Calcium Ca

Ca · CAS 7440-70-2

Calcium is a silvery alkaline-earth metal, the fifth most abundant element in the Earth's crust, and it is never found as the free metal in nature.

12 sources · Updated 2026-10-26 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Capacity

1338 mAh/g

Melting

842 degC

Stiffness

20 GPa

Heat and electricity

200 W/(m K)

Recipe, share of the weight

  • Ca 100.0%Calcium

Best for

Deoxidising steel and as a reactive getter for residual gases; research anodes for calcium batteries, where its theoretical volumetric capacity is 2073 mAh/cm3

Weakest at

Any contact with water or moist air, which releases flammable hydrogen (H261), and self-ignition at about 730 to 750 degC in air

Risk at a glance

  • People Severe. Water-reactive and flammable on contact with water
  • If it fails High. Hydrogen release on contact with water
  • Corrosion Severe. Calcium reacts with water to form calcium hydroxide and hydrogen. The supplier safety data sheet calls the reaction violent.

Quick facts: Ca

Key properties of Ca
PropertyValueBasis
Density1.54 to 1.57 g/cm³3 sourced values across conditions
Young's modulus20 GPa1 sourced value
Thermal conductivity200 W/(m·K)1 sourced value
Thermal expansion (CTE)22.3 ppm/K1 sourced value
Melting point842 °C1 sourced value
Electrical resistivity3.4e-8 Ω·m1 sourced value

What is the density of Calcium?

Calcium has a density of 1.54 to 1.57 g/cm³. The range covers 3 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the thermal conductivity of Calcium?

Calcium has a thermal conductivity of 200 W/(m·K). The source and test conditions are listed in the properties table on this page.

What is the coefficient of thermal expansion of Calcium?

Calcium has a coefficient of thermal expansion of 22.3 ppm/K. The source and test conditions are listed in the properties table on this page.

What is the melting point of Calcium?

Calcium has a melting point of 842 °C. The source and test conditions are listed in the properties table on this page.

What is the Young's modulus of Calcium?

Calcium has a Young's modulus of 20 GPa. The source and test conditions are listed in the properties table on this page.

What is Calcium used for?

Uses recorded in the sources include Rechargeable calcium-metal battery (research stage); Vacuum tubes (calcium as a getter); Steel and alloys (deoxidiser and desulphuriser).

Why it exists

Calcium is the fifth most abundant element in the Earth's crust but is never found as the free metal. As a metal it is a strong reducing agent. Industry uses it to remove oxygen and sulphur from steel, and it has been used as a getter for residual gases in vacuum tubes. It is studied as a battery anode because its volumetric capacity is high. Its reactivity with water and air is the main problem for handling and for any cell that uses it.

Where it's used

Steelmaking

WebElements lists calcium as a deoxidiser, desulphuriser and decarbonizer for various alloys, and as a reducing agent for preparing other metals such as thorium, uranium and zirconium.

Vacuum tubes

Calcium is used as a getter for residual gases in vacuum tubes, according to WebElements. The sources read give no pumping numbers.

Rechargeable batteries, still under research

A thesis abstract gives calcium metal a theoretical volumetric capacity of 2073 mAh/cm3, against 850 for graphite. It also says only a handful of reversible electrolytes have been reported since 2015, so calcium metal anodes are not yet in use.

Recipe

Ca

Calcium metal is the pure element, Ca, with one atom per formula unit. It is not an alloy in this profile.

What Ca is made of
IngredientAtoms per unitShare of the weightWhat it does
Calcium Ca 1 100.0% The only element in the metal. The NIST standard atomic weight is 40.078, as printed.

Weight shares are calculated from standard atomic weights.

What it can do

Capacity

1338 mAh/g

A 2019 review gives 1338 mAh/g for calcium metal as an anode, with each calcium atom giving two electrons. Its volumetric capacity is 2073 mAh/cm3 in the thesis abstract.

Melting

842 degC

Calcium melts at 842 degC and boils at 1484 degC. Its heat of fusion is 8.54 kJ/mol.

Stiffness

20 GPa

Young's modulus is 20 GPa, bulk modulus 17 GPa and Poisson's ratio 0.31, as printed by WebElements.

Heat and electricity

200 W/(m K)

Thermal conductivity is 200 W/(m K), and electrical resistivity is 3.4 microohm cm at a temperature the source does not state.

How it compares

Calcium sits directly below magnesium in the periodic table, the closest metal type in this collection. WebElements describes calcium as more reactive with air and water than magnesium, which is virtually unreactive with cold water. For a battery anode, the thesis abstract gives calcium metal 2073 mAh/cm3 by volume, against 850 mAh/cm3 for graphite.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details. Other materials are shown beside it; each was measured under its own conditions, so open its page before comparing closely. Compare every grade in the family.

