic conductivity stop reversible plating and stripping, so the anode cannot be recharged reliably. |
Side effects on surrounding parts
| Affects | Effect |
|---|---|
| Sealed containers and storage areas | Product may release hydrogen gas, and storage at increased temperature accelerates this. |
| Nearby surfaces and equipment | Burning calcium gives calcium oxide and calcium nitride, and reaction with water gives calcium hydroxide. |
Handling and storage
- Keep in an inert gas, protect from moisture and do not allow contact with water (P231+P232, P223).
- Store in a dry place in a closed container (P402+P404).
- Fire extinguishing media differ between the two safety data sheets. Chemos lists foam, dry powder and dry sand and names a water jet as unsuitable. Laboratory-grade granules from Lab Alley list extinguisher powder or CO2 and warn against a direct water stream.
- Skin contact: brush off loose particles and immerse the skin in cool water (P302+P335+P334).
Mitigations
- Handle and store under inert gas, and keep the metal dry, so that it does not react with air or moisture.
Supply and geography
How common the raw materials are and where they come from.
Calcium (producer shares are for lime, not calcium metal, because USGS reports no calcium metal production)
41,500 ppm in the Earth's crust (thesis abstract). WebElements: fifth in abundance in the crust, forming more than 3 per cent, and found in limestone, gypsum and fluorite but never as the free metal. Crustal rocks row: 50000000 ppb by weight.
- Top producers (2025)
- China 73.8%, India 4%, United States 3.6%, Russia 2.9%
- Critical mineral lists
- US: not listed, EU: not listed
- Recycling
- No recycling figure for calcium metal was found in the sources read.
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
Show the full YAML
spore: profile
id: calcium
spore_version: 0.2
family: alkali-and-alkaline-earth-metals
name: Calcium
abbreviation: Ca
role: deoxidiser, vacuum getter and research battery anode
category: metals
type: magnesium
summary: |
Calcium is a silvery alkaline-earth metal, the fifth most abundant element in the Earth's crust, and it is never found as the free metal in nature. Its main industrial use is as a deoxidiser and desulphuriser in steelmaking, and it has been used as a getter for residual gases in vacuum tubes. It reacts with water to release flammable hydrogen, burns in air once ignited, and melts at 842 degC. Calcium metal is studied as an anode for rechargeable calcium batteries because its volumetric capacity is high, but only a handful of electrolytes have been shown to plate and strip it reversibly.
best_for: Deoxidising steel and as a reactive getter for residual gases; research anodes for calcium batteries, where its theoretical volumetric capacity is 2073 mAh/cm3
weakest_at: Any contact with water or moist air, which releases flammable hydrogen (H261), and self-ignition at about 730 to 750 degC in air
identity:
formula: Ca
cas: 7440-70-2
source: chemos-sds
where: Section 1.1 Product identifier (CAS number 7440-70-2, substance Calcium)
tags:
environments: []
stresses:
- extreme-heat
applications:
- batteries
- structures
- electronics-and-chips
properties:
- benchmark: density
value: 1550
unit: kg/m3
scope: material
conditions:
basis: density of solid as printed by the source
temperature: not stated by the source
method: Value printed in a database element page (WebElements)
status: ground
source: webelements-physics
where: 'Physical properties, Density properties: Density of solid'
- benchmark: density
value: 1.54
unit: g/cm3
scope: material
conditions:
temperature: 20 degC
method: Value printed in a supplier safety data sheet under REACH
status: ground
source: chemos-sds
where: Section 9, Density and/or relative density
- benchmark: density
label: Density used for calcium metal in an electrode model
value: 1.57
unit: g/cm3
scope: material
conditions:
basis: density the review uses for calcium metal in its electrode model, not a measured value
temperature: not stated by the source
method: Table value in an open-access review of multivalent batteries
status: ground
source: frontiers-ca-2019
where: Table 1, row Calcium metal (conf. 1), density column
- benchmark: melting_point
value: 842
unit: degC
scope: material
conditions:
