Fomblin Y LVAC perfluoropolyether vacuum pump fluid PFPE

Perfluorinated polyether (PFPE), a fluorinated polymer built only of carbon, fluorine and oxygen, made from hexafluoropropylene (named in the SDS as 1-Propene, 1,1,2,3,3,3-hexafluoro-, oxidized, polymd.) · CAS 69991-67-9

Fomblin Y LVAC is a perfluorinated polyether (PFPE) liquid used as the sealing and lubricating fluid in mechanical vacuum pumps.

7 sources · Updated 2026-11-01 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Recipe, share of the weight

  • C not statedCarbon
  • F not statedFluorine
  • O not statedOxygen

Best for

Mechanical vacuum pumps where a low vapour pressure matters: the Syensqo datasheet lists low vapor pressure as a feature of the 25/6 grade

Weakest at

Heat and metals: the SDS says decomposition starts above 290 °C and that metals lower that temperature, and no outgassing or space flight test was found

Risk at a glance

  • People None found. Not classified
  • If it fails High. Thermal decomposition of the fluid
  • Corrosion Severe. Above 290 °C the fluid breaks down and releases hydrogen fluoride, a corrosive gas.

Quick facts: PFPE

Key properties of PFPE
PropertyValueBasis
Density1.9 g/cm³1 sourced value

What is the density of Fomblin Y LVAC perfluoropolyether vacuum pump fluid (PFPE)?

Fomblin Y LVAC perfluoropolyether vacuum pump fluid (PFPE) has a density of 1.9 g/cm³. The source and test conditions are listed in the properties table on this page.

What is Fomblin Y LVAC perfluoropolyether vacuum pump fluid (PFPE) used for?

Uses recorded in the sources include Rotary and Roots mechanical vacuum pumps (sealing and lubricant fluid); Turbomolecular vacuum pumps; Vacuum processing equipment in the electronic and electrical industries.

Why it exists

Fomblin Y LVAC is a perfluorinated polyether, a liquid with a very low vapour pressure that is sold for mechanical vacuum pumps. The Syensqo datasheet lists low vapor pressure as a feature of the 25/6 grade. The manufacturer's chain is built only of carbon, fluorine and oxygen, which the SPI product page links to chemical inertness and high thermal stability.

Where it's used

Rotary and Roots vacuum pumps

A reseller lists Fomblin Y LVAC Grade 25/6 for rotary pumps, as a sealing and lubricant fluid, and for Roots pumps, for lubrication. The statement is from SPI Supplies, not from the manufacturer.

Turbomolecular pumps

The same reseller lists Grade 06/6 for turbomolecular pumps.

Electronics and electrical industries

The 2014 Solvay safety data sheet lists the electronic and electrical industries as recommended uses, for industrial use only.

Recipe

Perfluorinated polyether (PFPE), a fluorinated polymer built only of carbon, fluorine and oxygen, made from hexafluoropropylene (named in the SDS as 1-Propene, 1,1,2,3,3,3-hexafluoro-, oxidized, polymd.)

Fomblin Y is a perfluorinated polyether, a mixture of fluorinated polymers made by a photochemical process that begins with hexafluoropropylene (SPI product page). Wikipedia's Manufacture section says photooxidation of hexafluoropropylene is applied to PFPE-Y. The 2014 SDS names it '1-Propene, 1,1,2,3,3,3-hexafluoro-, oxidized, polymd.' with CAS 69991-67-9 at more than 99.9 % (Solvay 2014 SDS). The chain contains only carbon, fluorine and oxygen (SPI page, quoting the manufacturer). The sources give no atom counts.

What PFPE is made of
IngredientShare of the weightWhat it does
Carbon C not stated The backbone of the polymer chain, bonded to fluorine and oxygen.
Fluorine F not stated Part of the perfluorinated chain. The SPI page lists chemical inertness and low surface tension among the properties of this chain family.
Oxygen O not stated Links the carbon units into the polyether chain.

Weight shares are as printed in the sources.

What it can do

Low vapour pressure

The Syensqo datasheet lists low vapor pressure as a feature of the 25/6 grade and prints values at two temperatures. The five grades in the Edwards sheet differ in vapour pressure, and the grade sets how low it is.

Stays liquid when cold

The 25/6 grade has a pour point of -35 °C (ASTM D97, Syensqo datasheet).

Viscosity

The 25/6 grade has a kinematic viscosity of 276 cSt at 20 °C and a viscosity index of 113 (ASTM D445 and D2270, Syensqo datasheet).

Heat limit

The fluid starts to decompose above 290 °C (Solvay 2014 sheet). Heat above that point should be avoided.

