Avcoat Avcoat
Epoxy novolac resin filled with silica microballoons, phenolic microballoons and silica fibres, in a honeycomb (exact recipe proprietary)
Also known as Avcoat 5026-39-HC G, AVCOAT-5026 H/CG
Avcoat is a charring ablator: it protects a capsule on re-entry by burning off (ablating) and leaving an insulating char.
Evidence level
2 of 5
Lab-measured
- 0Predicted only. No one has made it, or no measurement exists.
- 1Calculated. Only calculated or predicted values from sources.
- 2Lab-measured. Measured properties with their conditions stated.
- 3Space-relevant tests. Measured in conditions relevant to space, such as vacuum or atomic oxygen.
- 4Ground-qualified. Qualified for an application on the ground.
- 5Flown or field-proven. Flight or field results exist.
Density
530.0 kg/m3 at 75 °F
Heat absorbed
0.6364 MJ/kg at 733 °F
Thermal conductivity
0.0502 W/m-K at 154 K
Specific heat
0.606 kJ/kg-K at 144 K
Recipe, share of the weight
- not statedEpoxy novolac resin
- not statedSilica microballoons
- not statedPhenolic microballoons
- not statedSilica fibres
- not statedHoneycomb
Best for
Single-use heat shields for atmospheric re-entry, the design role NASA used it for on Apollo and on the Orion EM-1 capsule
Weakest at
Single use: the material is designed to char and erode on every entry, so the shield is consumed. Its decomposition model is fitted from thermogravimetric data, and the Orion paper reports large uncertainty in the reaction orders.
Risk at a glance
- People No data. No hazard data recorded
- If it fails Moderate. Decomposition kinetics uncertainty in the heat-shield model
- Corrosion Moderate. Avcoat loses 11.2 % of its weight by 502 °F and 27.5 % by 733 °F in the enthalpy test.
Quick facts: Avcoat
| Property | Value | Basis |
|---|---|---|
| Density | 0.53 g/cm³ | 1 sourced value |
| Thermal conductivity | 0.05 to 0.11 W/(m·K) | 2 sourced values across conditions |
| Specific heat | 606 to 1,780 J/(kg·K) | 2 sourced values across conditions |
What is the density of Avcoat?
Avcoat has a density of 0.53 g/cm³. The source and test conditions are listed in the properties table on this page.
What is the thermal conductivity of Avcoat?
Avcoat has a thermal conductivity of 0.05 to 0.11 W/(m·K). The range covers 2 sourced values across the tempers, forms and test conditions the sources report; room-temperature values are used where a source states a temperature.
What are the other names and codes for Avcoat?
Avcoat is also written as Avcoat 5026-39-HC G, AVCOAT-5026 H/CG. Each code is printed in the source listed beside it in the designations table.
What is Avcoat used for?
Uses recorded in the sources include Apollo command module heat shield; Apollo command module heat shield, flight history; Orion EM-1 crew module heat shield (molded Avcoat).
Why it exists
Avcoat is the ablative heat shield NASA used on Apollo and designed into the Orion EM-1 capsule. An ablator protects the vehicle by burning away and forming an insulating char on re-entry. The sources here describe a low-density epoxy-based material, and the data show how its density, thermal conductivity and specific heat change with temperature, and how much of its weight is lost as it heats.
Where it's used
Apollo command module
TPSX states that AVCOAT was the primary heat shield for Apollo. The Avcoat article lists uncrewed tests from AS-201 and AS-202 to Apollo 6, and crewed missions from Apollo 7 through Apollo 17.
Orion EM-1 capsule
The Orion paper says the EM-1 capsule has been designed to use a molded Avcoat material system, and that its heat shield thickness is sized with a Monte Carlo analysis that includes the material's own uncertainties.
Artemis I (uncrewed, 2022)
The Avcoat article says the Artemis I shield was redesigned to use shaped AVCOAT blocks, and that Artemis I flew uncrewed in 2022. The post-flight condition of the shield is not confirmed in the sources read.
Recipe
Epoxy novolac resin filled with silica microballoons, phenolic microballoons and silica fibres, in a honeycomb (exact recipe proprietary)
Avcoat is a composite, not a single compound. TPSX lists its constituents as an epoxy novolac resin, silica microballoons, phenolic microballoons and silica fibres, in a honeycomb. The exact proportions are proprietary (TN D-2991).
| Ingredient | Share of the weight | What it does |
|---|---|---|
| Epoxy novolac resin | not stated | Binder that holds the fillers together; it decomposes on heating to form the char. |
| Silica microballoons | not stated | Hollow silica spheres listed by TPSX as a filler. |
| Phenolic microballoons | not stated | Hollow phenolic spheres listed by TPSX as a filler. |
| Silica fibres | not stated | Fibre reinforcement listed by TPSX as a constituent. |
| Honeycomb | not stated | Cell structure that holds the filled resin. TPSX lists phenolic or stainless-steel honeycomb. |
Weight shares are as printed in the sources.
What it can do
Density
530.0 kg/m3 at 75 °F
measured
Room-temperature density of the low-density filled epoxy in honeycomb is 530.0 kg/m3 at 75 °F, measured in TN D-2991. TPSX gives 529 kg/m3 for the virgin material at standard conditions, which it marks as assumed.
Heat absorbed
0.6364 MJ/kg at 733 °F
measured
In the TN D-2991 enthalpy test, the material absorbed 0.6364 MJ/kg of enthalpy on heating to 733 °F (661.9 K), relative to 32 °F.
