Krytox 143AB perfluoropolyether oil PFPE

F-(CF(CF3)-CF2-O)n-CF2CF3, n = 10 to 60 (perfluoropolyether, PFPE)

Also known as Krytox 143AB

Krytox 143AB is a clear, colorless perfluoropolyether (PFPE) oil sold by Chemours for lubrication in aerospace and other demanding service.

8 sources · Updated 2026-11-01 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Viscosity over temperature

44620 cSt

Cold start

-40 °C

Vacuum and heat loss

5×10^-6 torr

Heat

1.9 wt%

Recipe, share of the weight

  • C 21.6%Carbon
  • O 9.4%Oxygen
  • F 69%Fluorine

Best for

Liquid lubrication where a nonflammable, chemically inert oil must work from -40 °C to 232 °C; the Chemours datasheet calls the 143 series safe in chemical and oxygen service

Weakest at

Volatility and creep: the datasheet shows 17.3 wt% loss in 22 hours at 204 °C, and NASA reports that PFPE oils creep over bearing surfaces

Risk at a glance

  • People None found. Not classified hazardous
  • If it fails Moderate. Creep out of the bearing raceway
  • Corrosion Moderate. Decomposition starts at 350 °C and gives off hydrogen fluoride and carbonyl difluoride.

Quick facts: PFPE

Key properties of PFPE
PropertyValueBasis
Density1.93 g/cm³1 sourced value
Melting pointat least -55 °C1 sourced value
Maximum service temperature232 °C1 sourced value

What is the density of Krytox 143AB perfluoropolyether oil (PFPE)?

Krytox 143AB perfluoropolyether oil (PFPE) has a density of 1.93 g/cm³. The source and test conditions are listed in the properties table on this page.

What is the melting point of Krytox 143AB perfluoropolyether oil (PFPE)?

Krytox 143AB perfluoropolyether oil (PFPE) has a melting point of at least -55 °C. The source and test conditions are listed in the properties table on this page.

What is the maximum service temperature of Krytox 143AB perfluoropolyether oil (PFPE)?

Krytox 143AB perfluoropolyether oil (PFPE) has a maximum service temperature of 232 °C. The source and test conditions are listed in the properties table on this page.

What is Krytox 143AB perfluoropolyether oil (PFPE) used for?

Uses recorded in the sources include Spacecraft mechanism bearings (ground life tests); Liquid lubricants for spacecraft mechanisms (heritage PFPE class); Valves, packings, seals and O-rings in oxygen service (industrial and aerospace listing).

Why it exists

Krytox 143AB is a perfluoropolyether oil used where a lubricant must be nonflammable, chemically inert and usable across a wide temperature range. Its pour point is -40 °C, its viscosity index is 113, and its estimated useful range runs from -40 °C to 232 °C. Its drawbacks come from the same chemistry: it creeps over bearing surfaces, it evaporates in heat, and its decomposition products are toxic. NASA's space tribology review says the Pennzane and PFPE families are the two used on most current spacecraft.

Where it's used

Spacecraft mechanism bearings (ground tests)

In NASA Glenn's full-scale scanner bearing tests, four of five pairs of Krytox 143AB lubricated bearings had failed when the report was written. All eight pairs lubricated with Bray 815Z oil had failed by then.

Heritage liquid lubricant class

NASA's space tribology review says the great majority of current spacecraft use either a formulated Pennzane or one of the PFPE materials, and that space lubricants have historically been chosen for flight heritage.

Valves, packings, seals and O-rings

ChemPoint lists Krytox 143AB for valves, packings, seals and O-rings, and under transportation for aerospace and aviation. The Chemours datasheet describes the 143 series as safe in chemical and oxygen service.

Recipe

F-(CF(CF3)-CF2-O)n-CF2CF3, n = 10 to 60 (perfluoropolyether, PFPE)

Krytox 143AB is a perfluoropolyether (PFPE): a saturated chain of carbon, oxygen and fluorine atoms with trifluoromethyl side groups, built from repeat units. The Chemours datasheet gives the structure as F-(CF-CF2-O)n-CF2CF3 with n = 10 to 60. The datasheet does not describe the manufacturing process.

What PFPE is made of
IngredientShare of the weightWhat it does
Carbon C 21.6% Forms the backbone of the chain together with the CF2 and CF units. The fluorinated chain is fully saturated, so it has no double bonds.
Oxygen O 9.4% Ether links between the repeat units. NASA notes that, for unbranched PFPE fluids, the carbon-to-oxygen ratio sets how viscosity changes with temperature.
Fluorine F 69% Surrounds the chain and gives the oil its nonflammable, chemically inert character.

Weight shares are as printed in the sources.

