spore: profile
id: soda-lime-glass
spore_version: 0.2
family: glass-and-composites
name: Soda-lime glass
abbreviation: Soda-lime
role: window and container glass
category: glasses-optics
type: borosilicate
summary: |
  Soda-lime glass is the common window and container glass. It is silica with sodium and calcium oxides added so that it melts at a lower temperature. Continental Trade's properties sheet gives a density of 2500 kg/m3 at 18 °C and Pilkington's float-glass bulletin gives a linear thermal expansion of 8.3 x10^-6 /°C. Pilkington gives an annealing point of 548 °C and a softening point of 715 °C. Wikipedia says soda-lime glass accounts for about 90% of manufactured glass. Its high thermal expansion means it tolerates sudden temperature changes poorly, so Continental Trade sets working limits of 110 °C for not-toughened glass and 150 °C for toughened glass. See the property list for the values and conditions.
best_for: Windows and containers where low cost and wide availability matter more than thermal shock or alkali resistance
weakest_at: 'Resistance to sudden temperature changes (high thermal expansion) and to alkaline solutions (NGA: poor resistance to alkalis)'
identity:
  formula: 'Silica-soda-lime glass: about 72.6% SiO2, 13.9% Na2O and 8.4% CaO, with 3.9% MgO and 1.1% Al2O3 (typical sheet composition)'
  source: continental-trade-sheet
  where: Composition list, Soda-lime glass properties (Continental Trade)
tags:
  environments: []
  stresses: []
  applications:
    - structures
    - mechanisms
properties:
  - benchmark: density
    value: 2500
    unit: kg/m3
    scope: material
    conditions:
      temperature: 18 °C
    method: Printed as 2 500 kg/m3 in the Density (at 18 °C) row. Pilkington ATS-129 gives the same 2500 kg/m3 (156 lb/ft3).
    status: ground
    source: continental-trade-sheet
    where: Properties list, Density row
  - benchmark: elastic_modulus
    label: Young's modulus
    value: 72
    unit: GPa
    scope: material
    conditions:
      basis: float glass, Pilkington North America
    method: Printed as 10.4 x 10^6 psi (72 GPa) in the Modulus of Elasticity (Young's) row.
    status: ground
    source: pilkington-ats129
    where: Mechanical properties, Modulus of Elasticity (Young's) row
  - benchmark: shear_modulus
    label: Modulus of rigidity (shear)
    value: 30
    unit: GPa
    scope: material
    conditions:
      basis: float glass, Pilkington North America
    method: Printed as 4.3 x 10^6 psi (30 GPa) in the Modulus of Rigidity (Shear) row.
    status: ground
    source: pilkington-ats129
    where: Mechanical properties, Modulus of Rigidity (Shear) row
  - benchmark: poissons_ratio
    value: 0.22
    unit: '-'
    scope: material
    conditions:
      basis: float glass, Pilkington North America
    method: Printed as 0.22 in the Poisson's Ratio row.
    status: ground
    source: pilkington-ats129
    where: Mechanical properties, Poisson's Ratio row
  - benchmark: cte
    label: Linear thermal expansion coefficient
    value: 8.3
    unit: x10^-6 /°C
    scope: material
    conditions:
      temperature_range: 75 to 575 °F
    method: Printed as 4.6 x 10-6 in/in.°F (8.3 x10-6 mm/mm.°C). The metric value is used here, unconverted.
    status: ground
    source: pilkington-ats129
    where: Properties list, Coefficient of Linear Expansion row
  - benchmark: cte
    label: Linear thermal expansion coefficient (flat glass)
    value: 9.5
    unit: ppm/K
    scope: material
    conditions:
      temperature_range: about 100 to 300 °C
    method: Printed as 9.5 in the Coefficient of thermal expansion row, flat-glass column. Wikipedia gives 9 for container glass in the same row. The temperature range differs from the Pilkington value.
    status: ground
    source: wikipedia-soda-lime
    where: Typical compositions and properties table, Coefficient of thermal expansion row, flat glass column
  - benchmark: thermal_conductivity
    value: 0.937
    unit: W/(m·K)
    scope: material
    conditions:
      temperature: 75 °F
    method: Printed as 6.5 Btu.in/hr.°F.ft2 (0.937 W.m/m2.°C). The metric value is used here.
