Guides/Comparisons

Aluminium nitride vs alumina

aluminium-nitride-vs-alumina

Aluminium nitride (AlN) and Alumina (Al2O3) at a glance

This page compares Aluminium nitride (AlN) and Alumina (Al2O3) using only values that carry a source, a test condition and an evidence level. Ranges run across temper, heat treatment and product form, measured at room temperature where the source says so.

  • Density: alumina is higher (AlN 3.25 to 3.3 g/cm³; alumina 3.72 to 3.9 g/cm³), about 1.2 times the midpoint of AlN.
  • Young's modulus: alumina is higher (AlN 276 to 330 GPa; alumina 370 GPa), about 1.2 times the midpoint of AlN.
  • Thermal conductivity: AlN is higher (AlN 140 to 180 W/(m·K); alumina 30 W/(m·K)), about 5.3 times the midpoint of alumina.
  • Thermal expansion: alumina is higher (AlN 4.5 ppm/K; alumina 8.2 ppm/K), about 1.8 times the midpoint of AlN.

"Higher" means the whole range is higher, not just one value. Where a value is a specified minimum, the table says "at least".

Side by side

Aluminium nitride vs alumina: thermal conductivity compared
PropertyAluminium nitride (AlN)Alumina (Al2O3)
Density 3.25 to 3.3 g/cm³ 3.72 to 3.9 g/cm³
Young's modulus 276 to 330 GPa 370 GPa
Thermal conductivity 140 to 180 W/(m·K) 30 W/(m·K)
Melting point no data 2,030 to 2,072 °C
Service temperature no data 1,750 °C
Thermal expansion 4.5 ppm/K 8.2 ppm/K

Composition

Composition
ElementAluminium nitride (AlN)Alumina (Al2O3)
Aluminiumnot listed52.9%
Oxygennot listed47.1%

Shares are as printed in the sources, by weight.

When to use which

Best use and weak spots
MaterialBest forWeakest at
Aluminium nitride (AlN)Electronic substrates, packages and heat spreaders where heat must leave a part without conducting electricity.Water and humid storage: it hydrolyzes slowly, and the sources print no moisture limit. Thermal values also differ by grade.
Alumina (Al2O3)Hard, stiff, electrically insulating parts that must stay stable at high temperature (CoorsTek chart: AD-995 volume resistivity above 10^14 ohm-cm at 25 °C)Brittle fracture and sudden temperature change (fracture toughness 4 to 5 MPa·m½ for AD-995; thermal shock temperature difference of 200 °C for Kyocera's 99% grade)

Where each is used

Uses
MaterialUse
Aluminium nitride (AlN)Substrates for electronic packages, IC packages and power transistor bases
Aluminium nitride (AlN)Heat sinks
Aluminium nitride (AlN)Semiconductor heater plates and chucks
Alumina (Al2O3)Semiconductor process chambers, wafer handling, laser devices and power tubes (ground industrial use)
Alumina (Al2O3)Heat, corrosion and wear resistant parts (ground industrial use)
Alumina (Al2O3)Sheath insulator layers for a thermionic space power system (ground reactor test, not flown)
Alumina (Al2O3)Charge cup of the NASA standard initiator (thermal modelling, ground)