What it can do

Viscosity over temperature

44620 cSt

measured

Kinematic viscosity falls from 1070 cSt at 0 °C to 78 cSt at 40 °C and 10.2 cSt at 100 °C (ASTM D445, Chemours datasheet). The viscosity index is 113 (ASTM D2270).

Cold start

-40 °C

measured

The pour point is -40 °C (ASTM D97), and the estimated useful range also starts at -40 °C.

Vacuum and heat loss

5×10^-6 torr

measured

Vapour pressure is 5 x 10^-6 torr at 38 °C by the Knudsen method (Chemours datasheet). NASA's table gives 2 x 10^-4 Pa at 20 °C.

Heat

1.9 wt%

measured

In a 22-hour volatility test at 204 °C, 17.3 wt% evaporated (ASTM D2595, Chemours datasheet).

How it compares

Among the Chemours 143 grades in the datasheet, Krytox 143AB sits in the middle for volatility. At 38 °C its vapour pressure is 5 x 10^-6 torr, against 8 x 10^-8 torr for 143AC and 6 x 10^-9 torr for 143AD, so the heavier grades lose less oil in vacuum and heat. The trade is viscosity: 143AB is thinner than the heavier grades, and it is the more volatile of the two heavier-grade comparisons. In NASA's Table 4, its 20 °C vapour pressure is the highest of the five PFPE and Pennzane fluids listed.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details.

Benchmarks
MeasurementPFPE
Thermal behavior and safety
Vapour pressure at 38 °C (Knudsen method)5×10^-6 torr9
Vapour pressure at 260 °C (Knudsen method)Typical value printed in the Chemours table0.03 torr
Vapour pressure at 20 °C (NASA table)2×10^-4 Pa10
Vapour pressure at 100 °C (NASA table)0.04 Pa11
Vapour pressure at 38 °C for Krytox 143AC (comparison grade)8×10^-8 torr12
Vapour pressure at 38 °C for Krytox 143AD (comparison grade)6×10^-9 torr13
Volatility, 22 hours at 149 °C1.9 wt%14
Volatility, 22 hours at 204 °CTypical value printed in the Chemours table17.3 wt%15
Volatility, 22 hours at 260 °CTypical value printed in the Chemours table76.2 wt%16
Melting or freezing point (lower bound as printed)> -55 °C21
Physical and electrical
Oil density at 0 °C1.93 g/mL7
Oil density at 100 °C1.75 g/mL8
Temperature behavior
Decomposition temperature350 °C20
Other measurements
Kinematic viscosity at -32 °C44620 cSt1
Kinematic viscosity at 0 °C1070 cSt2
Kinematic viscosity at 20 °C240 cSt3
Kinematic viscosity at 40 °C78 cSt4
Kinematic viscosity at 100 °C10.2 cSt5
Kinematic viscosity at 204 °C2.1 cSt6
Viscosity indexTypical value printed in the Chemours table113 -
Pour pointTypical value printed in the Chemours table-40 °C
Distillation range215 to 290 °C17
Estimated useful range, upper limit232 °C18
Estimated useful range, lower limit-40 °C19
Pressure-viscosity coefficient at 38 °C4.2 Pa-1 x 10^8 (as printed)22
Pressure-viscosity coefficient at 149 °C3 Pa-1 x 10^8 (as printed)23

Why choose it, and why not

Good for

  • Nonflammable lubrication from -40 °C to 232 °C (estimated useful range) where a chemically inert oil is needed.
  • Oxygen and chemical service: the Chemours datasheet describes the 143 series as safe in both.
  • Spacecraft mechanisms that follow PFPE heritage, where ground tests such as NASA's scanner bearing tests are the evidence.

Watch out for

  • Creep: PFPE oils spread over bearing surfaces and can dissolve fluorocarbon barrier films (NASA).
  • Volatility: 17.3 wt% evaporated in 22 hours at 204 °C (ASTM D2595).
  • Bearing life: four of five 143AB bearing pairs had failed in NASA's scanner tests, and 143AB was not better than Bray 815Z.
  • Decomposition above 350 °C gives off hydrogen fluoride.

Krytox 143AB is a nonflammable, chemically inert PFPE oil with a wide estimated useful range. Its volatility and creep, and the ground-test bearing results, mean it needs a test on the specific design. The evidence here is ground data and heritage, with no flight record read in this run.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Other names and standards

The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.

