Barium sulfate BaSO4

BaSO4 · CAS 7727-43-7 · orthorhombic

Barium sulfate (BaSO4) is a dense, white, very poorly water-soluble barium salt.

8 sources · Updated 2026-11-02 · CC BY 4.0

Evidence level

2 of 5

Lab-measured

Density

4.49 g/cm³

Filler capacity

Up to 70%

Melting

1580 °C

Water solubility

2.448 mg/L

Recipe, share of the weight

  • Ba not statedBarium
  • S not statedSulfur
  • O not statedOxygen

Best for

Dense X-ray and gamma shielding fillers where density matters more than mechanical strength (USGS: used as aggregate in high-density radiation-shielding concrete)

Weakest at

No space, vacuum or long-term radiation-durability data were found in the sources read; hazard data are inconsistent between sources

Risk at a glance

  • People None found. Mixed: most reports not classified; some list H372
  • If it fails Moderate. Violent reaction with aluminium powder
  • Corrosion Low. Barium sulfate dissolves only in concentrated, hot sulfuric acid among the solvents the Chembox lists.

Quick facts: BaSO4

Key properties of BaSO4
PropertyValueBasis
Density4.48 to 4.5 g/cm³4 sourced values across conditions
Melting point1,580 °C1 sourced value

What is the density of Barium sulfate (BaSO4)?

Barium sulfate (BaSO4) has a density of 4.48 to 4.5 g/cm³. The range covers 4 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.

What is the melting point of Barium sulfate (BaSO4)?

Barium sulfate (BaSO4) has a melting point of 1,580 °C. The source and test conditions are listed in the properties table on this page.

What is Barium sulfate (BaSO4) used for?

Uses recorded in the sources include Concrete aggregate for shielding around X-ray units; Filler in polymer composites.

Why it exists

Barium sulfate is a dense, poorly soluble barium salt that is used where a heavy, inert filler is needed. Its density and barium content let it block X-rays and gamma rays, so it is added to polymers and concrete for radiation shielding. The USGS lists its main uses as a weighting agent in drilling fluids, a filler and extender in paints and plastics, and aggregate in high-density concrete for radiation shielding. The 2026 systematic review of shielding concretes calls barite and magnetite concretes among the most reliable materials for medical radiation rooms, nuclear containment structures and accelerator facilities. No space or vacuum test was found.

Where it's used

Concrete for X-ray and gamma shielding

The USGS says barite significantly blocks X-ray and gamma-ray emissions, so it is used as aggregate in high-density concrete around X-ray units in hospitals, nuclear power plants and university nuclear research facilities.

Polymer composites

Barium sulfate is used as a filler for polypropylene and polystyrene plastics in proportions up to 70%, and such composites are also used as X-ray shielding materials.

Drilling fluids

Wikipedia says the largest use of barium sulfate is as a component of oil-well drilling fluid, where it raises the density of the fluid and reduces the chance of a blowout.

Recipe

BaSO4

Barium sulfate is BaSO₄, a salt of barium and sulfate. It occurs in nature as the mineral barite, which is the main commercial source of barium according to the Wikipedia article. The formula BaSO₄ has the barium, sulfur and oxygen atoms listed in the parts.

What BaSO4 is made of
IngredientShare of the weightWhat it does
Barium Ba not stated The heavy element that gives the material its high density and its ability to absorb X-rays and gamma rays.
Sulfur S not stated Forms the sulfate group that binds the barium into a stable, insoluble salt.
Oxygen O not stated Complete the sulfate group around the sulfur atom.

Weight shares are as printed in the sources.

What it can do

Density

4.49 g/cm³

measured

The Chembox gives a density of 4.49 g/cm3, and the ICSC card gives 4.5 g/cm3. The barite mineral has a density of 4.48 g/cm3 according to Ahmad et al. (2024).

Filler capacity

Up to 70%

measured

Polymer composites carry barium sulfate in proportions up to 70%, per Wikipedia. The filler raises the density of the plastic and adds X-ray opacity.