Benchmarks
MeasurementCaNa
Capacity and energy
Theoretical specific capacity1338 mAh/g131166 mAh/g
Theoretical volumetric capacity2073 mAh/cm³14no data
Thermal behavior and safety
melting point842 °C497.82 °C
enthalpy of fusion8.54 kJ/mol6no data
Thermal conductivity200 W/(m K)1187.22 W/m K
Physical and electrical
Density1550 kg/m310.968 g/cm³
Density1.54 g/cm³20.968 g/cm³
Density used for calcium metal in an electrode model1.57 g/cm³30.968 g/cm³
electrical resistivity3.4 µΩ·cm104.77 µΩ·cm
Temperature behavior
Relative self-ignition temperature of solid calciumValue printed in a supplier safety data sheet730 to 750 °Cno data
Other measurements
boiling point1484 °C5881.4 °C
Young's modulus20 GPa7no data
bulk modulus17 GPa8no data
poissons ratio0.31 -9no data
Thermal expansion (CTE)22.3 10^-6/K12no data

Why choose it, and why not

Good for

  • Deoxidising steel, where it removes oxygen and sulphur.
  • Research anodes for calcium batteries, where its volumetric capacity is high.

Watch out for

  • Water and moist air. Calcium releases hydrogen on contact with water, and its surface reacts with air.
  • Heat. Solid calcium self-ignites at about 730 to 750 degC in air.
  • Rechargeable cells. Electrolytes that plate and strip calcium reversibly are few, and a passivating layer forms on the metal.

Calcium is a useful reactive metal for steel and getters, and a promising but unproven anode for rechargeable batteries. Handling needs inert, dry conditions.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1DensityValue printed in a database element page (WebElements)basis density of solid as printed by the sourcetemperature not stated by the source—
2DensityValue printed in a supplier safety data sheet under REACHtemperature 20 °C—
3Density used for calcium metal in an electrode modelTable value in an open-access review of multivalent batteriesbasis density the review uses for calcium metal in its electrode model, not a measured valuetemperature not stated by the source—
4melting pointValue printed in a database element page (WebElements) and in a supplier safety data sheetbasis melting point as printed (the page also gives 1115 K)—
5boiling pointValue printed in a database element page (WebElements) and in a supplier safety data sheetpressure 1 atm—
6enthalpy of fusionValue printed in a database element page (WebElements)temperature at the melting point—
7Young's modulusValue printed in a database element page (WebElements)basis polycrystalline metal as printed; temperature not stated—
8bulk modulusValue printed in a database element page (WebElements)basis as printed; temperature not stated—
9poissons ratioValue printed in a database element page (WebElements)basis as printed (no units)—
10electrical resistivityConverted by Space Mushroom from ohm m to microohm cm (1 ohm m is 100 million microohm cm); the source prints the value in ohm munit in source 3.4 x 10^-8 ohm m, printed as 3.4 x 10-8 ohm m with the alternative unit mohm cmtemperature not stated by the source—
11Thermal conductivityValue printed in a database element page (WebElements)basis as printed; temperature not stated—
12Thermal expansion (CTE)Value printed in a database element page (WebElements)basis linear coefficient as printed (22.3 x 10-6 per K); temperature not stated—
13Theoretical specific capacityValue stated in an open-access review of multivalent batteries; no working is shownreaction Ca to Ca2+, two electrons per calcium atomelectrode calcium metal anode (conf. 1 and conf. 2 in the source both list 1338)—
14Theoretical volumetric capacityValue stated in a doctoral thesis abstract; no working is shownelectrode calcium metal anodecomparison graphite 850 mAh/cm3 and lithium metal 2062 mAh/cm3 as quoted in the same abstract—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Liquid water severe Calcium reacts with water to form calcium hydroxide and hydrogen. The supplier safety data sheet calls the reaction violent.1
Room air at room temperature moderate A thin oxide layer protects calcium in air, though less well than the layer on magnesium.2
Air or oxygen when heated severe Calcium self-ignites at about 730 to 750 degC in air.3
Halogen gases (fluorine, chlorine, bromine, iodine) severe Calcium burns in fluorine and chlorine and reacts with bromine and iodine when heated.4
Dilute or concentrated hydrochloric acid severe Calcium dissolves readily in hydrochloric acid and releases hydrogen.5
Electrolyte in a calcium battery cell (research) moderate In battery electrolytes a passivating interphase forms on calcium and blocks calcium-ion transport.6
Corrosion details
#EnvironmentDetailsTest conditions
1 Liquid water The metal sinks in water and after about an hour hydrogen bubbles stick to its surface (WebElements, which calls the reaction slow). The Chemos safety data sheet classifies calcium as water-reactive, category 2, with H261 (in contact with water releases flammable gases) and EUH014 (reacts violently with water). form calcium metal in water, form not stated by the sourcenote the two sources disagree on speed: slow in WebElements, violent in the safety data sheet
2 Room air at room temperature The surface of calcium metal is covered with a thin oxide layer that protects it from air, but less well than the layer on magnesium. Once ignited it burns to calcium oxide and calcium nitride. No corrosion rate is given in the source. atmosphere air at room temperaturerate not measured in the source
3 Air or oxygen when heated The supplier safety data sheet gives a relative self-ignition temperature for solid calcium of more than 730 and less than 750 degC (ECHA). Burning calcium forms calcium oxide and calcium nitride (WebElements). state solidbasis relative self-ignition temperature, not a single ignition point
4 Halogen gases (fluorine, chlorine, bromine, iodine) Calcium is very reactive towards the halogens and forms calcium fluoride, chloride, bromide and iodide. The reactions with bromine and iodine need heat to start. state gas phase, temperature not stated by the source
5 Dilute or concentrated hydrochloric acid Calcium metal dissolves readily in dilute or concentrated hydrochloric acid, forming calcium ions in solution and hydrogen gas (Ca + 2HCl gives Ca2+ + 2Cl- + H2). acid hydrochloric acid, dilute or concentrated
6 Electrolyte in a calcium battery cell (research) The thesis names two key problems for calcium metal anodes: a passivating solid electrolyte interphase between calcium and the electrolyte, which inhibits Ca2+ transport to the anode, and strong Ca2+-anion interactions that suppress ionic conductivity. Only a handful of reversible electrolytes have been reported since the first plating and stripping demonstration in 2015. setting laboratory calcium-metal cells; electrolyte types not listed in the abstract