    status: ground
    source: pilkington-ats129
    where: Properties list, Thermal Conductivity at 75 °F row
  - benchmark: specific_heat
    value: 0.88
    unit: kJ/(kg·K)
    scope: material
    conditions:
      temperature: 75 °F
    method: Printed as 0.21 Btu/lbm.F (0.88 kJ/kg.C).
    status: ground
    source: pilkington-ats129
    where: Properties list, Specific Heat at 75 °F row
  - benchmark: refractive_index
    value: 1.523
    unit: '-'
    scope: material
    conditions:
      wavelength: sodium D line (printed as 0.5893 m)
    method: Printed as 1.523 for the sodium D line. The NGA paper gives a mean of 1.5, which is a rounded figure.
    status: ground
    source: pilkington-ats129
    where: Index of Refraction, sodium D line row
  - benchmark: softening_point
    label: Softening point (ASTM C338)
    value: 715
    unit: °C
    scope: material
    conditions:
      standard: ASTM C338
    method: Printed as 1319 °F (715 °C). The NGA paper gives 715 to 729 °C.
    status: ground
    source: pilkington-ats129
    where: Softening Point (ASTM C338) row
  - benchmark: annealing_point
    label: Annealing point (ASTM C336)
    value: 548
    unit: °C
    scope: material
    conditions:
      standard: ASTM C336
    method: Printed as 1018 °F (548 °C). The NGA paper gives 544 to 548 °C.
    status: ground
    source: pilkington-ats129
    where: Annealing Point (ASTM C336) row
  - benchmark: strain_point
    label: Strain point (ASTM C336)
    value: 511
    unit: °C
    scope: material
    conditions:
      standard: ASTM C336
    method: Printed as 952 °F (511 °C). The NGA paper gives 504 to 511 °C.
    status: ground
    source: pilkington-ats129
    where: Strain Point (ASTM C336) row
  - benchmark: knoop_hardness
    label: Knoop hardness
    value: 470
    value_high: 605
    unit: kg/mm2
    scope: material
    conditions:
      basis: NGA range for typical soda-lime float glass
    method: Printed as ~470 - 605 kg/mm2 on the Hardness (Knoop's scale) line. It is a range, not a single measured value.
    status: ground
    source: nga-fm05
    where: Hardness (Knoop's Scale) line, page 2
  - benchmark: hardness_mohs
    label: Mohs hardness
    value: 5
    value_high: 6
    unit: Mohs
    scope: material
    conditions:
      basis: Mohs scale, float glass (Pilkington) and sheet (Continental Trade)
    method: Printed as 5-6 in the Hardness (Mohs scale) row of the Pilkington bulletin. The Continental Trade sheet gives 5-6 as well.
    status: ground
    source: pilkington-ats129
    where: Properties list, Hardness (Mohs scale) row
  - benchmark: flexural_strength
    label: Modulus of rupture, annealed, mean
    value: 41
    unit: MPa
    scope: material
    conditions:
      glass_kind: annealed
      basis: mean MOR, 50% probability of breakage, 60 s load on weathered in-service glass
    method: Printed as 6,000 psi (41 MPa) in the Typical Mean MOR table.
    status: ground
    source: pilkington-ats129
    where: Mechanical properties, Typical Mean MOR table, Annealed row
  - benchmark: flexural_strength
    label: Design stress, annealed (0.8% breakage probability)
    value: 19
    unit: MPa
    scope: material
    conditions:
      glass_kind: annealed
      basis: design stress for 0.8% breakage probability
    method: Printed as 2,800 psi (19 MPa) in the Typical Design Stress table.
    status: ground
    source: pilkington-ats129
    where: Mechanical properties, Typical Design Stress table, Annealed row
  - benchmark: flexural_strength
    label: Modulus of rupture, heat-strengthened, mean
    value: 83
    unit: MPa
    scope: material
    conditions:
      glass_kind: heat-strengthened
      basis: mean MOR, 50% probability of breakage
    method: Printed as 12,000 psi (83 MPa).
    status: ground
    source: pilkington-ats129
    where: Typical Mean MOR table, Heat-Strengthened row
  - benchmark: flexural_strength
    label: Modulus of rupture, fully tempered, mean
    value: 165
    unit: MPa
    scope: material
    conditions:
      glass_kind: fully tempered
      basis: mean MOR, 50% probability of breakage
    method: Printed as 24,000 psi (165 MPa).