How it compares

The Edwards sheet prints a vapour pressure at 20 °C for each of its five grades (06/6, 14/6, 16/6, 25/6 and 25/9), and the grades differ widely in volatility. The Syensqo datasheet prints 25/6 in torr at 25 °C and the Edwards sheet in mbar at 20 °C, so the two are not directly comparable and none is converted here. The vapour pressure values are not in the table because their exponent notation could not be matched to the printed text. The table compares density, evaporation loss and viscosity.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details.

Benchmarks
MeasurementPFPE
Thermal behavior and safety
Heat of vaporization of the 25/6 grade7 cal/g7
Evaporation weight loss of the 25/6 grade0.6 wt%8
Physical and electrical
Density of the 25/6 grade1.9 g/cm³1
Temperature behavior
Decomposition temperature of the Fomblin Y LVAC product family290 °C10
Other measurements
Average molecular weight of the 25/6 grade3300 amu2
Kinematic viscosity of the 25/6 grade276 cSt3
Viscosity index of the 25/6 grade113 -4
Pour point of the 25/6 grade-35 °C5
Surface tension of the 25/6 grade22 dyne/cm6
Boiling point of the Fomblin Y LVAC product family270 °C9
Average molecular weight range of the Fomblin Y LVAC product family1800 amu11
Dynamic viscosity range of the Fomblin Y LVAC product family at 20 °C95 mPa.s12
Specific gravity range of the Fomblin Y/LVAC series at 20 °C1.84 -13

Why choose it, and why not

Good for

  • Low volatility in a vacuum: the Syensqo datasheet lists low vapor pressure as a feature of grade 25/6, with a 0.6 wt% evaporation loss in 22 h at 149 °C.
  • Pump sealing and lubrication in mechanical pumps, named by a reseller for rotary and Roots pumps.

Watch out for

  • Heat and metals: decomposition starts above 290 °C, and metals lower that temperature (Solvay 2014 sheet).
  • Decomposition releases hydrogen fluoride, which is toxic and corrosive (Edwards sheet).
  • Grade choice matters: the Edwards sheet prints very different vapour pressures at 20 °C for grades 06/6 and 25/9.
  • No outgassing, radiation or space flight test result was found, so the fluid is not shown to be flight-qualified.

Fomblin Y LVAC is a low-volatility perfluoropolyether pump fluid, and the grade sets how low. It is chemically inert below 290 °C, but it breaks down above that temperature into hydrogen fluoride, and metals and Lewis acids lower the limit. No space outgassing or flight result was found.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Density of the 25/6 gradeTypical value printed in a manufacturer technical data sheetgrade 25/6temperature 20 °Ctest ASTM D4052unit in source g/cm³—
2Average molecular weight of the 25/6 gradeTypical value printed in a manufacturer technical data sheetgrade 25/6—
3Kinematic viscosity of the 25/6 gradeTypical value printed in a manufacturer technical data sheetgrade 25/6temperature 20 °Ctest ASTM D445—
4Viscosity index of the 25/6 gradeTypical value printed in a manufacturer technical data sheetgrade 25/6test ASTM D2270—
5Pour point of the 25/6 gradeTypical value printed in a manufacturer technical data sheetgrade 25/6test ASTM D97—
6Surface tension of the 25/6 gradeTypical value printed in a manufacturer technical data sheetgrade 25/6temperature 20 °C—
7Heat of vaporization of the 25/6 gradeTypical value printed in a manufacturer technical data sheetgrade 25/6temperature 200 °Cprinted as 7.00 cal/g—
8Evaporation weight loss of the 25/6 gradeTypical value printed in a manufacturer technical data sheetgrade 25/6temperature 149 °Ctime 22 h—
9Boiling point of the Fomblin Y LVAC product familyPrinted by the manufacturer's safety data sheet as a lower bound ('greater than'), not as a measured pointgrades 06/6; 14/6; 16/6; 25/6; 300 (grades named in the SDS)printed as > 270 °C (518 °F)—
10Decomposition temperature of the Fomblin Y LVAC product familyPrinted by the manufacturer's safety data sheet as a lower bound ('greater than'); no test method is givengrades 06/6; 14/6; 16/6; 25/6; 300 (grades named in the SDS)printed as > 290 °C (554 °F)atmosphere not statedtime not stated—
11Average molecular weight range of the Fomblin Y LVAC product familyRange printed in the manufacturer's safety data sheet for the product family, not a value for one gradegrades 06/6; 14/6; 16/6; 25/6; 300 (grades named in the SDS)printed as 1,800 - 3,300—
12Dynamic viscosity range of the Fomblin Y LVAC product family at 20 °CApproximate range printed in the manufacturer's safety data sheet; the test method is not printedtemperature 20 °Cgrades 06/6; 14/6; 16/6; 25/6; 300 (grades named in the SDS)printed as ca. 95 - 560 mPa.s—
13Specific gravity range of the Fomblin Y/LVAC series at 20 °CRange printed in the BOC Edwards safety data sheet for the series; the test method is not printedtemperature 20 °Cgrades 06/6, 14/6, 16/6, 25/6 and 25/9 (grades named in the Edwards SDS)printed as 1.84 - 1.93 @ 20oC/68o F—