basis: melting point as printed (the page also gives 1115 K)
method: Value printed in a database element page (WebElements) and in a supplier safety data sheet
status: ground
source: webelements-thermo
where: 'Thermochemistry: Melting point, 1115 [842 degC (1548 degF)] K'
- benchmark: boiling_point
value: 1484
unit: degC
scope: material
conditions:
pressure: 1 atm
method: Value printed in a database element page (WebElements) and in a supplier safety data sheet
status: ground
source: webelements-thermo
where: 'Thermochemistry: Boiling point, 1757 [1484 degC (2703 degF)] K'
- benchmark: enthalpy_of_fusion
value: 8.54
unit: kJ/mol
scope: material
conditions:
temperature: at the melting point
method: Value printed in a database element page (WebElements)
status: ground
source: webelements-thermo
where: 'Thermochemistry: Enthalpy of fusion'
- benchmark: elastic_modulus
label: Young's modulus
value: 20
unit: GPa
scope: material
conditions:
basis: polycrystalline metal as printed; temperature not stated
method: Value printed in a database element page (WebElements)
status: ground
source: webelements-physics
where: 'Physical properties, Elastic properties: Young''s modulus'
- benchmark: bulk_modulus
value: 17
unit: GPa
scope: material
conditions:
basis: as printed; temperature not stated
method: Value printed in a database element page (WebElements)
status: ground
source: webelements-physics
where: 'Physical properties, Elastic properties: Bulk modulus'
- benchmark: poissons_ratio
value: 0.31
unit: '-'
scope: material
conditions:
basis: as printed (no units)
method: Value printed in a database element page (WebElements)
status: ground
source: webelements-physics
where: 'Physical properties, Elastic properties: Poisson''s ratio'
- benchmark: electrical_resistivity
value: 3.4
unit: microohm cm
scope: material
conditions:
unit_in_source: 3.4 x 10^-8 ohm m, printed as 3.4 x 10-8 ohm m with the alternative unit mohm cm
temperature: not stated by the source
method: Converted by Space Mushroom from ohm m to microohm cm (1 ohm m is 100 million microohm cm); the source prints the value in ohm m
status: ground
source: webelements-physics
where: 'Electrical properties: Electrical resistivity'
- benchmark: thermal_conductivity
value: 200
unit: W/(m K)
scope: material
conditions:
basis: as printed; temperature not stated
method: Value printed in a database element page (WebElements)
status: ground
source: webelements-physics
where: 'Heat and conduction: Thermal conductivity'
- benchmark: cte
value: 22.3
unit: 10^-6/K
scope: material
conditions:
basis: linear coefficient as printed (22.3 x 10-6 per K); temperature not stated
method: Value printed in a database element page (WebElements)
status: ground
source: webelements-physics
where: 'Heat and conduction: Coefficient of linear thermal expansion'
- benchmark: theoretical_capacity
value: 1338
unit: mAh/g
scope: material
conditions:
reaction: Ca to Ca2+, two electrons per calcium atom
electrode: calcium metal anode (conf. 1 and conf. 2 in the source both list 1338)
method: Value stated in an open-access review of multivalent batteries; no working is shown
status: calculated
source: frontiers-ca-2019
where: Table 1, row Calcium metal (conf. 1), capacity column
- benchmark: volumetric_capacity
label: Theoretical volumetric capacity
value: 2073
unit: mAh/cm3
scope: material
conditions:
electrode: calcium metal anode
comparison: graphite 850 mAh/cm3 and lithium metal 2062 mAh/cm3 as quoted in the same abstract
method: Value stated in a doctoral thesis abstract; no working is shown
status: calculated
source: mit-calcium-thesis
where: Abstract, sentence beginning 'Ca metal also offers attractive electrochemical metrics'
- benchmark: auto_ignition_temperature
label: Relative self-ignition temperature of solid calcium
value: 730
value_high: 750
bound: range
unit: degC
scope: material
conditions:
basis: relative self-ignition temperature for solids (ECHA), printed as more than 730 and less than 750 degC
method: Value printed in a supplier safety data sheet
status: ground
source: chemos-sds
where: Section 9, Auto-ignition temperature
corrosion:
- environment: Liquid water
headline: Calcium reacts with water to form calcium hydroxide and hydrogen. The supplier safety data sheet calls the reaction violent.