    status: ground
    source: pilkington-ats129
    where: Typical Mean MOR table, Fully Tempered row
  - benchmark: max_service_temp
    label: Maximum working temperature, not toughened
    value: 110
    unit: °C
    scope: material
    conditions:
      glass_kind: not toughened
    method: Printed as 110 °C on the Max. working temperature list, not-toughened line.
    status: ground
    source: continental-trade-sheet
    where: Max. working temperature list, not toughened line
  - benchmark: max_service_temp
    label: Maximum working temperature, toughened
    value: 150
    unit: °C
    scope: material
    conditions:
      glass_kind: toughened
    method: Printed as 150 °C on the Max. working temperature list, toughened line.
    status: ground
    source: continental-trade-sheet
    where: Max. working temperature list, toughened line
corrosion:
  - environment: Acids other than hydrofluoric acid
    headline: Excellent resistance to acids, other than hydrofluoric acid.
    effect: NGA rates the chemical resistance of typical float glass as excellent to acids other than HF. No rate or test duration is printed.
    rating: low
    conditions:
      basis: general chemical-resistance statement; no test conditions given
    source: nga-fm05
    where: Properties list, Chemical Resistance line, page 3
  - environment: Alkaline solutions
    headline: Poor resistance to alkalis.
    effect: NGA rates the chemical resistance of typical float glass as poor to alkalis. No rate, concentration or duration is printed in the paper.
    rating: severe
    conditions:
      basis: general chemical-resistance statement; no test conditions given
    source: nga-fm05
    where: Properties list, Chemical Resistance line, page 3
  - environment: Humid air under load, 80% relative humidity at 50 °C for 28 days
    headline: Humidity cut the failure strain of weathered soda-lime-silicate glass by 80%.
    effect: Ronchetto reports that failure strains decreased by 80% and that the fatigue parameter increased from 16 to 25 under these conditions. The specimens are commercial soda-lime-silicate glass, tested in the form the dissertation describes.
    rating: moderate
    conditions:
      relative_humidity: 80%
      temperature: 50 °C
      time: 28 days
    source: ronchetto-2019
    where: Abstract and results, fatigue and weathering tests
  - environment: Humid air, 10% relative humidity at 50 °C for over 30 days
    headline: At low humidity the fatigue parameter did not change over 30 days.
    effect: Ronchetto reports that weathering for over 30 days did not change the fatigue parameter, and that failure strain increased by about 10% over the first three days.
    rating: low
    conditions:
      relative_humidity: 10%
      temperature: 50 °C
      time: over 30 days
    source: ronchetto-2019
    where: Abstract and results, weathering at 10% RH
risks:
  hazards:
    - text: 'PubChem''s aggregated GHS for sodium carbonate, the raw material soda ash, is H319: causes serious eye irritation (Warning, 100% of reports). These classes describe the powder, not the finished glass.'
      ghs:
        - H319
      source: pubchem-sodium-carbonate
      where: Safety and Hazards, GHS Classification (CID 10340)
  failure_risks:
    - mode: Thermal shock of not-toughened glass
      trigger: Temperature difference across the sheet
      consequence: Continental Trade gives a thermal shock limit of 50 °C for not-toughened soda-lime glass, and 118 °C for toughened glass.
      severity: moderate
      source: continental-trade-sheet
      where: Thermal shock list, not toughened line
    - mode: Breakage of annealed glass under design load
      trigger: Load at the design stress for 0.8% breakage probability
      consequence: Pilkington gives a mean bending strength of 41 MPa for annealed glass, and a design stress of 19 MPa for 0.8% breakage probability.
      severity: moderate
      source: pilkington-ats129
      where: Typical Design Stress table, Annealed row
    - mode: Humidity fatigue and ageing of commercial soda-lime-silicate glass
      trigger: 80% relative humidity at 50 °C for 28 days
      consequence: Failure strains decreased by 80% (Ronchetto 2019).
      severity: moderate
      source: ronchetto-2019
      where: Abstract and results, fatigue and weathering tests
    - mode: Attack by alkaline solutions
      trigger: Contact with alkaline solutions
      consequence: NGA rates the chemical resistance of float glass as poor to alkalis, so the surface can be attacked.