Thermal conductivity
0.0502 W/m-K at 154 K
measured
Thermal conductivity in direction C is 0.0502 W/m-K at 154 K (-182 °F) and 0.109 W/m-K at 528 K (491 °F), both measured by Melpar in TN D-2991.
Specific heat
0.606 kJ/kg-K at 144 K
measured
Specific heat rises from 0.606 kJ/kg-K at 144 K (-200 °F) to 1.78 kJ/kg-K at 671 K (750 °F), per Table 2 of TN D-2991.
How it compares
The only other material in these sources with a measured density at the same temperature is the carbon-fibre-reinforced phenolic Narmco 4028, tested in TN D-2991. At 75 °F, Avcoat's density is 530.0 kg/m3, against 1390 kg/m3 for Narmco 4028, so Avcoat is much the lighter of the two. The Orion paper names PICA and another earlier ablator as comparison points, but these sources give no property values for them, so no further comparison is made.
The same measurements for each material, so you can compare them. Each row names the key condition under the value; the full conditions and methods are in the numbered notes under Technical details.
| Measurement | Avcoat |
|---|---|
| Thermal behavior and safety | |
| Thermal conductivity, Avcoat 5026-39-HC G (direction C), low temperature | 0.0502 W/m-K3 |
| Thermal conductivity, Avcoat 5026-39-HC G (direction C), 491 °F | 0.109 W/m-K4 |
| Specific heat, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G), low temperature | 0.606 kJ/kg-K5 |
| Specific heat, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G), high temperature | 1.78 kJ/kg-K6 |
| Lifetime and stability | |
| Uncertainty of the pyrolysis gas enthalpy | 0.18 -12 |
| Physical and electrical | |
| Room-temperature density, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G) | 530 kg/m31 |
| Density after heating, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G) | 467.7 kg/m32 |
| Other measurements | |
| Emissivity (TPSX) | 0.667 -7 |
| Enthalpy change of the material on heating to 733 °F, relative to 32 °F | 0.6364 MJ/kg8 |
| Weight loss on heating to 733 °F | 27.5 %9 |
| Weight loss on heating to 502 °F | 11.2 %10 |
| Uncertainty of the normalized ablation rate (char recession rate, Bc') | 0.15 -11 |
Why choose it, and why not
Good for
- Single-use re-entry heat shields. NASA used this design role on Apollo and on the Orion EM-1 capsule.
- Low-density thermal protection: 530.0 kg/m3 at room temperature in TN D-2991.
Watch out for
- Post-flight condition after Artemis I is reported differently by two sources, and neither was confirmed in a primary NASA source in this run.
- The decomposition model is fitted, not measured directly: the Orion paper reports reaction-order uncertainties of 0.263 to 0.388 and says the fitted reaction orders varied greatly.
- Thermal conductivity rises with temperature in direction C: 0.0502 W/m-K at 154 K and 0.109 W/m-K at 528 K, so use the value at the temperature of interest.
Avcoat is the heritage ablator: NASA used it on Apollo and designed Orion EM-1 around it. Most property values here come from a 1965 report and a database, so check them against current NASA data before any design use, and get a hazard data sheet before handling.
Technical details
For scientists and researchers. Everything above comes from the record below: every number with its method, its conditions and its source.
Other names and standards
The same grade under other systems, as datasheets and standards print them. Each code was checked against the page it comes from.
| System | Codes |
|---|---|
| Trade name | Avcoat 5026-39-HC G, AVCOAT-5026 H/CG |
Notes
The method, full conditions and any caveat for the numbered rows above.
| # | Measurement | Method | Conditions | Caveat |
|---|---|---|---|---|
| 1 | Room-temperature density, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G) | Room-temperature measurement (Table 6 footnote b). Printed in lb/ft3 and kg/m3; the kg/m3 value is copied as printed. | temperature 75 °F (297 K), room-temperature measurementform low-density filled epoxy in honeycomb (Melpar)printed in source 33.09 lb/ft3 | — |
| 2 | Density after heating, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G) | Calculated from thermal-expansion data and weight measurements after exposure to temperature (Table 6 footnote a) | temperature 500 °F (532 K)form low-density filled epoxy in honeycomb (Melpar)printed in source 29.20 lb/ft3 | — |
| 3 | Thermal conductivity, Avcoat 5026-39-HC G (direction C), low temperature | Measured by Melpar (Table 3). The SI value is copied as printed. | temperature -182 °F (154 K) mean temperaturedirection Cspecimen 1printed in source 0.0290 Btu/ft-hr-F | — |
| 4 | Thermal conductivity, Avcoat 5026-39-HC G (direction C), 491 °F | Measured by Melpar (Table 3). The SI value is copied as printed. | temperature 491 °F (528 K) mean temperaturedirection Cspecimen 5printed in source 0.0631 Btu/ft-hr-F | — |
| 5 | Specific heat, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G), low temperature | Measured by Melpar (Table 2). The SI value is copied as printed. | temperature -200 °F (144 K)form low-density filled epoxy in honeycomb (Melpar)printed in source 0.145 Btu/lb-F | — |
| 6 | Specific heat, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G), high temperature | Measured by Melpar (Table 2). The SI value is copied as printed. | temperature 750 °F (671 K)form low-density filled epoxy in honeycomb (Melpar)printed in source 0.425 Btu/lb-F | — |
| 7 | Emissivity (TPSX) | Database value printed in TPSX as 6.67e-01. TPSX marks it as assumed, not measured. | stp flag assumed/assumed (TPSX)form virgin Avcoat-5026 H/CG | — |
| 8 | Enthalpy change of the material on heating to 733 °F, relative to 32 °F | Measured in the enthalpy test reported in Table 1. The SI value is copied as printed. | temperature 733 °F (661.9 K)reference temperature 32 °F (273 K)form low-density filled epoxy in honeycomb (Melpar)printed in source 273.37 Btu/lb | — |
| 9 | Weight loss on heating to 733 °F | Weight loss measured with the enthalpy data (Table 1, weight-loss column) | temperature 733 °F (661.9 K)form low-density filled epoxy in honeycomb (Melpar) | — |
| 10 | Weight loss on heating to 502 °F | Weight loss measured with the enthalpy data (Table 1, weight-loss column) | temperature 502 °F (533.7 K)form low-density filled epoxy in honeycomb (Melpar) | — |
| 11 | Uncertainty of the normalized ablation rate (char recession rate, Bc') | Relative uncertainty calculated by the authors (Eq. 3); not a measured property of the material | basis uncertainty u = 2 x (standard deviation / mean), Monte Carlo runs of the ACE wrapper scriptform molded Avcoat (Orion) | — |
| 12 | Uncertainty of the pyrolysis gas enthalpy | Relative uncertainty calculated by the authors (Eq. 3); not a measured property of the material | basis uncertainty u = 2 x (standard deviation / mean), Monte Carlo runs of the ACE wrapper scriptform molded Avcoat (Orion) | — |
Corrosion and compatibility
What happens when it meets other materials and environments.