Melting

1580 °C

measured

The Chembox gives a melting point of 1580 °C. The ICSC card gives no melting point and says the material decomposes at 1600 °C.

Water solubility

2.448 mg/L

measured

The Chembox gives a water solubility of 2.448 mg/L at 20 °C, which keeps the solid largely undissolved in water.

How it compares

Barium sulfate is the pure, manufactured form of the mineral barite, and the two are the same chemical. Ahmad et al. (2024) give a density of 4.48 g/cm3 for barite, and the Chembox gives 4.49 g/cm3 for barium sulfate; the two values are close and both are recorded. Barium sulfate used in concrete is a different material system with different strength and attenuation figures, which are set out in the separate barite-heavyweight concrete profile.

The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details.

Benchmarks
MeasurementBaSO4
Capacity and energy
Molar heat capacity101.7 J/(mol K)6
Thermal behavior and safety
Melting pointValue in the Chembox of an encyclopedia article1580 °C
Physical and electrical
Density (Chembox)4.49 g/cm³1
Density (ICSC 0827)4.5 g/cm³2
Specific gravity of barite (mineral data page)Value in a note on a mineral data page4.48 gm/cc
Density of barite as a heavy mineral (Ahmad et al. 2024)Value in the text of an open-access paper4.48 g/cm³
Temperature behavior
Decomposition temperature1600 °C4
Other measurements
Molar mass233.4 g/mol3
Solubility in water at 20 °C2.448 mg/L5
Refractive index (alpha form)Value in the Chembox of an encyclopedia article1.636 -
Standard molar entropy132 J/(mol·K)7
Filler loading in polymers< 70 %8
MAK (as barium, respirable fraction)0.3 mg/m39
TLV (inhalable fraction)4 ppm10

Why choose it, and why not

Good for

  • Dense filler for X-ray and gamma shielding in polymers and concrete, per the USGS and Wikipedia.
  • Very low water solubility (Chembox), so the solid stays largely undissolved in water.

Watch out for

  • Dust hazard, and one notification lists H372 for repeated exposure.
  • Reacts violently with aluminium powder, per the ICSC card.
  • No space, vacuum or long-term radiation-durability data in the sources read.
  • The ICSC card and the Chembox disagree on water solubility.

Barium sulfate is a dense, very poorly soluble filler for X-ray and gamma shielding. Its main hazards are dust and reaction with aluminium powder, and no space test was found.

Technical details

For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.

Notes

The method, full conditions and any caveat for the numbered rows above.

Notes for the numbered rows
#MeasurementMethodConditionsCaveat
1Density (Chembox)Value in the infobox of an encyclopedia article, which cites secondary referencesform barium sulfate, solidbasis Chembox value for the pure compound—
2Density (ICSC 0827)Value printed on the International Chemical Safety Cardform barium sulfate, as listed on the cardThe card and the Chembox agree to the precision the card prints; both are recorded.
3Molar massValue printed in the infobox of an encyclopedia articlebasis molar mass of BaSO4 as printed in the Chembox—
4Decomposition temperatureValue printed on the International Chemical Safety Cardbasis statement on the card: 'Decomposes at 1600°C'note The ICSC card lists no melting point—
5Solubility in water at 20 °CValue in the Chembox; the same box gives 2.85 mg/L at 30 °Ctemperature 20 °Csolvent waterThe ICSC card gives 'none' for solubility in water, which disagrees with the Chembox figure; both are recorded in corrosion.
6Molar heat capacityValue in the Chembox thermochemistry section, which cites a textbookbasis Chembox thermochemistry field; temperature not stated in the box—
7Standard molar entropyValue in the Chembox thermochemistry section, which cites a textbookbasis standard conditions as given in the Chembox thermochemistry section—
8Filler loading in polymersValue stated in the text of an encyclopedia articlepolymers polypropylene and polystyrenebasis maximum proportion stated in the text—
9MAK (as barium, respirable fraction)Value printed on the International Chemical Safety Cardbasis MAK value printed on the card, as Ba, respirable fractioncategory peak limitation category II(8)—
10TLV (inhalable fraction)Value printed on the International Chemical Safety Cardbasis TLV as TWA, inhalable fraction, as printed on the cardThe card prints the unit ppm for a dust limit; it is copied as printed.