effect: The metal sinks in water and after about an hour hydrogen bubbles stick to its surface (WebElements, which calls the reaction slow). The Chemos safety data sheet classifies calcium as water-reactive, category 2, with H261 (in contact with water releases flammable gases) and EUH014 (reacts violently with water).
rating: severe
conditions:
form: calcium metal in water, form not stated by the source
note: 'the two sources disagree on speed: slow in WebElements, violent in the safety data sheet'
source: chemos-sds
where: Section 2.1 (Water-react 2), Section 2.2 (H261, EUH014), Section 5.2
- environment: Room air at room temperature
headline: A thin oxide layer protects calcium in air, though less well than the layer on magnesium.
effect: The surface of calcium metal is covered with a thin oxide layer that protects it from air, but less well than the layer on magnesium. Once ignited it burns to calcium oxide and calcium nitride. No corrosion rate is given in the source.
rating: moderate
conditions:
atmosphere: air at room temperature
rate: not measured in the source
source: webelements-chem
where: 'Element reactions: Reaction of calcium with air'
- environment: Air or oxygen when heated
headline: Calcium self-ignites at about 730 to 750 degC in air.
effect: The supplier safety data sheet gives a relative self-ignition temperature for solid calcium of more than 730 and less than 750 degC (ECHA). Burning calcium forms calcium oxide and calcium nitride (WebElements).
rating: severe
conditions:
state: solid
basis: relative self-ignition temperature, not a single ignition point
source: chemos-sds
where: Section 9, Auto-ignition temperature
- environment: Halogen gases (fluorine, chlorine, bromine, iodine)
headline: Calcium burns in fluorine and chlorine and reacts with bromine and iodine when heated.
effect: Calcium is very reactive towards the halogens and forms calcium fluoride, chloride, bromide and iodide. The reactions with bromine and iodine need heat to start.
rating: severe
conditions:
state: gas phase, temperature not stated by the source
source: webelements-chem
where: 'Element reactions: Reaction of calcium with the halogens'
- environment: Dilute or concentrated hydrochloric acid
headline: Calcium dissolves readily in hydrochloric acid and releases hydrogen.
effect: Calcium metal dissolves readily in dilute or concentrated hydrochloric acid, forming calcium ions in solution and hydrogen gas (Ca + 2HCl gives Ca2+ + 2Cl- + H2).
rating: severe
conditions:
acid: hydrochloric acid, dilute or concentrated
source: webelements-chem
where: 'Element reactions: Reaction of calcium with acids'
- environment: Electrolyte in a calcium battery cell (research)
headline: In battery electrolytes a passivating interphase forms on calcium and blocks calcium-ion transport.
effect: 'The thesis names two key problems for calcium metal anodes: a passivating solid electrolyte interphase between calcium and the electrolyte, which inhibits Ca2+ transport to the anode, and strong Ca2+-anion interactions that suppress ionic conductivity. Only a handful of reversible electrolytes have been reported since the first plating and stripping demonstration in 2015.'
rating: moderate
conditions:
setting: laboratory calcium-metal cells; electrolyte types not listed in the abstract
source: mit-calcium-thesis
where: Abstract
risks:
hazards:
- text: 'Classified under CLP as water-reactive, category 2 (H261: in contact with water releases flammable gases). The signal word is Danger and the pictogram is GHS02 (flame).'
ghs:
- H261
source: chemos-sds
where: Section 2.1 (Classification), Section 2.2 (Label elements)
- text: 'Supplemental hazard EUH014: reacts violently with water.'
ghs:
- EUH014
source: chemos-sds
where: Section 2.2, Supplemental hazard information
- text: 'OSHA HCS classification of the granular lab-grade metal: water-reactive, category 2, with the hazard statement that in contact with water it releases flammable gases.'
ghs: []
source: laballey-sds
where: Section 2.1 (Classification) and Section 2.2 (Label elements)
failure_risks:
- mode: Hydrogen release on contact with water
trigger: Water, moisture or a wet surface contacts the metal
consequence: Flammable hydrogen is released and may ignite spontaneously, according to the safety data sheet. Storage at higher temperature speeds the release.