| Environment | Concern | What happens |
|---|---|---|
| Heating to 502 °F and 733 °F in the enthalpy test (thermal decomposition, no oxidation data) | moderate | Avcoat loses 11.2 % of its weight by 502 °F and 27.5 % by 733 °F in the enthalpy test.1 |
| Thermal decomposition modelled from thermogravimetric analysis (TGA) of molded Avcoat | moderate | A single Arrhenius reaction does not fit molded Avcoat, so the Orion team fitted three.2 |
| # | Environment | Details | Test conditions |
|---|---|---|---|
| 1 | Heating to 502 °F and 733 °F in the enthalpy test (thermal decomposition, no oxidation data) | The TN report says weight loss in these tests comes from the loss of volatile products from thermochemical reaction, and the density figures were corrected for it. This decomposition is the designed ablation, not a corrosion failure. | basis weight loss reported with the enthalpy data; test atmosphere not printed in the sections readform low-density filled epoxy in honeycomb (Melpar) |
| 2 | Thermal decomposition modelled from thermogravimetric analysis (TGA) of molded Avcoat | The Orion paper fits three Arrhenius equations to six TGA runs with nine independent parameters. The best-fit reaction orders vary greatly, so their uncertainty is high (see the decomposition uncertainties in watch_out). | basis six laboratory TGA measurements, nine fitted Arrhenius parametersform molded Avcoat (Orion) |
Risks and side effects
Hazards to people, what happens when a cell overheats, and how the material is handled and stored.
For people
No safety data sheet for Avcoat 5026-39-HC G was read in this run. PubChem gives hazard statements for three constituent classes, but not for the proprietary Avcoat formulation.
- Constituents
- PubChem lists skin, eye and respiratory irritation and skin sensitisation for these classes. Its silica record also carries cancer and organ-damage statements that it does not tie to a silica form. Check the supplier's safety data sheet before handling any Avcoat material.
On re-entry
The shield is designed to char and erode during entry, and the sources give the heating and weight-loss data for that process.
- Weight loss
- In the TN D-2991 enthalpy test, the material had lost 11.2 % of its weight by 502 °F and 27.5 % by 733 °F.
- Design margin
- The Orion sizing method reduces the allowable bondline temperature limit by 60 °C to cover material property uncertainty.
Handling and storage
No handling or storage guidance was found in the sources read.
- Storage
- No storage or shelf-life data were found. Treat the material as single-use: it is designed to char and erode on each entry.
Test details
The original wording and numbers from the sources, for readers who want them.
Failure risks
| Failure | Trigger and consequence |
|---|---|
| Decomposition kinetics uncertainty in the heat-shield modelmoderate severity | Predicting char recession with Arrhenius parameters fitted to TGA dataThe Orion paper reports relative uncertainty of 0.263 to 0.388 in the decomposition reaction orders, and says the fitted reaction orders varied greatly. |
Side effects on surrounding parts
| Affects | Effect |
|---|---|
| Heat transfer to the structure under the shield in the sizing model | Decomposition releases pyrolysis gas, which the Orion model handles through a pyrolysis gas enthalpy table with a relative uncertainty of 0.18. |
Mitigations
- The current Orion sizing method reduces the allowable bondline temperature limit by 60 °C to cover material property uncertainty. The paper asks whether that value is still appropriate for molded Avcoat.
Supply and geography
How common the raw materials are and where they come from.
Silica (feedstock for the silica fibres and silica microballoons)
USGS Silicon chapter: 'The source of the silicon is silica in various natural forms, such as quartzite.' It also says 'World and domestic resources for making silicon metal and alloys are abundant.'
AVCOAT material (produced by Lockheed Martin, licensed by Textron)
- Top producers
- United States
Documents
Datasheets, safety data sheets, papers and standards you can open.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0. Images keep the licence shown with each one.