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Lewis acids and metals at high temperature moderate Above 100 °C, Lewis acids and metals lower the temperature at which the fluid breaks down.1
Metals, plastics and elastomers in contact with the fluid at normal temperature not rated The datasheet lists compatibility with metals, plastics and elastomers as a feature. It does not print a test result.2
Thermal breakdown above 290 °C severe Above 290 °C the fluid breaks down and releases hydrogen fluoride, a corrosive gas.3
Corrosion details
#EnvironmentDetailsTest conditions
1 Lewis acids and metals at high temperature The SDS says to avoid Lewis acids (Friedel-Crafts) such as AlCl3, SbF5 and CoF3 above 100 °C, and aluminium and magnesium powder above 200 °C. It also says metals promote and lower the decomposition temperature. No corrosion rate or metal test is given. temperature above 100 °C for Lewis acids; above 200 °C for aluminium and magnesium powder
2 Metals, plastics and elastomers in contact with the fluid at normal temperature The Syensqo datasheet lists 'Excellent compatibility with metals, plastics, elastomers' among the features of the Y LVAC line. The datasheet gives no test method, exposure time or measured change for any material. basis feature list in a manufacturer datasheet; no test conditions printed
3 Thermal breakdown above 290 °C The Edwards SDS says the product may decompose above 290 °C with emissions of hydrogen fluoride and carbonyl fluoride, which are toxic and corrosive. The Solvay 2014 SDS lists the same hydrogen fluoride and names fluorophosgene as a product too. No rate of decomposition is given. temperature above 290 °Catmosphere not stated

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

The 2014 Solvay safety data sheet does not classify the fluid under the US hazard communication standard, and the Edwards sheet describes it as not dangerous when handled properly.

The fluid
The Solvay sheet gives an acute oral LD50 in rat of more than 15,000 mg/kg and an acute dermal LD50 of more than 5,000 mg/kg. It shows no skin or eye irritation in rabbits.
Vapour
The Edwards sheet says vapours that may irritate the respiratory system can be released above 290 °C (554 °F).

If it overheats

These are the failure routes named in the safety data sheets. No rate or test result is given for any of them.

Above 290 °C
The fluid may decompose above 290 °C, releasing hydrogen fluoride and carbonyl fluoride, which are toxic and corrosive (Edwards sheet). The Solvay 2014 sheet also names fluorophosgene.
Metals and Lewis acids
Metals promote and lower the decomposition temperature. Lewis acids such as AlCl3, SbF5 and CoF3 should be avoided above 100 °C (Solvay 2014 sheet).

Handling and storage

Heat
Avoid heating above 290 °C (554 °F) and keep the fluid away from heat and ignition sources.
Containers
Store in glass or polyethylene containers. Take measures against the build-up of static electricity during transfer.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Thermal decomposition of the fluidhigh severityHeating above 290 °C, or contact with free flames, which the SDS says to avoidReleases hydrogen fluoride and carbonyl fluoride (Edwards SDS) or hydrogen fluoride and fluorophosgene (Solvay 2014 SDS). These gases are toxic and corrosive.
Breakdown catalysed by metals and Lewis acidsmoderate severityLewis acids above 100 °C, or aluminium and magnesium powder above 200 °CThe SDS says metals promote and lower the decomposition temperature. The lowered temperature is not quantified in any source read.

Handling and storage

  • Avoid heating above the decomposition temperature of 290 °C (554 °F). Keep away from heat and sources of ignition.
  • Store in glass or polyethylene containers. The Solvay 2014 SDS lists polyethylene as the packaging material.
  • Take measures to prevent the build-up of electrostatic charge, and ensure equipment is electrically grounded before transfer operations.
  • In a thermal decomposition, wear self-contained breathing apparatus, and wear rubber gloves and safety goggles for handling.

Supply and geography

How common the raw materials are and where they come from.

Perfluoropolyether (Fomblin Y), made by Solvay Specialty Polymers, a member of the Syensqo group

Not found in any source read in this run. The product is a manufactured polymer, and no feedstock share or production figure was read.

Recycling
Not found in any source read in this run.

Fluorine, the element in the fluorinated chain, supplied through fluorspar (calcium fluoride) and hydrogen fluoride

Not found in any source read in this run.

Top producers (2025)
China 60%, Mexico 15%, Mongolia 15%
Recycling
Not found in any source read in this run.