severity: high
source: chemos-sds
where: Section 2.1, Section 5.2
- mode: Self-ignition when heated in air
trigger: Heating solid calcium in air to its self-ignition range
consequence: Calcium self-ignites at about 730 to 750 degC and burns to calcium oxide and calcium nitride (ECHA value in the safety data sheet; WebElements for the products).
severity: high
source: chemos-sds
where: 'Section 9, Auto-ignition temperature; WebElements Element reactions: Reaction of calcium with air'
- mode: Passivating interphase in calcium battery cells (research)
trigger: Calcium metal in contact with the electrolyte during plating and stripping
consequence: A passivating interphase and poor ionic conductivity stop reversible plating and stripping, so the anode cannot be recharged reliably.
severity: moderate
source: mit-calcium-thesis
where: Abstract
side_effects:
- text: Product may release hydrogen gas, and storage at increased temperature accelerates this.
affects: Sealed containers and storage areas
source: chemos-sds
where: Section 5.2 Special hazards
- text: Burning calcium gives calcium oxide and calcium nitride, and reaction with water gives calcium hydroxide.
affects: Nearby surfaces and equipment
source: webelements-chem
where: 'Element reactions: reaction with air and with water'
handling:
- text: Keep in an inert gas, protect from moisture and do not allow contact with water (P231+P232, P223).
source: chemos-sds
where: Section 7 (precautionary statements P223, P231+P232)
- text: Store in a dry place in a closed container (P402+P404).
source: chemos-sds
where: Section 2.2 precautionary statements
- text: Fire extinguishing media differ between the two safety data sheets. Chemos lists foam, dry powder and dry sand and names a water jet as unsuitable. Laboratory-grade granules from Lab Alley list extinguisher powder or CO2 and warn against a direct water stream.
source: laballey-sds
where: Section 5.1 Extinguishing media
- text: 'Skin contact: brush off loose particles and immerse the skin in cool water (P302+P335+P334).'
source: chemos-sds
where: Section 2.2 precautionary statements
mitigations:
- text: Handle and store under inert gas, and keep the metal dry, so that it does not react with air or moisture.
source: chemos-sds
where: Section 7 (P231+P232)
uses:
- application: batteries
device: Rechargeable calcium-metal battery (research stage)
example: Calcium metal has a theoretical volumetric capacity of 2073 mAh/cm3, against 850 mAh/cm3 for graphite and 2062 mAh/cm3 for lithium metal, and the thesis says it is the basis of calcium battery research. Only a handful of reversible electrolytes have been reported since 2015.
source: mit-calcium-thesis
where: Abstract
- application: electronics-and-chips
device: Vacuum tubes (calcium as a getter)
example: Calcium is used as a getter for residual gases in vacuum tubes, and WebElements lists it among the uses of the metal.
source: webelements-uses
where: Uses list, item on getter for residual gases in vacuum tubes
- application: structures
device: Steel and alloys (deoxidiser and desulphuriser)
example: Calcium is used as a deoxidiser, desulphuriser or decarbonizer for various alloys, according to WebElements. The metal is not a common alloying element in steel because its solubility is low.
source: webelements-uses
where: Uses list, item on deoxidiser, desulphurizer or decarbonizer
supply:
- subject: Calcium (producer shares are for lime, not calcium metal, because USGS reports no calcium metal production)
abundance: '41,500 ppm in the Earth''s crust (thesis abstract). WebElements: fifth in abundance in the crust, forming more than 3 per cent, and found in limestone, gypsum and fluorite but never as the free metal. Crustal rocks row: 50000000 ppb by weight.'
producers:
- country: China
share_percent: 73.8
year: 2025
- country: India
share_percent: 4
year: 2025
- country: United States
share_percent: 3.6
year: 2025
- country: Russia
share_percent: 2.9
year: 2025
critical_lists:
- list: USGS Final 2025 List of Critical Minerals (Table 6)
listed: false
- list: EU critical raw materials list (RMIS, 34 materials)
listed: false
recycling: No recycling figure for calcium metal was found in the sources read.
substitutes: []
source: usgs-mcs-2026
where: Lime chapter, World Lime Production and Reserves table (2025e; shares calculated by Space Mushroom against the 420,000 thousand t world total); Table 6 of the USGS summaries for the US list; EU RMIS page for the EU list; WebElements Geology page for abundance.