Show the full YAML
spore: profile
id: avcoat
spore_version: 0.2
family: epoxy-ablators
name: Avcoat
abbreviation: Avcoat
role: Charring ablative heat shield for atmospheric re-entry (Apollo command module, Orion)
category: thermal-protection
type: ablators
summary: |
Avcoat is a charring ablator: it protects a capsule on re-entry by burning off (ablating) and leaving an insulating char. NASA's TPSX database lists the virgin material (Avcoat-5026 H/CG) at 529 kg/m3 and 0.242 W/m-K thermal conductivity at standard conditions. NASA TN D-2991 measured the room-temperature density of the Avcoat 5026-39-HC G material at 530.0 kg/m3 (75 °F) and its thermal conductivity at 0.0502 W/m-K at 154 K (-182 °F, direction C). In the enthalpy test of TN D-2991 the material had lost 11.2 % of its weight by 533.7 K (502 °F) and 27.5 % by 661.9 K (733 °F).
best_for: Single-use heat shields for atmospheric re-entry, the design role NASA used it for on Apollo and on the Orion EM-1 capsule
weakest_at: 'Single use: the material is designed to char and erode on every entry, so the shield is consumed. Its decomposition model is fitted from thermogravimetric data, and the Orion paper reports large uncertainty in the reaction orders.'
identity:
formula: Epoxy novolac resin filled with silica microballoons, phenolic microballoons and silica fibres, in a honeycomb (exact recipe proprietary)
source: tpsx-avcoat
where: Description (constituents) and Name fields. TN D-2991 calls the material a low-density filled epoxy in honeycomb and says its composition is proprietary.
designations:
- system: Trade name
code: Avcoat 5026-39-HC G
source: tn-d2991
where: Section Materials, paragraph naming the commercial designation (Avco Corporation, Research and Advanced Development Division)
- system: Trade name
code: AVCOAT-5026 H/CG
source: tpsx-avcoat
where: Page title and Name field (Avcoat-5026 H/CG [virgin])
tags:
environments:
- re-entry
applications:
- heat-shields
properties:
- benchmark: density
label: Room-temperature density, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G)
value: 530
unit: kg/m3
scope: material
conditions:
temperature: 75 °F (297 K), room-temperature measurement
form: low-density filled epoxy in honeycomb (Melpar)
printed_in_source: 33.09 lb/ft3
method: Room-temperature measurement (Table 6 footnote b). Printed in lb/ft3 and kg/m3; the kg/m3 value is copied as printed.
status: ground
source: tn-d2991
where: Table 6 (Density), Avcoat block, row at 75 °F (297 K) marked b. For comparison, the carbon-fibre-reinforced phenolic Narmco 4028 row at the same 75 °F reads 1390 kg/m3 in the same table.
- benchmark: density
label: Density after heating, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G)
value: 467.7
unit: kg/m3
scope: material
conditions:
temperature: 500 °F (532 K)
form: low-density filled epoxy in honeycomb (Melpar)
printed_in_source: 29.20 lb/ft3
method: Calculated from thermal-expansion data and weight measurements after exposure to temperature (Table 6 footnote a)
status: calculated
source: tn-d2991
where: Table 6 (Density), Avcoat block, row at 500 °F (532 K)
- benchmark: thermal_conductivity
label: Thermal conductivity, Avcoat 5026-39-HC G (direction C), low temperature
value: 0.0502
unit: W/m-K
scope: material
conditions:
temperature: '-182 °F (154 K) mean temperature'
direction: C
specimen: '1'
printed_in_source: 0.0290 Btu/ft-hr-F
method: Measured by Melpar (Table 3). The SI value is copied as printed.
status: ground
source: tn-d2991
where: Table 3 (Thermal conductivity), Avcoat row, first row at -182 °F (154 K)
- benchmark: thermal_conductivity
label: Thermal conductivity, Avcoat 5026-39-HC G (direction C), 491 °F
value: 0.109
unit: W/m-K
scope: material
conditions:
temperature: 491 °F (528 K) mean temperature
direction: C
specimen: '5'
printed_in_source: 0.0631 Btu/ft-hr-F
method: Measured by Melpar (Table 3). The SI value is copied as printed.
status: ground
source: tn-d2991
where: Table 3 (Thermal conductivity), Avcoat row at 491 °F (528 K)
- benchmark: specific_heat
label: Specific heat, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G), low temperature
value: 0.606
unit: kJ/kg-K
scope: material
conditions:
temperature: '-200 °F (144 K)'
form: low-density filled epoxy in honeycomb (Melpar)
printed_in_source: 0.145 Btu/lb-F
method: Measured by Melpar (Table 2). The SI value is copied as printed.
status: ground
source: tn-d2991
where: Table 2 (Specific heat), Avcoat row at -200 °F (144 K)
- benchmark: specific_heat
label: Specific heat, low-density filled epoxy in honeycomb (Avcoat 5026-39-HC G), high temperature
value: 1.78
unit: kJ/kg-K
scope: material
conditions:
temperature: 750 °F (671 K)
form: low-density filled epoxy in honeycomb (Melpar)
printed_in_source: 0.425 Btu/lb-F
method: Measured by Melpar (Table 2). The SI value is copied as printed.
status: ground
source: tn-d2991
where: Table 2 (Specific heat), Avcoat row at 750 °F (671 K)
- benchmark: emissivity
label: Emissivity (TPSX)
value: 0.667
unit: '-'
scope: material
conditions:
stp_flag: assumed/assumed (TPSX)
form: virgin Avcoat-5026 H/CG
method: Database value printed in TPSX as 6.67e-01. TPSX marks it as assumed, not measured.
status: calculated
source: tpsx-avcoat
where: Properties at Standard Conditions table, Emissivity row
- benchmark: enthalpy_change
label: Enthalpy change of the material on heating to 733 °F, relative to 32 °F
value: 0.6364
unit: MJ/kg
scope: material
conditions:
temperature: 733 °F (661.9 K)
reference_temperature: 32 °F (273 K)
form: low-density filled epoxy in honeycomb (Melpar)
printed_in_source: 273.37 Btu/lb
method: Measured in the enthalpy test reported in Table 1. The SI value is copied as printed.