Other names and standards
SystemCodes
Trade nameKrytox 143AB

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Kinematic viscosity at -32 °CTypical value printed in the Chemours table. The footnote calls the table typical properties, not specifications, and says viscosity may vary within ±10%.temperature -32 °C (-25 °F)method printed ASTM D445grade Krytox 143AB—
2Kinematic viscosity at 0 °CTypical value printed in the Chemours table; the footnote says viscosity may vary within ±10%.temperature 0 °C (32 °F)method printed ASTM D445—
3Kinematic viscosity at 20 °CTypical value printed in the Chemours table; the footnote says viscosity may vary within ±10%.temperature 20 °C (68 °F)method printed ASTM D445—
4Kinematic viscosity at 40 °CTypical value printed in the Chemours table; the footnote says viscosity may vary within ±10%.temperature 40 °C (104 °F)method printed ASTM D445—
5Kinematic viscosity at 100 °CTypical value printed in the Chemours table; the footnote says viscosity may vary within ±10%.temperature 100 °C (212 °F)method printed ASTM D445—
6Kinematic viscosity at 204 °CTypical value printed in the Chemours table; the footnote says viscosity may vary within ±10%.temperature 204 °C (400 °F)method printed ASTM D445—
7Oil density at 0 °CTypical value printed in the Chemours table; the table gives no ASTM method for oil densitytemperature 0 °C (32 °F)The Chemours SDS, section 9, gives a relative density of 1.86 - 1.91 with no temperature. Both are listed; neither is averaged.
8Oil density at 100 °CTypical value printed in the Chemours table; the table gives no ASTM method for oil densitytemperature 100 °C (212 °F)—
9Vapour pressure at 38 °C (Knudsen method)Typical value printed in the Chemours table; the table gives the test method as Knudsentemperature 38 °C (100 °F)method printed Knudsen—
10Vapour pressure at 20 °C (NASA table)Value printed in Table 4 of the NASA report. The report does not state the test method for these values.temperature 20 °Cgrade Krytox 143ABDifferent document and possibly a different test from the Chemours Knudsen values above. Both are listed; they are not averaged.
11Vapour pressure at 100 °C (NASA table)Value printed in Table 4 of the NASA report. The report does not state the test method for these values.temperature 100 °Cgrade Krytox 143ABDifferent document from the Chemours values above; both are listed, not averaged.
12Vapour pressure at 38 °C for Krytox 143AC (comparison grade)Typical value for a neighbouring grade in the same Chemours table, included for comparison onlytemperature 38 °C (100 °F)method printed Knudsengrade Krytox 143AC—
13Vapour pressure at 38 °C for Krytox 143AD (comparison grade)Typical value for a neighbouring grade in the same Chemours table, included for comparison onlytemperature 38 °C (100 °F)method printed Knudsengrade Krytox 143AD—
14Volatility, 22 hours at 149 °CTypical value printed in the Chemours table; the table gives the result as weight percent losstemperature 149 °C (300 °F)time 22 hoursmethod printed ASTM D2595—
15Volatility, 22 hours at 204 °C—temperature 204 °C (400 °F)time 22 hoursmethod printed ASTM D2595—
16Volatility, 22 hours at 260 °C—temperature 260 °C (500 °F)time 22 hoursmethod printed ASTM D2595—
17Distillation rangeTypical value printed in the Chemours table (printed as 215/290 °C and 420/555 °F)method printed ASTM D1160pressure 53 Pa (0.4 torr)—
18Estimated useful range, upper limitEstimate printed in the Chemours table (also 450 °F); the page does not give the basis for the estimatebasis estimated useful range printed in the Chemours table, not a specification—
19Estimated useful range, lower limitEstimate printed in the Chemours table (also -40 °F)basis estimated useful range printed in the Chemours table, not a specification—
20Decomposition temperatureValue printed in SDS section 9. The SDS does not state the test method or atmosphere.printed 662 °F / 350 °C—
21Melting or freezing point (lower bound as printed)SDS section 9 prints the melting or freezing point as greater than -55 °C. This is a bound, not a measured freezing point.printed > -67 °F / > -55 °C—
22Pressure-viscosity coefficient at 38 °CTable 5 of the NASA report, which credits the values to Jones et al. 1975. Printed as alpha, Pa-1 x 10^8.temperature 38 °Cfluid K Fluid (143AB)—
23Pressure-viscosity coefficient at 149 °CTable 5 of the NASA report, which credits the values to Jones et al. 1975. Printed as alpha, Pa-1 x 10^8.temperature 149 °Cfluid K Fluid (143AB)—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Heating to the decomposition temperature moderate Decomposition starts at 350 °C and gives off hydrogen fluoride and carbonyl difluoride.1
Heating in the ASTM D2595 volatility test moderate The oil loses weight on heating: 17.3 wt% in 22 hours at 204 °C.2
Corrosion details
#EnvironmentDetailsTest conditions
1 Heating to the decomposition temperature The Chemours SDS gives a decomposition temperature of 350 °C (662 °F). It lists hydrogen fluoride, carbonyl difluoride, carbon dioxide and carbon monoxide as products of thermal decomposition, and warns that vapours of fluorinated plastics can cause polymer fume fever. basis decomposition temperature as printed; the SDS does not give the test method or atmosphere
2 Heating in the ASTM D2595 volatility test ASTM D2595 volatility results printed by Chemours are 1.9 wt% at 149 °C, 17.3 wt% at 204 °C and 76.2 wt% at 260 °C, each over 22 hours. The table gives typical values and does not test vacuum. time 22 hoursmethod printed ASTM D2595basis typical values from the Chemours table