media: []
documents:
- title: 'Safety data sheet: Calcium (Chemos GmbH, CAS 7440-70-2, version GHS 1.0, compiled 2021-04-08)'
type: sds
url: https://www.chemos.de/import/data/msds/GB_en/7440-70-2-A0010604-GB-en.pdf
year: 2021
- title: 'Safety data sheet: Calcium metal, granular lab grade (Lab Alley, revision 2 dated 2025-07-03)'
type: sds
url: https://media.laballey.com/docbuilder/calcium-metal-granular-lab-grade-safety-data-sheet-6866d1beb0d43.pdf
year: 2025
- title: Calcium (WebElements periodic table, physical, thermochemistry, chemistry, geology and uses pages)
type: database
url: https://www.webelements.com/calcium/
year: 2026
- title: 'Multivalent Batteries: Prospects for High Energy Density, Ca Batteries (Frontiers in Chemistry, open access)'
type: paper
url: https://doi.org/10.3389/fchem.2019.00079
year: 2019
- title: Mineral Commodity Summaries 2026 (lime chapter and Table 6, Final 2025 Critical Minerals List)
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026.pdf
year: 2026
gaps:
- Calcium metal production by country is not reported separately; the supply shares are for lime (quicklime and hydrated lime), which is a calcium compound, not the metal.
- No recycling figure and no substitute list for calcium metal were found in the sources read.
- The standard potential of the Ca2+/Ca couple (-2.868 V vs SHE) is printed on a LibreTexts table with a Unicode minus sign, so it was not entered; it can be added once a source prints an ASCII minus sign.
- Auto-ignition is entered as a range under the non-canonical name auto_ignition_temperature; it is not in the canonical property list.
- No vacuum, outgassing, radiation, cold or thermal-vacuum data for calcium were found. The getter use has no numbers in the sources read.
- The two safety data sheets disagree on suitable fire extinguishing media (foam and dry sand in one, powder and CO2 in the other). Both are recorded; check the sheet for the product you hold.
- WebElements describes the reaction with water as slow, while the Chemos safety data sheet classifies it as violent (EUH014). Both are recorded in the corrosion section.
- Specific heat capacity and Brinell hardness (167 MN m-2, WebElements) are printed in the physical properties page but were not entered because no canonical name fitted the unit as printed.
- Gravimetric and volumetric capacities come from a 2019 review and a thesis abstract, and no measured capacity of calcium metal in a cell was read.
sources:
webelements-physics:
title: 'WebElements: Calcium, physical properties'
id: WebElements, Mark Winter, University of Sheffield
url: https://www.webelements.com/calcium/physics.html
year: 2026
kind: database
license: WebElements copyright (cited, not reproduced)
webelements-thermo:
title: 'WebElements: Calcium, thermochemistry'
id: WebElements, Mark Winter, University of Sheffield
url: https://www.webelements.com/calcium/thermochemistry.html
year: 2026
kind: database
license: WebElements copyright (cited, not reproduced)
webelements-chem:
title: 'WebElements: Calcium, element reactions'
id: WebElements, Mark Winter, University of Sheffield
url: https://www.webelements.com/calcium/chemistry.html
year: 2026
kind: database
license: WebElements copyright (cited, not reproduced)
webelements-uses:
title: 'WebElements: Calcium, uses'
id: WebElements, Mark Winter, University of Sheffield
url: https://www.webelements.com/calcium/uses.html
year: 2026
kind: database
license: WebElements copyright (cited, not reproduced)
webelements-geo:
title: 'WebElements: Calcium, geology'
id: WebElements, Mark Winter, University of Sheffield
url: https://www.webelements.com/calcium/geology.html
year: 2026
kind: database
license: WebElements copyright (cited, not reproduced)
nist-atomic-weights:
title: NIST Atomic Weights and Isotopic Compositions, element Ca
id: NIST, standard atomic weight of calcium
url: https://physics.nist.gov/cgi-bin/Compositions/stand_alone.pl?ele=Ca&all=all
year: 2026
kind: database
license: public domain (US government work)
chemos-sds:
title: 'Safety Data Sheet: Calcium (Chemos GmbH and Co. KG, REACH format)'
id: CAS 7440-70-2; article A0010604; version GHS 1.0
url: https://www.chemos.de/import/data/msds/GB_en/7440-70-2-A0010604-GB-en.pdf