status: ground
source: tn-d2991
where: Table 1 (Enthalpy), Avcoat row at 733.0 °F (661.9 K)
- benchmark: weight_loss
label: Weight loss on heating to 733 °F
value: 27.5
unit: '%'
scope: material
conditions:
temperature: 733 °F (661.9 K)
form: low-density filled epoxy in honeycomb (Melpar)
method: Weight loss measured with the enthalpy data (Table 1, weight-loss column)
status: ground
source: tn-d2991
where: Table 1 (Enthalpy), weight-loss column, Avcoat row at 733.0 °F (661.9 K)
- benchmark: weight_loss
label: Weight loss on heating to 502 °F
value: 11.2
unit: '%'
scope: material
conditions:
temperature: 502 °F (533.7 K)
form: low-density filled epoxy in honeycomb (Melpar)
method: Weight loss measured with the enthalpy data (Table 1, weight-loss column)
status: ground
source: tn-d2991
where: Table 1 (Enthalpy), weight-loss column, Avcoat row at 502.0 °F (533.7 K)
- benchmark: normalized_ablation_rate_uncertainty
label: Uncertainty of the normalized ablation rate (char recession rate, Bc')
value: 0.15
unit: '-'
scope: material
conditions:
basis: uncertainty u = 2 x (standard deviation / mean), Monte Carlo runs of the ACE wrapper script
form: molded Avcoat (Orion)
method: Relative uncertainty calculated by the authors (Eq. 3); not a measured property of the material
status: calculated
source: orion-avcoat-uq
where: Table 1 (Resulting uncertainty values), row Char Recession Rate Bc', Current Study column
- benchmark: pyrolysis_gas_enthalpy_uncertainty
label: Uncertainty of the pyrolysis gas enthalpy
value: 0.18
unit: '-'
scope: material
conditions:
basis: uncertainty u = 2 x (standard deviation / mean), Monte Carlo runs of the ACE wrapper script
form: molded Avcoat (Orion)
method: Relative uncertainty calculated by the authors (Eq. 3); not a measured property of the material
status: calculated
source: orion-avcoat-uq
where: Table 1 (Resulting uncertainty values), row Pyrolysis gas Enthalpy, Current Study column
corrosion:
- environment: Heating to 502 °F and 733 °F in the enthalpy test (thermal decomposition, no oxidation data)
headline: Avcoat loses 11.2 % of its weight by 502 °F and 27.5 % by 733 °F in the enthalpy test.
effect: The TN report says weight loss in these tests comes from the loss of volatile products from thermochemical reaction, and the density figures were corrected for it. This decomposition is the designed ablation, not a corrosion failure.
rating: moderate
conditions:
basis: weight loss reported with the enthalpy data; test atmosphere not printed in the sections read
form: low-density filled epoxy in honeycomb (Melpar)
source: tn-d2991
where: Table 1 (weight-loss column); Density section, paragraph on bulk density of virgin materials
- environment: Thermal decomposition modelled from thermogravimetric analysis (TGA) of molded Avcoat
headline: A single Arrhenius reaction does not fit molded Avcoat, so the Orion team fitted three.
effect: The Orion paper fits three Arrhenius equations to six TGA runs with nine independent parameters. The best-fit reaction orders vary greatly, so their uncertainty is high (see the decomposition uncertainties in watch_out).
rating: moderate
conditions:
basis: six laboratory TGA measurements, nine fitted Arrhenius parameters
form: molded Avcoat (Orion)
source: orion-avcoat-uq
where: Section II.A (Decomposition Parameters) and Figure 1
risks:
hazards:
- text: PubChem silica record (CID 24261) pools company reports, and its summary notes say information may vary between notifications depending on impurities, additives and other factors. The largest block reads Not Classified, reported as not meeting GHS hazard criteria per 7724 of 9127 reports by companies. Other blocks in the record give H315, H319 and H335 (skin, eye and respiratory irritation) and H350 and H372 (may cause cancer; organ damage from prolonged or repeated exposure). The extracted record does not say which silica form each block covers, so it is not specific to the silica fibres in Avcoat.
ghs: []
source: pubchem-silica
where: 'Safety and Hazards, GHS Classification (CID 24261): summary note and GHS Hazard Statements blocks, with their report counts'
- text: Bisphenol A diglycidyl ether (BADGE, CID 2286) is a bisphenol-A epoxy, not the epoxy novolac resin in Avcoat. PubChem lists H315 (causes skin irritation), H317 (may cause an allergic skin reaction) and H319 (causes serious eye irritation) in its company reports, and one notification block adds H411 (toxic to aquatic life with long lasting effects) for 50.9% of its reports.
ghs: []
source: pubchem-badge
where: 'Safety and Hazards, GHS Classification (CID 2286): GHS Hazard Statements blocks'
- text: Phenolic resin (PubChem CID 24754) is the nearest class in PubChem to the phenolic microballoons in Avcoat; the sources read do not confirm that the microballoons are this resin. PubChem lists H317 (may cause an allergic skin reaction) for 100% of 4 company reports from 2 notifications, and H302 (harmful if swallowed) and H312 (harmful in contact with skin) from a single company notification.
ghs: []
source: pubchem-phenolic
where: 'Safety and Hazards, GHS Classification (CID 24754): GHS Hazard Statements blocks'
failure_risks:
- mode: Decomposition kinetics uncertainty in the heat-shield model
trigger: Predicting char recession with Arrhenius parameters fitted to TGA data
consequence: The Orion paper reports relative uncertainty of 0.263 to 0.388 in the decomposition reaction orders, and says the fitted reaction orders varied greatly.