Corrosion and compatibility

What happens when it meets other materials and environments.

Corrosion and compatibility
EnvironmentConcernWhat happens
Concentrated, hot sulfuric acid low Barium sulfate dissolves only in concentrated, hot sulfuric acid among the solvents the Chembox lists.1
Water low The sources disagree on water solubility: the Chembox gives a figure, while the ICSC card says none.2
Fire and high temperature low The card says the material is not combustible, but it gives off irritating or toxic fumes in a fire.3
Corrosion details
#EnvironmentDetailsTest conditions
1 Concentrated, hot sulfuric acid The Chembox lists barium sulfate as soluble in concentrated, hot sulfuric acid and as insoluble in ethanol. It gives a water solubility of 2.448 mg/L at 20 °C, so it does not dissolve appreciably in water. basis solubility fields in the Chembox; no test of corrosion rates is given
2 Water The ICSC card gives 'none' for solubility in water. The Chembox gives 2.448 mg/L at 20 °C. Both are recorded here and neither is filled in. basis two sources compared side by side
3 Fire and high temperature ICSC 0827 says 'Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.' It also says the material decomposes at 1600 °C. The card does not name the fumes. basis fire-fighting section of the card; the gases are not named

Risks and side effects

Hazards to people, what happens when a cell overheats, and how the material is handled and stored.

For people

PubChem's aggregated summary says most company reports do not meet GHS hazard criteria, but other notifications list hazard statements, including a repeated-exposure hazard.

Most reports
PubChem's summary reads: 'This chemical does not meet GHS hazard criteria for 91% (1648 of 1811) of all reports.'
Harmful if swallowed
One notification lists H302, harmful if swallowed, with the signal word Warning.
Repeated exposure
Another notification lists H372, causes damage to organs through prolonged or repeated exposure, with the signal word Danger.
Dust
The ICSC card advises preventing dust from spreading and says repeated or prolonged inhalation of dust may affect the lungs, possibly as baritosis.

Handling powder

Barium sulfate is usually handled as a powder or a filler, so the main concerns are dust and mixing with reactive metals.

Reaction
The ICSC card warns that the material reacts violently with aluminium powder.
Fire
The card says it is not combustible but gives off irritating or toxic fumes in a fire.

Test details
The original wording and numbers from the sources, for readers who want them.

Failure risks

Failure risks
FailureTrigger and consequence
Violent reaction with aluminium powdermoderate severityContact with aluminium powder in a mix or spillICSC 0827 lists 'Reacts violently with aluminium powder' under chemical dangers.

Handling and storage

  • The ICSC card says to prevent dispersion of dust, use local exhaust or breathing protection, and wear protective gloves and safety spectacles.
  • The card says to sweep spilled substance into covered containers and, if appropriate, to moisten it first to prevent dusting, using a particulate filter respirator.
  • No barium sulfate safety data sheet from a supplier was read in this run. Check the supplier's data sheet before handling bulk powder.

Mitigations

  • The ICSC card's eye first aid is to rinse first with plenty of water for several minutes, then refer for medical attention.

Supply and geography

How common the raw materials are and where they come from.

Barite (barium sulfate mineral)

Top producers (2025)
India 34.5%, China 25.3%, Morocco 11.5%, Kazakhstan 8%, Mexico 3.4%
Critical mineral lists
EU: listed
Recycling
USGS barite chapter: 'Recycling: None.'
Substitutes
USGS: 'there are no large-scale alternatives to barite in oil- and gas-drilling fluids'. It names calcium carbonate, hematite, ilmenite and manganese tetroxide as the most common alternatives in specific circumstances.

Updated