year: 2021
kind: datasheet
license: supplier document, linked not reproduced
laballey-sds:
title: 'Safety Data Sheet: Calcium Metal Granular Lab Grade (Lab Alley)'
id: Revision 2, 2025-07-03
url: https://media.laballey.com/docbuilder/calcium-metal-granular-lab-grade-safety-data-sheet-6866d1beb0d43.pdf
year: 2025
kind: datasheet
license: supplier document, linked not reproduced
mit-calcium-thesis:
title: Calcium metal battery thesis, abstract (MIT DSpace record 1721.1/159078)
id: MIT DSpace handle 1721.1/159078
url: https://dspace.mit.edu/handle/1721.1/159078
kind: paper
license: MIT DSpace abstract, cited
frontiers-ca-2019:
title: 'Multivalent Batteries: Prospects for High Energy Density, Ca Batteries (Frontiers in Chemistry)'
id: doi:10.3389/fchem.2019.00079
url: https://doi.org/10.3389/fchem.2019.00079
year: 2019
kind: paper
license: CC BY 4.0
usgs-mcs-2026:
title: Mineral Commodity Summaries 2026 (USGS), lime chapter and Table 6 Final 2025 Critical Minerals List
id: USGS MCS 2026, February 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026.pdf
year: 2026
kind: report
license: public domain (USGS)
rmis-eu-crm:
title: 'EU Raw Materials Information System: critical raw materials'
id: Regulation (EU) 2024/1252 list of critical raw materials
url: https://rmis.jrc.ec.europa.eu/eu-critical-raw-materials
year: 2026
kind: web
license: European Commission web page
license: CC-BY-4.0
updated: '2026-10-26'
review:
status: draft
method: assistant
checked_values: 15
unreachable: 0
caveats: 3
note: Written by an AI assistant on 2026-10-26 from pages read in this run; values to be checked with verify-values.
story:
recipe:
line: Calcium metal is the pure element, Ca, with one atom per formula unit. It is not an alloy in this profile.
parts:
- name: Calcium
symbol: Ca
atoms: 1
atomic_weight: 40.078
role: The only element in the metal. The NIST standard atomic weight is 40.078, as printed.
risk_groups:
- title: For people
level: 4
verdict: Water-reactive and flammable on contact with water
lead: Calcium metal is classified under CLP as water-reactive, category 2. It releases flammable hydrogen on contact with water and self-ignites at about 730 to 750 degC in air.
points:
- label: Classification
line: The Chemos safety data sheet uses the signal word Danger and the GHS02 flame pictogram, with H261 (in contact with water releases flammable gases) and EUH014 (reacts violently with water).
- label: Fire
line: Fire extinguishing advice differs between the two safety data sheets, so use the sheet for the product you hold. Avoid water jets; one sheet names sand, dry powder and foam, the other powder and CO2.
- label: Skin
line: Brush off loose particles and immerse the skin in cool water, following the precautionary statement P302+P335+P334.
- title: If the metal meets water or heat
lead: These are hazard properties from the safety data sheets and reference pages, not field incidents.
points:
- label: Water
line: Water releases flammable hydrogen, which may ignite. Storage at higher temperature speeds the release.
- label: Heat in air
line: Solid calcium self-ignites at about 730 to 750 degC and burns to calcium oxide and calcium nitride.
- label: Halogens and acids
line: Calcium burns in fluorine and chlorine, reacts with bromine and iodine when heated, and dissolves readily in hydrochloric acid with release of hydrogen.
- title: Handling and storage
points:
- label: Storage
line: Store in an inert gas, in a dry place, in a closed container, and keep away from water (P223, P231+P232, P402+P404).
why: Calcium is the fifth most abundant element in the Earth's crust but is never found as the free metal. As a metal it is a strong reducing agent. Industry uses it to remove oxygen and sulphur from steel, and it has been used as a getter for residual gases in vacuum tubes. It is studied as a battery anode because its volumetric capacity is high. Its reactivity with water and air is the main problem for handling and for any cell that uses it.
uses:
- where: Steelmaking
line: WebElements lists calcium as a deoxidiser, desulphuriser and decarbonizer for various alloys, and as a reducing agent for preparing other metals such as thorium, uranium and zirconium.