      severity: high
      source: nga-fm05
      where: Properties list, Chemical Resistance line
  side_effects: []
  handling:
    - text: Keep not-toughened soda-lime glass below 110 °C and toughened glass below 150 °C (Continental Trade working limits).
      source: continental-trade-sheet
      where: Max. working temperature list
    - text: Keep temperature differences within 50 °C for not-toughened glass and 118 °C for toughened glass (Continental Trade thermal shock list).
      source: continental-trade-sheet
      where: Thermal shock list
    - text: Keep the glass away from alkaline solutions. NGA rates acid resistance as excellent, except to hydrofluoric acid.
      source: nga-fm05
      where: Properties list, Chemical Resistance line
  mitigations: []
uses:
  - application: structures
    device: Window glazing (flat glass)
    example: Wikipedia says soda-lime glass is used for windowpanes, and that the float process makes window glass.
    source: wikipedia-soda-lime
    where: Lead and Applications section
  - application: mechanisms
    device: Soda-lime glass spheres for valves, bearings and mixers
    example: Kugelpompel lists special bearings and valves, mixers, low-cost control valves, metering pumps and flow meters as fields of application for its soda-lime glass spheres.
    source: kugelpompel-soda-lime
    where: Field of application
supply:
  - subject: Soda ash (sodium carbonate)
    abundance: 'USGS: world natural soda ash was about 19 million t in 2025 (estimated) and total world soda ash about 71 million t (2025e). China produced about 38 million t, mostly synthetic. Glass took 45% of US soda ash use in 2025.'
    producers:
      - country: United States
        production: 12,000 thousand t, natural (2025e)
        year: 2025
      - country: Turkey
        production: 6,000 thousand t, natural (2025e)
        year: 2025
      - country: China
        production: about 38 million t, mostly synthetic (2025e)
        year: 2025
    critical_lists: []
    recycling: 'USGS: no soda ash was recycled by producers, but glass container producers use cullet, which reduces soda ash consumption.'
    substitutes:
      - 'USGS: caustic soda can replace soda ash in certain uses, particularly pulp and paper, water treatment and some chemical sectors.'
    source: usgs-soda-ash
    where: Domestic Production and Use; Salient Statistics; World Mine Production and Reserves table (2025e); Recycling; Substitutes
  - subject: Soda ash, United States import sources
    abundance: 'USGS: import sources for soda ash, 2021 to 2024, as printed.'
    producers:
      - country: Turkey
        share_percent: 89
        year: 2024
        basis: import sources 2021-24, as printed
      - country: Canada
        share_percent: 3
        year: 2024
        basis: import sources 2021-24, as printed
      - country: Mexico
        share_percent: 3
        year: 2024
        basis: import sources 2021-24, as printed
      - country: Other
        share_percent: 5
        year: 2024
        basis: import sources 2021-24, as printed
    critical_lists: []
    recycling: 'USGS: as above.'
    substitutes: []
    source: usgs-soda-ash
    where: Import Sources (2021-24)
  - subject: Silica sand (glassmaking sand)
    abundance: 'USGS: US industrial sand and gravel sold or used was about 120 million t in 2025 (estimated). About 81% went to hydraulic-fracturing sand and 7% to glassmaking sand. Reserves are listed as large.'
    producers:
      - country: China
        production: 92,000 thousand t (2025)
        year: 2025
      - country: United States
        production: 120,000 thousand t, sold or used (2025e)
        year: 2025
      - country: Netherlands
        production: 68,000 thousand t (2025)
        year: 2025
    critical_lists: []
    recycling: 'USGS: about 33% of glass containers are recycled, so cullet is a significant proportion of reused silica.'