severity: moderate
source: orion-avcoat-uq
where: Section III (Results) and Table 2 (Decomposition Parameter Uncertainties)
side_effects:
- text: Decomposition releases pyrolysis gas, which the Orion model handles through a pyrolysis gas enthalpy table with a relative uncertainty of 0.18.
affects: Heat transfer to the structure under the shield in the sizing model
source: orion-avcoat-uq
where: Section II.B (Pyrolysis Gas Enthalpy) and Table 1
handling: []
mitigations:
- text: The current Orion sizing method reduces the allowable bondline temperature limit by 60 °C to cover material property uncertainty. The paper asks whether that value is still appropriate for molded Avcoat.
source: orion-avcoat-uq
where: Section I (Introduction), paragraphs 2 and 3
uses:
- application: heat-shields
device: Apollo command module heat shield
example: TPSX states that AVCOAT was used as the primary heatshield for Apollo.
source: tpsx-avcoat
where: Description field
- application: heat-shields
device: Apollo command module heat shield, flight history
example: The Avcoat article says it flew on uncrewed tests (AS-201, AS-202, Apollo 4, Apollo 6) and on crewed missions from Apollo 7 through Apollo 17, plus Skylab 2 to 4 and Apollo-Soyuz.
source: wiki-avcoat
where: History and Apollo Command Module sections
- application: heat-shields
device: Orion EM-1 crew module heat shield (molded Avcoat)
example: The Orion paper says the EM-1 capsule has been designed to use a molded Avcoat material system, and that the heat shield thickness is sized with Monte Carlo analysis of material uncertainty.
source: orion-avcoat-uq
where: Section I (Introduction), first paragraph
- application: heat-shields
device: Orion capsule on Artemis I (uncrewed, 2022)
example: The Avcoat article says the Artemis I shield was redesigned to use shaped AVCOAT blocks, and that Artemis I flew uncrewed in 2022.
source: wiki-avcoat
where: Orion EFT-1 and Artemis I sections
supply:
- subject: Silica (feedstock for the silica fibres and silica microballoons)
abundance: 'USGS Silicon chapter: ''The source of the silicon is silica in various natural forms, such as quartzite.'' It also says ''World and domestic resources for making silicon metal and alloys are abundant.'''
producers: []
critical_lists: []
substitutes: []
source: usgs-mcs2026-silicon
where: Silicon chapter, World Resources and Domestic Production and Use paragraphs. The chapter covers silicon metal and ferrosilicon, not silica fibre, so it gives no silica producers. The chapter says silicon was added to the U.S. Final 2025 List of Critical Minerals; that listing is for silicon, not silica.
- subject: AVCOAT material (produced by Lockheed Martin, licensed by Textron)
producers:
- country: United States
critical_lists: []
substitutes: []
source: wiki-avcoat
where: 'Orion EFT-1 Crew Module section, paragraph beginning ''Licensed by Textron'': ''AVCOAT material is produced at New Orleans''s Michoud Assembly Facility by Lockheed Martin.'' The page names New Orleans, not the country; United States is taken from that city. No production shares are given.'
media: []
documents:
- title: 'NASA Ames TPSX Materials Database: AVCOAT-5026 H/CG [virgin]'
type: database
url: https://tpsx.arc.nasa.gov/Material?id=37
year: 1996
- title: 'NASA TN D-2991: Thermophysical Properties of Six Charring Ablators (R. Gale Wilson, compiler)'
type: report
url: https://ntrs.nasa.gov/api/citations/19650024901/downloads/19650024901.pdf
year: 1965
- title: Determination of Uncertainties for Analytically Derived Material Properties to be used in Monte Carlo Based Orion Heatshield Sizing (NTRS 20190029074)
type: paper
url: https://ntrs.nasa.gov/api/citations/20190029074/downloads/20190029074.pdf
year: 2019
- title: PubChem compound record, Silica (CID 24261)
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/24261
year: 2026
- title: PubChem compound record, Bisphenol A diglycidyl ether (CID 2286)
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/2286
year: 2026
- title: PubChem compound record, Phenolic resin (CID 24754)
type: database
url: https://pubchem.ncbi.nlm.nih.gov/compound/24754
year: 2026
- title: 'USGS Mineral Commodity Summaries 2026: Silicon'
type: report
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-silicon.pdf
year: 2026
gaps:
- No safety data sheet or GHS classification for Avcoat 5026-39-HC G itself was found. risks.hazards holds PubChem entries for three constituent classes (silica, a bisphenol-A epoxy and a phenolic resin), which are not the proprietary Avcoat formulation. Check the supplier's SDS before handling.
- No handling, storage or shelf-life guidance was found in the sources read.
- No humidity, moisture-absorption, UV or chemical-resistance data were found. Only the enthalpy-test weight loss and the Orion decomposition model are reported.
- No production shares were found for Avcoat. The Wikipedia article names Lockheed Martin as producer at Michoud and Textron as licensor, but gives no shares. The USGS silicon chapter describes silica feedstock in general terms only and gives no silica-fibre producers.
- Mechanical properties (tensile, compressive, Young's modulus) for Avcoat in TN D-2991 Tables 7 to 10 were not transcribed; the scanned tables are hard to read reliably in this run.
- Virgin composition percentages were not found; TN D-2991 says the composition is proprietary.
- 'Post-flight condition after Artemis I is reported differently: the Avcoat article says post-flight inspection found material loss, and the Orion article reports no heat-shield findings. Neither claim was confirmed in a primary NASA source in this run, so no failure is listed.'