- where: Vacuum tubes
line: Calcium is used as a getter for residual gases in vacuum tubes, according to WebElements. The sources read give no pumping numbers.
- where: Rechargeable batteries, still under research
line: A thesis abstract gives calcium metal a theoretical volumetric capacity of 2073 mAh/cm3, against 850 for graphite. It also says only a handful of reversible electrolytes have been reported since 2015, so calcium metal anodes are not yet in use.
can_do:
- label: Capacity
value: 1338 mAh/g
line: A 2019 review gives 1338 mAh/g for calcium metal as an anode, with each calcium atom giving two electrons. Its volumetric capacity is 2073 mAh/cm3 in the thesis abstract.
- label: Melting
value: 842 degC
line: Calcium melts at 842 degC and boils at 1484 degC. Its heat of fusion is 8.54 kJ/mol.
- label: Stiffness
value: 20 GPa
line: Young's modulus is 20 GPa, bulk modulus 17 GPa and Poisson's ratio 0.31, as printed by WebElements.
- label: Heat and electricity
value: 200 W/(m K)
line: Thermal conductivity is 200 W/(m K), and electrical resistivity is 3.4 microohm cm at a temperature the source does not state.
compare: Calcium sits directly below magnesium in the periodic table, the closest metal type in this collection. WebElements describes calcium as more reactive with air and water than magnesium, which is virtually unreactive with cold water. For a battery anode, the thesis abstract gives calcium metal 2073 mAh/cm3 by volume, against 850 mAh/cm3 for graphite.
compare_rows:
- label: Density
benchmark: density
- label: Melting point
benchmark: melting_point
- label: Theoretical capacity as an anode
benchmark: theoretical_capacity
handling:
- Store in an inert gas in a dry, closed container, away from water.
- Protect from moisture; contact with water releases flammable hydrogen.
- Choose the extinguisher from the product's own safety data sheet. Do not use a water jet.
good_for:
- Deoxidising steel, where it removes oxygen and sulphur.
- Research anodes for calcium batteries, where its volumetric capacity is high.
watch_out:
- Water and moist air. Calcium releases hydrogen on contact with water, and its surface reacts with air.
- Heat. Solid calcium self-ignites at about 730 to 750 degC in air.
- Rechargeable cells. Electrolytes that plate and strip calcium reversibly are few, and a passivating layer forms on the metal.
verdict: Calcium is a useful reactive metal for steel and getters, and a promising but unproven anode for rechargeable batteries. Handling needs inert, dry conditions.
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
| # | Source | Type | Year | Used for |
|---|---|---|---|---|
| WebElements: Calcium, physical properties | database | 2026 | 7 values | |
| WebElements: Calcium, thermochemistry | database | 2026 | 3 values | |
| WebElements: Calcium, element reactions | database | 2026 | 4 values | |
| WebElements: Calcium, uses | database | 2026 | 2 values | |
| WebElements: Calcium, geology | database | 2026 | 0 values | |
| NIST Atomic Weights and Isotopic Compositions, element Ca | database | 2026 | 0 values | |
| Safety Data Sheet: Calcium (Chemos GmbH and Co. KG, REACH format) | datasheet | 2021 | 14 values | |
| Safety Data Sheet: Calcium Metal Granular Lab Grade (Lab Alley) | datasheet | 2025 | 2 values | |
| Calcium metal battery thesis, abstract (MIT DSpace record 1721.1/159078) | paper | 4 values | ||
| Multivalent Batteries: Prospects for High Energy Density, Ca Batteries (Frontiers in Chemistry) | paper | 2019 | 2 values | |
| Mineral Commodity Summaries 2026 (USGS), lime chapter and Table 6 Final 2025 Critical Minerals List | report | 2026 | 1 value | |
| EU Raw Materials Information System: critical raw materials | web | 2026 | 0 values |