    substitutes: []
    source: usgs-industrial-sand
    where: Domestic Production and Use; World Mine Production and Reserves table (2025 column); Recycling
documents:
  - title: Soda-lime glass properties (Continental Trade information sheet)
    type: datasheet
    url: https://www.continentaltrade.com.pl/en/download/WhfvdEYg1jSqsBXM5x9dRJnJfIPvp1gO/soda-lime-glass-properties.pdf
  - title: ATS-129 Properties of soda-lime silica float glass (Pilkington North America, 04/2025)
    type: datasheet
    url: https://www.pilkington.com/-/media/pilkington/site-content/usa/window-manufacturers/technical-bulletins/ats-129---properties-of-soda-lime-silica-float-glass.pdf
    year: 2025
  - title: FM05-12 (2023) Physical and Mechanical Properties of Typical Soda Lime Float Glass (National Glass Association)
    type: report
    url: https://www.glass.org/sites/default/files/2023-07/FM05-12_2023_Physical_Mechanical_Properties_Typical_Soda_Lime_Float_Glass.pdf
    year: 2023
  - title: 'Mineral Commodity Summaries 2026: Soda ash (USGS)'
    type: report
    url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-soda-ash.pdf
    year: 2026
  - title: 'Mineral Commodity Summaries 2026: Sand and gravel (industrial) (USGS)'
    type: report
    url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-sand-industrial.pdf
    year: 2026
  - title: Sodium carbonate, PubChem CID 10340
    type: database
    url: https://pubchem.ncbi.nlm.nih.gov/compound/10340
  - title: Data sheet Soda lime glass V1.01 (Kugelpompel, glass spheres)
    type: datasheet
    url: https://www.kugelpompel.at/img/cms/Datenbl%C3%A4tter%20Glas/Data%20sheet%20Soda-lime%20glass%20V1-01.pdf
    year: 2020
  - title: Soda-lime glass (Wikipedia)
    type: report
    url: https://en.wikipedia.org/wiki/Soda%E2%80%93lime_glass
  - title: The effects of fatigue and weathering on the failure behavior of commercial soda-lime-silicate glass (Missouri S&T, Ronchetto 2019)
    type: report
    url: https://scholarsmine.mst.edu/doctoral_dissertations/2845
    year: 2019
gaps:
  - 'Property names not in spores/property-canon.yaml: softening_point, annealing_point, strain_point, knoop_hardness and hardness_mohs are used as snake_case names. The canon file needs them added before import.'
  - 'Thermal stress coefficient (0.62 MPa/°C, Pilkington and Continental Trade) is not used: it has no canonical name.'
  - Continental Trade thermal shock values (50 °C not toughened, 118 °C toughened) are used in failure_risks and handling only, because no canonical name fits.
  - 'Container glass values: the Wikipedia table''s container column is not used for composition or expansion, because its columns were matched from a flattened table. Container-glass CTE is recorded only as Wikipedia''s 9 ppm/K in this note.'
  - No glass-specific safety data sheet was read. The hazard entry uses PubChem's classes for sodium carbonate, the raw material, not for the finished glass.
  - No open paper on soda-lime leaching or weathering could be read in this run. The Engineering and Technology Journal article URL returned 404 and the Venice repository returned 403.
  - Dielectric constant, loss tangent and volume resistivity values were not found for soda-lime glass. NGA gives electrical resistivity only as High.
  - No radiation, vacuum or space test of soda-lime cover glass was found. NASA TN D-7245 (1973) tests ceria-doped Micro-Sheet against undoped glass but gives no composition, so it is not used.
  - Critical-mineral status of soda ash and industrial sand was not checked in this run.
  - Ronchetto 2019 figures were read from the fetched dissertation landing page. The full-text PDF link returned an HTML page in this run, not a PDF.
  - Kugelpompel data are for soda-lime glass spheres, not sheet or container glass. The sheet is used only for applications.
  - Continental Trade prints Poisson's ratio as 0,23 with a decimal comma, which verify-values could not match, so that row was removed. Pilkington's 0.22 is kept. The sheet's 0,23 is a second reading for a future check.
  - Wikipedia gives a flat-glass CTE of 9.5 ppm/K for about 100 to 300 °C, and Pilkington gives 8.3 x10^-6 /°C for 75 to 575 °F. The temperature ranges differ, so both are kept.