- Mean Arrhenius parameters (pre-exponential factors, activation temperatures) from Orion Table 2 were not stored. Only the uncertainties are in the file.
- The TPSX blowing corrections (0.7 laminar, 0.37 turbulent) are marked assumed and are not stored as properties.
- 'Custom property names used because no canonical name exists in property-canon.yaml: emissivity, effective_heat_of_ablation, enthalpy_change, weight_loss, normalized_ablation_rate_uncertainty, pyrolysis_gas_enthalpy_uncertainty.'
- No flight-condition char recession or ablation rate data were read; the Orion paper gives only uncertainties on these inputs.
- Wikipedia pages are used for history, composition and the producer name only; no numbers are taken from them.
sources:
tpsx-avcoat:
title: 'NASA Ames Thermal Protection Materials Database: Avcoat-5026 H/CG [virgin]'
id: TPSX material id 37 (Last Modified 1996-02-01)
url: https://tpsx.arc.nasa.gov/Material?id=37
year: 1996
kind: database
license: public domain (NASA)
tn-d2991:
title: Thermophysical Properties of Six Charring Ablators from 140 to 700 K and Two Chars from 800 to 3000 K (NASA TN D-2991, R. Gale Wilson, compiler, NASA Langley)
id: NASA TN D-2991; NTRS 19650024901
url: https://ntrs.nasa.gov/api/citations/19650024901/downloads/19650024901.pdf
year: 1965
kind: report
license: public domain (NASA)
orion-avcoat-uq:
title: Determination of Uncertainties for Analytically Derived Material Properties to be used in Monte Carlo Based Orion Heatshield Sizing (Coughlin, Sixel, Sepka, McGuire)
id: NTRS 20190029074
url: https://ntrs.nasa.gov/api/citations/20190029074/downloads/20190029074.pdf
year: 2019
kind: paper
license: NASA-authored (NTRS)
wiki-avcoat:
title: Avcoat (Wikipedia article, read for composition, manufacturer and flight history only)
id: Wikipedia, read in this run
url: https://en.wikipedia.org/wiki/Avcoat
year: 2026
kind: web
license: CC BY-SA 4.0 (Wikipedia)
wiki-orion:
title: Orion (spacecraft) (Wikipedia article, read for the Artemis I flight date and heat-shield context)
id: Wikipedia, read in this run
url: https://en.wikipedia.org/wiki/Orion_(spacecraft)
year: 2026
kind: web
license: CC BY-SA 4.0 (Wikipedia)
pubchem-silica:
title: PubChem compound record, Silica (CID 24261)
id: CID 24261
url: https://pubchem.ncbi.nlm.nih.gov/compound/24261
year: 2026
kind: database
license: public domain (NCBI)
pubchem-badge:
title: PubChem compound record, Bisphenol A diglycidyl ether (CID 2286)
id: CID 2286
url: https://pubchem.ncbi.nlm.nih.gov/compound/2286
year: 2026
kind: database
license: public domain (NCBI)
pubchem-phenolic:
title: PubChem compound record, Phenolic resin (CID 24754)
id: CID 24754
url: https://pubchem.ncbi.nlm.nih.gov/compound/24754
year: 2026
kind: database
license: public domain (NCBI)
usgs-mcs2026-silicon:
title: 'USGS Mineral Commodity Summaries 2026: Silicon'
id: USGS MCS 2026
url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-silicon.pdf
year: 2026
kind: report
license: public domain (USGS)
license: CC-BY-4.0
updated: '2026-11-02'
review:
status: draft
method: assistant
checked_values: 12
note: Written by an AI assistant on 2026-11-01 from three NASA documents and two Wikipedia pages read in this run. Deepened on 2026-11-02 with hazard entries from three PubChem records and supply entries from the USGS silicon chapter and the Wikipedia article; property count unchanged. Values were copied as printed; table values were read from rendered page images of TN D-2991 Tables 1, 2, 3 and 6. Not yet checked by a second reader.
story:
recipe:
line: Avcoat is a composite, not a single compound. TPSX lists its constituents as an epoxy novolac resin, silica microballoons, phenolic microballoons and silica fibres, in a honeycomb. The exact proportions are proprietary (TN D-2991).
parts:
- name: Epoxy novolac resin
role: Binder that holds the fillers together; it decomposes on heating to form the char.
- name: Silica microballoons
role: Hollow silica spheres listed by TPSX as a filler.
- name: Phenolic microballoons
role: Hollow phenolic spheres listed by TPSX as a filler.
- name: Silica fibres
role: Fibre reinforcement listed by TPSX as a constituent.
- name: Honeycomb
role: Cell structure that holds the filled resin. TPSX lists phenolic or stainless-steel honeycomb.
risk_groups:
- title: For people
verdict: Constituent hazards only
lead: No safety data sheet for Avcoat 5026-39-HC G was read in this run. PubChem gives hazard statements for three constituent classes, but not for the proprietary Avcoat formulation.
points:
- label: Constituents
line: PubChem lists skin, eye and respiratory irritation and skin sensitisation for these classes. Its silica record also carries cancer and organ-damage statements that it does not tie to a silica form. Check the supplier's safety data sheet before handling any Avcoat material.
- title: On re-entry
lead: The shield is designed to char and erode during entry, and the sources give the heating and weight-loss data for that process.
points:
- label: Weight loss
line: In the TN D-2991 enthalpy test, the material had lost 11.2 % of its weight by 502 °F and 27.5 % by 733 °F.
- label: Design margin
line: The Orion sizing method reduces the allowable bondline temperature limit by 60 °C to cover material property uncertainty.