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

The safety data sheet does not classify Krytox 143AB as hazardous. Its thermal decomposition vapours are the hazard to plan for.

The oil
The Chemours SDS (revision 04/15/2026) classifies it as not a hazardous substance or mixture, with no GHS label elements.
Overheating
Above its decomposition temperature of 350 °C, the oil gives off hydrogen fluoride and carbonyl difluoride. The SDS warns that fluoropolymer vapours can cause polymer fume fever.
Flash
The oil does not flash in a Pensky-Martens closed-cup test, and it will not burn (SDS sections 5 and 9).

Handling and storage

Ventilation
Use only with adequate ventilation, and do not breathe decomposition products (SDS section 7).
Storage
Keep containers properly labelled. The SDS lists no special storage restrictions with other products, and says there is no decomposition if the oil is stored and applied as directed.
Temperature
Keep the oil within the estimated useful range of -40 °C to 232 °C given in the datasheet.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Creep out of the bearing racewaymoderate severityContact with bearing surfaces; PFPE fluids have low surface tensionNASA reports that PFPE fluids, with surface tension of 17 to 25 dynes/cm at 20 °C, creep more than hydrocarbons, esters and silicones. They can dissolve fluorocarbon barrier films with prolonged contact, so those films do not stop the migration.
Oil loss by evaporation in servicemoderate severityLong operation at elevated temperature, or in vacuumNASA states that for a fixed temperature and outlet area, lubricant loss is directly proportional to vapour pressure. It also says PFPE fluids are particularly good candidates compared with conventional lubricants for a similar viscosity range (Figure 4 of the report).
Early bearing failure in full-scale scanner bearingsmoderate severityHard preloaded angular-contact ball bearings at 0.75 GPa mean Hertz stress, dithered through plus or minus 12 degreesFour of five pairs of Krytox 143AB lubricated bearings had failed when the report was written. NASA says 143AB bearing lives were statistically comparable to those lubricated with Bray 815Z oil, and the Pennzane 2001 oil gave a significant life advantage over both.

Side effects on surrounding parts

Side effects on surrounding parts
AffectsEffect
Workers and the air near overheated oilDecomposition gives off hydrogen fluoride and carbonyl difluoride. The SDS lists exposure limits for hydrogen fluoride, including a NIOSH TWA of 3 ppm and an ACGIH TWA of 0.5 ppm (as fluorine).

Handling and storage

  • Use only with adequate ventilation, and do not breathe decomposition products (SDS section 7).
  • Wear safety glasses and wash skin after contact (SDS section 8).
  • Keep containers properly labelled. The SDS lists no special storage restrictions with other products, and says there is no decomposition if stored and applied as directed (section 7).

Mitigations

  • Keep the operating temperature within the estimated useful range of -40 °C to 232 °C, and well below the 350 °C decomposition temperature.
  • Where evaporation is the limit, the Chemours table shows 143AD with a lower vapour pressure (6 x 10-9 torr at 38 °C) than 143AB (5 x 10-6 torr at 38 °C). 143AD has a higher pour point, so the trade-off must be checked for the design temperature.

Supply and geography

How common the raw materials are and where they come from.

Krytox 143AB, made by The Chemours Company FC, LLC, 1007 Market Street, Wilmington, Delaware, USA (SDS section 1)

Not found in any source read in this run. It is a manufactured fluorinated polymer, and the sources give no feedstock share or production figure.

Recycling
Not found in any source read in this run. The SDS says to dispose of waste oil under local regulations and not into a sewer (section 13).

Fluorine feedstock: fluorspar (calcium fluoride, CaF2), processed into hydrogen fluoride for fluoropolymer chemistry

USGS: global mine production of fluorspar was estimated to have decreased by 1% to 10 million tons in 2025.

Top producers
China, Mexico, Mongolia
Recycling
USGS: primary aluminum producers recycle HF and fluorides from smelting operations.
Substitutes
USGS: FSA has been used as an alternative to fluorspar in the production of AlF3 and HF.

Updated