sources:
  continental-trade-sheet:
    title: Soda-lime glass properties (information sheet)
    id: Continental Trade Sp. z o.o., Soda-lime glass properties
    url: https://www.continentaltrade.com.pl/en/download/WhfvdEYg1jSqsBXM5x9dRJnJfIPvp1gO/soda-lime-glass-properties.pdf
    kind: datasheet
    license: supplier information sheet, cited not reproduced
  pilkington-ats129:
    title: ATS-129 Properties of soda-lime silica float glass
    id: Pilkington North America, technical bulletin ATS-129 (04/2025)
    url: https://www.pilkington.com/-/media/pilkington/site-content/usa/window-manufacturers/technical-bulletins/ats-129---properties-of-soda-lime-silica-float-glass.pdf
    kind: datasheet
    year: 2025
    license: manufacturer document, cited not reproduced
  nga-fm05:
    title: FM05-12 (2023) Physical and Mechanical Properties of Typical Soda Lime Float Glass
    id: National Glass Association, Glass Technical Paper FM05-12
    url: https://www.glass.org/sites/default/files/2023-07/FM05-12_2023_Physical_Mechanical_Properties_Typical_Soda_Lime_Float_Glass.pdf
    kind: report
    year: 2023
    license: trade association paper, cited not reproduced
  wikipedia-soda-lime:
    title: Soda-lime glass
    id: Wikipedia, Soda-lime glass
    url: https://en.wikipedia.org/wiki/Soda%E2%80%93lime_glass
    kind: web
    license: CC BY-SA 4.0
  usgs-soda-ash:
    title: 'Mineral Commodity Summaries 2026: Soda ash'
    id: USGS, MCS 2026
    url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-soda-ash.pdf
    kind: report
    year: 2026
    license: US government work, public domain
  usgs-industrial-sand:
    title: 'Mineral Commodity Summaries 2026: Sand and gravel (industrial)'
    id: USGS, MCS 2026
    url: https://pubs.usgs.gov/periodicals/mcs2026/mcs2026-sand-industrial.pdf
    kind: report
    year: 2026
    license: US government work, public domain
  pubchem-sodium-carbonate:
    title: Sodium carbonate, PubChem CID 10340
    id: PubChem, GHS classification of sodium carbonate
    url: https://pubchem.ncbi.nlm.nih.gov/compound/10340
    kind: database
    license: PubChem, public domain
  kugelpompel-soda-lime:
    title: Data sheet Soda lime glass V1.01
    id: Kugelpompel, soda-lime glass sphere data sheet
    url: https://www.kugelpompel.at/img/cms/Datenbl%C3%A4tter%20Glas/Data%20sheet%20Soda-lime%20glass%20V1-01.pdf
    kind: datasheet
    year: 2020
    license: manufacturer document, cited not reproduced
  ronchetto-2019:
    title: The effects of fatigue and weathering on the failure behavior of commercial soda-lime-silicate glass
    id: Missouri S&T doctoral dissertation, Ronchetto, 2019
    url: https://scholarsmine.mst.edu/doctoral_dissertations/2845
    kind: paper
    year: 2019
    license: open-access thesis
license: CC-BY-4.0
updated: '2026-10-26'
review:
  status: draft
  method: assistant
  checked_values: 20
  unreachable: 1
  caveats: 3
  note: Written by an AI assistant on 2026-10-26 from sources read in this run. Continental Trade, Pilkington ATS-129, NGA FM05-12, Wikipedia, USGS soda ash and industrial sand, PubChem sodium carbonate, Kugelpompel and the Ronchetto 2019 dissertation. Two open papers could not be opened.
story:
  recipe:
    line: Soda-lime glass is an amorphous silica network modified by sodium and calcium oxides. Float glass is made from sand, soda ash, limestone, dolomite and salt cake, with about 20% recycled glass (cullet). Pilkington says making glass from cullet takes half the energy of making it from raw materials. The composition below is a typical sheet composition from Continental Trade. No producer's exact batch recipe is published.
    parts:
      - name: Silica
        symbol: SiO2
        share: about 72.6%
        role: The main network former. It gives the glass its rigid, mostly silica framework.
        share_percent: 72.6
      - name: Sodium oxide
        symbol: Na2O
        share: about 13.9%
        role: Added as soda ash (sodium carbonate). It lowers the melting temperature of the silica.
        share_percent: 13.9
      - name: Calcium oxide
        symbol: CaO
        share: about 8.4%
        role: Added as limestone. It stabilises the glass network.
        share_percent: 8.4
      - name: Magnesium oxide
        symbol: MgO
        share: about 3.9%
        role: Comes in with the dolomite in the batch.
        share_percent: 3.9
      - name: Aluminium oxide
        symbol: Al2O3
        share: about 1.1%
        role: Minor oxide in the typical sheet composition.
        share_percent: 1.1
      - name: Recycled glass
        symbol: cullet
        share: about 20% of float glass
        role: Broken glass put back into the batch as a melting aid.
        share_percent: 20
    source: continental-trade-sheet
    where: Composition list (Continental Trade); raw materials list and cullet paragraph (Pilkington ATS-129, pages 2 and 3)
  risk_groups:
    - title: For people
      level: 0
      verdict: 'Hazard data partly checked: PubChem''s classes for the raw…'
      lead: No source opened in this run classes the finished glass. The only classes read are for its raw material, sodium carbonate (H319, eye irritation). No SDS for the finished glass was opened.
      points:
        - label: Sharp edges
          line: Broken glass is sharp. Handle broken pieces with gloves and dispose of them in a sharps container.