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

Calcium metal is classified under CLP as water-reactive, category 2. It releases flammable hydrogen on contact with water and self-ignites at about 730 to 750 degC in air.

Classification
The Chemos safety data sheet uses the signal word Danger and the GHS02 flame pictogram, with H261 (in contact with water releases flammable gases) and EUH014 (reacts violently with water).
Fire
Fire extinguishing advice differs between the two safety data sheets, so use the sheet for the product you hold. Avoid water jets; one sheet names sand, dry powder and foam, the other powder and CO2.
Skin
Brush off loose particles and immerse the skin in cool water, following the precautionary statement P302+P335+P334.

If the metal meets water or heat

These are hazard properties from the safety data sheets and reference pages, not field incidents.

Water
Water releases flammable hydrogen, which may ignite. Storage at higher temperature speeds the release.
Heat in air
Solid calcium self-ignites at about 730 to 750 degC and burns to calcium oxide and calcium nitride.
Halogens and acids
Calcium burns in fluorine and chlorine, reacts with bromine and iodine when heated, and dissolves readily in hydrochloric acid with release of hydrogen.

Handling and storage

Storage
Store in an inert gas, in a dry place, in a closed container, and keep away from water (P223, P231+P232, P402+P404).

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Hydrogen release on contact with waterhigh severityWater, moisture or a wet surface contacts the metalFlammable hydrogen is released and may ignite spontaneously, according to the safety data sheet. Storage at higher temperature speeds the release.
Self-ignition when heated in airhigh severityHeating solid calcium in air to its self-ignition rangeCalcium self-ignites at about 730 to 750 degC and burns to calcium oxide and calcium nitride (ECHA value in the safety data sheet; WebElements for the products).
Passivating interphase in calcium battery cells (research)moderate severityCalcium metal in contact with the electrolyte during plating and strippingA passivating interphase and poor ionic conductivity stop reversible plating and stripping, so the anode cannot be recharged reliably.

Side effects on surrounding parts

Side effects on surrounding parts
AffectsEffect
Sealed containers and storage areasProduct may release hydrogen gas, and storage at increased temperature accelerates this.
Nearby surfaces and equipmentBurning calcium gives calcium oxide and calcium nitride, and reaction with water gives calcium hydroxide.

Handling and storage

  • Keep in an inert gas, protect from moisture and do not allow contact with water (P231+P232, P223).
  • Store in a dry place in a closed container (P402+P404).
  • Fire extinguishing media differ between the two safety data sheets. Chemos lists foam, dry powder and dry sand and names a water jet as unsuitable. Laboratory-grade granules from Lab Alley list extinguisher powder or CO2 and warn against a direct water stream.
  • Skin contact: brush off loose particles and immerse the skin in cool water (P302+P335+P334).

Mitigations

  • Handle and store under inert gas, and keep the metal dry, so that it does not react with air or moisture.

Supply and geography

How common the raw materials are and where they come from.

Calcium (producer shares are for lime, not calcium metal, because USGS reports no calcium metal production)

41,500 ppm in the Earth's crust (thesis abstract). WebElements: fifth in abundance in the crust, forming more than 3 per cent, and found in limestone, gypsum and fluorite but never as the free metal. Crustal rocks row: 50000000 ppb by weight.

Top producers (2025)
China 73.8%, India 4%, United States 3.6%, Russia 2.9%
Critical mineral lists
US: not listed, EU: not listed
Recycling
No recycling figure for calcium metal was found in the sources read.