- title: Handling and storage
lead: No handling or storage guidance was found in the sources read.
points:
- label: Storage
line: 'No storage or shelf-life data were found. Treat the material as single-use: it is designed to char and erode on each entry.'
why: Avcoat is the ablative heat shield NASA used on Apollo and designed into the Orion EM-1 capsule. An ablator protects the vehicle by burning away and forming an insulating char on re-entry. The sources here describe a low-density epoxy-based material, and the data show how its density, thermal conductivity and specific heat change with temperature, and how much of its weight is lost as it heats.
uses:
- where: Apollo command module
line: TPSX states that AVCOAT was the primary heat shield for Apollo. The Avcoat article lists uncrewed tests from AS-201 and AS-202 to Apollo 6, and crewed missions from Apollo 7 through Apollo 17.
- where: Orion EM-1 capsule
line: The Orion paper says the EM-1 capsule has been designed to use a molded Avcoat material system, and that its heat shield thickness is sized with a Monte Carlo analysis that includes the material's own uncertainties.
- where: Artemis I (uncrewed, 2022)
line: The Avcoat article says the Artemis I shield was redesigned to use shaped AVCOAT blocks, and that Artemis I flew uncrewed in 2022. The post-flight condition of the shield is not confirmed in the sources read.
can_do:
- label: Density
benchmark: density
value: 530.0 kg/m3 at 75 °F
line: Room-temperature density of the low-density filled epoxy in honeycomb is 530.0 kg/m3 at 75 °F, measured in TN D-2991. TPSX gives 529 kg/m3 for the virgin material at standard conditions, which it marks as assumed.
- label: Heat absorbed
benchmark: enthalpy_change
value: 0.6364 MJ/kg at 733 °F
line: In the TN D-2991 enthalpy test, the material absorbed 0.6364 MJ/kg of enthalpy on heating to 733 °F (661.9 K), relative to 32 °F.
- label: Thermal conductivity
benchmark: thermal_conductivity
value: 0.0502 W/m-K at 154 K
line: Thermal conductivity in direction C is 0.0502 W/m-K at 154 K (-182 °F) and 0.109 W/m-K at 528 K (491 °F), both measured by Melpar in TN D-2991.
- label: Specific heat
benchmark: specific_heat
value: 0.606 kJ/kg-K at 144 K
line: Specific heat rises from 0.606 kJ/kg-K at 144 K (-200 °F) to 1.78 kJ/kg-K at 671 K (750 °F), per Table 2 of TN D-2991.
compare: The only other material in these sources with a measured density at the same temperature is the carbon-fibre-reinforced phenolic Narmco 4028, tested in TN D-2991. At 75 °F, Avcoat's density is 530.0 kg/m3, against 1390 kg/m3 for Narmco 4028, so Avcoat is much the lighter of the two. The Orion paper names PICA and another earlier ablator as comparison points, but these sources give no property values for them, so no further comparison is made.
compare_rows:
- label: Room-temperature density
benchmark: density
- label: Thermal conductivity
benchmark: thermal_conductivity
- label: Specific heat
benchmark: specific_heat
handling:
- No handling or storage guidance was found in the sources read. Do not assume a hazard classification without the supplier's safety data sheet.
- 'Treat the material as single-use: it is designed to char and erode on each re-entry.'
good_for:
- Single-use re-entry heat shields. NASA used this design role on Apollo and on the Orion EM-1 capsule.
- 'Low-density thermal protection: 530.0 kg/m3 at room temperature in TN D-2991.'
watch_out:
- Post-flight condition after Artemis I is reported differently by two sources, and neither was confirmed in a primary NASA source in this run.
- 'The decomposition model is fitted, not measured directly: the Orion paper reports reaction-order uncertainties of 0.263 to 0.388 and says the fitted reaction orders varied greatly.'
- 'Thermal conductivity rises with temperature in direction C: 0.0502 W/m-K at 154 K and 0.109 W/m-K at 528 K, so use the value at the temperature of interest.'
verdict: 'Avcoat is the heritage ablator: NASA used it on Apollo and designed Orion EM-1 around it. Most property values here come from a 1965 report and a database, so check them against current NASA data before any design use, and get a hazard data sheet before handling.'
References
Every number above carries a reference number. Click one to see the source and where in it the value comes from.
| # | Source | Type | Year | Used for |
|---|---|---|---|---|
| NASA Ames Thermal Protection Materials Database: Avcoat-5026 H/CG [virgin] | database | 1996 | 3 values | |
| Thermophysical Properties of Six Charring Ablators from 140 to 700 K and Two Chars from 800 to 3000 K (NASA TN D-2991, R. Gale Wilson, compiler, NASA Langley) | report | 1965 | 10 values | |
| Determination of Uncertainties for Analytically Derived Material Properties to be used in Monte Carlo Based Orion Heatshield Sizing (Coughlin, Sixel, Sepka, McGuire) | paper | 2019 | 7 values | |
| Avcoat (Wikipedia article, read for composition, manufacturer and flight history only) | web | 2026 | 3 values | |
| Orion (spacecraft) (Wikipedia article, read for the Artemis I flight date and heat-shield context) | web | 2026 | 0 values | |
| PubChem compound record, Silica (CID 24261) | database | 2026 | 1 value | |
| PubChem compound record, Bisphenol A diglycidyl ether (CID 2286) | database | 2026 | 1 value | |
| PubChem compound record, Phenolic resin (CID 24754) | database | 2026 | 1 value | |
| USGS Mineral Commodity Summaries 2026: Silicon | report | 2026 | 1 value |
Updated