        - label: Soda ash powder
          line: PubChem's aggregated GHS for sodium carbonate is H319, causes serious eye irritation (Warning, 100% of reports). This describes the powder, not the finished glass.
        - label: Heat
          line: 'Keep the glass below its working limits: 110 °C not toughened and 150 °C toughened (Continental Trade).'
  why: Soda-lime glass is the most common glass. Soda and lime added to silica lower the melting temperature, which keeps production cheap. Wikipedia says it accounts for about 90% of manufactured glass. The trade-off is a high thermal expansion, so Continental Trade says the glass has low resistance to sudden temperature changes.
  uses:
    - where: Windows
      line: Wikipedia gives windowpanes as the main use of flat soda-lime glass, and says the float process makes window glass.
    - where: Containers
      line: Wikipedia says container glass is used for beverages and food, where its durability is required for storage.
    - where: Valves and bearings
      line: Kugelpompel sells soda-lime glass spheres for special bearings and valves, mixers, metering pumps and flow meters.
  can_do:
    - label: Density
      benchmark: density
      value: 2500 kg/m3
      line: Continental Trade gives 2500 kg/m3 at 18 °C. Pilkington gives the same figure.
    - label: Working temperature
      benchmark: max_service_temp
      value: 110 °C not toughened
      line: Continental Trade gives a working limit of 110 °C for not-toughened glass and 150 °C for toughened glass.
    - label: Softening point
      benchmark: softening_point
      value: 715 °C
      line: Pilkington gives 715 °C (ASTM C338) for float glass. The NGA paper gives 715 to 729 °C.
    - label: Bending strength
      benchmark: flexural_strength
      value: 165 MPa fully tempered
      line: Pilkington's mean bending strength is 41 MPa for annealed glass, 83 MPa for heat-strengthened and 165 MPa for fully tempered glass.
    - label: Optics
      benchmark: refractive_index
      value: '1.523'
      line: Pilkington gives 1.523 for the sodium D line.
  compare: Soda-lime float glass has a linear thermal expansion of 8.3 x10^-6 /°C (Pilkington, 75 to 575 °F), and Wikipedia gives 9.5 ppm/K for the flat-glass column. Its working limits are 110 °C for not-toughened glass and 150 °C for toughened glass, with a softening point of 715 °C. Those limits and its annealing point of 548 °C set the practical ceiling for most uses. Its bending strength depends strongly on temper.
  compare_rows:
    - scope: material
      label: Density
      benchmark: density
    - scope: material
      label: Softening point
      benchmark: softening_point
    - scope: material
      label: Linear thermal expansion
      benchmark: cte
  handling:
    - Keep not-toughened soda-lime glass below 110 °C and toughened glass below 150 °C (Continental Trade working limits).
    - Keep temperature differences within 50 °C for not-toughened glass and 118 °C for toughened glass (Continental Trade thermal shock list).
    - Keep the glass away from alkaline solutions. NGA rates acid resistance as excellent, except to hydrofluoric acid.
  good_for:
    - Windows and container glass, where low cost and wide supply matter more than high-temperature or thermal-shock performance.
    - Spheres for valves and bearings, where chemical inertness and a smooth surface are needed (Kugelpompel).
  watch_out:
    - The thermal expansion is high. Continental Trade says the glass has low resistance to sudden temperature changes.
    - 'Bending strength depends strongly on temper: annealed glass has a design stress of 19 MPa against a mean of 41 MPa (Pilkington).'
    - Humidity can cut the failure strain of soda-lime-silicate glass (Ronchetto 2019, 80% RH at 50 °C for 28 days). Ageing of sheet glass in service is not covered by the sources read here.
  verdict: Soda-lime glass is the low-cost default for windows and containers. The sources agree on density, expansion and the softening point, and they give clear working and thermal-shock limits. Its weak points are alkali resistance and thermal shock. No flight, radiation or vacuum result was found.
